U.S. patent number 3,884,030 [Application Number 04/496,377] was granted by the patent office on 1975-05-20 for fibrillated foamed textile products and method of making same.
This patent grant is currently assigned to Monsanto Chemicals Limited. Invention is credited to Samuel Baxter, John Harold Gilbert.
United States Patent |
3,884,030 |
Baxter , et al. |
May 20, 1975 |
Fibrillated foamed textile products and method of making same
Abstract
A thermoplastic yarn is continuously produced from an extruded
cellular foam material which has been oriented in the direction of
extrusion by subjecting the oriented foamed material to forces
which break down the cell walls to form a three-dimensional
structure of interconnected fibre elements.
Inventors: |
Baxter; Samuel (Penhow,
EN), Gilbert; John Harold (Chepstow, EN) |
Assignee: |
Monsanto Chemicals Limited
(London, EN)
|
Family
ID: |
27546717 |
Appl.
No.: |
04/496,377 |
Filed: |
October 15, 1965 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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468269 |
Jun 30, 1965 |
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Foreign Application Priority Data
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Jul 17, 1964 [GB] |
|
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29324/64 |
Nov 30, 1964 [GB] |
|
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48527/64 |
Oct 28, 1964 [GB] |
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43936/64 |
Dec 1, 1964 [GB] |
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48726/64 |
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Current U.S.
Class: |
57/260; 28/140;
57/31; 57/246; 57/248; 57/907; 264/DIG.8; 264/103; 428/108;
428/397 |
Current CPC
Class: |
D01D
5/247 (20130101); D04H 13/00 (20130101); D02G
3/02 (20130101); Y10S 57/907 (20130101); Y10T
428/2973 (20150115); Y10T 428/24083 (20150115); Y10S
264/08 (20130101) |
Current International
Class: |
D01D
5/247 (20060101); D01D 5/00 (20060101); D02G
3/02 (20060101); D04H 13/00 (20060101); D02g
003/06 (); B29d 027/00 (); B32b 005/18 () |
Field of
Search: |
;57/31,34,140,155,157,167,157HS ;28/1.4F,1.4D,1,72,DIG.1
;264/53,321,168,290,291,51,54,288,289,103,DIG.8
;161/168,172,109,169,402,112,113,178 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Petrakes; John
Attorney, Agent or Firm: Ross, Jr.; J. Bowen Weinkauf;
Russell E.
Parent Case Text
The present application is a continuation-in-part of application
Ser. No. 468,269, filed June 30, 1965, by Samuel Baxter and John
Harold Gilbert, now abandoned.
Claims
What is claimed is:
1. An extruded thermoplastic yarn comprising a network of randomly
interconnected fibre elements generally residing longitudinally
with respect to the direction of extrusion, said fibre elements
being branched and being interconnected by having common branches
and at least portions of said fibre elements having a trilobate
construction in cross-section with respect to the direction of
extrusion said branched fibre elements and said trilobate
construction being formed by the breaking down of an extruded and
drawn cellular foam rod-shaped material, said rod shaped material
being drawn in the direction of extrusion.
2. The yarn of claim 1 wherein said yarn is provided with from 1 to
25 twists per inch.
3. The yarn of claim 2 wherein said yarn has a diameter of from
0.005 to 0.15 inches.
4. The yarn of claim 1 wherein a cross-section taken at right
angles to the axis of said yarn shows from 10 to 40% of said fibre
elements being branched.
5. The yarn of claim 4 wherein said fibre elements have a surface
area of between 0.05 and 1.5 square meters per gram.
6. The yarn of claim 5 wherein the average distance between points
of interconnection between the fiber elements is from 10 to 740
times greater than the average thickness of the fibre elements.
7. The yarn of claim 6 wherein the fibre elements are composed of a
thermoplastic material which is a synthetic polymer selected from
the group consisting of a polyamide, a polyester and a
polylactam.
8. The yarn of claim 6 wherein the fibre elements are composed of
polyethylene.
9. The yarn of claim 6 wherein the fibre elements are composed of
polypropylene.
10. The yarn of claim 6 wherein the fibre elements are composed of
polystyrene.
11. The yarn of claim 6 wherein the fibre elements are composed of
a copolymer of acrylonitrile and vinyl acetate.
12. A fabric woven from the yarn of claim 1.
13. A cord comprising a plurality of twisted yarn of claim 1.
14. A foamed, thermoplastic yarn structure comprising a plurality
of spaced apart, longitudinally extending fiber elements integrally
joined to one another by a plurality of spaced apart, cross fibers
to produce an integral net-like structure, the fibers of said
structure being characterized by internal voids throughout the
fibers, surface unevenness, and surface pits.
