U.S. patent number 3,867,170 [Application Number 05/280,289] was granted by the patent office on 1975-02-18 for method for cleaning liquid developers.
This patent grant is currently assigned to Xerox Corporation. Invention is credited to Robert M. Ferguson, Richard J. Komp.
United States Patent |
3,867,170 |
Ferguson , et al. |
February 18, 1975 |
Method for cleaning liquid developers
Abstract
An electrostatographic imaging system wherein the imaging
surface is cyclically cleaned of residual aqueous liquid developer
by contacting the imaging surface with a cleaning liquid which is
miscible with the liquid developer to disperse substantially all
the residual liquid developer. The cleaning liquid is preferably
applied to the imaging surface by contacting the imaging surface
with an absorbent fibrous material moistened with the cleaning
liquid. The cleaning liquid with any dispersed aqueous developer
may be removed from the imaging surface by means of an absorbent
fibrous material.
Inventors: |
Ferguson; Robert M. (Penfield,
NY), Komp; Richard J. (Bowling Green, KY) |
Assignee: |
Xerox Corporation (Rochester,
NY)
|
Family
ID: |
26960181 |
Appl.
No.: |
05/280,289 |
Filed: |
August 14, 1972 |
Related U.S. Patent Documents
|
|
|
|
|
|
|
Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
886633 |
Dec 19, 1969 |
|
|
|
|
Current U.S.
Class: |
430/117.3; 134/6;
430/104; 399/346 |
Current CPC
Class: |
G03G
5/005 (20130101); G03G 21/0088 (20130101); G03G
9/18 (20130101) |
Current International
Class: |
G03G
5/00 (20060101); G03G 9/00 (20060101); G03G
21/00 (20060101); G03G 9/18 (20060101); G03g
013/22 (); B08b 003/08 () |
Field of
Search: |
;134/6,9 ;117/37LE
;96/1LY ;355/10,15 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Sofocleous; Michael
Parent Case Text
This is a division of application Ser. No. 886,633, filed Dec. 19,
1969, and now abandoned.
Claims
1. The method of cyclically developing electrostatic latent images
on a reusable electrostatographic imaging surface comprising the
steps of forming an electrostatic latent image on the imaging
surface, developing the image with an aqueous liquid developer,
transferring the developer from the imaging surface to a receiving
surface in image configuration, contacting said imaging surface
with a cleaning liquid which is miscible with said aqueous liquid
developer, distributing said cleaning liquid over said imaging
surface to dissolve residual developer liquid and disperse residual
developer solids in said cleaning liquid and substantially
completely removing the cleaning liquid and residual developer from
said imaging surface by moving contact with a dry absorbent fibrous
material.
2. The method of cyclically developing electrostatic latent images
on a reusable electrostatographic imaging surface comprising the
steps of forming an electrostatic latent image on the imaging
surface, developing the image with an aqueous liquid developer,
transferring the developer from the imaging surface to the
receiving surface in image configuration, contacting the imaging
surface with an absorbent fibrous material moistened with a
cleaning liquid which is miscible with the aqueous liquid
developer, distributing said cleaning liquid over a portion of said
imaging surface to dissolve residual developer liquid and disperse
residual developer solids in said cleaning liquid, and
substantially completely removing said cleaning liquid containing
said dissolved liquid developer therein from said imaging surface
to prepare the imaging surface
3. The method of claim 2 wherein said absorbent fibrous material
comprises
4. The method of claim 2 wherein said absorbent fibrous material is
a web in contact with said imaging surface and said step of
contacting includes supplying said miscible cleaning liquid to the
opposite side of said
5. The method of claim 2 wherein said step of removing comprises
contacting
6. The method of claim 2 wherein said miscible cleaning liquid has
a
7. The method of claim 2 wherein said imaging member is a
reusable
8. The method of claim 7 wherein the photoconductor is selected
from the
9. The method of claim 2 wherein said contact is contact under a
pressure
10. The method of claim 2 wherein said liquid developer has a
conductivity of from about 10.sup..sup.-4 (ohm-cm).sup..sup.-1 to
10.sup..sup.-10 (ohm-cm).sup..sup.-1.
Description
BACKGROUND OF THE INVENTION
This invention relates to imaging systems, and more particularly,
to improved cleaning systems and techniques.
