U.S. patent number 3,868,512 [Application Number 05/393,960] was granted by the patent office on 1975-02-25 for composite input screen for x-ray imaging devices.
This patent grant is currently assigned to General Electric Company. Invention is credited to Stanley J. Lubowski, Jerome S. Prener.
United States Patent |
3,868,512 |
Prener , et al. |
February 25, 1975 |
Composite input screen for X-ray imaging devices
Abstract
A composite screen is made from a mixture of CsI:Tl and Gd.sub.2
O.sub.2 S:Tb phosphors. The composite is formed by slowly removing
a mixture of the phosphors from a hot zone so that molten CsI:Tl
progressively cools and hardens to bind the Gd.sub.2 O.sub.2 S:Tl
particles together. When completed, the composite material is
sliced to form a plurality of screens.
Inventors: |
Prener; Jerome S. (Schenectady,
NY), Lubowski; Stanley J. (Schenectady, NY) |
Assignee: |
General Electric Company
(Schenectady, NY)
|
Family
ID: |
23556951 |
Appl.
No.: |
05/393,960 |
Filed: |
September 4, 1973 |
Current U.S.
Class: |
250/483.1;
252/301.4S |
Current CPC
Class: |
H01J
9/20 (20130101); H01J 29/385 (20130101) |
Current International
Class: |
H01J
29/38 (20060101); H01J 29/10 (20060101); H01J
9/20 (20060101); H01j 001/62 () |
Field of
Search: |
;250/460,483,486
;252/31.4S |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Borchelt; Archie R.
Attorney, Agent or Firm: Wille; Paul F. Cohen; Joseph T.
Squillaro; Jerome C.
Claims
What we claim as new and desire to secure by Letters Patent of the
United States is:
1. An improved screen for x-ray imaging devices comprising:
a wafer comprising a high density, high conversion efficiency
phosphor powder bonded together with doped CsI;
said doped CsI forming approximately 60-80 percent by volume.
2. An improved screen as set forth in claim 1 wherein said doped
CsI comprised CsI:Tl.
3. An improved screen as set forth in claim 1 wherein said high
density, high conversion efficiency phosphor comprises Gd.sub.2
S.sub.2 O:Tb.
4. An improved screen as set forth in claim 1 wherein said screen
is from 3 to 10 mils thick.
5. The method of making an improved input screen for x-ray imaging
devices comprising the steps of:
mixing together in a container Gd.sub.2 O.sub.2 S:Tb and doped CsI
in the ratio of about 1:2.5 by weight;
sealing said container under vacuum;
heating said container to at least 621.degree. C to melt said doped
CsI;
slowing withdrawing said container from the heat to form a
composite of Gd.sub.2 O.sub.2 S:Tb -- CsI;
removing the composite from said container; and
forming a plurality of wafers from said composite, wherein each
wafer comprises a complete input screen.
6. The method as set forth in claim 5 wherein said container is
heated to approximately 700.degree. C.
7. The method as set forth in claim 5 wherein said composite is
formed by withdrawing the container at 0.1 to 1.0 centimeters per
hour.
8. The method as set forth in claim 5 wherein said wafers are
formed by slicing said crystal and grinding the slices to a curved
surface configuration to form an input screen for an x-ray imaging
device.
9. The method as set forth in claim 5 wherein said doped CdI
comprises CsI:Tl.
Description
This invention relates to x-ray imaging devices and, in particular,
to an improved input screen for x-ray imaging devices.
A typical fluoroscopic x-ray examination utilizes an x-ray source,
an x-ray image intensifier and a choice of viewing or recording
devices such as direct viewing optics, camera for still or cine
photography, or a television camera tube. The x-ray image
intensifier converts the x-ray image, essentially a shadow cast by
a subject positioned between the source and the image intensifier,
to a visible image capable of being viewed or recorded.
