U.S. patent number 3,886,800 [Application Number 05/406,235] was granted by the patent office on 1975-06-03 for gas sampling device.
Invention is credited to John R. Boehringer.
United States Patent |
3,886,800 |
Boehringer |
June 3, 1975 |
Gas sampling device
Abstract
Sealed crushable tube includes a puncturable segment and a
removable, snugly fitted internal piston and a reasonable closure
for an opening through which the piston is removable from the tube.
An uncontaminated gas sample is taken by removing the piston from
the tube in the atmosphere, exercizing the piston to secure a
thoroughly mixed and typical sample to be sampled, and resealing
the opening through which the piston is removed. The closed tube
may then be transferred long distances by mail or parcel service to
a gas analysis device where the gas is transferred to the device by
a tubular member which penetrates the puncturable segment and
delivers the sampled gas to the gas analysis apparatus with a
minimum of contamination. Various closure means and auxiliary
features are also disclosed. Generally, the device is constructed
of a metal or some other material inert and non-absorbent with
respect to the gas to be treated. An important feature of the
system is a gas tight fixed seal, and the ability to urge the gas
out of the container by crushing the container thus eliminating
sliding seals which leak.
Inventors: |
Boehringer; John R. (Wynnewood,
PA) |
Family
ID: |
23607108 |
Appl.
No.: |
05/406,235 |
Filed: |
October 15, 1973 |
Current U.S.
Class: |
73/864.62;
73/864.63; 141/83 |
Current CPC
Class: |
G01N
1/24 (20130101) |
Current International
Class: |
G01N
1/24 (20060101); G01n 001/24 () |
Field of
Search: |
;73/421.5,422,425.6
;141/83,18,1,4,5,7 ;220/DIG.7 ;222/92,106 ;128/DIG.5 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Swisher; S. Clement
Attorney, Agent or Firm: Paul & Paul
Claims
I claim:
1. Gas sampling device comprising a sealed crushable tube having a
puncturable segment therein, an opening closed by a resealable,
openable closure and a piston snugly fitting within said tube and
removable through said opening, said tube, said closure, and said
piston all being composed of a material inert and non-absorbent
with respect to any gases to be tested.
2. Gas sampling device, as recited in claim 1, wherein said
material is a metal.
3. Gas sampling device, as recited in claim 1, wherein said
material is a metal selected from the group consisting of aluminum,
zinc, lead, tin, and tin-lead alloys.
4. Gas sampling device, as recited in claim 1, wherein said opening
and closure consists of an opening in said tube surrounded by a
means for retaining said closure in firm contact therewith, said
closure abutting said opening with a metallic seal and being
retained thereagainst by means mating with said retaining means
surrounding said opening.
5. Gas sampling device, as recited in claim 4, wherein said
retaining means consists of a deformable segment extending
circumferentially about said tube and a mating non-deformable
segment on said closure, said closure being adapted to engage said
deformable segment in a manner to cause deformation thereof with a
resultant gripping and sealing effect between said tube and said
closure.
6. Gas sampling device, as recited in claim 4, wherein said
retaining means consists of threaded members adapted to mate with
correspondingly threaded members attached to said closure, said
members including posts extending between said retaining means and
said closure.
7. Gas sampling means, as recited in claim 1, wherein said tube
includes a dimple projecting inwardly in said tube and adapted to
be bent outward in response to a decrease in the ambient pressure
surrounding said tube.
8. Gas sampling device, as recited in claim 1, wherein said
puncturable segment is surrounded by a projection in said tube,
said projection being adapted to receive and retain, in sealed
engagement, a means including a pointed tubular member adapted to
puncture said segment and to protrude into said tube through said
punctured segment and to withdraw a gas sample therefrom.
9. Gas sampling device, as recited in claim 8, further including a
gas sample withdrawing means adapted first to engage and to be
retained in sealed engagement with said puncturable
segment-surrounding projection, and then to flush inert gas through
the closed space between said segment and said sample withdrawing
means, and finally to puncture said segment with a pointed tubular
member and to withdraw a gas sample from said tube through said
tubular member.