The formation and development of images on the surface of
photoconductive materials by electrostatic means is well known. The
basic electrostatographic process, as taught by C. F. Carlson in
U.S. Pat. No. 2,297,691 involves placing a uniform electrostatic
charge on a photoconductive insulating layer, exposing the layer to
a light-and-shadow image to dissipate the charge on the areas of
the layer exposed to the light and developing the resulting
electrostatic latent image by depositing on the image a finely
divided electroscopic material referred to in the art as "toner."
The toner will normally be attracted to those areas of the layer
which retain a charge, thereby forming a toner image corresponding
to the electrostatic latent image. This powder image may then be
transferred to a support surface such as paper. The transferred
image may subsequently be permanently affixed to a support surface
as by heat. Instead of latent image formation by uniformly charging
the photoconductive layer and then exposing the layer to a
light-and-shadow image, one may form the latent image directly by
charging the layer in image configuration. The powder image may be
fixed to the photoconductive layer if elimination of the powder
image transfer step is desired. Other suitable fixing means such as
solvent or overcoating treatment may be substituted for the
foregoing heat fixing step.
Similar methods are known for applying the electroscopic particles
to the electrostatic latent image to be developed. Included within
this group are the "cascade" development technique disclosed by E.
N. Wise in U.S. Pat. No. 2,618,552; the "powder cloud" technique
disclosed by C. F. Carlson in U.S. Pat. No. 2,221,776 and the
"magnetic brush" process disclosed, for example, in U.S. Pat. No.
2,874,063.
Development of an electrostatic latent image may also be achieved
with liquid rather than dry developer materials. In conventional
liquid development, more commonly referred to as electrophoretic
development, an insulating liquid vehicle having finely divided
solid material dispersed therein contacts the imaging surface in
both charged and uncharged areas. Under the influence of the
electric field associated with the charged image pattern, the
suspended particles migrate toward the charged portions of the
imaging surface separating out of the insulating liquid. This
electrophoretic migration of charged particles results in the
deposition of the charged particles on the imaging surface in image
configuration.
A further technique for developing electrostatic latent images is
the liquid development process disclosed by R. W. Gundlach in U.S.
Pat. No. 3,084,043 hereinafter referred to as polar liquid
development. In this method, an electrostatic latent image is
developed or made visible by presenting to the imaging surface a
liquid developer on the surface of a developer dispensing member
having a plurality of raised portions or "lands" defining a
substantially regular patterned surface and a plurality of portions
depressed below the raised portions or "valleys." The depressed
portions of the developer dispensing member contains a layer of
conductive liquid developer which is maintained out of contact with
the electrostatographic imaging surface. Development is achieved by
moving the developer dispensing member loaded with liquid developer
in the depressed portions into developing configuration with the
imaging surface. The liquid developer is believed to be attracted
from the depressed portions of the applicator surface in the
charged field or image areas only. The developer liquid may be
pigmented or dyed. The developer system disclosed in U.S. Pat. No.
3,084,043 differs from electrophoretic development systems where
substantial contact between the liquid developer and both the
charged and uncharged area of an electrostatic latent image bearing
surface occurs. Unlike electrophoretic development systems,
substantial contact between the polar liquid and the areas of the
electrostatic latent image bearing surface not to be developed is
prevented in the polar liquid development technique. Reduced
contact between a liquid developer and the nonimage areas of the
surface to be developed is desirable because the formation of
background deposits is thereby inhibited. Another characteristic
which distinguishes the polar liquid development technique from
electrophoretic development is the fact that the liquid phase of a
polar developer actually takes part in the development of a
surface. The liquid phase in electrophoretic developers functions
only as a carrier medium for developer particles.
An additional liquid development technique is that referred to as
"wetting development" or selective wetting as described in U.S.
Pat. No. 3,285,741. In this technique, an aqueous developer
uniformly contacts the entire imaging surface and due to the
selected wetting and electrical properties of the developer,
substantially only the charged areas of the imaging surface are
wetted by the developer. The developer should be relatively
conductive having a resistivity generally from about 10.sup.6 to
10.sup.10 ohm-cm and having wetting properties such that the
wetting angle measured when placed on the imaging surface is
smaller than 90.degree. at the charged area and greater than
90.degree. at the uncharged areas.
While capable of producing satisfactory images, these liquid
development systems can be improved upon in certain areas.
