U.S. patent number 3,870,778 [Application Number 05/264,402] was granted by the patent office on 1975-03-11 for process for pigmenting a pile surfaced product.
This patent grant is currently assigned to Imperial Chemical Industries Limited. Invention is credited to Margaret Lilian Steel.
United States Patent |
3,870,778 |
Steel |
March 11, 1975 |
Process for pigmenting a pile surfaced product
Abstract
A method of pigmenting a laminated pile surfaced product in
which the pile is formed by a tack spinning process. Pigment is
applied to a component of the laminate to be subjected to the tack
spinning process before the pile is formed.
Inventors: |
Steel; Margaret Lilian
(Runcorn, EN) |
Assignee: |
Imperial Chemical Industries
Limited (London, EN)
|
Family
ID: |
26259661 |
Appl.
No.: |
05/264,402 |
Filed: |
June 19, 1972 |
Foreign Application Priority Data
|
|
|
|
|
Jun 21, 1971 [GB] |
|
|
28958/71 |
Aug 9, 1971 [GB] |
|
|
37294/71 |
|
Current U.S.
Class: |
264/164; 156/72;
156/230; 156/238; 156/277; 264/243; 264/284; 428/96 |
Current CPC
Class: |
D04H
11/08 (20130101); D06B 11/0076 (20130101); Y10T
428/23986 (20150401) |
Current International
Class: |
D04H
11/00 (20060101); D04H 11/08 (20060101); B29c
017/02 (); B32b 005/00 () |
Field of
Search: |
;156/72,238,240,241,277
;161/62,67 ;117/38 ;8/2.5,4,180 ;264/164,280,284,241,243 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Fritsch; Daniel J.
Attorney, Agent or Firm: Cushman, Darby & Cushman
Claims
What we claim is:
1. A process for the production of a pile surfaced product
pigmented with a given pigment comprising passing a synthetic
thermoplastic material having at least one surface which is free of
the given pigment and a backing material to a heated pressing
surface with said one surface of the synthetic material against
said pressing surface under conditions such that if the synthetic
thermoplastic material is not prebonded to the backing material
bonding occurs between the two and the temperature of the pressing
surface being such that the synthetic thermoplastic material
temporarily adheres to said heated pressing surface, applying the
given pigment to at least one of the synthetic material or the
backing material prior to separating the synthetic thermoplastic
material from said surface, and then separating the synthetic
thermoplastic material from said heated pressing surface so that
fibrils are drawn out from the synthetic thermoplastic material,
the fibrils becoming pigmented with the given pigment under the
influence of the action of said heated pressing surface on the
synthetic thermosplastic material.
2. A process according to claim 1 in which the pigment is applied
to the backing material or the synthetic thermoplastic material in
such a way that the pigment is carried into the pile during pile
formation.
3. A process according to claim 1 in which the pigment is applied
so that its distribution is discontinuous.
4. A process according to claim 1 in which application of the
pigment occurs immediately prior to pile formation.
5. A process according to claim 1 in which the pigment is soluble
in the synthetic thermoplastic material forming the pile.
6. A process according to claim 1 in which the pigment is finely
particulate material insoluble but dispersible in the synthetic
thermoplastic material forming the pile.
7. A process according to claim 6 in which the pigment is applied
to a web component and bound loosely thereto by means of a
temporary bonding agent which in the pile forming process releases
the pigment which thereupon is carried into the pile.
8. A process according to claim 1 in which the pigment is
transferred from a carrier to either the backing material or the
synthetic thermoplastic material.
9. A process according to claim 8 in which the pigment is printed
on to the synthetic thermoplastic material by said heated pressing
surface.
10. A process according to claim 8 in which the pigment employed is
a volatilisable dispersion dye.
11. A tack-spinning process for making a pile surfaced product
pigmented with a given pigment comprising passing a laminate of a
synthetic thermoplastic material component having at least one
surface which is free of the given pigment and a backing material
component through a heated nip formed between the surfaces of two
moving elements one of which is heated to a temperature at which it
temporarily adheres to said one surface of the synthetic
thermoplastic material, feeding the given pigment into the nip
simultaneously with the laminate so that the action of the nip
causes migration of the pigment within the laminate, and separating
the laminate from the surfaces of the moving elements under
conditions such that the synthetic thermoplastic material is drawn
into fibrils thereby forming a pile surfaced product and such that
simultaneously the pigment is carried into the fibrils as they are
formed.
12. A process as in claim 11 wherein the given pigment is present
in or on the surface of said synthetic thermoplastic material
component which is opposite said one surface thereof, before said
laminate enters the nip.