15. A foamed, thermoplastic structure comprising a plurality of
spaced apart, longitudinally extending fiber elements integrally
joined to one another by a plurality of spaced apart, crossed
fibers to produce an integral net-like structure, the fibers of
said structure being characterized by internal voids throughout the
fibers, surface unevenness, and surface pits.
16. A process for manufacturing a fibrous product comprising the
steps of:
a. forming a cellular thermoplastic structure with the cells having
been formed by the expansion of a blowing agent;
b. drawing said cellular thermoplastic structure at a ratio of at
least about 3:1 to orient said structure and increase its
longitudinal strength relative its transverse strength; and
c. forming a network of spaced apart and interconnected fiber
elements generally being aligned in the direction of drawing, said
fiber elements being branched and being interconnected by having
common branches, by subjecting said structure to fibrillating
forces such that the walls defining said cells are broken down and
are converted into said network of interconnected fiber elements.
Description
This invention relates to textile yarns, and particularly to
certain new yarns derived from polymeric materials.
It has been previously proposed to produce textile yarns from
polymeric resins by a process in which a molten resin or a solution
of the resin is extruded from a very small orifice and caused to
solidify by one means or another; this produces a monofilament of
the resin. A monofilament that is sufficiently thick and strong to
be woven into cloth is, however, normally rather inflexible, and in
order to improve the flexibility it is accordingly necessary to
produce relatively fine monofilaments which are then used in
conjunction to give the necessary strength. Sometimes for example
the fine monofilaments are chopped up to form a staple fibre which
is then spun.
A new kind of yarn has now been developed which possesses many of
the attributes required of a yarn but which can nevertheless be
produced directly by a process that avoids the necessity for the
separate production of fine monofilaments.
The process of the invention for the production of the yarn
comprises drawing a strand or ribbon of an extruded foamed
thermoplastic material so that it becomes orientated essentially in
the direction of extrusion and subjecting the drawn foamed material
to forces such that the walls of the foam are broken down and
converted into a three-dimensional structure of interconnected
fibre elements.
The yarn obtained in this way can if desired be used as such, for
example as a yarn in carpet production, because it is one of the
features of the yarn produced by the process of the invention that
the number of loose ends is small. The yarn can however optionally
be subjected to a conventional type of spinning operation before
use, in which instance it will have a certain amount of twist,
although this may be only very slight. Higher degrees of twist can
be applied if required, and for example a highly twisted yarn can
be produced.
The invention also includes a new yarn that is a threedimensional
structure of a multiplicity of interconnecting thermoplastic fibre
elements, the fibre elements being aligned substantially in the
direction of production of the yarn and some of them having
cross-sections that are branched.
A yarn that has been twisted can for example be defined as a yarn
comprising a three-dimensional structure of a multiplicity of
interconnecting thermoplastic fibre elements arranged substantially
as a series of helices having a common axis along the length of the
yarn, some of the fibre elements having cross-sections that are
branched.
Fibre elements are referred to and not fibres because in general
the elements in question are essentially interconnecting in
three-dimensions. Accordingly the number of loose "ends" in the
yarn is normally low, and the yarn contains few "fibres" as such,
that is to say fibres each of which has two ends.
FIG. 1 is a section view taken at right angles to the major axis of
the fibre and showing the trilobate construction of a fibre
element;
FIG. 2 is the section view of FIG. 1 showing the fibre element
having a double trilobate construction;
FIG. 3 is an enlarged plan view of the yarn of this invention;
FIG. 4 is a section view of the yarn of FIG. 3 taken at right
angles to the main axis of the yarn;
FIG. 5 is a front elevation view of the apparatus for breaking down
the cell walls of the extruded cellular foam material to form the
yarn of this invention; and
FIG. 6 is a side elevation view of the apparatus shown in FIG.
5.
Fibre elements that have a cross-section, at right angles to the
major axis of the fibre element, that is branched are present in
the yarn because the fibre elements are obtained from an orientated
foamed thermoplastic material by the partial disintegration or
break down of the walls of the cells or pores making up the foamed
structure. The fibre elements accordingly consist of the remains of
the cell walls, and because of this possess certain characteristic
features as described below. Fibres that have cross-sections that
are branched are derived from parts of the walls of several cells
that were present in the original orientated foamed material, and
the "branch" occurs where a fragment of the wall of one cell is
joined to fragments of the wall of an adjoining cell or cells. In
the simplest instance a branched cross-section of a fibre element
can be termed "trilobate," because it consist of three lobes or
arms, as is exemplified in the cross-sections shown in FIG. I,
which are taken at right angles to the major axis of the fibre
elements. Related but more complicated branched cross-sections can
consist of two or more trilobate crosssections joined together, as
for example shown in FIG. II. Crosssections such as are for example
exemplified in FIGS. I and II are those which can exist at one
point along the major axis of a fibre element, and a fibre element
does not necessarily possess constant cross-section along its
length. Not only does the cross-section usually change along the
length of a fibre element, but the fibre element itself is not
straight and parallel to the yarn as a whole. Accordingly a series
of cross-sections across a yarn taken at right angles to the
direction of production of the yarn will show the crosssection of a
given fibre element in a number of different forms.