10. Gas sampling device, as recited in claim 9, wherein said
tubular member is connected directly to a gas analysis means.
11. Gas sampling device comprising a sealed crushable tube having a
puncturable segment therein and an opening closed by an openable
and sealable closure, said tube and said closure being composed of
a material inert and non absorbent with respect to any gases to be
tested, wherein the space within said tube is occupied by an inert
solid material adapted to be removed through said opening upon
removal of said closure.
12. A device as recited in claim 11 wherein said inert solid
material is in particulate form.
13. Gas sampling device comprising a sealed crushable tube having a
puncturable segment therein and an opening closed by an openable
and sealable closure, said tube and said closure being composed of
a material inert and non-absorbent with respect to any gasses to be
tested, wherein the surface of said tube at said opening defines at
least on preformed ridge, and said closure includes a sheet of
inert, malleable material to fit in sealable registry with said
ridge.
14. Gas sampling device, as recited in claim 13, wherein said sheet
of inert, malleable material is lead foil secured to said closure,
said ridges penetrating said foil as said closure is secured to
said tube.
15. Gas sampling device, as recited in claim 14, wherein a band is
provided to grip the tube in concert with the ridge for stress
raising in order to prevent over tightening and in order to
mechanically secure the tube.
Description
This invention is related to gas analysis, such as may be necessary
to detect the presence of anesthetic gases in an operating room
atmosphere, and particularly to sampling devices for removing an
uncontaminated sample of the gaseous atmosphere to be tested and
transferring the sample to a gas analysis apparatus with a minimum
of contamination.
Gas analysis for the detection of very small concentrations, on the
order of parts per million or parts per billion, of objectionable
gases are often necessary. For example, there is increasing
evidence that very minute concentrations of anesthetic gases in an
operating room atmosphere may have some adverse physiological
consequences on persons exposed to the atmosphere. Such
contamination may result from an inefficient or ineffective
scavenging system for removing such anesthetic gases.
Because of the very low level of concentrations of the
objectionable gases in such situations, it is often necessary to
detect their presence using specialized equipment found only in
certain locations in the U.S. therefore requiring transport by
mail.
Furthermore, it is usually impractical, if not impossible, to
deliver uncontaminated gas samples from such atmospheres to the
sophisticated gas analysis apparatus necessary to detect a very low
level of objectionable gases or conversely to move the
sophisticated analytical apparatus into the atmosphere to be
tested. All of the known existing systems use syringes with their
inherent leakage of the pistons or bags made of flexible material
with potentially serious leakage, adsorption, and absorption
problems.
In view of all of these circumstances, it is apparent that there is
a need for a gas sampling technique or device which permits the
transfer of an uncontaminated sample from a gaseous atmosphere to
be tested to the gas analysis apparatus. Plastic and glass
containers, particularly syringe-type devices, have not been
satisfactory due to the absorbent nature of plastic to many gases,
particularly objectionable gases such as anesthetics, and the
unavoidable leakage around syringe body and piston particularly
when such equipment is composed of glass. Such leakage permits
ready access of contaminant gases (defined for purposes of the
present invention as any gas not part of the gaseous atmosphere to
be sampled) into the gaseous sample, more likely, or, migration of
the gas to be sampled out of the container.
It is therefore an object of the present invention to provide a gas
sample device adapted to receive and hold an uncontaminated gas
sample for transfer to gas analysis apparatus.
It is a more specific object of this invention to provide a
non-absorbent, inert device which facilitates the transfer of the
gaseous sample into the gas analysis apparatus.
It is a further object of this invention to provide a variety of
optional designs for ensuring the sealed enclosure of the gas
sample in a relatively simple and economic manner.
