U.S. patent number 3,886,942 [Application Number 05/464,970] was granted by the patent office on 1975-06-03 for sanitary napkin.
This patent grant is currently assigned to Kimberly-Clark Corporation. Invention is credited to Leo J. Bernardin.
United States Patent |
3,886,942 |
Bernardin |
June 3, 1975 |
Sanitary napkin
Abstract
Sanitary napkins are disclosed comprised of an inner core of
absorbent material and a cover which consists essentially of
unfinished thermoplastic fibers. Preferably the cover is a web of
continuous filaments of unfinished polypropylene fibers.
Inventors: |
Bernardin; Leo J. (Appleton,
WI) |
Assignee: |
Kimberly-Clark Corporation
(Neenah, WI)
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Family
ID: |
27423873 |
Appl.
No.: |
05/464,970 |
Filed: |
April 29, 1974 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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15164 |
Feb 27, 1970 |
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Current U.S.
Class: |
604/366; 604/370;
604/374; 604/375 |
Current CPC
Class: |
A61F
13/51 (20130101); A61L 15/24 (20130101); A61L
15/24 (20130101); C08L 23/12 (20130101); A61F
2013/51042 (20130101); A61F 2013/530131 (20130101); A61F
2013/530182 (20130101); A61F 2013/51002 (20130101) |
Current International
Class: |
A61F
13/15 (20060101); A61L 15/16 (20060101); A61L
15/24 (20060101); A61f 013/16 () |
Field of
Search: |
;128/284,287,290,296,156 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Gaudet; Richard A.
Assistant Examiner: Layton; Henry S.
Attorney, Agent or Firm: Wolfe, Hubbard, Leydig, Voit &
Osann, Ltd.
Parent Case Text
This is a continuation of application Ser. No. 15,164, filed Feb.
27, 1970, now abandoned.
Claims
I claim as my invention:
1. A sanitary napkin comprising an inner core of absorbent material
having a shape and size adaptable to absorb body menstrual fluids
and a cover enclosing said inner core, said cover, in the body
contacting area thereof, consisting of a nonwoven, porous and dry
formed web having a basis weight of about 0.25 - 1 oz.lyd..sup.2,
said web consisting of unfinished polyolefin or polyester fibers,
said unfinished fibers being characterized by fiber surfaces which
are devoid of lubricants, antistatic, or wetting agents, said web
being intermittently autogenously bonded at discrete bond areas
occupying about 5-50% of the web area and disposed in a density of
about 50-3200/inch.sup.2 to permit the passage of menstrual fluid
therethrough and into the absorbent core under the body pressures
of normal usage to provide a substantially dry surface feel to the
wearer.
2. The sanitary napkin of claim 1 wherein the web is an
intermittently autogenously bonded porous nonwoven web of
unfinished polypropylene fibers.
3. The sanitary napkin of claim 1 wherein the web is an
intermittently autogenously bonded, porous web of substantially
continuous and randomly deposited unfinished, molecularly oriented
filaments of a polyolefin or a polyester.
4. The sanitary napkin of claim 3 wherein the continuous unfinished
filaments are of polypropylene.
5. The sanitary napkin of claim 4 wherein the unfinished
polypropylene filaments have a denier of about 1-5.
6. The sanitary napkin of claim 5 wherein the web has a basis
weight of about 0.3-0.7 oz./yd..sup.2, the unfinished polypropylene
filaments have a denier of about 1.2-2 and wherein the autogenous
bond areas occury about 8-20% of the web area and are disposed in a
density of about 100-500/in..sup.2.
Description
DESCRIPTION OF THE INVENTION
Sanitary napkins generally comprise an inner core of absorbent
material and a fluid permeable outer cover. The cover should serve
merely as an enclosing means for the absorbent material and have
substantially no capacity for fluid absorption or retention
itself.