In a typical cross-section of a yarn the number of crosssections of
fibre elements which are branched may be a minority, such as 30 or
40% or less, but nonetheless their presence (even to the extent of
from only 5 to 10% of the total) contributes a distinctive
character to the yarn. In certain instances the proportion of
branched cross-sections can be high (such as 60 or 70%), but in
many cases it will for example be in the range of 5 to 50%, for
instance from 10 to 40%, such as about 20%.
Because of the way in which they have been formed the fibre
elements are in the main "elongated" in cross-section. Very often a
cross-section of a fibre element contains at least one pair of
substantially parallel sides, although at least in the instance of
the fibre elements having a branched cross-section these parallel
sides will usually be curved. Other cross-sections may be
polygonal, for example quadrilateral, and can be rectangular or
essentially rectangular; more than four sides can however be
present. In considering a cross-section of a fibre element the
longer (or longest) dimension is taken as the breadth and the
smaller (or smallest) dimension is taken as the thickness. In
general terms the elongated cross-sections can have a breadth to
thickness ratio of from 3 to 1 to 20 to 1 or even more, such as for
example 30 to 1. A proportion, for example up to 50% of the total,
of the cross-sections can be compact, for example essentially
square; often the number of compact cross-sections is small.
A further characteristic of the fibre elements of the yarns of the
invention can be expressed as their surface area in square metres
per gram. This can for example range from 0.04 to 1.5, particularly
from 0.05 to 1.0. Useful yarns may for example contain fibre
elements having a surface area of between 0.1 to 0.5, such as, for
instance, about 0.2 or 0.3. In certain instances the surface area
can be higher, such as up to about 2.0 square metres per gram. The
surface areas can be controlled by operation of the process of
production of the yarns, for instance a higher density foamed
material normally results in a yarn having a lower surface
area.
The thickness of the fibre elements is often in the range of from
0.0001 to 0.004 or 0.005, for example, between 0.0002 and 0.003
inch; it can, for instance, be between 0.0004 and 0.002 inch, such
as about 0.0006 or about 0.001 inch.
The average distance between points of interconnection as referred
to above can be for example from 5 or 10 to 750 times the average
thickness of the fibre element or slightly more, for instance up to
1,000 times the average thickness. For example, useful yarns are
obtained when the average distances between points of
interconnection of fibre elements are from 20 to 500 times the
average fibre element thickness, such as from 50 to 300 times. A
distance of about 100 or 200 times the average thickness of the
major fibre elements is often characteristic. In absolute terms the
distance between points of interconnection is often in the range of
0.01 to 0.5 inch, such as from 0.02 to 0.3 inch, for instance, from
0.05 to 0.1 or 0.2 inch.
The yarns can be produced continuously and they can in any event be
obtained in any length convenient for the intended purpose. Their
cross-sections are those usual for yarns, and are normally compact.
In special instances, for example where the yarn is to be
subsequently twisted, the yarn cross-section can be more elongated,
for instance it can be an elongated rectangle, and the yarn then
can be in the form of a ribbon or strip, normally a narrow one.
Such a ribbon or strip might for example be up to one-fourth inch
wide. Where the yarn has the more normal compact cross-section this
can be a circular or similar cross-section and can vary within wide
limits; in general it will be at least 0.005 inch and can for
instance be from 0.01 to 0.15 inch or more, such as from 0.02 to
0.05 or 0.1 inch. Thicker yarns can have a diameter up to perhaps
0.25 inch. Yarns having diameters in the upper part of this range
are useful in the production of certain coarse fibre or yarn
products. In terms of denier, that is to say the weight in grams of
900 meters of yarn, the yarns of the invention can for instance
have values in the range of 15 to 25,000 , for example in the range
of 100 to 1,000, such as 200 to 500.
