U.S. patent number 3,875,678 [Application Number 05/430,941] was granted by the patent office on 1975-04-08 for method and apparatus for purifying exhaust air of a dryer apparatus.
This patent grant is currently assigned to Vits-Maschinenbau GmbH. Invention is credited to Hilmar Vits.
United States Patent |
3,875,678 |
Vits |
April 8, 1975 |
Method and apparatus for purifying exhaust air of a dryer
apparatus
Abstract
A method and apparatus for dryers for products containing
volatile hydrocarbons such as impregnated hard board, electrical
insulation having insulating varnish, aluminum sheets coated with
varnish, etc.; the products being dried normally producing, during
drying, gaseous hydrocarbons which, for ecological reasons, cannot
be discharged directly into the atmosphere but which must be
"treated;" the method and apparatus concerning a two-sectioned
dryer in series in which the material being dried, passes from
section to section; in the first section the more volatile
hydrocarbons are driven off and are "after-burned" with the heat of
combustion being recovered and used to heat the dryer sections; the
second section having less volatile hydrocarbons driven off which
are "washed" or condensed; the hydrocarbons precipitating out
during "washing" being used as a fuel to assist in the
"after-burning" of the more volatile hydrocarbons; the washed
exhaust from the second section and exhaust gases from
"after-burning" of the more volatile hydrocarbons being combined
after washing and after-burning for dehumidification of the washed
exhaust and discharged directly into the atmosphere.
Inventors: |
Vits; Hilmar (Leichlingen,
DT) |
Assignee: |
Vits-Maschinenbau GmbH
(Langenfeld, DT)
|
Family
ID: |
5868329 |
Appl.
No.: |
05/430,941 |
Filed: |
January 4, 1974 |
Foreign Application Priority Data
Current U.S.
Class: |
34/478; 34/480;
34/72; 34/79; 422/169; 431/5 |
Current CPC
Class: |
F26B
25/005 (20130101); F26B 23/022 (20130101) |
Current International
Class: |
F26B
25/00 (20060101); F26B 23/00 (20060101); F26B
23/02 (20060101); F26b 003/00 () |
Field of
Search: |
;431/5 ;34/32,72,79,210
;23/277C ;110/8A |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Sprague; Kenneth W.
Assistant Examiner: Schwartz; Larry I.
Attorney, Agent or Firm: Holman & Stern
Claims
What is claimed is:
1. A method for purifying the exhaust products from drying
apparatus for products containing light (low-boiling) and heavy
(high-boiling) hydrocarbons which become volative during drying of
the products and which are burned in a flame prior to being
exhausted into the atmosphere, comprising:
moving the product to be dried through two consecutive sections of
a dryer into contact with a heating medium at a temperature so that
light (low-boiling) hydrocarbons are first volatilized mainly in
the first section and in which heavy (high-boiling) hydrocarbons
are volatilized mainly in the second section;
directly after-burning the volative exhaust products of the first
section;
and washing the volatile exhaust products of the second section,
producing a residue including heavy hydrocarbons and directing the
residue together with burnable material of burned exhaust products
of the first section and burning it with the residue.
2. The method according to claim 1 including the step of supplying
sufficient supplemental fuel to the after-burning for igniting and
maintaining continuous after-burning of both the light hydrocarbons
and the residue including heavy hydrocarbons.
3. The method according to claim 1 including mixing the exhaust
products from the second section, purified by washing, with
afterburned exhaust products and emitting them as a mixture into
the atmosphere.
4. The method according to claim 2 including heating in a
heat-exchanger a heat-absorbing medium by the after-burner and
directing the heated heat-absorbing medium to the respective dryer
sections for treating the product being dried as it successively
passes through the first and second sections of the dryer.
5. Apparatus for purifying the exhaust air from a dryer containing
volatile hydrocarbons comprising:
a dryer divided in consecutive chambers through which a product
being dried is moved;
means in said chambers for passing heated air over said
product;
individual exhaust conduit means connected to the respective
chambers for drawing off exhaust air containing light (low-boiling)
hydrocarbons and heavy (high-boiling) hydrocarbons as they become
volatile in the respective chambers;
after-burning means connected to the conduit receiving the light
hydrocarbons for burning the same; and
washing means connected to the conduit receiving the volatile heavy
hydrocarbons for precipitating a residue including heavy
hydrocarbons.
6. The apparatus as claimed in claim 5 including heat-exchanger
means connected in series with the after-burner means for
recovering heat produced at the after-burner means; and
means for directing the recovered heat to the respective dryer
chambers.