Canadian Pat. No. 826,352 discloses a sanitary napkin which is said
to possess optimum properties. The napkin therein disclosed
consists of an inner core of absorbent material covered with a web
of autogenously bonded synthetic fibers such as polyethylene,
polypropylene, or polyesters. The web is disclosed as being
prepared by carding, garnetting, or air laying.
While the Canadian patent states that fluids will readily pass
through the outer cover and be retained in the inner core with no
resultant clammy or wet feeling to the wearer of the sanitary
napkin, and this is ture during periods of light flow; it has been
found that as the amount of fluid retained by the inner core
increases there is an increasing retention of fluid by the cover
and this contributes to some discomfort. Thus, in actual use, the
napkin surface does not remain as dry as would be expected; and,
accordingly, there is still a need for improvement over the napkins
disclosed in the Canadian patent.
Accordingly, it is a principal object of the present invention to
provide an improved sanitary napkin which readily absorbs and
retains fluid, and which maintains a substantially dry surface
during use.
Another object is to provide a sanitary napkin with an improved
cover. It is a further object to provide a napkin as
above-described with particularly desirable strength
characteristics and which can be prepared economically.
Other objects and advantages will become apparent as the
description proceeds and with reference to the drawings in
which:
FIG. 1 is a perspective view illustrating a sanitary napkin of the
present invention with a portion thereof cut away;
FIG. 2 is a plan view of a section of a web useful as a sanitary
napkin cover.
FIG. 3 is an enlarged view of a section of a preferred web useful
as a sanitary napkin cover.
While the invention is susceptible of various modifications and
alternative constructions, there is shown in the drawings and will
herein be described in detail the preferred embodiments. It is to
be understood, however, that it is not intended to limit the
invention to the specific forms disclosed. On the contrary, it is
intended to cover all modifications and alternative constructions
falling within the spirit and scope of the invention as expressed
in the appended claims.
Briefly, the sanitary napkins of the present invention comprise an
inner core of absorbent material and a cover consisting essentially
of a porous web of unfinished thermoplastic fibers. As used herein,
the term "unfinished" refers to fibers whose surfaces do not
contain lubricants, anti-static, or wetting agents. In this
respect, it should be noted that the fibers customarily employed in
preparing webs by techniques such as weaving, carding, air-laying
or garnetting are finished, i.e., -- have their surfaces dressed
with a combination of a lubricating, anti-static and wetting agent.
In the absence of a surface finish, it is extremely difficult to
handle the fibers during web preparation, and, accordingly,
finished fibers are universally employed when webs are to be
fabricated by such techniques. Typically, finished thermoplastic
fibers have receding contact angles with water of less than
90.degree.. Unfinished fibers, on the other hand, have somewhat
higher contact angles with, unfinished polypropylene having a
receding contact angle with water of greater than about 90.degree.,
and generally in the range of about 100.degree.-120.degree..
Also, as used herein, the term "consisting essentially of" means
that the porous web of unfinished thermoplastic fibers is an
indispensibly necessary component of the cover, but that other
cover components which do not detract from the desirable
characteristics of the napkin can also be present. For example,
those portions of the napkin cover which are not in contact with
the body of the wearer need not be prepared from unfinished
fibers.
Turning to the drawings, FIG. 1 depicts a sanitary napkin 10
comprised of an inner core of absorbent material 12 and a cover 14.
The absorbent material 12 can be of conventional shape and size and
can be any of those materials ordinarily used in sanitary napkin
applications such as wood pulp fluff, cellulose wadding, cotton or
rayon fibers, etc. Similarly, the manufacture of the sanitary
napkin can be accomplished by generally known techniques which
involve wrapping the core with the cover, and, thereafter, sealing
the cover in order to enclose the absorbent material within, and
provide means for securing the napkin to a belt or the like such as
tabs.