Where the yarn has been twisted, the common axis of the helices is
normally coincident with the axis of the yarn, and the helices can
for example have between 1/2 or 1 and 25 turns per inch, for
example from 2 to 12 turns per inch (such as from 4 or 6 to 10
turns per inch). The twisted yarns have a cross-section that is
substantially circular. A yarn having a low degree of twist is in
general softer than one where the degree of twist is high.
If the yarn of the invention is to be twisted this can be carried
out in any convenient way, and it can be performed as the extruded
material is partially disintegrated or as a separate operation. In
some instances the two procedures can be combined together in a
single step. One yarn can be twisted to give a oneply twisted yarn,
or two or three or more yarns can be produced and twisted together
to give yarns consisting of several plies. The twisted yarns can if
necessary be heat-set or wound under tension as in the conventional
practice.
The process of the invention also includes a modification in which
the yarns are produced by cutting or dividing up a band or web of
the appropriate three-dimensional structure of interconnected fibre
elements. In this modification the drawn foamed material will of
course have a cross-section that is greater than that of the
desired yarn, the drawn material is broken down and converted into
a three-dimensional structure of interconnected fibre elements, and
this structure is divided up longitudinally into a number of yarns
having the required cross-sections. Yarns produced in this way can
for example usefully be twisted together as described in the
preceding paragraph.
Some indication of the nature of the yarns of the invention is
given by the accompanying Drawings, where:
FIG. 3 -- shows a magnified (.times. 120) representation of the
plan view of a yarn, and
FIG. 4 -- shows a magnified (.times. 200) view of a portion only of
the same yarn along a cross-section taken at right angles to the
direction of extrusion.
It can be seen from FIG. 3 that a large number of interconnections
are present, and that in relation to the average thickness of the
fibre elements, the interconnections are relatively close together.
The portions of fibre elements which in FIG. 3 appear as ends were
not necessarily in that state in the yarn. Some of the ends were
formed when the small portion of material was broken away from the
yarn for examination, whilst others are not in fact loose ends at
all; they are portions of fibre elements which are curved and whose
remaining portions are aligned either directly towards or directly
away from the field of view. In FIG. 3 the distances between many
of the major points of interconnections are about 0.01 inch. FIG. 4
shows the presence of cross-sections (about 20% of the total) that
are "branched".
In general the new yarns of the invention have excellent
flexibility, and are capable of being woven into cloth and textile
materials, and of being converted into fibre and yarn products, for
instance nets, ropes and twines. The strength in the direction of
production is good, and as has been made clear virtually all the
fibre elements are interconnecting throughout the three-dimensional
structure of the yarn. The fibre elements are aligned substantially
in a similar direction, but this does not of course mean that they
are all aligned in precisely the same direction. The general
appearance of a yarn as produced by the process of the invention is
that it contains fibre elements which are substantially parallel,
as they might be for example in a yarn having an essentially
net-like form. In practice this means that the fibre elements are
aligned substantially in the direction of production of the yarn.
In general the yarns are attractive in appearance; for example they
often possess a sheen on the surface.
The thermoplastic material from which the yarn is derived is one
capable of being formed into an extruded foam; it is in practice
usually a synthetic material, and one that is fibre-forming.
Excellent results are obtained with a thermoplastic synthetic
material, for example a polymer or copolymer obtained by
polymerisation (which includes copolymerisation) of an
ethylenically unsaturated monomer. Such a monomer can be an
ethylenically unsaturated hydrocarbon, but it can be for instance a
nitrile, such as acrylonitrile, or methacrylonitrile; vinyl or
vinylidene chloride; a vinyl ester, such as vinyl acetate; or an
acrylate ester, such as ethyl acrylate or methyl methacrylate.
Where the monomer is a hydrocarbon this can be a mono-olefin, a
diene, or a vinyl-substituted benzene, for instance ethylene,
propylene, a butylene, a pentene or a hexene; butadiene; or a
vinyl-substituted benzene, such as styrene or
.alpha.-methylstyrene. For example the polymer can be polyethylene
(low density or high density material), crystalline polypropylene,
or polystyrene or a toughened polystyrene. A copolymer can be, for
instance, one involving two or more, such as three, of any of the
monomers referred to above. A comonomer can be, for instance, one
of a type which will impart a degree of flame-retardance to the
copolymer, and an example of such a substance is a vinyl halide,
such as vinyl chloride, vinyl bromide or vinylidene chloride.