13. A process as in claim 11 wherein said given pigment is present
in or on said one surface of one of the moving elements.
14. A process as in claim 13 wherein said pigmented surface of said
one moving element engages said one surface of said synthetic
thermoplastic material component in said nip.
15. A process as in claim 13 wherein said pigmented surface of said
one moving element engages said backing material component in said
nip.
16. A process as in claim 11 wherein said given pigment is present
in or on said backing material component, before said laminate
enters the nip.
Description
This invention relates to composite products.
Our copending U.K. Patent Applications Nos. 53265/69, 55242/70,
61325/70, 61326/70, 12336/71 and 28206/71 relate to the production
of pile-surfaced products by drawing a pile comprising a plurality
of fibres or tufts of fibres of polymeric material. Such a process
in which a pile is formed from polymeric material on a foundation
sheet or web may be referred to, for convenience, as "tack
spinning."
The processes described in the specifications of the aforementioned
applications comprise the steps of interposing a polymeric material
between a web (for convenience the polymer and web are referred to
as the laminate) and a temporary anchorage surface (the polymeric
material being in a state such that it is tacky and capable of
adhering to the web and also adhering temporarily to the temporary
anchorage surface), separating the web and the temporary anchorage
surface so that `stringing` of the polymeric material occurs with
the production of fibres of the polymeric material, hardening the
polymeric material by cooling (if it is thermoplastic and had been
rendered tacky by heat) or by completion of a cross-linking
reaction (where the polymer is a curable polymer and undergoes cure
during or after fibre formation), and separation of the fibres from
the temporary anchorage surface.
The present invention provides a modification of pile-forming
processes involving the processes set out above, in that the
product comprises a pigment which is soluble in, adsorbent upon or
dispersible in the polymeric material under the pile-drawing
conditions employed, or is easily removable from the web for
example by mere mechanical forces occuring during pile formation so
that on formation of the pile the pigment is carried into the
fibres of the pile. By use of the word pigment it will be realised
that we do not exclude the use of soluble (whether in water or
other solvent) dyestuffs, or volatile colouring materials, whether
inorganic or organic in nature.
Accordingly the invention provides a method of pigmenting a pile
surfaced product in which the pile is formed by a tack-spinning
process, which method comprises the steps of applying pigment to a
component of the laminate to be subjected to the tack spinning
process before the pile is formed.
The pigment employed may be dispersed within the fabric of the web,
as in conventional dip dyeing processes, it may merely be applied
to the surface of the web, in which case it may be applied in
solution or as a suspension of solid pigment particles in a
suspending fluid, and/or it may be applied to the polymeric
material. The pigment may be distributed evenly to produce a `self
coloured` product or it may be distributed in a discontinuous
fashion, either randomly or to a predetermined pattern, and
pigments of different colour may also be employed as in the
production of multi-coloured patterned products.
When the web is pigmented it will be apparent that if desired it
may be pigmented immediately before contacting it with the
polymeric material, application of the pigment may be effected on
the same apparatus as that in which pile formation occurs.
The pigment applied to the web may be soluble in the in the
polymeric material, or any component, including solvent, of the
polymer composition, employed in pile formation.
Where the pigment is insoluble in the polymer component and is
carried into the fibres from the web by flow currents in a
mechanical fashion the only requirement is that the pigment should
be particulate so that it may be so carried, and that it be
sufficiently loosely adhered to the web that it may be dislodged
from it and carried into the pile under the pile drawing conditions
employed. It may be desirable to apply pigment to the web in the
presence of a bonding agent which may enhance its adhesion to the
web but which, under the pile drawing conditions employed, releases
the pigment into the polymeric pile forming material. Thus, where
pile formation involves the application of heat to the web a
thermoplastic bonding agent may be employed which softens to
release the pigment at the temperature employed.
A preferred method of applying pigment to one or more components of
the laminate is by a transfer printing process, optinally while the
polymeric material is in contact with the temporary anchorage
surface used to form the pile in the tack-spinning process.
Transfer printing may involve the transfer of pigment by a
combination of heat and pressure of a volatilisable disperse dye
which is capable of dyeing the polymeric material forming the pile.
Dyestuffs particularly suitable for this application are those
listed in the Colour Index Second Edition Vol 1, p. 1,655 et seq.
and generally are dyes without water-solubilising groups and with
appreciable solubility. These volatilisable dyes are well known
from the literature, for example U.K. Pat. Specification Nos.