With respect to the cover 14, it has been indicated that it
consists essentially of a porous web of unfinished thermoplastic
fibers. While webs of unfinished polypropylene fibers exhibit
optimum characteristics, webs of other unfinished polyolefin fibers
(e.g., polyethylene, polybutene, etc.) as well as polyester fibers
can be advantageously used. FIG. 2 illustrates a preferred cover
web 16 which, as shown, is made up of a plurality of substantially
continuous, molecularly oriented, unfinished fiber filaments 18
arranged in a substantially random array.
Concerning the web 16, it is not essential that the fiber filaments
therein be continuous, so long as they are unfinished. However, the
fact that a continuous filament web can be directly obtained from
unfinished fiber filaments renders such webs economically
attractive. Moreover, as hereinafter discussed with respect to
further aspects of the present invention, napkins prepared with
covers as illustrated in FIG. 2 possess especially desirable
strength characteristics. However, while continuous filament webs
are preferred, other webs, such as those prepared by carding,
wherein after preparation the surface fiber finish is removed, can
also be used.
A variety of methods exist for preparing continuous filament webs
of thermoplastic fibers. U.S. Pat. Nos. 3,341,394 and 3,338,992 to
Kinney disclose several presently known techniques. In general, web
formation involves continuously extruding polymer through a
spinneret, drawing the spun filaments, and thereafter depositing
the drawn filaments on a continuously moving surface in a
substantially random fashion. Drawing serves to give the polymer
filaments tenacity, while substantially random deposition gives the
web desirable isotropic strength characteristics.
In addition to presently known methods of initial web formation, a
particularly useful technique is described in copending application
Ser. No. 865,128, titled Continuous Filament Nonwoven Web and
Process For Producing the Same, filed on Oct. 9, 1969 and now U.S.
Pat. No. 3,692,618. Use of the method therein disclosed permits
especially high rates of web formation and, as hereinafter
discussed, results in desirable product attributes. The disclosed
method involves conventional spinning of continuous filaments of a
synthetic polymer by, for example, extruding the polymer through a
multiple number of downwardly directed spinning nozzles, preferably
extending in a row or multiple number of rows. The filaments, as
they are spun, are gathered into a straight row of side-by-side,
evenly spaced apart, untwisted bundles each containing at least 15
and preferably from 50 to 150 filaments. These filament bundles are
simultaneously drawn downwardly at a velocity of at least 3,000
meters per minute, and preferably from 3,500 to 8,000 meters per
minute, in individually surrounding gas columns flowing at a
supersonic velocity and directed to impinge on a substantially
horizontal carrier. The gathering of the filaments into the bundles
and their drawing and directing to impinge on the carrier is
preferably effected by passing the bundles through air guns which
surround the filaments with a column or jet of air which is
directed downward at supersonic velocity. The air guns are arranged
so as to extend in a straight row in a direction extending across
the carrier at right angles to its direction of movement, so that
the bundles confined in the gas columns as the same strike the
moving carrier extend in a line or row at right angles across the
carrier. In order to enhance intermingling of the bundles, the air
guns can be made to oscillate, the plane of oscillation being
transverse to the direction of carrier movement. The carrier can be
a conventional carrier used in a nonwoven art, such as an endless
carrier or belt screen or the upper portion of a drum, as for
example a screen drum.
When prepared as described above, the filament bundles, containing
a number of parallel filaments, are laid down on the carrier in a
loop-like arrangement with primary loops extending back and forth
across the width of a section defined by the impingement of the air
column from one air gun on the carrier. Before and as the parallel
filaments bundles impinge the carrier, they are broken up into
sub-bundles containing a lesser number of parallel filaments and
forming secondary smaller loops and swirls. The secondary loops and
swirls overlap each other, and those of adjacent sections, to
result in substantially complete intermingling with the overlapping
portions of adjacent sections. Thus, the laid-down filament bundles
form a continuous uniform nonwoven web.
A portion of a web prepared as described above is shown in FIG. 3.
Several filament sub-bundles, such as those numbered 20, 22, and
24, are depicted. Due to the presence of filament bundles, rather
than all single filaments as with other continuous filament webs,
large "inter" bundle pores exist. It is felt that the existance of
these pores helps promote fluid penetration into the inner core of
a napkin when such a web is employed as the cover.