Examples of other comonomers are vinylpyrollidone and a
vinylpyridine such as methylvinylpyridine. A copolymer can be for
example one derived from two hydrocarbon monomers, such as an
ethylene-propylene or a styrenebutadiene copolymer; or a
hydrocarbon and a different type of monomer, such as an
ethylenevinyl acetate copolymer; or a copolymer derived from
dissimilar monomers such as for example acrylonitrile and a minor
proportion of vinyl acetate. The thermoplastic material can also
consist of a mixture of two or more polymers or copolymers; it can
for example comprise a mixture of a copolymer of acrylonitrile with
a minor amount of vinyl acetate, for instance, about 10% by weight,
and polyvinyl chloride; or a mixture of an acrylonitrile-vinyl
acetate copolymer and a copolymer of acrylonitrile with
methylvinylpyridine. Preferably the polymer is a thermoplastic
resin material, but it can be an elastomeric material, for instance
a copolymer derived from sufficient of a diene monomer, such as
butadiene, to impart some degree of elastomeric properties to the
copolymer; natural rubber; or a synthetic rubber such as for
instance a polybutadiene, styrene-butadiene or
acrylonitrilebutadiene rubber. A thermoplastic resin material can
be non-crystalline, as in amorphous polystyrene, or crystalline, as
in crystalline polyethylene or polypropylene. Other types of
synthetic materials that can be employed include polyamides, such
as for example nylon 11, nylon 610 and nylon 66; polyurethanes;
polylactams, such as a polycaprolactam; and polyesters, such as of
the polyethylene terephthalate type. Where the thermoplastic
material is regenerated natural fibre it is preferably one based on
cellulose, for example rayon, cellulose acetate, cellulose
triacetate or cellulose acetate-butyrate.
In the process of the invention the starting material is an
extruded foamed polymeric material, and if desired this can be
produced by conventional extrusion techniques. However it is
produced the extruded strand or ribbon of foamed material has a
cross-section consistent with the ultimate aim of producing a yarn.
The extruded strand, which includes a rod or ribbon, can be of
virtually any relatively compact cross-section, but often the
cross-section is circular or substantially circular, although it
can also be square or rectangular. Where the yarn is for example to
be twisted it can if desired have a less compact cross-section, and
hence the extruded foamed material can (although this is not
essential) have a cross-section that is a more elongated rectangle
or similar shape, and the extruded material can then be a ribbon or
strip, although a relatively narrow one. If desired, a suitable
strand or ribbon can be obtained by slitting longitudinally a sheet
or board of a drawn extruded foamed material. In general, and by
way of example, where the extruded strand has a circular or roughly
circular cross-section the average diameter can be between 0.1 and
1 inch for instance between 0.2 to 0.5 inch. The density of the
foamed material can for instance be between 1 pound and 10 pounds
or more per cubic foot, such as from about 2 to 4 or 5 pounds per
cubic foot. The fact that the starting material is foamed can also
be expressed in terms of the volume fraction of voids that it
contains, and this can be as low as 0.5. However, in practice the
volume fraction of voids is often not less than 0.9, so that the
range can for instance be from 0.95 to 0.985, for instance from
0.96 or 0.97 to 0.98. A volume fraction of voids of 0.5 is equal to
a ratio of the volume of foam over the volume of thermoplastic
material it contains of two to one.
In general in the production of the extruded foamed thermoplastic
material the blowing agent will be a low boiling substance or a
chemical blowing agent. The foamed material usually contains closed
cells, although material (for instance polyethylene) can be
employed which contains cells which to some extent are
interconnecting or "open". In many instances the agent is a
volatile substance, and is often one that is a gas or vapour under
normal atmospheric conditions (such as 20.degree.C. and 1
atmosphere pressure), but which while under pressure before
extrusion will be present in solution in the molten or semi-molten
thermoplastic material. The blowing agent can however be one, such
as pentane or a pentane fraction, which is a volatile liquid under
normal conditions. Examples of volatile substances that can be used
include lower aliphatic hydrocarbons, such as methane, ethane,
ethylene, propane, a butane, or a pentane; low alkyl halides, such
as methyl chloride, trichloromethane or
1,2-dichlorotetrafluorethane; acetone; and inorganic gases, such as
carbon dioxide or nitrogen. The lower aliphatic hydrocarbons,
especially butane, are useful in respect of polyolefinic materials,
such as polystyrene and polyethylene. The blowing agent can also be
a chemical blowing agent, which can for example be a bicarbonate
such as for example sodium bicarbonate or ammonium bicarbonate, or
an organic nitrogen compound that yields nitrogen on heating, such
as for example dinitrosopentamethylenediamine or barium
azodicarboxylate. From 3 to 30%, especially 7 to 20%, by weight
based on the weight of the thermoplastic material is often a
suitable proportion of blowing agent, and for example the use of
from 7 to 15% by weight of butane in conjunction with a
polyolefinic material has given excellent results. Sometimes the
blowing agent will be employed in conjunction with a nucleating
agent, which assists in the formation of a large number of small
cells. A wide range of nucleating agents can be employed, including
finely-divided inert solids such as for example silica or alumina,
perhaps in conjunction with zinc stearate, or small quantities of a
substance that decomposes at the extrusion temperature to give a
gas can be used. An example of the latter class of nucleating
agents is sodium bicarbonate, used if desired in conjunction with a
weak acid such as for example tartaric acid or citric acid. A small
proportion of the nucleating agent, for example up to 5% by weight
of the thermoplastic material, is usually effective. A plasticiser
can also be present where this is appropriate.