7. The apparatus as claimed in claim 5 including sump means
operatively connected to said wash means for recovering the
precipitated residue including heavy hydrocarbons; and means
connected between said sump means and said after-burner means for
burning the precipitated residue including heavy hydrocarbons and
said light hydrocarbons together in the after-burner means.
8. The apparatus as claimed in claim 6 in which said heat-exchanger
means includes a heat-carrier comprising a heat-absorbing fluid,
and means for circulating the heat-absorbing fluid through the
heat-exchanger means and about said dryer chambers.
9. The apparatus as claimed in claim 7 including nozzle means
connected to the after-burner means and said sump means for
directing the precipitated residue including hydrocarbons into the
after-burner means.
10. The apparatus as claimed in claim 6 including auxiliary burners
in said after-burner means for providing supplemental igniting fuel
to maintain continuous operation of said after-burner means.
11. The apparatus as claimed in claim 6 including exhaust gas
conduits each respectively connected to one of the washing means
and said heat-exchanger means, and a common flue-gas conduit
joining the respective exhaust conduits whereby the wet exhaust gas
from the washing means and causes products passing through said
heat exchanger means are mixed prior to discharge into the
atmosphere.
Description
FIELD OF THE INVENTION
The instant invention concerns method and apparatus for purifying
the exhaust gases and by-products from a dryer apparatus for
products moving therethrough, wherein said products contain light
and heavy hydrocarbons which become volatile during the drying
phase and are incinerated before their exit into the
atmosphere.
BACKGROUND OF THE INVENTION
In dryers for such type of products, the drying air must be
retained at a predetermined temperature, for example at
160.degree.C, so that the light and heavy hydrocarbons become
volatile and, mixed with the air, can be exhausted as spent or used
air. The heated gases which are drawn from the dryer are replaced
by a corresponding amount of fresh air, which must be heated to the
predetermined temperature; this requires a continuous supplying of
heat. The fresh air is drawn into a suspension dryer through the
dryer inlet and outlet for the products moving therethrough and
through non-sealed points of the suspension dryer by an
extractor-fan or vacuum blower.
In the drying of the aforementioned products of the character
involved, there exist certain regulations for the environmental
protection under which the volatilized hydrocarbons must be
rendered almost completely safe by utilizing an after-burning of
the dryer exhaust air.
A first solution for partial recovery of the drying heat, and to
render the volatilized hydrocarbons safe by means of
"after-burning," consists of the system shown diagramatically in
FIG. 1, the exhaust gases of the dryer are entirely subjected to
after-burning and a part of the flue-gas which has been heated for
example up to 800.degree.C, is directed back into the dryer for the
purpose of heating the dryer-atmosphere, while the remaining part
of the flue-gas is emitted into the open atmosphere.
This method is impractical for a multitude of reasons: firstly, a
large part of heat is lost with the flue-gas which is being
discharged into the free atmosphere; secondly, the installation
required for such a process is costly since on one hand the large
volumes, large-column, long flue-gas pipes and the large valves
must be heat-resistant on account of the high temperatures of the
flue-gas and must therefore be manufactured from expensive
material, such as, for example, chrome-nickel steel, and on the
other hand, it is difficult to retain the under-pressure in the
dryer which is required for a satisfactory suspension of the
products due to the flue-gas supplied in addition to the fresh-air
and the additional sealing points at the connections of the
flue-gas conduits which are distributed throughout the dryer.
Another system to render the polluted drying air safe for the
environment, and to partially recover the heat with a less
expensive installation, consists in the system shown in FIG. 2;
wherein the flue-gas of the entire dryer is subjected to an
after-burning phase and the thus produced flue-gas is directed into
the open atmosphere through an economizer, whereby the flue-gas
heats a heat-carrier in an economizer, for example, a heating-oil,
which is supplied to the dryer, in order to retain its
oven-temperature at the desired temperature level. This method, due
to the low temperature of, for example 300.degree.C, does not
require conduits of a high heat-resistant steel and ordinary steel
products suffice. On the basis of this special heat-recovery, the
difficulties in retaining the required under-pressure in the dryer
do not exist since, in addition to the fresh air, no flue-gas is
directed into the dryer; however, in this type of heat-recovery,
the heat-loss is still too high. Additionally, in such type of
heat-recovery there exists the danger that the heating-oil in the
economizer may become overheated due to the flue-gas being heated
to approximately 800.degree.C.