The web illustrated in FIG. 2 when used as a sanitary napkin cover
can have a basis weight of about 0.25-1 oz./yd..sup.2, and
preferably about 0.3-0.7 oz./yd..sup.2. The filaments thereof can
have a denier of about 1-5 and, preferably, about 1.2-2.
In order to be useful as a sanitary napkin cover, the web of
unfinished thermoplastic fibers must be bonded in a manner which
imparts sufficient web strength, and yet does not adversely affect
web softness or porosity of fluid transfer. In this respect, it has
been found that those techniques which involve overall web bonding
are generally unsatisfactory both with respect to porosity and
sofness. Referring again to FIGS. 2 and 3, a preferred manner of
web bonding is illustrated. As therein shown, the filaments of the
webs are bonded together at a discrete number of spot bond areas 26
distributed intermittently throughout the web. A desirable
combination of cover porosity and strength is present in a web
wherein the total bonded area is about 5-50% of the web area and
wherein the density of individual bond areas is about 50-3200 per
inch.sup.2, the higher bond densities being employed with higher
total bonded areas. Particularly preferred webs are those having a
total bonded area of about 8-20% and a bond density of 100-500 per
inch.
An especially suitable manner of preparing a bonded web such as
illustrated in the figures is disclosed in copending Hansens et al.
application Ser. No. 15,034 titled Pattern Bonded Continuous
Filament Web, which application was abandoned in favor of
application maturing into U.S Pat. No. 3,855,046. The bonding
process illustrated therein comprises passing the unbonded
continuous filament web through the pressure nip formed between a
smooth hard roll and a heated embossing roll. By appropriately
controlling the temperature of the rolls and the nip pressure, a
web with a highly desirable type of bond, termed a "release" bond,
can be obtained. At web speeds of about 275-350 ft./min., such
bonding can be achieved by maintaining the smooth roll at a
temperature of less than about 270.degree.F., keeping the heated
embossing roll at 300.degree.-320.degree.C., and applying a nip
pressure, on each raised embossing point, of 5,000-50,000
p.s.i.
The relaease bonds achieved by the process illustrated in Hansen et
al. are characterized by the absence of a uniform degree of fiber
bonding throughout an individual spot bond area which contain
autogenously bonded filaments. When viewed under a microscope, the
fibers bonded in the surface next to the embossing roll are seen to
have substantially lost their filamentary character, while the
fibers bonded in the other surface are cohesively secured together
but retain their filament identity.
A significant advantage of the sanitary napkins described herein is
their ability to absorb menstrual and other body fluids under the
applied pressures of normal usage, and still provide a dry surface
feel to the wearer. Such is believed to be due to the fact that the
unfinished thermoplastic filaments in the cover are not only
resistant to fluid absorption themselves, but additionally prevent
fluid, when once absorbed within the inner core of the napkin, from
coming back out to stain clothing or rewet the body. The
superiority of a web of unfinished fibers for sanitary napkin
covers is particularly unexpected in view of the fact that the webs
illustrated herein do not exhibit such superior utility in related
uses, such as diaper liners.
The above-mentioned desirable fluid behavior characteristics of the
cover described herein are illustrated by comparatively evaluating
the capillary transfer characteristics of a variety of covers. Such
is accomplished as follows:
A standard capillary transfer cell (Textile Research J. 37, No. 5:
356-366)(May, 1967) is filled with water and 3 grams of filler from
a conventional regular Kotex feminine napkin is placed on one side
of the cell. A single layer of the web to be tested is placed on
the other side. Weights exerting about 0.1 psi are used on both
sides of the cell to assure contact between the cell and the
materials. After positioning, 7.5 ml. of water (or 10 ml.) is added
to the web sample side of the cell after which the cell valve is
opened and water transfer to the filler permitted for 100 minutes.