These and other objects, which will become apparent in the course
of the subsequent discussion of this invention, are met, briefly,
by a sealed crushable tube having a puncturable segment and a
removable piston snugly fitting within the tube and removable
through an opening in the tube, which is in turn covered by a
sealable closure. Generally, the device is composed of a material
inert and non-absorbent with respect to any gases to be tested. In
many cases, this excludes plastics as a primary material of
construction due to their absorbent nature, although vacuum
metalized plastic may provide a suitable alternative to metallic
materials and some of the more advanced plastics now being
developed may prove to be sufficiently non-absorbent and inert to
be used in the present invention. Glass is generally not suitable
due to its fragile nature and the cost of including a puncturable
segment in the glass, as well as the inability to urge the sample
out of the tube by squeezing. Therefore, the preferred material of
construction is a metal such as aluminum, zinc, lead, tin-lead
alloys and other relatively soft and easily formable metals, or
alternatively the metallized plastics.
In the preferred form of the present invention, the puncturable
segment of the tube is surrounded by a mating means through which
the tube may be connected to an inert gas purgeable passageway to a
gas analysis apparatus, the delivery means including a sharp tipped
tubular member, such as a hypodermic needle, which penetrates the
puncturable segment and through which the gas sample in the tube is
delivered, again with a minimum of contamination, directly to the
gas analysis apparatus.
This invention may be better understood by reference to the
following detailed description thereof and the appended claims,
taken in conjunction with the accompanying drawings, in which:
FIG. 1 is an assembly view, partially in cross-section, of one form
of gas sampling device within the scope of the present invention,
including an internal piston as is included at the time of
manufacture and showing the tube assembled with means for
transferring the gas sample to a gas analysis apparatus;
FIG. 2 is a sectional view of the assembly shown in FIG. 1 with the
internal piston removed;
FIG. 3 is a sectional detail view of a particular feature of the
present invention;
FIG. 4 is a view, partially in cross-section, showing a gas
sampling tube of the type shown in FIG. 1 with a modified form of
internal piston and sealing means;
FIG. 5 is a partially sectioned assembly view of a gas sampling
tube, similar to that shown in FIG. 1 but having a different
sealing means, in a shipping container for transporting the gas
sample to suitable gas analysis apparatus; and
FIGS. 6 and 7 are detail views showing other forms of closure seals
which may be used in the gas sampling device of the present
invention.
FIGS. 8, 9, and 10 show alternative forms of closure seals which
may be used in the gas sampling device of the present
invention.
Referring now more specifically to FIGS. 1 and 2, there is shown a
closure member 1 threadedly engaging a retaining collar 2 secured
by means of a swaged upper lip 4a to a crushable tube 4, composed
of an inert and non-absorbent material with respect to any gas to
be sampled, typical materials including metals such as aluminum,
zinc, lead, tin, and tinlead alloys.
To ensure a proper non-absorbent seal, a deformable metallic facing
3 on closure member 1 abuts swaged upper lip 4a as closure member 1
is drawn into engagement with tube 4 by turning within retaining
collar 2.
As shown in FIG. 1, disposed within tube 4 prior to the time a gas
sample is to be taken, is a snugly fitted piston 15, removable
through the opening of tube 4 created upon removal of closure
member 1 to permit the filling of the interior space in tube 4 with
the gaseous atmosphere to be sampled. The assembly, with piston 15
removed as it would be when the gas sample is taken, is shown in
FIG. 2. Puncturable segment 7 in tube 4 in this preferred form of
the present invention is surrounded by protrusion 6 threadedly
engagable with a transfer means for removing the gas sample from
tube 4 and delivering it to a gas sampling apparatus, not shown but
typically consisting of a gas chromatograph or infrared spectrum
analyzer.