The drawing operation is preferably conducted on a continuous basis
(although this is not essential), and the step of breaking down the
foam may follow immediately or it may be carried out subsequently,
for instance on discrete lengths of drawn foamed material. The
extruded foamed thermoplastic material is drawn along the extrusion
direction, and in doing so it is orientated unidirectionally
(uniaxially) and the cells of the foam are elongated. The drawn
material usually has a slightly higher density than the material
before drawing. The precise conditions that are necessary in the
drawing operation to achieve the required results depend on the
particular thermoplastic material that is employed, but in general
draw-down ratios of from 20:1 to 2:1 have been found useful, for
example from 15:1 to 3:1. Good results have been obtained with a
ratio between 12:1 and 5:1, for instance from 10:1 to 7:1. The
temperature employed again depends on the particular thermoplastic
material, but it is an elevated one in most instances, for example
above 40.degree.C. or 50.degree.C. and up to 130.degree.C. or
140.degree.C. or rather more in some cases. A temperature in the
range of 80.degree.C. to 100.degree.C. such as about 90.degree.C.,
is often useful. In principle it is desirable for the foamed
material to be heated to a moderately elevated temperature, not
high enough to damage the foam structure but high enough for the
material to be sufficiently ductile. For instance, extruded foamed
styrene can be drawn at from 120.degree.C. to 140.degree.C., while
for foamed high density polyethylene a temperature between
40.degree.C. and 100.degree.C. is preferable. An amorphous
thermoplastic material should normally be drawn above its glass
transition temperature, whilst a crystalline thermoplastic material
can be drawn at a temperature lower than its crystalline melting
point. If the foamed material is still hot from the extrusion
operation it may need to be cooled before it is possible to draw it
in a subsequent operation, but in the more normal course of events
a foamed material needs to be heated to a suitable temperature
before it can be drawn, because for example even in a continuous
operation the temperature of the foamed material can have dropped
too low by the time it is possible to draw it. The heat treatment
that is applied is as has been explained such that the extruded
foam is sufficiently ductile to be drawn, and this can involve for
instance either heating the foamed material at a steady
temperature, or subjecting it to a relatively high temperature
(perhaps as high as 200.degree.C.) for a short time followed by a
period (normally longer) at a lower temperature. For example a
foamed material that is produced in a form which has an outer
"skin" of material (which has a higher density than the inner
material) may give better results with a heat treatment which
involves a short initial period at a higher temperature. This
initial treatment can be useful in the instance of a thermoplastic
material such as crystalline polypropylene, and can be as short as
a few seconds. The precise conditions necessary in order to ensure
that a foamed material is in a condition suitable for drawing can
easily be found by simple experiments. In general any convenient
method of applying heat can be employed. For example the extruded
foamed material can passed through hot air or some inert gas, or
through a heated bath of suitable inert liquid, such as water,
glycerol or ethylene glycol. In certain instances the drawing can
be performed at room temperatures, for example with nylon
materials.
After the foamed thermoplastic material has been drawn it is
partially disintegrated to the yarn, i.e. it is broken down into
the three-dimensional network of interconnected fibre elements. In
this operation the walls of the elongated cells of thermoplastic
material are broken down or "fibrillated" to give fibre elements.
The solid three-point connections at the ends of the cells are in
some instances the junction points of a number of interconnecting
fibre elements. The disintegration can for example be effected by
mechanically working the drawn material so that some shear is
applied to it, preferably in a transverse direction, and several
ways of doing this can be employed, including rubbing, rolling,
twisting, shaking, beating or otherwise subjecting the material to
forces tending to draw it laterally at right angles to the
direction of orientation. For example there can be employed a
reciprocating "nip" in conjunction with an adjacent stationary nip,
as is described later. Other methods can entail use of two
cylindrical brushes, one stationary and one revolving; a hammer
mill; and moving rubber surfaces, in the form of plates, belts or
rolls. Ultrasonic vibrations can also be used, or suitable directed
jets of air. In general in the instance of thermoplastic resins the
temperature at which the partial disintegration is carried out is
room temperature, 20.degree.C., or somewhat higher perhaps up to
30.degree.C. In the instance of certain specific thermoplastic
resins, particularly those which possess a degree of elasticity and
are therefore relatively tough, and of elastomeric materials in
general, the temperature used is normally lower then room
temperature, for instance 5.degree.C. or 0.degree.C. or even
lower.