1,189,026 and 1,211,149, and generally are volatilisable, or
sublime, at a temperature between 140.degree. and 230.degree.C. The
dye may be applied to the surface of a suitable substrate, for
example paper or metal foil, for example by known printing methods,
and then transferred to the material to be coloured.
The disperse dye may be applied to the polymeric component or it
may be applied also or alternatively to the web, and particularly
where the web is porous (i.e., has a structure such that the
disperse dye may pass through it upon being made volatile e.g., a
textile fabric) the disperse dyestuff may be applied to the side of
the web distant from the polymeric material, migration of the
dyestuff through the web occurring under the appropriate
conditions.
In another embodiment, the substrate bearing the dyestuff acts as
the temporary anchorage in the pile formation step, the dyestuff
being transferred to the newly formed pile from the temporary
anchorage prior to and/or during pile formation.
The time during which transfer of the disperse dye occurs will vary
with the dyestuff, but generally will be considerably less than 30
seconds, and conditions will be chosen appropriately.
Web materials employed according to the invention include any of
those mentioned in the aforementioned patent applications, but
particularly preferred is paper, for example in the production of
pile-surfaced wall paper, and textile materials of natural or
synthetic fibre, which may be employed for the production, for
example of patterned pile-surfaced textiles for clothing, furniture
covering and the like.
Embossing techniques as described in the aforementioned patent
specifications may also be employed in the present invention, to
produce figured products in which embossed regions may or may not
coincide with patterning obtained by the process of the present
invention. Equally, embossing techniques may be employed to impart
a surface pattern to self coloured pile-surfaced products.
Preferred embossing techniques involve for example the prevention
of pile drawing locally by preventing adhesion of the polymeric
material to the temporary anchorage surface e.g. by embossing said
surface or by interposing between the temporary anchorage surface
and the polymeric pile forming material masking material of
appropriate pattern. Said masking material is preferably applied to
the temporary anchorage surface for example as a coating of
suitable non-stick material. Local melting or softening of the pile
whereby it is collapsed in predetermined or random areas may
produce an embossed effect.
The attached drawings show in diagrammatic sectional elevation
different types of apparatus suitable for carrying out the process
of the invention in which disperse dyes are employed.
In FIG. 1, a film of thermoplastic material 1 and a woven fabric
web 2 are supplied from feed rolls 3 to the nip between
contrarotating rollers 4,5. The roller 4 is heated and forms the
temporary anchorage surface from which the fibrils are drawn, and
the roller 5 is a resilient backing roll. A continuous flexible
metal strip 6 passes through the nip between the web 2 and the
roller 5, and at a point 7 is printed with a disperse dye by means
not shown. In the nip of the rollers, the dye is transfer printed
to the back of the web, migrates through the web and into the
thermoplastic layer, and is drawn up into the fibrils formed when
the web parts from the hot-roll. The fibrils of the pile are cooled
by a jet of fluid from a nozzle 8, and the coloured pile surface
material 9 is taken up on a roll 10, while the flexible strip 6
returns for further printing at 7.
It may be necessary for the substrate bearing the disperse dye to
remain in contact with the web for a longer period than that
provided by the passage through the nip of the rollers. This may be
achieved as shown in FIG. 2, in which a resilient belt 11 replaced
the backing roller 5 and urges the substrate against the web over
approximately half of the circumference of the hot roller 4. The
substrate in this case is transfer paper previously printed with a
pattern of disperse dye. The transfer paper 12 is fed between the
web 2 and the resilient belt 11, with the printed side towards the
web. During the half revolution of the hot roll the transfer
printing and migration of the dye through the web 2 and into the
thermoplastic material 1 takes place, and when fibrils are drawn
the web leaves the hot roll, the dye is present in the fibrils. The
used transfer paper is stripped off at 13.
FIG. 3 shows apparatus in which the substrate is a flexible metal
strip 6, printed with disperse dye 7, which passes between the
hot-roll 4 and the thermoplastic material 1. Leaving the nip
between the hot roll 4 and the resilient backing roll 5, fibrils
are drawn between the web 2 and the metal strip 6, which acts as
the temporary anchorage and at the same time the dye is transferred
to the thermoplastic. A cooled tube 14 contacting the underside of
the web 2 provides the necessary cooling of the drawn fibrils. The
strip 6 recirculates for further printing.
FIG. 4 shows a further embodiment in which a dye-coated transfer
paper 12 is supplied from a feed roll 3 between the hot roll 4 and
the thermoplastic material 1, with the coated face away from the
hot roll. Fibrils are drawn from the transfer paper as temporary
anchorage, used paper being pulled off at 13. Finally in FIG. 5,
dye is printed directly upon the hot roll by means not shown, but
which could for example involve contacting the hot roll with the
coated side of dye-coated transfer paper, and the dye is
transferred to the polymeric material 1 from the hot roll and
appears in the drawn fibrils.