The x-ray image intensifier comprises an evacuated glass envelope
containing an input phosphor screen for absorbing the incident
x-ray photons and converting these into light photons. In intimate
contact with the input screen is a photoemissive surface for
absorbing the light photons and converting them into
photoelectrons. A series of electrodes focuses and accelerates the
electrons so that they impinge on an output phosphor screen, which
converts the electron image back to a visible light image. The
image on the output phosphor screen is much brighter than that
formed by the input phosphor screen. This increase in brightness is
due partly to the acceleration of the electrons and partly to the
reduced size of the output screen as compared to the input screen,
typically 10:1 for a 6 inch input screen.
Input phosphor screens available in the prior art have comprised,
for example, ZnCdS:Ag or Gd.sub.2 O.sub.2 S:Tb powder in a resin
binder, or evaporated films of CsI:Na or CsI:Tl. Taking one
phosphor powder as an example, Gd.sub.2 O.sub.2 S:Tb, known to be
an efficient x-ray phosphor, must be mixed in powder form with a
resin, such as Dow Corning R-61-049 junction coating resin, to make
a screen. The screen thus comprises both active material, the x-ray
phosphor, and inactive material, the resin, which contributes
nothing to the conversion of the x-ray image to a visible image.
Further, approximately 58 percent by volume of the screen is the
inactive resin, i.e., the density and hence the x-ray absorption of
the screen is much lower than that of bulk Gd.sub.2 O.sub.2 S:Tb,
for a given thickness.
For doped films of CsI, the density of the films is approximately
that of a doped, single crystal of CsI.
For a given thickness, at x-ray energies greater than 50 keV, the
x-ray absorption of a Gd.sub.2 S.sub.2 O:Tb crystal is higher than
that of a CsI crystal or a ZnCdS crystal. Although one can make
evaporated CsI screens readily with a density approximately that of
a single crystal, it has not been possible to make screens from
Gd.sub.2 O.sub.2 S:Tb with a density close to that of a single
crystal and a thickness of several mils. However, the efficiency of
the evaporated CsI film in converting x-ray photons to light
photons is not as high as for Gd.sub.2 S.sub.2 O:Tb.
Increasing the thickness of either screen, while providing more
active material, is off-set by a decrease in the resolution
obtainable. Conversely, decreasing the thickness of the screen,
while increasing resolution, reduces the amount of active material,
thereby absorbing less x-rays.
Increased x-ray absorption and x-ray to light conversion efficiency
is desirable due to the discrete nature of the x-ray information.
Information contained in the x-ray photons incident upon the input
screen is lost unless the photons are absorbed and converted into
light photons. Simply increasing the brightness of the output light
image, e.g. by accelerating the electrons to higher energies, does
not increase the available information. If the x-ray absorption of
screen made from high conversion efficiency x-ray phosphors were
increased, then more information can be gleaned from the same x-ray
does. Conversely, the dosage could be decreased with no loss of
information as compared to other input screens of the prior
art.
In view of the foregoing, it is therefore an object of the present
invention to provide a phosphor screen with higher x-ray absorption
for a given thickness than has been obtainable in the prior
art.
Another object of the present invention is to provide a brighter
input screen, for a given thickness.
A further object of the present invention is to provide a higher
resolution input screen for a given thickness for x-ray imaging
devices.
Another object of the present invention is to provide an improved
x-ray input screen enabling lower x-ray dosage of human
subjects.
The foregoing objects are achieved in the present invention wherein
a composite of CsI:Tl and Gd.sub.2 O.sub.2 S:Tb powder is grown
from a mixture of the two materials by heating a sealed evacuated
tube containing the mixture above the melting point of the CsI:Tl
(621.degree. C) and slowly lowering the container from the hot to a
cooler zone so that the CsI:Tl crystallizes slowly and
progressively from one end to the other to form the solid
composite. The solid composite is then sliced into wafers, where
each wafer forms a screen. The CsI:Tl, which is also an efficient
x-ray phosphor, acts as a binder for the Gd.sub.2 O.sub.2 S:Tb
particles, thereby providing an active binder.