While the particular transfer means may take a variety of forms, it
generally includes a sharp tipped tubular member 12 which
penetrates puncturable segment 7 for delivery of sampled gas from
the interior of tube 4, upon the collapse or forced crushing of
tube 4 to a connection 14 to the gas analyzing apparatus. In the
transfer means shown, tube 12 is mounted within a mounting block 8
with an opening 9 therein through which tubular piercing member 12
passes. Mounting block 8 also includes a resilient bushing or
bearing member 8a facing puncturable segment 7 and an o-ring seal
10, both of which are intended to minimize the introduction of
contaminant gas into tubular passageway 9. Further to minimize
leakage of contaminant gas into the gas analyzer along with the
sampled gas in tube 4, an inert gas purge passageway 9a is adapted
to exhaust inert purged gas from tubular passageway 9 and around
tubular piercing member 12 prior to the piercing of puncturable
segment 7 by tubular member 12. The needle is arranged to be
withdrawn clear of elements 8a and 10 so as to provide for this
scrubbing action. Connecting member 14 is also secured within a
second mounting block 11 which by means such as a spring 13 urges
mounting block 8 away from second mounting block 11.
In using the assembly shown in FIGS. 1 and 2, tube 4 assembled with
piston 15 and top closure member 1, together with retaining collar
2 and facing seal 3 is opened to the ambient atmosphere to be
sampled by removing closure member 1 and facing seal 3 and
withdrawing piston 15 from tube 4. Facing seal 3 is then replaced
along with closure member 1 and urged into engagement with swaged
upper lip 4a by the threaded engagement of closure member 1 and
retaining collar 2. Thus, an uncontaminated sample of gas air to be
tested is enclosed in the sealed interior space of tube 4.
Tube 4 is then taken or transmitted (and in fact can be shipped
over great distances to a central test facility) to a gas analysis
apparatus where it is mounted in a sample transfer means such as by
threadedly engaging protrusion 6 in a mounting block 8. Inert gas
is then passed through the needle, exhausting out passageway 9a to
purge the space surrounding tubular piercing member 12 and the
entire assembly of tube 4 with closure member 1 and mounting block
8 is forced against the resistive pressure of spring 13 and against
piercing tubular member 12 so that piercing member 12 extends and
remains in the interior space of tube 4. Upon crushing or
collapsing tube 4, the sampled gas within the interior space of
tube 4 is forced through tubular member 12 and connection 14 to the
gas analyzing apparatus.
In FIG. 4, there is shown an alternative form of tube 4 wherein
retaining collar 2, which may be composed of aluminum, for example,
includes a hard metal (aluminum or steel, for example) lip ring 2a
for mating with and deforming a correspondng deformable facing seal
member (not shown) on closure member 1. Also seen in FIG. 4 is a
modified piston 15a including a long tubular gas inlet for
admitting the gas to be sampled into the interior space of tube 4
as piston 15a is moved back toward the opening in tube 4 surrounded
by retaining collar 2.
Note that a liquid or solid or particulate material could be used
to fill the internal space of tube 4 in place of piston 15. Gas
sample is then introduced into tube 4 simply by emptying the liquid
or solid particulate material from tube 4.
In FIG. 5, there is shown a schematic view of another assembly,
similar to that shown in FIG. 1, but differing in that closure
member 1 is mated with retaining collar 2 by means of threaded post
members 18 with retaining bolt heads 19 or nuts. Further, the
assembly of tube 4 in closure member 1 is retained in a shipping
container 20 with a screw cap 21 and a spacer 22 for preventing
movement of the sampling device within the shipping container. Such
a shipping container may be used for shipping the originally
manufactured sampling device to the point of use and would be
necessary for shipping the sampling device after the internal
support has been removed therefrom and after the sampled gas has
been introduced into the interior space of tube 4 to some remote
facility where complex and sophisticated gas analysis apparatus may
be located.
Various other details and auxiliary features may be incorporated in
tubular member 4 and the means by which it is sealably closed by
closure member 1.
One such feature, not pertaining to closure member 1, but intended
to facilitate the shipment by air of tubular member 4 without
causing its inadvertent collapse due to the reduced ambient
atmosphere such as might be present in the cargo compartment of a
commercial airliner, is a dimpled recess 23, as seen in FIG. 3. A
corresponding dimpled recess 23a would, of course, be included in
piston 15. Rather than overall collapse or deformation of tube 4
upon being subjected to dissimilar ambient pressures on the
interior and exterior of tube 4, dimple 23 is adapted to spring
inwardly or outwardly to compensate for such differential
pressures.