The reciprocating and stationary nips referred to above can in
practice for example consist of two pairs (1 and 2) of metal bars
as shown in end elevation in FIG. 5 an in side elevation in FIG. 6.
The bars 1 and 2 are of square cross-section, with radiused edges,
and each pair consists of two similar bars mounted vertically above
each other. The bars in each pair are maintained lightly in contact
by means of the spring-loaded guides 3. The left hand pair of bars
1 are stationary, and are maintained in contact with the bars 2 by
the action of a leaf spring 4. Supporting means (not shown) are
provided for supporting the assembly of bars. The bars 2 are moved
reciprocally up and down by the freely-moving vertical plunger 5,
which is driven by a circular eccentric 6 on the shaft of an
electric motor (not shown). The drawn foamed material moves through
the bars from right to left, by means of the pair of driven rollers
7.
The three-dimensional network of fibre elements as obtained by
breaking down the drawn foam can be disintegrated to a greater or
lesser extent, to give yarns which are potentially more or less
voluminous respectively. The yarns as produced can if desired to
"teazed out" to give bulkier and lighter-weight products, and this
operation can be carried out by conventional textile means, for
instance mechanically, such as by corrugated rollers, or by use for
example of air jets.
In certain of the yarns some of the fibre elements may be present
as "bundles," with some of the component fibres being
interconnected to the fibres of adjacent bundles. The bundles occur
particularly where the yarn has been produced using only a low
degree of disintegration of the drawn extruded foam.
Additional operations, for example dyeing or sizing, can be carried
out on a yarn of the invention if desired.
The invention is illustrated by the following Examples.
EXAMPLE 1
This Example described a new high density polyethylene yarn of the
invention and a process for its production.
The starting material was a strand, or rod, of foamed high density
polyethylene having a circular cross-section of diameter 0.4 inch,
which had been produced by extrusion, through an orifice die 0.1
inch in diameter and of "land" 0.3 inch, of a foamable polyethylene
composition containing 100 parts by weight of a high density
polyethylene of density 0.96 grams per cc., 12 parts by weight of
butane as blowing agent, and 1 part of finely-divided silica as a
nucleating agent. The foamed strand was passed through an ethylene
glycol bath at about 110.degree.C. and whilst at this temperature
was drawn in the longitudinal direction to approximately 10 times
its original length; this caused orientation in a longitudinal
direction of the cells of the foamed polyethylene. The drawn
material was allowed to cool to room temperature, and was subjected
to a shearing action from the reciprocating motion of a nip (of the
type described above and shown in FIGS. 5 and 6) through which the
orientated foamed polyethylene was passed. This procedure resulted
in the yarn of the invention.
The bars 1 and 2 of the nip assembly were of polished aluminium,
and each was 4 inches long with a cross-section of one-fourth inch
by one-fourth inch. The speed of the electric motor was 1,400
revolutions per minute, and the vertical movement of the bars 2 was
one-half inch. The foamed drawn thermoplastic material was passed
through the nip assembly at a linear rate of 2 feet per minute.
This yarn was very flexible and possessed a useful tensile
strength; it could be employed as a twine or made use of as a yarn
in weaving a cloth. The yarn consisted of a mass of high density
polyethylene fibres that were interconnected in three dimensions at
a large number of points. The fibres were substantially parallel to
the length of the yarn (although there were many "bridging" or
interconnecting fibres that were not parallel to the main body of
fibres), and there were very few unconnected or "loose" ends of
fibre. The fibre elements had on average a mean thickness of about
0.001 inch, and their appearance was substantially as shown in
FIGS. 3 and 4. The average surface area of the fibre elements was
0.35 square metres per gram.
A sample of the yarn was twisted to the extent of 10 turns per inch
to give a twisted yarn with an average diameter of 0.06 inch; again
it was flexible with an excellent tensile strength.
A further sample of the yarn as produced was twisted to the extent
of 4 turns per inch, and then three lengths of this were twisted
together to the extent of 6 turns per inch. The resulting product
was doubled and twisted again to the extent of 6 turns per inch.
The denier of this 2 .times. 3 ply yarn was 4,600, and its tensile
strength was 1.2 gram per denier.