The notation ":Tb" or ":Tl", as known in the art, indicates that
the preceding material is doped with terbium or thallium,
respectively. For Gd.sub.2 O.sub.2 S:Tb, the phosphor contains from
3 .times. 10.sup..sup.-4 to 1 .times. 10.sup..sup.-2 mole fraction
Tb.sub.2 O.sub.2 S. For CsI:Tl, the phosphor contains from 5
.times. 10.sup..sup.-4 to 5 .times. 10.sup..sup.-3 mole fraction
TlI.
A more complete understanding of the present invention can be
obtained by considering the following detailed description in
conjunction with the accompanying drawings, in which:
FIG. 1 illustrates the apparatus used in growing a composite in
accordance with the present invention.
FIG. 2 illustrates the input screen in accordance with the present
invention in use in an x-ray image intensifier.
Input screens in accordance with the present invention comprise a
dense ceramic like composite material, Gd.sub.2 O.sub.2
S:Tb-CsI:Tl. In these, the CsI:Tl x-ray phosphor acts as a binder
for the powdered Gd.sub.2 O.sub.2 S:Tb x-ray phosphor. The screen
is mounted on the input side of a suitable evacuated glass envelope
containing the remaining parts of the image intensifying device.
The Gd.sub.2 O.sub.2 S:Tb and CsI:Tl compounds, while known
separately in the art as efficient x-ray phosphors, have not been
utilized together. Thus, for example, Gd.sub.2 O.sub.2 S:Tb must be
mixed with a silicone resin binder to provide a mechanically strong
input screen. However, in so doing, the screen is less dense than
desired for absorbing the incident x-rays. Thus screens of the
prior art are less x-ray absorbing than would be otherwise
desirable for obtaining maximum information from the x-ray beam. In
accordance with the present invention, input screens with higher
x-ray absorption for a given thickness are obtainable than from
either phosphors in resin or evaporated phosphors. Alternatively,
thinner screens with the same x-ray absorption for a given
thickness may be produced than are obtainable from the prior art,
thus increasing their resolution. Further, since CsI:Tl is a
phosphor while the resin is not, brighter screens are obtainable
for the same thickness and x-ray dosage than from either phosphors
in resin or evaporated phosphors.
FIG. 1 illustrates suitable apparatus for making screens in
accordance with the present invention. Generally, the apparatus
comprises a furnace from which a container of the phosphors may be
slowly removed. Further, provision must be made for agitating the
mixture periodically as it cools to prevent the formation of
bubbles or voids in the final composite.
Specifically, screens in accordance with the present invention are
made by mixing together the CsI:Tl and Gd.sub.2 O.sub.2 S:Tb
powders and placing them in a suitable container, such as a clear
fused quartz tube. The tube is then outgassed and sealed under
vacuum. The container, illustrated in FIG. 1 as container 11, is
then inserted in furnace 14 and heated to a temperature in excess
of the melting point of the CsI:Tl phosphor, that is, in excess of
621.degree. C. For example, 700.degree. C has been found to be a
convenient temperature. The proportion of the phosphors in mixture
12 is such that, upon melting of the CsI:Tl, excess CsI:Tl forms a
pool 13 at the top of the container.
Container 11 is preferably fixed to a support by connecting means
16 and heated by moveable furnace 14 having heating coils 15.
Moveable furnace 14 may be moved by any suitable means, such as a
platform jack. During the progressive cooling of container 11,
furnace 14 is slowly raised so that more and more of container 11
protrudes from furnace 14. As the melt cools, the CsI solidifies
and bonds together the particles of Gd.sub.2 O.sub.2 S:Tb to form a
ceramic like, composite material 17. At the end of the cooling
cycle, furnace 14 is shut off and lowered out of the way.
