U.S. patent number 3,882,877 [Application Number 05/352,868] was granted by the patent office on 1975-05-13 for filter for tobacco smoke.
This patent grant is currently assigned to Rothmans of Pall Mall Canada Limited. Invention is credited to Warren A. Brackmann, Daniel DiIanni.
United States Patent |
3,882,877 |
Brackmann , et al. |
May 13, 1975 |
Filter for tobacco smoke
Abstract
A tobacco smoke filter, particularly for use in cigarettes,
consists wholly of or includes elements consisting wholly of
non-crimped fibers of thermoplastic polymeric non-adsorbent
materials having a diameter less than 5 microns. A filter of this
type reduces tar and nicotine levels in the smoke to low values
while at the same time the filter has satisfactory draw properties
and the smoke has enhanced "taste."
Inventors: |
Brackmann; Warren A.
(Cooksville, Ontario, CA), DiIanni; Daniel (Toronto,
Ontario, CA) |
Assignee: |
Rothmans of Pall Mall Canada
Limited (Toronto, Ontario, CA)
|
Family
ID: |
10130320 |
Appl.
No.: |
05/352,868 |
Filed: |
April 20, 1973 |
Foreign Application Priority Data
|
|
|
|
|
Apr 26, 1972 [GB] |
|
|
19495/72 |
|
Current U.S.
Class: |
131/332; 131/340;
131/361; 131/341 |
Current CPC
Class: |
A24D
3/04 (20130101); A24D 3/08 (20130101) |
Current International
Class: |
A24D
3/00 (20060101); A24D 3/04 (20060101); A24D
3/08 (20060101); A24b 015/02 () |
Field of
Search: |
;131/261-269,10,10.5,10.7,10.9 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rein; Melvin D.
Attorney, Agent or Firm: Sim & McBurney
Claims
What we claim is:
1. A self-sustaining filter for tobacco smoke comprising a
plurality of filter elements, and including a substantially
airtight tubular holder, a pair of cylindrical cellulose acetate
filter elements positioned within and in contact with the inner
wall of the holder, said pair of filter elements being spaced apart
from each other to define a gap therebetween, said pair of filter
elements and said tubular holder combining to provide sufficient
crush-resistance to provide a self-sustaining filter, and a third
filter element consisting wholly of a plurality of
randomly-oriented, non-crimped, smooth-surfaced, solid fibers of a
thermoplastic polymeric non-absorbent material selected from
polyolefins, polyesters, polyamides and polystyrene, each of said
fibers having a uniform diameter less than about 5 microns, with
substantially all of the fibers being below 2 microns in diameter
and having an average fiber diameter of about 1 micron, the
majority of the said fibers being oriented transverse to the flow
of the tobacco smoke, said third filter element being positioned in
the gap between said pair of filter elements, said third filter
element having a diameter substantially that of said tubular holder
and being in engagement with said inner wall.
2. The filter of claim 1 wherein said thermoplastic polymeric
material is a nylon.
3. The filter of claim 1 wherein said thermoplastic polymeric
material is poly (methylmethacrylate).
4. The filter of claim 1 wherein said third filter element is in
the form of a disc.
5. The filter of claim 4 wherein the faces of said disc engage the
opposed ends of the pair of elements.
Description
FIELD OF THE INVENTION
This invention relates to filters for tobacco smoke, more
particularly to cigarette filters.
BACKGROUND TO THE INVENTION
Tobacco smoke essentially consists of a dispersion of solid and
liquid particles in air, and this dispersion will be referred to as
an aerosol in this specification. The aerosol is extremely stable
due to the small size of the particles concerned and hence gravity
has a negligible effect compared with the effect of convection
currents and Brownian movement. Tobacco smoke is thought to contain
constituents injurious to health and many suggestions have been
made of filters to at least partially remove constituents of the
smoke prior to entry into the smoker's mouth.
Tar and nicotine values of tobacco smoke entering the smoker's
mouth, ie. after filtration, are considered by Government bodies to
be a significant indication of the effectiveness of a filter to
remove injurious components of tobacco smoke. While it is possible
to achieve very low levels of tar and nicotine values in tobacco
smoke, frequently this is at the expense of taste and smoker
satisfaction. For example, the filter may not allow adequate
quantities of smoke to pass through the filter and hence the "draw"
of the cigarette may not be satisfactory to the consumer.
SUMMARY OF THE INVENTION
In accordance with the present invention there is provided a filter
for tobacco smoke which reduces tar and nicotine levels in the
smoke to low values while at the same time providing a filter
having satisfactory draw properties and enhanced "taste"
properties. Further, the invention is concerned with methods of
making the filter material.
