U.S. patent number 3,879,297 [Application Number 05/295,979] was granted by the patent office on 1975-04-22 for liquid fire extinguishing composition.
This patent grant is currently assigned to Rhone-Progil. Invention is credited to Antony Roland Guillemont, Philippe Languille, Jean-Pierre Remond, Jean-Claude Vitat.
United States Patent |
3,879,297 |
Languille , et al. |
April 22, 1975 |
Liquid fire extinguishing composition
Abstract
Liquid fire extinguishing composition formulated to contain 50%
to 99.9% by weight of one or more fire extinguishing halogenated
aliphatic hydrocarbons and 0.1% to 20% by weight of one or more
polysiloxanes which may or may not include a solvent for the
polysiloxane and a pressurizing agent.
Inventors: |
Languille; Philippe
(Courbevoie, FR), Vitat; Jean-Claude (Bourg-la-Reine,
FR), Guillemont; Antony Roland (Bourg-la-Reine,
FR), Remond; Jean-Pierre (Massy-Villaine,
FR) |
Assignee: |
Rhone-Progil (Paris,
FR)
|
Family
ID: |
9084095 |
Appl.
No.: |
05/295,979 |
Filed: |
October 10, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Oct 8, 1971 [FR] |
|
|
71.36238 |
|
Current U.S.
Class: |
252/8 |
Current CPC
Class: |
A62D
1/0057 (20130101); C08K 5/02 (20130101); C08K
5/02 (20130101); C08L 83/04 (20130101) |
Current International
Class: |
A62D
1/00 (20060101); C08K 5/00 (20060101); C08K
5/02 (20060101); A62d 001/00 () |
Field of
Search: |
;252/8 ;260/33.8SB |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Sebastian; Leland A.
Claims
We claim:
1. A liquid fire extinguishing composition consisting essentially
of from 50% to 99.5% by weight of at least one fire extinguishing
halogenated aliphatic hydrocarbon selected from the group
consisting of fluorohalogenated C1-C5 aliphatic hydrocarbon, ethyl
bromide, chlorobromomethane and bromoform, from 0.5% to 20% by
weight of at least one polysiloxane, 0 to 49.9% by weight of a
polysiloxane solvent, and 0 to 49.9% by weight of a pressurizing
agent, and in which the amount of polysiloxane solvent and/or
pressurizing agent does not exceed 4% by weight of the fire
extinguishing composition when the polysiloxane solvent and
pressurizing agent are inflammable.
2. A composition as claimed in claim 1 in which the polysiloxane is
straight chained and is represented by the formula: ##SPC7##
in which each R is a hydrogen atom or a group having the formula
##SPC8##
in which R.sub.1, R.sub.2 and R.sub.3 is selected from the group
consisting of a C.sub.1-3 alkyl, C.sub.6 or C.sub.10 aryl,
C.sub.7-9 aralkyl and C.sub.7-10 alkaryl radical unsubstituted or
substituted by one or more halogen atoms, X is a halogen atom, y is
O or an integer from 1 to 3, and n is 0 or an integer from 1 to
7000.
3. A composition as claimed in claim 1 in which the polysiloxane is
cyclic and is represented by the formula: ##SPC9##
in which X is a halogen atom, y is 0 or an integer of from 1 to 3
and m is 0 or an integer of from 1 to 20.
4. A composition as claimed in claim 1 in which the solvent is
selected from the group consisting of a C.sub.1-3 halogenated
aliphatic hydrocarbon (other than a C.sub.1-3 fire-extinguishing
halogenated aliphatic hydrocarbon), a C.sub.2-12 aliphatic
hydrocarbon, a C.sub.6-10 aromatic hydrocarbon, a complex mixture
of hydrocarbons, a C.sub.6-10 cycloaliphatic hydrocarbon, a
C.sub.3-7 carbonyl compound, a C.sub.2-5 aliphatic acid ester, a
C.sub.2-6 ether, a C.sub.2-18 hydroxyl compound, and a cyclic
ether.
5. A composition as claimed in claim 1 in which the
fire-extinguishing halogenated aliphatic hydrocarbon is a C.sub.1-5
chlorofluorinated, bromofluorinated or bromochlorofluorinated
aliphatic hydrocarbon.
6. A composition as claimed in claim 5, in which the
fire-extinguishing halogenated aliphatic hydrocarbon is a
chlorofluorinated, bromofluorinated or bromochlorofluorinated
methane.
7. A composition as claimed in claim 1 in which the
fire-extinguishing halogenated aliphatic hydrocarbon is selected
from the group consisting of trichlorofluoromethane,
1,1,2-trichloro-1,2,2-trifluoroethane, bromotrifluoromethane,
bromochlorodifluoromethane, 1,2-dibromo-1,1,2,2-tetrafluoroethane,
1,2-dibromohexafluoropropane or 3-bromo-1,1,1-trifluoropropane.