Furnace 14 is moved at a sufficiently slow rate, e.g. 0.1 to 1.0
centimeters per hour, to assure that the melt solidifies from one
end to form a compact solid free of internal voids. Internal voids
may form due to the large decrease in volume the CsI undergoes upon
solidification. Due to the high viscosity of the liquid containing
the suspended particles of Gd.sub.2 O.sub.2 S:Tb, voids may become
trapped in the composite during solidification. To prevent this,
some means of agitation must be provided, such as by solenoid 18.
Solenoid 18 is actuated to tap container 11 and agitate the
contents thereof. The frequency of the agitation depends upon the
growth rate of composite 17. At a growth rate of 0.5 centimeters
per hour, agitation once per second is adequate.
As previously noted, pool 13 is formed at the top of liquid 12.
This pool acts as a reservoir from which sufficient CsI is
withdrawn to replace the volume lost through shrinkage upon
solidification. Thus, despite the high viscosity of the liquid
portion containing the suspended Gd.sub.2 O.sub.2 S:Tb particles,
voids are prevented through the combination of agitation and pool
13.
A sufficient excess of CsI is obtained from a typical ratio by
weight of 2.5:1, CsI:Tl to Gd.sub.2 O.sub.2 S:Tb, respectively.
While less CsI:Tl may be utilized, for example, a ratio of 2:1, the
care required in assuring an adequate supply of phosphor binder
makes it inconvenient and inadvisable to work near the minimum
ratio of compounds. In other words, by providing an excess of the
phosphor binder, a convenient indicator is obtained of whether or
not an adquate amount of phosphor binder has been provided. Once
pool 13 is obtained, adding further CsI:Tl phosphor binder is
unnecessary.
After passing through furnace 14, container 11 is broken and the
composite removed. The composite does not adhere to the clear fused
quartz tube and is easily removed. After removal, the composite is
cut into thin wafers, for example, 3 to 10 mils thick, to provide a
plurality of screens from a single growth. The solidified excess
CsI:Tl is removed and can be re-used. The wafers from the composite
are cut in a flat plane by any suitable mechanism known in the art
and sagged into the desired spherical shpe by heating to slightly
less than the melting point of the CsI:Tl, e.g. 615.degree. C.
Alternatively, the wafers can be cut spherically or cut thicker
than desired and ground to the desired spherical shape. Suitable
mechanisms for performing the cutting and shaping of the wafers are
known in the art.
FIG. 2 illustrates a screen in accordance with the present
invention. Wafer 21, formed as described above, is placed at the
input face of tube 20 and cemented to it to act as a mechanically
strong substate. Formed in contact therewith is a photoemissive
screen 22 for converting the faint optical image into an electron
image. The electrons emitted by photoelectrode 22 are accelerated
to output phosphor screen 23 where the electron image is converted
into a brighter optical image. Suitable accelerating and focusing
electrodes 24 and 25, respectively, are provided as known in the
art to accelerate and focus the electrons. Due to the increase in
energy of the electrons, the brightness of the visible image formed
is intensified.
In operation, x-rays from a suitable source, designated as source
26, irradiate a subject 27 so that the shadow formed by the varying
degrees of x-ray opacity of subject 27 falls upon input screen 21.
The image is converted and intensified as described above and may
be viewed on screen 23 directly or a television camera tube may be
used so that the image is displayed on a TV monitor. Alternatively,
still or motion pictures may be taken of the output screen
image.
There is thus provided by the present invention an improved input
screen for x-ray imaging devices wherein one can obtain an output
visible image containing a higher information content, a brighter
image, a higher resolution image or, by decreasing the dosage, a
longer exposure of the subject so that the subject can be studied
for a longer period of time without exceeding recommended x-ray
dosages. In addition, the screen in accordance with the present
invention is mechanically strong and can be easily made in
quantity.
Having thus described the invention it will be apparent to those of
skill in the art that various modifications can be made within the
spirit and scope of the present invention. For example, while
container 11 has been described as fixed and furnace 14 moveable,
the same relative motion can be obtained with a fixed furnace by
moving container 11 together with the agitation mechanism 16.
Further, other dopants may be utilized in the cesium iodide, such
as sodium for example.
* * * * *