Thereafter, the web sample is weighed and the retained moisture
therein determined and reported as per cent moisture retention
based on the weight of dry fiber. For sanitary napkin covers, a low
value of moisture retention is desirable. Moisture retention values
obtained on several conventionally available webs used as sanitary
napkin covers and on a web prepared as described herein are
presented in Table 1.
TABLE 1
__________________________________________________________________________
% Moisture Retention Web Basis Wt. g/yd..sup.2 Initial 7.5 ml.
Initial 10 ml.
__________________________________________________________________________
A. Adhesively Bonded Carded Rayon Web 14 220 370 B. Nylon Scrim
with Cotton Applique 7.8 100 260 C. Autogenously Bonded Carded Web
of Finished Polypropylene Fibers 20.3 75 108 D. Autogenously Bonded
Carded Web of Unfinished Polypropylene Fibers* 20.3 2 11 E. Spot
Bonded Web of Continuous Filaments of Unfinished Poly- propylene
Fibers** 15 2 3
__________________________________________________________________________
*Finish removed from immediately preceding finished fiber web by 3
step Soxhlet extraction with hexane, methanol, and water (4 hours
each). **Prepared as described in Serial No. 865,128, with filament
denier of 1. and fiber tenacity of 4.4 g/denier. Bonding
accomplished as described in the above-mentioned Hansen et al.
application by passing web at 330 ft./min. through a smooth
roll-embossing roll nip under following conditions: Smooth roll
temp. = 240.degree.F.; Embossed roll temp. = 300.degree.F.;
Individual bond areas = 0.0285" on a side and spaced 10 pe inch in
both machine and cross-direction; 17% of total area bonded; Nip
pressure on a raised point = 28,000 psi.
As can be appreciated from the results presented in Table 1,
sanitary napkin covers consisting essentially of unfinished fibers,
particularly polypropylene, possess superior fluid behavior
characteristics than do conventional webs of either rayon, nylon,
or finished polypropylene fibers.
In addition to the above-discussed fluid behavior, the mechanical
and aesthetic characteristics of the continuous filament webs
illustrated herein make them especially desirable for sanitary
napkin covers. Due to the randomness of filament orientation
present in such webs, the tensile strength and stretch
characteristics are more isotropic than in existing webs. Such
isotropic characteristics are particularly important in sanitary
napkin applications since, in use, stresses are present in all
directions. Moreover, by appropriate web bonding, as previously
discussed, such isotropic strength can be obtained in combination
with a desirable softness and overall feel. Optimum mechanical
characteristics, particularly with respect to the combination
tensile strength and elongation, can be achieved with a web
containing release bonds as described in the previously referred to
Hansen et al. application. When such a web is used as a napkin
cover, the web surface which was in contact with the smooth roll
during bonding should be placed adjacent to the inner core. By
doing such, high abrasion resistance of the cover material can be
obtained.
Table 2 illustrates the mechanical and overall feel characteristics
of web covers prepared as described herein compared with
conventional webs used as sanitary napkin covers.
TABLE 2
__________________________________________________________________________
Tensile Strength Elongation Drape* gram/inch % Handle-o-Meter Web
MD CD MD CD MD CD
__________________________________________________________________________
A. Adhesively bonded Rayon Web 1930 125 9 20 11 2.8 B. Nylon Scrim
with Cotton Applique 1700 440 26 32 2.3 0.8 C. Autogenously Bonded
Carded Web of Finished Poly- propylene Fibers 2660 148 7.6 9.5 12.4
3.4 E. Spot Bonded Web of Continuous Fila- ments of Unfinished
Polypropylene Fibers 1600 1200 28 36 4.8 2.8
__________________________________________________________________________
*Determined using a Thwing-Albert Instrument Company
Handle-o-Meter.
Thus, it is apparent that there has been provided, according to the
invention, an improved sanitary napkin whichfully satisfies the
aims, objectives, and advantages as set forth above.
* * * * *