8. A method of extinguishing a fire with or without a flame
comprising projecting from a container onto the fire a liquid
composition of claim 1.
Description
This invention relates to liquid fire extinguishing compositions
based on halogenated aliphatic hydrocarbons.
Because of their high fire-extinguishing capacity, various
halogenated derivatives of C.sub.1-3 aliphatic hydrocarbons have
been used to extinguish fires, especially of liquid hydrocarbons or
flameless fires, such as those caused by defective electrical
installations. However, irrespective of the conditions under which
they are used, the distance from which these fire extinguishing
agents can be employed for extinguishing a fire is limited.
It has been proposed that the volatility of fire-extinguishing
halogenated aliphatic hydrocarbons might be reduced by adding to
the composition high boiling point liquid or solid chlorinated
hydrocarbons such as hexachloroethane, perchloronaphthalene,
hexachlorobenzene and perchlorotriphenylbenzene. However, such
chlorinated hydrocarbons usually have only a low solubility in the
fire-extinguishing halogenated aliphatic hydrocarbons used as
fire-extinguishing agents. In order to increase the solubility of
such chlorinated hydrocarbons in the fire-extinguishing
compositions, it has been proposed to include a solvent, such as
trichloroethylene, in the compositions. However, such solvents have
little if any fire-extinguishing action and therefore their
inclusion in the compositions causes a dilution of the efficiency
of the fire-extinguishing compositions.
It has also been proposed that from 0.5% to 10% by weight alkyl
ethers of cellulose might be added to the fire-extinguishing
agents. However, since cellulose alkyl ethers are almost insoluble
in halogenated hydrocarbons, the cellulose alkyl ethers must be
suspended in the halogenated hydrocarbons and, consequently, such
ethers do not satisfactorily reduce vaporization of the
extinguishing agents.
It is an object of this invention to remedy the above mentioned
disadvantages by providing a fire-extinguishing composition that
has a much greater capacity for penetrating into the seat of a fire
and can therefore be used to combat a fire from a considerably
greater distance than known fire extinguishing compositions.
The invention provides a liquid fire-extinguishing composition
comprising from 50% to 99.9% by weight of one or more
fire-extinguishing halogenated aliphatic hydrocarbons and from 0.1%
to 20% by weight of one or more polysiloxanes.
Compositions in accordance with the invention have better
penetration and can be projected from greater distances than known
fire-extinguishing compositions, especially when they are used to
fight various types of fires, referred to as dry fires, greasy
fires and/or gas fires. Moreover, their fire-extinguishing
properties are as good as or even better than those of known
fire-extinguishing compositions.
The fire-extinguishing halogenated aliphatic hydrocarbon is
preferably a fluoro-halogenated aliphatic hydrocarbon, especially a
C.sub.1-5 chlorofluorinated, bromofluorinated or
bromochlorofluorinated aliphatic hydrocarbon, such as a
chlorofluorinated, bromofluorinated or bromochlorofluorinated
methane, e.g., trichlorofluoromethane, bromochlorodifluoromethane
or bromotrifluoromethane, or 1,1,2 -trichloro- 1,2,2
-trifluoroethane, 1,2 -dibromo- 1,1,2,2 -tetrafluoroethane, 1,2
-dibromohexafluoropropane or 3 -bromo- 1,1,1 -trifluoropropane.
However, it is also possible to use a non-fluorinated halogenated
aliphatic hydrocarbon such as ethyl bromide, chlorobromomethane or
bromoform.
Examples of polysiloxanes that may be used in the compositions of
the invention are straight-chain polysiloxanes having the formula:
##SPC1##
in which each R is a hydrogen atom or a group of the formula
##SPC2##
in which R.sub.1, R.sub.2 and R.sub.3 is a C.sub.1-3 alkyl, C.sub.6
or C.sub.10 aryl, C.sub.7-9 aralkyl or C.sub.7-10 alkaryl radical
optionally substituted by one or more halogen atoms, X is a halogen
atom, y is 0 or an integer from 1 to 3, and n is 0 or an integer
from 1 to 7,000, and cyclic polysiloxanes of the formula
##SPC3##
in which X and y are as defined above and m is 0 or an integer from
1 to 20.
In order to facilitate the dissolution of the polysiloxane(s) in
the composition, in the case where the polysiloxane is insoluble or
only slightly soluble in the fire-extinguishing halogenated
aliphatic hydrocarbon(s), from 0 to 49.9% by weight of one or more
solvents for the polysiloxanes and/or a pressurizing agent can be
included in the composition.