A further system to render the flue-gases safe for the environment
and to more efficiently recover more heat than in the two
above-described systems of FIGS. 1 and 2, whereby the costs of the
installation can be minimized, and whereby difficulties with the
retention of the reduced pressure in the dryer can be avoided,
consists of the system of FIG. 3 in that all of the flue-gas from
the dryer is directed to the apparatus for an after-burning process
by means of a recuperator, whereby the flue-gases first are
directed through the recuperator and then through an economizer for
a heat-carrier (thermo-oil) then the flue-gases are exhuasted into
the free atmosphere. As noted in the above example, there exists
also in this method the danger that the heating-oil, which is being
utilized as the heat-carrier, and which is supplied to the dryer
for heating its atmosphere, may be overheated. In contrast to the
earlier mentioned example, this method has, however, the advantage
that the heat is more efficiently recouped, however, the higher
costs for such an installation because of the recuperator must be
taken into consideration.
SUMMARY OF THE INVENTION
It is the scope of the instant invention to provide a method and
apparatus of the above-mentioned type in which, under low
expenditures, for the installation, a reduced amount of heat
compared to the amount of the above-described methods, is required
in order to purify the exhuasted air.
This problem is solved by the instant invention in that only the
flue-gas from a first section of the dryer in the path of the
products moving therethrough are immediately "after-burned," while
the flue-gas from the second section of the dryer is washed and the
residue or precipitate from this washing phase together with the
burnable materials is burned off with the flue-gas of the first
section of the dryer.
In this method, surprisingly, it is possible to remove and burn
approximately 95 percent of light hydrocarbons from the first
section of the dryer, while approximately 95 percent of the heavy
hydrocarbons from the second section of the dryer are removed and
burned. The inventive method distinguishes over the prior art with
regard to heat-balance (thermal balance) as well as with regard to
the expenditure for the installation. Since the flue-gas is
after-burned immediately from the first section of the dryer, it is
possible to maintain the installation on a smaller scale for the
after-burning process as well as for the heat-exchanger installed
for reheating the dryer air, in contrast to expenditures of prior
art methods in which all of the flue-gases of the dryer are
after-burned. Even though the inventive method requires a purifyer
or wash column for the flue-gas from the second section of the
dryer, the costs are by far not as high as the additional costs for
a device for the after-burning and the heat-exchanger, which must
process all of the flue-gases emitted from the dryer apparatus. The
total heat- or thermal-balance in the inventive method compared
with the prior art methods is improved, first since the flue-gas
from the first section contains more volatile (readily evaporated)
concentrations up to the permissible limits so that in the
after-burning phase only a small amount of supplemental fuel-gas is
required; in general, the light and heavy hydrocarbons deliver the
heat for the reheating of the dryer, and secondly since only a part
of the column of the exhaust gases received from the dryer will
have to pass as flue-gas, a drop in temperature (or heat gradient)
twice the size in comparison to the prior art methods, since it has
to deliver the heat which is required for the first and the second
sections of the dryer.
Since the washed spent air has a high degree of humidity, it is
advantageous to mix the after-burned exhaust from the economizer
with the spent air which has been washed in the wash column before
exhausting into the open atmosphere so that the entire
flue-gas/used-air mixture is dehumidified.
Preferably, heating-oil is utilized as the heat-carrier.
An installation for performing the preferred method comprises a
dryer which is divided into two adjacently-arranged chambers
disposed in the direction the products to be dried therein are
moved, whereby the first chamber of the dryer is connected, by
means of an exhaust conduit, with a device for after-burning phase,
the conduit being series-connected, for the purpose of removing the
after-burned spent air, with a heat-exchanger for the purpose of
reheating the product dryer, and the second chamber having a
further exhaust conduit which is connected with a wash-column in
which the washed-out heavy or less volatile hydrocarbons from the
sump of which, via a conduit, the washed out heavy hydrocarbons are
supplied to a burner device used for the purpose of after-burning
the more volatile exhaust from the first section of the dryer.
Embodiments of such installations consist in that the
heat-exchanger is an economizer using heating-oil as a
heat-carrier, whereby the device for the after-burning process is
provided with means for atomizing the heavier hydrocarbons which
are extracted from the sump of the wash-column, wherein the device
for the after-burning is provided with auxiliary burners, and
wherein the outlet of the heat-exchanger for the after-burned spent
air and the outlet gas of the wash column for the washed spent
exhaust gases terminate into a common flue-gas conduit.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a schematic view of one proposed dryer installation in
which flue-gas is directed back to the dryer section;
FIG. 2 is a schematic view of another dryer installation in which
an economizer is provided between the after-burner and flue-gas
outlet and in which a heating oil is used to recover the heat from
after-burning of the dryer byproducts or exhaust for heating the
dryer;
FIG. 3 is a schematic view showing still another proposed
installation of an after-burning system utilizing a recuperator
intermediate and after-burner and economizer for treating the spent
air of the dryer; and
FIG. 4 is a schematic view of the preferred embodiment of the
after-burning system of the invention.
