U.S. patent number 3,872,021 [Application Number 05/305,931] was granted by the patent office on 1975-03-18 for cleaning composition.
Invention is credited to Audrey M. McKnight.
United States Patent |
3,872,021 |
McKnight |
March 18, 1975 |
Cleaning composition
Abstract
A dry cleaning pre-spotter composition including soap, anionic
and nonionic detergents, and organic dry cleaning solvents.
Inventors: |
McKnight; Audrey M. (Palmdale,
CA) |
Family
ID: |
23182974 |
Appl.
No.: |
05/305,931 |
Filed: |
November 13, 1972 |
Current U.S.
Class: |
510/282; 510/338;
510/430; 510/342; 510/412 |
Current CPC
Class: |
D06L
1/04 (20130101) |
Current International
Class: |
D06L
1/00 (20060101); D06L 1/04 (20060101); C11d
009/32 () |
Field of
Search: |
;252/121,127,122,126,558,559,170,172,173 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Lechert, Jr.; Stephen J.
Claims
What is claimed is:
1. A dry cleaning agent for textiles and the like comprising about
4 to 15 weight percent of a high molecule weight fatty acid soap,
about 5 to 20 weight percent of anionic alkyl benzene sulfonate
wherein the alkyl group contains from about 10 to 15 carbon atoms,
about 5 to 20 weight percent amyl acetate, about 1 to 10 weight
percent of a nonionic detergent, and from about 35 to 80 weight
percent dry cleaning solvent.
2. The dry cleaning agent of claim 1 wherein the high molecular
weight fatty acid soap is sodium stearate.
3. The dry cleaning agent of claim 1 wherein the anionic alkyl
benzene sulfonate is ammonium dodecylbenzene sulfonate.
4. The dry cleaning agent of claim 1 wherein the nonionic detergent
comprises 2,3-bis(alkoxy)-1-proponal wherein the alkoxy group
contains from about 10 to 15 carbon atoms.
5. A dry cleaning agent for textiles and the like comprising a
formulation having the ingredients and approximate weight
percentage concentrations as follows:
Description
This invention relates to a dry cleaning pre-spotter formulation
for treating textile materials before they are subjected to
conventional dry cleaning operations.
Previously, considerable difficulty had been experienced in
providing a pre-spotting formulation that will effectively remove a
wide spectrum of spots from textile materials. Such spots on
textile materials may be formed by paints, greases, oils,
beverages, inks, chemicals, and the like. All of these stains may
be found on one garment or in a random sampling of garments that
come through a dry cleaning establishment during the course of a
day. It is very difficult to determine in some instances precisely
what the stain on the textile was caused by. If pre-spotting agents
are used that are effective against one stain but are not effective
in removing other types of stains, there is a risk that the wrong
cleaner will be used, and the stain will remain or, worse, it will
be fixed in place so that it will be impossible to remove it. There
is a need for a universal pre-spotting composition.
According to the present invention, a substantially universal
pre-spotting composition for use in dry cleaning is provided.
The pre-spotting composition of this invention is an admixture
including a liquified soap, an anionic synthetic detergent, a
nonionic detergent, and certain organic solvents.
The vehicle for providing the composition in an homogeneous liquid
admixture is a conventional dry cleaning solvent; such as, the
petroleum distillate solvents identified as Stoddard's solvent or
140.degree. Fahrenheit solvent or the chlorinated solvents; such
as, carbon tetrachloride, trichloroethylene, and perchloroethylene.
The chlorinated solvents are preferred, and perchloroethylene is
the most preferred solvent vehicle.
The pre-spotting composition includes a substantial proportion of
an amyl acetate which is an effective solvent for a wide variety of
organic materials that frequently occur in spots on textiles.
