U.S. patent number 3,887,744 [Application Number 04/866,032] was granted by the patent office on 1975-06-03 for coated transparent sheets.
This patent grant is currently assigned to Sumitomo Chemical Co., Ltd.. Invention is credited to Nobuyuki Tomita, Ken Yoshiki.
United States Patent |
3,887,744 |
Tomita , et al. |
June 3, 1975 |
Coated transparent sheets
Abstract
A transparent structure comprising a transport sheet having a
non-continuous coating of aluminum distributed over at least one
surface of the sheet in a regular pattern, to provide means of
controlling the percentage transmission of visible light and
infra-red radiation.
Inventors: |
Tomita; Nobuyuki (Tokyo,
JA), Yoshiki; Ken (Tokyo, JA) |
Assignee: |
Sumitomo Chemical Co., Ltd.
(Osaka, JA)
|
Family
ID: |
13603769 |
Appl.
No.: |
04/866,032 |
Filed: |
October 13, 1969 |
Foreign Application Priority Data
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|
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Oct 18, 1968 [JA] |
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43-76382 |
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Current U.S.
Class: |
428/208; 428/38;
359/350; 428/433 |
Current CPC
Class: |
G02B
5/208 (20130101); E06B 7/28 (20130101); Y10T
428/24909 (20150115) |
Current International
Class: |
G02B
5/20 (20060101); E06B 7/00 (20060101); E06B
7/28 (20060101); B29d 011/00 (); B44d 005/06 ();
C03c 017/00 () |
Field of
Search: |
;117/33.3,124C,16R,38 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lesmes; George F.
Assistant Examiner: McDonald; Alan T.
Attorney, Agent or Firm: Cushman, Darby & Cushman
Claims
We claim:
1. A transparent structure comprising a transparent sheet having a
non-continuous coating of aluminum distributed over at least one
surface of the sheet in a regular pattern, in the form of closely
spaced parallel lines, there being from 10 to 50 lines of coating
per inch, to provide a means of controlling the percentage
transmission of visible light and infra-red radiation.
2. A transparent article as in claim 1 wherein the transparent
sheet is a polymethyl methacrylate sheet.
3. A transparent article as in claim 1 wherein the transparent
sheet is a glass sheet.
4. A transparent article as in claim 1 having a total luminous
transmission of from 20 percent to 80 percent.
5. A transparent article as in claim 1 having a transmittance for
infra-red rays of from 5 percent to 50 percent.
6. A window comprising a transparent article according to claim
1.
7. A window as in claim 6 mounted with the coated surface of the
sheet facing outwardly from the building.
8. A transparent article as in claim 1 in which the areas coated
with aluminum are overcoated with a transparent lacquer.
9. A transparent article as in claim 1 wherein the non-continuous
aluminum coating comprises aluminum powder dispersed in a vehicle
tightly adhering to the surface of said transparent sheet.
10. A transparent article as in claim 9 wherein the coating also
contains a color component selected from the group consisting of
pigments and dye.
Description
The invention relates to a sheet which is coated over discrete
areas of its surface with aluminium in such a manner that when
sun-light is transmitted by the sheet, the infra-red ray is
effectively masked whereas the percentage transmission of the
visible light ray may be adjusted by control of the aluminium
coating.
Domes or windows particularly for exhibition buildings, and the
like are often constructed from transparent glass and plastics to
enable the maximum amount of sun-light to be transmitted to within
the building. However the infra-red rays which pass into the
building with the visible light rays contain radiant heat energy,
which causes an increase in the temperature inside the building.
The temperature increase is particularly noticeable inside
buildings with large domes or windows and necessitates the costly
installation of air-conditioning.
It is known to overcome these inconveniences by the erection of
aluminium sunshades on the upper vault of the dome. Alternatively a
translucent film obtained by vacuum-metallizing polyester film with
a very thin coating of aluminium may be stuck to the dome or
window.
These methods have technical disadvantages, and cannot be used for
general purposes although they may be used for some special
purposes. The sunshade used in the first method outlined consists
of a number of aluminium plates and cannot therefore give a
homogeneous percentage transmission across the entire area of the
dome or sheet. Furthermore, the high erection costs tend to make
this system uneconomical. The second method outlined above is used
effectively. The translucent films are bonded onto a transparent
base sheet but their application is limited to certain kinds of
base sheet. Furthermore, the cost of fitting the sheets is high and
the transmitted ray tends to have a bluish tinge and is different
from natural light.
The biggest disadvantage common to both these methods is that the
masking materials are structurally weak and have poor weathering
resistance or durability and must therefore be fitted inside the
glass or plastic transparent sheet. As a result, the infra-red ray
is partly absorbed by the glass or plastic sheet itself. At the
same time, the ray reflected by the aluminium is re-absorbed by the
same sheet. Thus the sheet temperature rises sharply and, when used
in closed type buildings, the temperature inside the building
rises. In the case of a plastic sheet, which has a large heat
expansion this provides a serious technical problem in the
designing and erection of building structures.