DESCRIPTION OF THE PREFERRED EMBODIMENT
The instant invention is explained hereinbelow by means of a
schematic illustration shown in FIG. 4. A suspension dryer 1 is
divided into a first section and a second section disposed in
series in the direction of the path 2 for the products to be dried
therein, for example, impregnated hard carboard, electrical
insulating material comprising base-material and insulating
varnish, varnished aluminum foil (sheets) etc. The dividing of the
dryer 1 into a first and a second section is accomplished in such a
way so that in the area of the first section, at temperatures of
about 130.degree.C, approximately 95 percent of the light or more
volatile hydrocarbons are driven off, while in the second section
at temperatures of about 150.degree.C approximately 95 percent of
the heavy or less volatile hydrocarbons become volatile and are
driven off. A mixing of the dryer air from both sections of the
dryer (which occurs with regard to the concentration of the
hydrocarbons in both parts of the air of the dryer) generally does
not occur since a trnsformation of the dryer air occurs
zonally.
On one hand, the dryer must be provided with openings for the
path-entry and path-exit for the purpose of the suspended guiding
of the products, and on the other hand there should not exit from
the opening the dryer-air which is mixed with volatiles, the dryer
is maintained under low pressure. Fresh air is continuoursly
supplied to the dryer by means of the suspended jets or nozzles
(not shown) which are necessary for the suspended transport of the
products. In order to enable the retention of the under-pressure,
spent air is continuously removed or drawn from the first and the
second section and is directed to an after-burning device 3. In
addition to that, the heavy hydrocarbons are sprayed as a fuel into
the after-burner device 3 by means of an atomizing nozzle 4. In
order to permit after-burning, auxiliary burners 5 are provided
through which supplemental fuel which is supplied to the device 3
for after-burning exhaust dryer gases. The portion of the
extraneous fuels must be sufficient to ignite and retain the
burning of the light and heavy hydrocarbons in the device 3. At an
exotherm of about 400.degree.C of the spent air from the first
section, it is necessary to supply enough supplemental fuel in
order to heat the exhaust air to an average of about 400.degree.C.
The light hydrocarbons and the heavy hydrocarbons which are
contained in the exhaust air of the dryer are then heating the
exhaust since they burn at about 800.degree.C. The flue-gases which
are heated to this temperature level are taken from the device 3
and are directed through an economizer 6 to which they transfer a
large part of their heat to a heat-carrier, for example heating
oil, which is circulated via a conduit system 7 to the first and
the second section of the dryer 1 to thus maintain the
dryer-section atmosphere at predetermined drying temperature
levels.
The exhaust gases sucked from the second section of the dryer 1,
containing the heavy or less volatile hydrocarbons, are moved
through a wash column 8 in which the heavy hydrocarbons are
extracted or precipitated by means of water which is sprayed
thereinto. From a sump 9 of the wash column 8, the liquified heavy
hydrocarbons, as explained, are drained off in the form of a water
slurry and supplied to the after-burner device 3 through nozzle 4
where they are burned. The cleaned humid exhaust gas of the wash
column 8 passes into a mutual flue-gas canal 10, joining the dry
flue-gases which exit from the economizer 6, whereafter they exit
as dehumidified dry flue-gas mixture into the open atmosphere.
SUMMARY
The dryer utilizes the principal in FIg. 4 of the fact that certain
hydrocarbons become volatile at about 130.degree.C and are drawn
off in the first drying section; accordingly, less heat is required
in this section to remove the more volatile byproducts of the
drying process; in the second section, the product is subjected to
about 160.degree.C at which the heavier hydrocarbons become
volatile. The exhaust from the second section is "washed " where
the heavier carbons precipitate to a sump and are pumped to a fuel
nozzle to be used as a fuel supplementing the fuel at burner 5 in
the after-burner 3. The heat produced at the after-burner 3 is
recovered at the economizer 6 which includes a circulating
heat-absorbing medium which is redirected back to the dryer for
heating the respective first and second sections of the dryer; the
washed exhaust from washer 8 is combined with the exhaust from the
economizer 6 for dehumidification and passes from outlet 10 to the
atmosphere and comprises afterburned exhaust (of the lighter
hydrocarbons) and washed exhaust (of the heavier hydrocarbons) from
respective dryer sections 1 and 2.
* * * * *