The solvent and pressurizing agent may or may not have
fire-extinguishing properties. Examples of solvents that may be
used are C.sub.1-3 halogenated aliphatic hydrocarbons other than
C.sub.1-3 fire-extinguishing halogenated aliphatic hydrocarbons,
e.g. methylene chloride, chlorodifluoromethane,
dichlorofluoromethane, dichlorodifluoromethane, carbon
tetrachloride, dichloroethane, trichloroethylene and
perchloroethylene; C.sub.2-12 aliphatic hydrocarbons such as
iso-octane; C.sub.6-10 aromatic hydrocarbons, such as benzene,
toluene and solvent naphtha; terpene hydrocarbons, such as oil or
terpentine; complex mixtures of hydrocarbons, such as oil gas,
kerosene and Stoddard solvent; C.sub.6-10 cycloaliphatic
hydrocarbons such as cyclohexane and cyclodecane; C.sub.3-7
carbonyl compounds, such as acetone and methylethylketone;
C.sub.2-5 aliphatic acid esters, such as amyl acetate; C.sub.2-6
ethers, such as methyl ether and ethyl ether; C.sub.2-18 hydroxyl
compounds, such as ethanol, isopropanol, butanol, and heptadecanol;
and cyclic ethers, such as dioxane.
When the composition includes an inflammable solvent or
pressurizing agent, the amount of such solvent or pressurizing
agent in the composition should not exceed a low percent, for
example 4%, by weight of the composition.
A preferred composition in accordance with the invention comprises
from 80% to 99.5% by weight of the fire-extinguishing halogenated
aliphatic hydrocarbon(s), from 0.5% to 5% by weight of the
polysiloxane(s) and from 0 to 19.5% by weight of the said solvent
or pressurizing agent.
Liquid fire-extinguishing compositions embodying the features of
this invention can be used in mobile, portable or easily carried
devices, and in fixed fire-fighting devices, particularly automatic
installations for fighting burning liquids or combustible gases.
They can be projected under pressure by means of a gas (e.g.,
nitrogen, carbon dioxide, dichlorofluoromethane) which is
compressed, liquefied or dissolved under pressure in per se known
manner or by any mechanical system for producing a pressure (e.g.,
a pump or compressor).
The following examples are given to illustrate the invention:
EXAMPLE 1
4 cubic meters of petrol F (distillation cut between 110.degree.
and 160.degree.C, having a specific gravity of 0.742 at
15.degree.C) was burned for one minute, the petrol being contained
in a pit having a surface area of 20 square meters. A liquid
mixture comprising 95% by weight of the bromochlorodifluoromethane,
as extinguishing agent, and 5% by weight of a polysiloxane having
the following formula: ##SPC4##
in which n corresponds to a substance with a viscosity of 50 Csk at
25.degree.C, was then projected onto the seat of the fire through a
diffuser having a diameter of 26 mm, under a pressure of 10
bars.
The flames were extinguished after 10 seconds when the liquid
mixture was projected from a distance of 30 meters from the seat of
the fire and the initial ambient temperature was 30.degree.C.
By way of comparison, the procedure described above was carried out
with the exception that the liquid mixture did not contain any
polysiloxane. The flames were extinguished after 10 seconds when
the liquid mixture was projected from a distance of 20 meters from
the seat of the fire.
EXAMPLE 2
The procedure described in Example 1 was carried out with the
exception that the liquid mixture comprised 98% by weight of
bromochlorodifluoromethane and 2% by weight of a polysiloxane
having the formula: ##SPC5##
in which n has a value of about 6000.
The fire was extinguished in 8 seconds when the liquid mixture was
projected from a distance of 35 meters from the seat of the
fire.
EXAMPLE 3
The procedure described in Example 1 was carried out with the
exception that the liquid mixture comprised 88% by weight of
bromochlorodifluoromethane, 10% by weight of trichlorofluoromethane
and 2% by weight of polysiloxane as used in Example 2.
The fire was extinguished in 8 seconds when the liquid mixture was
projected from a distance of 38 meters from the seat of the
fire.
EXAMPLE 4
The procedure described in Example 1 was carried out with the
exception that the liquid mixture comprised 98% by weight of
bromochlorodifluoromethane and 2% by weight of a mixture of
polydimethylcyclopolysiloxanes having the formula: ##SPC6##
in which n is from 0 to 17.
The fire was extinguished in 12 seconds when the liquid mixture was
projected from a distance of 30 meters from the seat of the
fire.
EXAMPLE 5
The procedure described in Example 1 was carried out with the
exception that the liquid mixture comprised 80% by weight of
bromochlorodifluoromethane, 18% by weight of trichlorofluoromethane
and 2% by weight of polysiloxane as used in Example 2.
The fire was extinguished in 12 seconds when the liquid mixture was
projected from a distance of 40 meters from the seat of the
fire.
It will be understood that changes may be made in the details of
formulation and operation without departing from the spirit of the
invention, especially as defined in the following claims.
* * * * *