It may be advantageous to retain some solvent in the printed dye at
the point where the substrate heating the dye comes in contact with
the web or the polymeric material, as this may ensure greater
mobility of the dye into the polymer. Different disperse dyes have
different mobilities, and conditions of temperature, pressure and
contact time must be selected appropriately for the dye to be used
and for the nature of the web and the polymer. Where the substrate
bearing the dye acts as the temporary anchorage in the pile-drawing
step, it is desirable to avoid high local concentrations of dye
which may interfere with the adhesion of the polymeric material to
the substrate.
The invention will be further described with reference to the
following Examples, in Nos. 1,2,3 and 4 of which the apparatus used
was a Kodak 15 TC glazing machine incorporating a hot roll with a
resilient belt as illustrated diagrammatically in FIG. 2. The hot
roll was at 180.degree.C and the contact time was approximately 2
minutes.
Example 1
A sheet of polyethylene coated fabric was fed between the roll and
the belt of the glazing machine, the polyethylene coating
contacting the hot roll. A sheet of paper previously printed by
conventional printing techniques with a pattern of disperse dyes
(the printing ink employed comprises one or more disperse dyes, a
liquid medium and a thickener or binder which is soluble in the
liquid. Water or organic solvents, e.g., alcohols, are typical
liquid media; in this example the dyes employed were three disperse
dyes, each used in 8 percent solution in isopropanol/toluene/ethyl
cellulose solution. The dyes employed were:
2-hydroxy-5-methyl-4'-acetylaminoazobenzene,
1:4-diamino-2-methoxyanthraquinone,
1-hydroxy-4-(p-toluidino)anthraquinone), was fed between the coated
fabric and the belt, with the printed side in contact with the
fabric. On stripping the fabric from the hot roll and cooling the
side nearer the hot roll with a blast of air at ambient
temperature, a pile-surfaced fabric was obtained in which the
pattern originally on the transfer paper appeared both in the
fabric and in the fibrils of the pile.
Example 2
The process of Example 1 was repeated except that in place of
previously printed transfer paper, a PTFE-coated release paper was
coated locally with solutions of the same three disperse dyes as
used in Example 1, dried partially or competely and fed into the
glazing machine as before.
The pile-surfaced product showed the colours of the three dyes both
in the web and the pile. Better results were obtained if the
solvent was not allowed to evaporate fully before the release paper
contacted the fabric.
Example 3
Polyethylene coated fabric was fed between the hot roll and the
belt as described in Example 1 and previously printed transfer
paper was fed between the polyethylene and the hot roll, with the
printed surface contacting the polyethylene. On forming a pile
surface as described in Example 1 by stripping the fabric from the
transfer paper, the pattern originally on the transfer paper
appeared in the fibrils of the pile.
Example 4
The three dyes listed in Example 1 were applied directly to the hot
roll, and the polyethylene coated fabric fed in as described. On
stripping the fabric from the hot roll a pile-surfaced product was
obtained in which the pile showed colouring due to the dyes applied
to the hot roll.
Example 5
A piece of newspaper printed with printer's carbon black ink, had
applied to one printed surface a sheet of colourless polyethylene
0.1 mm and a polyethylene pile was produced on the paper by
pressing the polyethylene against a polished stainless steel sheet
at 115.degree.C for 10 seconds. On parting the paper from the steel
fibres of polyethylene formed between the paper and the steel, and
on being cooled by a stream of cold air the fibres separated from
the steel surface to form a pile on the paper. It was found that
the carbon black had migrated in the polymer so that black fibrils
occurred in regions corresponding to printed areas in the original
newsprint.
Example 6
Example 5 was repeated using a white porous paper to which had been
applied a thin coating of a finely ground coloured mineral-based
pigment immediately before contacting the pigmented paper with the
polyethylene sheet. The pigment migrated into the polyethylene
pile, giving a coloured pile surface to the paper.
Example 7
Example 6 was repeated using a bleached kraft paper which had been
printed with a disperse dye of the type described in Example 1.
This was contacted with polyethylene sheet. The dyestuff sublimed
into the polyethylene pile giving a coloured pile surface to the
paper.
Example 8
Bleached kraft paper and disperse dye printed polyethylene film
were fed together around a heated roll with the non-printed side
adjacent to the hot roll. Tack-spinning was accomplished in the
normal way to give a coloured pile product.
* * * * *