Using as starting material a foamed strand of diameter 0.07 inch,
the other conditions being similar, there was produced a finer
yarn. In twisted form this had an average diameter of 0.01
inch.
EXAMPLE 2
This Example describes a new yarn obtained from crystalline
polypropylene, having a melt index of 0.3.
Extruded foamed polypropylene was obtained by extrusion of a
mixture of the polypropylene and 12% by weight of butane. A 1 inch
extruder was employed, with a circular aperture of diameter five
sixty-fourths inch, the land being one-half inch long. The
extrusion temperature was 140.degree.C. and the die pressure 1,000
pounds per square inch. The resulting foamed polypropylene
consisted of a rod of material about one-half inch in diameter
having a density of 1.28 pound per cubic foot; the material was
fairly flexible, with a silvery skin.
The foamed material was heated by passing it through a zone fitted
with electric heaters; the heat treatment was for 15 seconds at
250.degree.C. The temperature was then allowed to fall to
90.degree.C., and at this temperature the material was drawn at a
rate of 7,000% per minute to give an elongation of 1,300%.
The extruded drawn material was cooled to room temperature and then
passed through the reciprocating nip referred to in Example 1.
There resulted in a length of very flexible yarn having a thickness
of about 0.08 inch, and consisting of a mass of interconnected
fibre elements having a few loose ends. The surface area of the
yarn was 0.26 square metres per gram. As produced the yarn
possessed a useful tensile strength, of 4 - 5 pounds at
90.degree.C. and 10,000% per minute rate of elongation. The
thickness of the fibre elements varied between 0.0008 and 0.006
inch and the breadth between 0.0076 and 0.112 inch. The tensile
strength could be increased by twisting the yarn, for instance in
the range of 1/4 to 10 turns per inch.
Three lengths of the yarn as produced were each twisted to the
extent of 4 turns per inch and then twisted together to the extent
of 6 turns per inch. The resulting 3 ply yarn had a denier of 8,150
and a tensile strength of 1.9 per denier.
EXAMPLE 3
This Example describes a yarn of the invention produced from
polystyrene.
The starting material was a long rod of foamed polystyrene which
had been produced by extrusion through a circular die of a foamable
polystyrene composition containing a butane blowing agent and
finely-divided silica as a nucleating agent. The rod of foamed
polystyrene, which was one-half inch thick and had a density of 2
pounds per cubic foot, was passed through a bath of glycerol at
130.degree.C. and whilst at this temperature was drawn to 6 times
its original length. This caused orientation in a longitudinal
direction of the cells of the foamed polystyrene, which was now
about 0.1 inch in diameter.
The drawn foamed material was cooled to room temperature and passed
through the reciprocating nip referred to in Example 1. The
resulting yarn possessed an attractive white "satiny" sheen and it
was very flexible. It consisted of a mass of polystyrene fibre
elements that were interconnected in three dimensions at a large
number of points. The fibre elements were substantially parallel to
the direction of extrusion, although there were many "bridging" or
interconnecting fibre elements that were not parallel to the main
body, and there were very few loose ends.
An increase in tensile strength was achieved by twisting the yarn
to the extent of 10 turns per inch.
Similar polystyrene yarns were obtained from a web 0.1 inch thick
of the interconnected fibre elements, which had been produced by
drawing a sheet of extruded foamed polystyrene and then breaking
down the walls of the foam. The web was cut longitudinally into
narrow ribbons each one-fourth inch wide, three of which could be
twisted together to give a yarn.
EXAMPLE 4
This Example describes a new fibre assembly obtained from a nylon,
which was a copolymer type having a low melting point
(160.degree.C.) and known as a 6, 6:6 and 6:10 copolymer; it was
sold under the trade-mark Maranyl DA. This nylon copolymer
comprised an interpolyamide of caprolactam, hexamethylene adipamide
and hexamethylene sebacamide.
Foamed material was obtained by extruding a mixture of the nylon,
5% by weight of acetone and 2% by weight of finely-divided silica
through a circular die of diameter 3/32 inch, using a 11/2 inch
extruder; the die temperature was 131.degree.C. and the pressure
1,200 pounds per square inch. The cooled extruded foamed strand had
a diameter of about one-fourth inch.
The foamed strand was heated to a temperature of 60.degree.C. in a
hot air oven, and then was drawn to over 1000% at 1000 - 10,000%
per minute rate of elongation.
The surfaces of the drawn extruded strand were moistened with ethyl
alcohol, and then passed through the mechanical nip described in
Example 1 to give a length of yarn having a three-dimensional
structure of interconnected nylon fibre elements.
* * * * *