The soaps that are suitable for use in this composition are
conventional soaps that are used as dry cleaning detergents,
including generally the sodium, ammonium, and potassium salts of
fatty acids containing from 12 to 18 carbon atoms. Typical soaps
include sodium, potassium, and ammonium stearate; sodium,
potassium, and ammonium palmitate; sodium, potassium, and ammonium
oleate; sodium, ammonium, and potassium abietate; sodium,
potassium, and ammonium ricinoleate; and the like. Also, the soap
must be liquified in order to be incorporated in the pre-spotting
composition. Conventional liquification procedures are employed and
include, for example, admixing the soap with an organic solvent, a
coupling agent, and water. As used herein, the term soap is
intended to refer to the liquified sodium, potassium, and ammonium
salts of the fatty acids containing from about 12 to 18 carbon
atoms.
Synthetic anionic detergents that are suitable for inclusion in the
pre-spotting composition of this invention include the sodium,
potassium, and ammonium salts of the alkyl aryl sulfonates in which
the aryl group is generally benzene, and the alkyl group contains
about 10 to 15 carbon atoms. As used herein, the term anionic alkyl
benzene sulfonate is intended to include the compounds wherein the
cation is sodium, potassium, or ammonia, and the alkyl group
contains about 10 to 15 carbon atoms.
Additional components of the pre-spotting composition include
nonionic synthetic detergents; such as, fatty acid-alkanolamine
condensates formed by condensing fatty acids with amines, such as
diethanolamine; ethylene oxide-fatty acid condensate formed by the
condensation of from about 12 to 15 mols of ethylene oxide with 1
mol of a fatty acid; and alkyl aryl polyether alcohols formed by
the condensation of from about 9 to 12 mols of ethylene oxide with
an alkyl phenol; various other surfactant glycols and ethers; and
the like.
Throughout this specification parts and percentages are by weight
unless otherwise indicated.
A very effective and substantially universal pre-spotting
composition of this invention is prepared according to the
following formulation.
EXAMPLE ______________________________________ Water 0.6% Methyl
Isobutyl Ketone 0.8% Cyclohexanol 2.9% Sodium Oleate 2.4%
2-Methylnaphthalene 0.9% 2,3-Bis(Dodeoxy)-1-Proponal 4.8% Amyl
Acetate 12.5% Ammonium Dodecylbenzene Sulfonate 10.8% Neopentylene
Glycol 0.3% Perchloroethylene 64.0%
______________________________________
This formulation is tested on a wide variety of stains and fabrics,
including oil, carbon black, paint, blood, and ink on silk, cotton,
wool, rayon acetate, nylon, polyesters, and the blends of wool and
polyester.
The sodium oleate in this example is liquified by premixing it with
the water, cyclohexanol, and methyl isobutyl ketone before admixing
it with the balance of the composition.
The composition set forth in this example is the preferred
composition; however, substitutions and alterations may be made
therein without adversely affecting the spot removal capabilities
of the composition. For example, carbon tetrachloride or
trichloroethylene may be substituted for the perchloroethylene, and
the proportion of the solvent may be varied from approximately 35
to 80 weight percent. Various soaps, such as ammonium stearate and
potassium ricinoleate, may be substituted for the sodium oleate;
and the proportion of the soap in the composition, including the
agents required to liquify it, may range from about 4 to 15 percent
by weight. Various liquification materials may be used; for
example, methylcyclohexanol may be used instead of cyclohexanol and
various ketones; such as, methylamyl ketone, ethylbutyl ketone
methylcyclohexanone, may be used if desired. In general the
quantity of materials required to liquify the soap are
approximately equal to the weight of the solid soap before it is
liquified for use in the composition of this invention. The
proportion of amyl acetate in the composition may be varied from
approximately 5 to 20 percent and is preferably employed in the
range of from about 5 to 15 percent. Various nonionic surfactant
materials may be utilized, such as polyalkylene oxide phenolic and
fatty acid condensates. In general the nonionic materials are
present in amounts ranging from approximately 1 percent to 10
percent and preferably from about 3 to 8 percent by weight. If
desired, admixtures of various materials may be employed. For
example, a mixture of sodium and ammonium oleate could be employed
if desired. Likewise, admixtures of anionic or nonionic detergents
may be used. The anionic alkyl benzene sulfonate may be present in
amounts ranging from about 5 to 20 weight percent and is preferably
employed in quantities ranging from about 8 to 15 weight percent of
the composition.
* * * * *