Another possibility is to incorporate an infra-red absorber in the
sheet; however as the temperature of the sheet itself rises the
effect of the infra-red absorber is reduced significantly.
It is common knowledge that the reflectivity of infra-red rays (or
near infra-red rays) by aluminium is high, and because of this
aluminium sheet or some other sheet to which aluminium suspension
paint has been applied is often used to mask infra-red rays. The
suspension paint has, however, to be applied to the total surface
area and it is not then possible to adjust the amount of the
visible ray that is transmitted.
We have devised a novel inexpensive method whereby the percentage
transmission of visible light and infra-red rays can be
controlled.
The present invention provides a transparent sheet coated over only
a part of its surface with aluminium whereby the percentage
transmission of the visible light and the infra-red ray is
controlled.
The infra-red ray absorption by the sheet itself is controlled by
local coating with aluminium. In this way the heat expansion and
contraction due to the temperature fluctuations may be minimized.
This makes designing and erection work much easier.
The present invention also provides a method for controlling the
transmission by a transparent sheet of infra-red rays and visible
rays comprising coating directly certain areas of the sheet with
aluminium. Transmission of infra-red rays and visible rays can thus
be reduced to any desired value. The aluminium may be applied as
paste, as a liquid medium such as an ink or a paint containing
aluminium. The liquid medium containing aluminium paste may be
securely coated on the base sheet by painting, spraying or
printing.
If the liquid is applied by painting or spraying it is difficult to
control the thickness of the coating and thus difficult to control
the amount of light transmitted to a specified value, and it is
unavoidable that the silhouette becomes distorted or dim. Printing
and particularly screen printing methods are therefore preferred.
Under this method, the amount of light transmitted can be adjusted
for the whole surface of the sheet; furthermore the distortion of
the silhouette viewed through the sheet can be avoided by providing
a reticular print on the plate. The ratio of printed area to the
total area (hereinafter referred to as the coated area ratio) can
be changed so that the percentage transmission within the visible
limit and percentage transmission of infra-red ray can be
accurately reduced to a predetermined level.
In the production of the coated sheet a negative with the desired
coated area ratio may be prepared by the phototype process
generally used for printing. And thus using this negative a liquid
medium containing aluminium paste may be printed on the base sheet,
by screen printing techniques and a sheet having the desired
surface coated area ratio obtained.
If the percentage transmission of visible and infra-red rays is to
be reduced the coated area ratio should be increased, it must be
understood that the percentage transmission of infra-red ray
depends not only on the coated area ratio but also on the
transmission spectrum of the sheet in the near infra-red limit and
to the energy distribution of the light source.
For example, according to an experiment which we have performed in
which a transparent sheet of polymethyl methacrylate (5mm thick)
was used as the base sheet, and an infra-red ray bulb was used as
the light source, the percentage transmission of the visible ray
was adjusted from 20 percent to 80 percent and the percentage
transmission of infra-red ray was adjusted from 5 percent to 50
percent by changing the coated area ratio. If the sun is the light
source used in the above experiment, accurate values cannot be
obtained, because the power of the light source does not remain
constant. We found however that the percentage transmission of
infra-red rays could be adjusted from about 10 percent to about 65
percent.
It is common practice to adjust the percentage transmission of the
visible ray, by adding different amounts of translucent dyestuffs
or pigments to the base sheet. These pigmented sheets are called
smoked sheets but they do not mask infra-red rays. For instance, by
using smoked sheets of polymethyl methacrylate (5 mm thick) as the
base sheet, the percentage transmission of the visible ray may be
adjusted from 20 percent to 80 percent when an infra-red ray bulb
is used as the light source; however, the percentage transmission
of infra-red ray remains constant at about 55 percent.
The temperature rise of the base sheet, and hence the absorption
coefficient of the infra-red ray varies depending on the thickness
of the base sheet, the transmission spectrum of the sheet in the
near infra-red limit, the energy distribution of the light source,
the type and particle size of aluminium paste contained in the
liquid medium and the concentration of aluminium paste in the
liquid medium. The temperature also depends on whether the light
comes directly to the printed surface or first passes through the
base sheet. In the latter case, a part of the infra-red rays are
absorbed in the base sheet before the transmitted ray reaches the
printed surface, and then part of infra-red rays reflected by the
printed surface are also absorbed. Thus the absorption coefficient
of infra-red rays of the coated sheet is larger if the rays pass
through the sheet to reach the coating rather than first striking
the coating.
In the case of translucent film vacuum-metallized with aluminium,
which is generally known as half mirror, adhesion between aluminium
and the film as well as between the metallized film and the base
sheet is not strong enough to withstand the outdoor exposition, and
therefore, the film must be adhered to the inner surface of the
base sheet. Consequently, the base sheets absorption coefficient of
infra-red rays is increased and the over-all insulating effect is
reduced. The coatings of the present invention which are applied
directly to the transparent sheet have good adhesion to the sheets
and may be exposed to inclement weather.