Particular areas of improvement include those liquid development
systems employing reusable or cycling electrostatographic imaging
surfaces. In these systems, for example, a photoconductor such as a
selenium or selenium alloy drum as the photoconductor surface is
charged, exposed to a light and shadow image and developed by
bringing the image bearing surface into developing configuration
with an applicator containing developing quantities of liquid
developer thereon. The liquid developer is transferred according to
the appropriate technique from the developer applicator onto the
image bearing surface in image configuration. Thereafter, the
developer pattern on the electrostatographic imaging surface is
transferred to copy paper and the liquid developer may be absorbed
by the paper to form a permanent print. During the transfer
operation, not all the liquid developer is transferred to the copy
paper and a considerable quantity remains on the photoconductor
surface. In order to recycle the imaging surface, this residual
developer must be either removed or its effects counteracted,
otherwise it will tend to be present as background in subsequent
cycles. When the liquid developer is relatively conductive having,
for instance, a resistivity less than about 10.sup.10 ohm-cm, any
residue remaining on the imaging surface may dissipate any charge
subsequently put on it. That is, lateral conductivity of the liquid
developer on the imaging surface may become excessive and the
resolution of the resulting image will be poor. On repeated cycling
there is also a progressive accumulation of liquid developer on the
imaging surface since in each cycle not all the developer is
transferred to the copy paper. This progressive accumulation of
developer residue results in an overall loss of density,
deterioration of fine detail and contributes to increased
background deposits on the final copy particularly since accurate
imaging on the imaging surface may be inhibited.
Procedures to remove the residual liquid developer from the imaging
surface have been employed. A simple wiping technique with a cloth,
brush or weblike material has been proposed. However, to provide
adequate cleaning of the electrostatographic imaging surface, the
contact between the imaging surface and the cleaning member must be
so extensive and severe that there is a degradation of the imaging
surface. Otherwise, a film of residual developer will remain on the
imaging surface and interfere with any subsequent imaging cycle. An
additional proposed method of cleaning has been the use of a wiper
blade held in contact with the imaging surface which may be moved
over the imaging surface. Difficulties have been encountered with
this technique in that the entire residual developer is not
removed. Many of the difficulties described with respect to the
cleaning systems proposed are due to the fact that on cleaning a
film from a surface the film is progressively split so that on each
separate cleaning only about one half the film is removed.
SUMMARY OF THE INVENTION
It is therefore an object of this invention to provide a developing
system which overcomes the above noted deficiencies.
It is another object of this invention to provide a novel cleaning
system.
It is another object of this invention to provide a simple cleaning
system capable of cyclical use.
It is another object of this invention to provide a simple
mechanical means for cyclically cleaning a reusable imaging
surface.
It is another object of this invention to provide a cleaning means
for cleaning residual liquid developer from a reusable
electrostatographic imaging surface.
It is another object of this invention to provide a cleaning system
which makes more efficient use of cleaning materials.
It is another object of this invention to provide a liquid
development system superior to known systems.
It is another object of this invention to provide a cleaning system
superior to known systems.
The above objects and others are accomplished, generally speaking,
by providing a cycling electrostatographic imaging system having a
cleaning system which enables cleaning of residual liquid developer
without degradation of the imaging surface. The cycling
electrostatographic imaging system is cyclically cleaned by
contacting the residual developer on the electrostatographic
imaging surface with a cleaning liquid which is miscible with the
liquid developer. The cleaning liquid is employed in an amount
sufficient to dilute and disperse within it substantially all of
the residual liquid developer. More specifically, in a liquid
development system employing a cycling or reusable
electrostatographic imaging surface, the residual developer
remaining on the imaging surface in any one cycle, is cleaned from
the surface by directly contacting the imaging surface with a
fibrous material moistened with the cleaning liquid and then
removing the excess liquid by contacting the imaging surface with a
dry fibrous material. By so applying the cleaning liquid to the
imaging surface, the residual liquid developer is effectively
dispersed within the miscible cleaning liquid and substantially
completely removed from the imaging surface. After contact with the
dry fibrous material, any cleaning fluid remaining on the imaging
surface following removal of the residual liquid developer may be
removed by means of a stream of warm air.
The invention may be further illustrated by reference to the
accompanying drawings in which:
FIG. 1 is a schematic view of an embodiment of an
electrostatographic imaging system employing the cleaning system of
this invention.
FIG. 2 is a schematic view of a portion of an electrostatographic
imaging system employing an alternative cleaning system.
FIG. 3 is a schematic view of an alternative cleaning system.