Two other means by which closure member 1 may be mated with tube 4
are seen in FIGS. 6 and 7. In FIG. 6, for example, tube 4 includes
a flared upper section 4b. Closure member 1 includes a protruding
plug 24 with coining ridges 25 on its outer face. As closure member
1 is turned and pressed into tube 4, coining ridges 25 deform the
relatively soft metal of tube 4 at the flared upper portion 4b and
produce, in effect, a threaded seal on engagement of the members.
In addition, a back up resilient seal 26, which may be composed,
for example, of teflon, may be included to provide a complete seal
between closure member 1 and tube 4.
In still another embodiment of closure member 1, as seen in FIG. 7,
a resilient plate 27 may be forced against the top of tube 4 (not
shown in FIG. 7) by a pressure plate 28 retained against the
periphery of plate 27 and including a threaded tightening plug 29
having a tapered face for engaging ball pressure members 30.
Tightening of plug 29 presses on ball members 30 and in turn on
resilient member 27 pressing resilient member 27 against the top of
tube 4.
In FIGS. 8 and 9, an impact extrusion tube 906 is provided to
capture the sample by removing the cap 903 and exercizing the
piston 907 in and out, approximately 6 times to introduce a
representative sample, waiting a reasonable time interval on the
order of 5 minutes. The piston 907 may be discarded in that it too
is of an inexpensive impact extrusion construction. The cap 902 is
tightened to the base ring 902 by uniformly tightening socket head
cap screws 901, 911, etc. The torque is limited by use of smooth
surfaces on ring 902 and cap 903 to encourage hand slipping and by
use of a short (eg 3 inch) hex key wrench, not shown. A depression
912 is formed in the cap 903 to save weight for shipping. A "thumb
print" depression, not shown, may be formed in the side of the tube
906 to provide for gas expansion in the tube during shipping or the
like. This depression also prevents the piston 907 from moving
within the tube 906 during shipping. A closed threaded end 908 is
provided for adaption to the sampling fixture. The cap 903 is lined
with lead foil 913, or other similar soft inert material, which is
fastened to the cap 903 with double faced pressure sensitive tape,
not shown. When tightened by screws 901, 911, etc., the cap 903
swages the lead 913 into the sealing grooves 908, which are
preformed in the flange 908 of the tube 906 by a coining operation
using a master tool. Preferentially, the base ring 902 includes a
raised ring, not shown, which increases the unit stress for a given
load calculated so that the yield point of the lead is exceeded and
flow takes place. A paper insert 10 is provided to prevent shipping
damage to the lead or grooves. Preliminarily, a paper insert is
provided to overlay the meeting point between the grooves 908 and
the foil 913. When gas is to be sealed in the tube, the paper is
discarded and a seal as described above is achieved by tightening
the screws 901, 911, etc.
Finally, the embodiment of FIG. 10 shows an alternative to the one
of FIG. 9. In FIG. 10, the base ring 1002 is formed differently
from the one of FIG. 9, in that a small lip 1012 and a land area
1013 are utilized. This structure reduces sensitivity to over - or
undertightening the cap 1003. That is, the lip 1012 increases unit
stress to handle light assembly cases while the land area 1013
"bottoms" on the cap 1003 before the lip 1012 can cut through the
tube 1006 or the lead seal 1008 (such as for example, in cases of
heavy assembly pressures).
Having described my invention particularly with respect to specific
embodiments thereof, I should like it understood that the invention
is not necessarily limited to these specific embodiments, which
have been chosen primarily to illustrate a variety of designs
within the true spirit and scope of the present invention and with
which the objectives of the present invention can be met. It should
be understood, however, that this invention comprehends and the
appended claims are intended to be construed to include all other
modifications and variations of this invention as would be apparent
to those skilled in the art and within the true spirit and scope of
the present invention.
* * * * *