Accordingly, the present invention is concerned with filters
consisting wholly of or including elements consisting wholly of
non-crimped fibers of thermoplastic natural or synthetic polymeric,
non-absorbent material, the fibers having a diameter less than 5
microns.
BRIEF DESCRIPTION OF DRAWING
The accompanying drawing is a part-sectional view of a cigarette
filter in accordance with one embodiment of the invention.
DESCRIPTION OF PREFERRED EMBODIMENTS
Tobacco smoke filters of polyolefin have been suggested heretofore
in U.S. Pat. No. 2,966,157. However, the fibers forming this prior
art filter medium have diameters considerably in excess of 5
microns and are crimped. If fibers having diameters greater than 5
microns are used, it is found that the superior tar and nicotine
removal values observed for the filters of the present invention
are not achieved for reasons outlined below.
Crimping of the filamentary material for tobacco smoke filters
usually is considered necessary in order to displace portions of
the individual filaments at angles to the axis of the filter tow so
that, in the filter, these displaced portions of the filaments will
be disposed across the flow path of the tobacco smoke for
intercepting the particles to be filtered from the smoke. The
crimping and crimp-deregistering operations are particularly
critical to the production of high quality filters from cellulose
acetate filaments and have been thought to be necessary for
polyolefins fibers, as described in U.S. Pat. No. 2,966,157
referred to above. However, such operations add materially to the
cost of production, and unless they are carried out with care,
products lacking in uniformity are apt to result. It has been found
that the filters of the present invention wherein micro-fine fibers
are used do not require the crimping of the individual fibers to
provide effectiveness.
As indicated above, the filter elements provided in accordance with
the present invention consist of a mass of noncrimped fibers of a
thermoplastic material in which the individual fibers have a
particle size less than 5 microns. The thermoplastic material
fibers used preferably have substantially all of the fibers below 2
microns diameter, more preferably the fibers have an average
diameter of about 1 micron. This element is positioned in the path
of the cigarette smoke and is found to provide superior tar and
nicotine reducing properties.
The mass of fibers in the filter element may be in the form of a
scrambled mass of long fibers which may be self-sustaining or a mat
of short fibers, generally supported on a tobacco smoke-permeable
backing.
The filter elements of the present invention when utilized with
cigarettes may be the sole filter element of the cigarette,
although this may provide some crush problems if a paper sleeve is
employed since the filter elements lack physical strength. The
required structural strength, however, could be provided by the use
of a plastic or cardboard sleeve.
In a preferred construction in accordance with this invention, the
filter element of this invention forms one element of a
multi-element filter. In accordance with this preferred aspect of
the present invention there is provided a cigarette filter element
comprising an outer sleeve, at least a pair of plugs of cellulose
acetate filter material, or other commonly employed filter
material, disposed within the sleeve in longitudinally spaced apart
relation and a filter element consisting of a mass of thermoplastic
fibers, each of the fibers having a diameter less than 5 microns
and positioned between the plugs.
In this way there is provided a filter element which has
substantially the strength of the conventional cellulose acetate
fiber filter and the enhanced tar and nicotine reducing properties
of the microfine polymeric fibers.
A cigarette filter in accordance with this embodiment of the
invention as shown in the accompanying drawing, wherein a
cylindrical filter 10, suitable for a cigarette, consists of three
elements. An outer sleeve 12 of cork paper, plastic or any other
convenient material, surrounds the elements. Two elements 14 and 16
constitute the majority of the length of the filter and are
constructed of conventional filter material, such as cellulose
acetate fibers. The elements 14 and 16 are longitudinally displaced
from each other a short distance and in the gap 18 is positioned a
third filter element 20. More than two such elements 14 and 16 may
be provided, if desired. The third filter element 20 consists of a
disc of a mass of polymeric fibers, each of which has a fiber size
less than 5 microns. Preferably, in the disc 20 the majority of the
fibers are positioned in the disc so that they are transverse to
the flow of tobacco smoke. The gap 18 usually is substantially
filled by the third filter element 20.
It will be seen that the filter disc 20 engages the inside wall of
the sleeve 12 and hence is positioned in such a manner that tobacco
smoke passing through the filter 10 all passes through the disc.
The element 20 may have other forms, for example, a ball or similar
mass of fibers positioned in the gap 18 and engaging the inner wall
of the sleeve 12. In order to have efficient reduction of tar and
nicotine levels from the smoke, it is necessary for the element 20
in whatever form it may take to be positioned in the path of the
tobacco smoke so that substantially all of the smoke passes through
the filter.