It is therefore preferred to have the partially coated surface
facing the outside for the purpose of insulating closed buildings
or domes from the infra-red rays of sun-light. We have found that,
application of the coating by screen printing, produces a good
thickness of coating which has good surface weathering properties.
If however it is only desired to adjust the transmission of the
visible ray, it makes no difference which surface of the sheet is
coated.
In this specification, percentage transmission of the visible ray
means the total ray percentage transmission of light, through the
sheet. The light being derived from a photo-electric photometer
with an intergrating sphere provided with a green filter.
Percentage transmission of the infra-red ray and of the absorption
coefficient were measured by the following methods.
Firstly the light absorption coefficient of a sooted copper sheet
was considered to be 96 percent. The infra-red ray transmission of
the sheet of the present invention was then determined from the
relationship between the curve showing the temperature rise of the
sooted copper sheet, where all the absorbed light was converted to
heat energy and a curve showing the temperature rise of the sooted
copper sheet when the coated sheet of the present invention was
placed between the sooted copper sheet and the light source.
The absorption coefficient of the coated sheet of the present
invention was measured by measuring the temperature rise of the
inside surface of the partially surface coated sheet.
The partially surface coated sheet not only transmits and absorbs
the light, but also reflects the infra-red ray, and the sum of its
percentage transmission, absorption coefficient and reflectivity is
unitary and thus the reflection may also be determined.
The spots of aluminium (number of lines per 1 inch) applied by
screen printing can be selected arbitrarily. The greater the number
of lines per inch the narrower the space becomes between the
printed part and the blank part and the clarity of vision through
the sheet is reduced; furthermore as the number of lines increase
it becomes increasingly difficult to maintain uniformity of the
printed surface because of the plugging of the screen with the
liquid medium. Therefore, a smaller number of spots is desirable
particularly if the sheet is to be used to view an object which is
a long distance from the printed surface. Our preferred coating is
made up of 10-50 spots.
Any transparent sheet may be used as the base sheet. For example,
glass sheet and transparent plastic sheet such as polystyrene,
polyvinyl chloride and polymethyl methacrylate which is our
preferred material can be used.
The liquid coating medium may be a silver coloured ink which is
made from aluminium powder which may be mixed with other inks made
from yellow, red or other colour pigments or dyestuffs. For example
gold and other coloured coatings can be obtained by mixing suitably
coloured inks with the silver coloured ink. By the use of a liquid
medium prepared in accordance with the invention a surface
comprising a tightly adhered coating of aluminium paste is
obtained. This coating has good weathering properties which may be
improved still more if the coated surface is covered by a
transparent lacquer by printing or painting.
If reticular printing is carried out by a screen printing method,
any transparent coloured ink can be printed within the outline of
the aluminium printing space by using a negative having the same
number of spots as that of the negative used for printing with the
aluminium paste, and having a coated area ratio which is equal to
or less than that of the negative used for printing with the
aluminium paste. Thus if this method is applied to a dome, white
light is transmitted into the building and a decorative coloured
metallic gloss is observed from the side of the light source.
Another application of reticulately surface printed sheet is as
follows. If two surface printed sheets are placed back-to-back or
if both sides of the base sheet are printed, what is called "moire
pattern" is obtained, and this can be used for ornamental
purposes.
The invention is illustrated but in no way limited by reference to
the following examples:
EXAMPLE 1
A sheet of 5 mm thick polymethyl mathacrylate was printed by screen
printing techniques using a negative designed to produce a pattern
having 30 spots and a 50 percent coated area ratio, with a silver
ink, containing 30.0 percent aluminium powder 5.0 percent pigment
5.0 percent polyethylene wax: and 60.0 percent organic solvent
solution of polymethyl methacrylate and a very small amount of a
foaming agent.
______________________________________ The sheet obtained had the
following properties : Percentage transmission of visible ray: 56%
Percentage transmission of infra-red ray: 33% Absorption
coefficient: 21% ______________________________________
The percentage transmission of the infra-red ray was determined
using an infra-red ray bulb with the printed surface of the sheet
facing the bulb. Clear vision was obtained at a distance of more
than 2 m away from the surface printed sheet.
EXAMPLE 2
The surface printed sheet produced in Example 1 was placed with the
printed surface facing away from the light source, and the
absorption coefficient of the infra-red ray was found to be 40
percent.
EXAMPLE 3
The process of Example 1 was repeated using a negative having 50
spots and a 35 percent coated area ratio. The printed surface of
the finished sheet of polymethyl methacrylate was then printed with
a transparent red lacquer, using the same negative in the same
position as in Example 1. The sheet produced was placed with the
printed surface facing the light source, and the percentage
transmission of visible ray, infra-red ray and the absorption
coefficient were observed as below.
______________________________________ Percentage transmission of
visible ray: 74% Percentage transmission of infra-red ray: 46%
Absorption coefficient: 21%
______________________________________
Clear vision is obtained at a distance of more than 1 m away from
the surface printed sheet and a beautiful red metallic gloss is
observed from the side of light source, while natural light is
transmitted through the sheet.
* * * * *