The precise mechanism whereby efficient filtration is achieved
using the filters of the present invention is not fully understood,
but the following theory is proposed. The diameter of the particles
of the smoke aerosol is about 0.1 to 0.6 microns. Due to the small
diameter of the fibers used in the filters of the present
invention, the particles collide with the fibers and are removed
from the aerosol. This action is in contrast to the situation when
the conventional thicker fibers are employed, typically in
conventional cellulose acetate filters and in the polyolefin fiber
filters proposed in U.S. Pat. No. 2,966,157 discussed above, in
which the particles are displaced by air flow slip lines round the
fiber and hence are not impinged on the fibers. Therefore, when
fibers of conventional filter fiber size are employed (typically
about 10 to 25 microns average diameter), the quantity of particles
removed from the aerosol is considerably less than when the filter
of the present invention is employed.
Conventional filter materials, such as cellulose acetate, absorb
materials from the aerosol, including tar and nicotine, and as
noted above have fibre sizes in excess of 10 microns. Therefore,
when a cellulose acetate cigarette filter is examined after use it
is found to be substantially dry, although stained. In contrast,
the filters provided in accordance with the present invention are
constructed of non-absorbent, thermoplastic fibres having fibre
sizes less than 5 microns and it is found that the filter material
of the invention after use is wet with impinged material removed
from the aerosol.
It is observed that the "taste" of tobacco smoke filtered using the
filter of the present invention is superior to that of
conventionally-filtered tobacco smoke. It is theorized that this
observed effect is due to the essentially different manner of
removel of material from the aerosol by the present invention as
compared with conventional filters. In the absorption of material
using cellulose acetate fibers, taste-producing volatile materials
may be absorbed in addition to the tar and nicotine, whereas in the
impingement of materials on fine diameter non-absorbent fibers when
the filters of the present invention are used, it is possible for
the flavorful volatiles to pass to the smoker's mouth.
The polymeric materials used in the filters of the present
invention may be any natural or synthetic thermoplastic material
capable of formation into the fiber diameters required in the
present invention. In addition, the material must be capable of
withstanding the temperature of the tobacco smoke without
substantial degradation and must be substantially inert to chemical
attack by the tobacco smoke. Typical examples of materials which
may be utilized to provide the fibers are polyolefins, polyesters
and polyamides. Polyolefins which may be employed include
polyethylene and polypropylene, or polymers of substituted olefins,
such as, polytrifluorochloroethylene. Many polyesters may be used,
such as polyethylene terephthalate. Among the polyamides which may
be utilized are nylon 6, nylon 66 and nylon 610. Other
thermoplastic polymeric materials also may be employed in the
filters of the invention, such as polystyrene, and
poly(methylmethacrylate. Fibers formed from copolymers also may be
used.
While generally the filter element consists of a mass of a single
polymeric material, it is possible to utilize a mass of fibers
which is a mixture of fibers of two or more polymeric
materials.
In the mass of fibers, the orientation of the fibers relative to
the stream of tobacco smoke may be varied. Althoug it is possible
to employ a mass of fibers in which the fibers are randomly
oriented, it is preferred to employ a mass of fibers in which the
individual fibers substantially are oriented transverse to the flow
of smoke. It has been found that statistically orienting the fibers
in this manner results in higher tar and nicotine removal than when
a randomly-oriented mass of fibers is employed.
The filters of the present invention may be formed in any
convenient manner. For example, fibers may be melt spun from a die
having a plurality of openings therein, so that a mass of fibers is
extruded. The mass may be collected and used as such, or may be
subjected to physical treatment before use. Polymeric materials
having low melting points and low melt viscosities are preferred
since the heat required in the spinning operation thereby may be
minimized.
EXAMPLE
The invention is illustrated further by the following Example.
EXAMPLE
Cigarettes were tested in a smoking apparatus capable of collecting
and measuring total particulate solids which includes tar and
nicotine, in smoke. Cigarettes tested, at the same pressure drop
along the length thereof, were a cigarette with no filter, a
cigarette with a conventional cellulose acetate filter and a
cigarette with a filter including a disc of Acrylite fibers having
an average diameter about 1 micron. The results are reproduced
below:
Total Particulate solids ______________________________________
cigarette with Acrylite fiber filter 8.4 mg cigarette with
cellulose acetate filter 16.5 mg cigarette with no filter 30.5 mg
______________________________________
These results show the effectiveness of a filter constructed in
accordance with the present invention in removing tar and nicotine
from cigarette smoke as compared to a conventional filter and no
filter at all.
While the invention has been described with particular reference to
cigarettes, the filters provided by the present invention may be
utilized with other tobacco smoking articles, such as, pipes and
cigarette and cigar holders.
Modifications are possible within the scope of the invention.
* * * * *