In the electrostatographic imaging system depicted in FIG. 1, an
electrostatic latent image is placed on the imaging surface here
illustrated as a rotating cylindrical drum photoconductor 10, such
as a selenium drum, by uniformly placing a positive charge on the
drum by charging means 11, exposing the charged surface to a
light-and-shadow image through exposure means 12. The electrostatic
latent image is developed at developing station 13 and the
developer on the imaging surface in image configuration is
transferred to a receiver sheet such as ordinary paper 14, which is
moved through the transfer zone in contact with the drum at the
same rate and in the same direction as the periphery of the drum.
The paper to which the developed image is transferred is held in
transfer position by idlers 15. The residual liquid developer
present on the electrostatographic imaging member is then cleaned
from the imaging member at cleaning station 16. At cleaning station
16, a porous absorbent roll 24, is rotating in a bath 23, of
cleaning liquid 25, and is in contact with one side of an absorbent
fibrous cleaning web 17. The cleaning web 17, is slowly advanced
from supply reel 19, through idlers 21 and 22, into wiping contact
with the imaging surface and finally into takeup reel 18. The
cleaning web is preferably moved slowly in the direction
counter-current to the direction of the advancing imaging surface
so that the cleanest portion of the web contacts the cleanest
portion of the imaging surface. In any imaging cycle, in the
initial stages of contact between the cleaning web and imaging
surface, the cleaning liquid and the residual liquid developer are
intimately mixed together with large or gross quantities of liquid
being absorbed by the cleaning web. As a result of the
countercurrent motion of the imaging surface and the cleaning web,
the residual liquid developer and the cleaning liquid are removed
from the imaging surface by the cleanest portion of the cleaning
web. The cleaning liquid applicator roller 24, supplies cleaning
liquid to the absorbent cleaning web 17, which passes through the
cleaning web and contacts the imaging surface, and there dilutes
and dissolves the liquid developer. This countercurrent movement of
imaging surface and cleaning web provides, in the order of sequence
in which they take place on the imaging surface, the removal of
gross quantities of cleaning liquid and liquid developer, dilution
and solution of the liquid vehicle of the developer in the cleaning
liquid together with dispersion of any solid developer materials
such as pigments in the cleaning liquid, and removal of residual
mixture of cleaning liquid and liquid developer. While it is
anticipated that the absorbing cleaning web will be adequate to
remove substantially all the liquid developer, a heat source such
as lamp 26, may be provided to dry or volatilize any residual
liquid remaining on the imaging surface. The cleaning liquid
applicator roller 24, may be independently driven or driven by
contact with the absorbent fibrous material and may be retractable
from the web surface to provide cleaning liquid only on demand. It
may also be desirable in certain machine configurations to provide
a cleaning system which is retractably engagable with the imaging
surface.
FIG. 2 depicts the cleaning portion of a schematic view of the
technique according to this invention in which an
electrostatographic imaging surface 36, is in contact with cleaning
web 30, advanced in countercurrent direction to the imaging
surface. In this embodiment, the liquid cleaning material 34, in
bath 35, is applied to the cleaning web 30, held in the cleaning
bath by roller 33, but out of contact with the imaging surface. The
cleaning web is advanced from a supply roll 37, through idler
rollers 32 in contact with the imaging surface and thereafter
advanced through the cleaning liquid bath 35, and again advanced
past the imaging surface by idler 32, on to takeup roll 31.
The embodiment shown in FIG. 3 is an alternative to the cleaning
system of this invention in which two web cleaning stations are
provided. In the direction of movement of the electrostatographic
imaging surface, after transfer of the developed image in image
configuration to a receiver sheet, the imaging surface 41, first
comes in contact with fibrous web 44, having absorbed therein
cleaning liquid. The cleaning liquid 43, is supplied from bath 45,
by immersing the fibrous web supply roll 42, in the bath. The
fibrous web is supported in contact with the imaging surface by
means of idler 47, and is stored when dirty on takeup roll 46.
Following cleaning with the cleaning liquid, the imaging surface
may be in moving contact with dry absorbent fibrous web 49,
supplied from supply roll 51, and held in wiping contact with the
imaging surface by means of idlers 48, and stored after use by
means of takeup roll 50. This embodiment provides an initial
cleaning of the imaging surface by cleaning web 44, with cleaning
liquid 43, followed by a cleaning with a dry fibrous web.
The cleaning technique and apparatus according to the instant
invention has been found to be particularly effective in the
cleaning of aqueous liquid developers from electrostatographic
imaging surfaces. By aqueous development or aqueous developers, it
is intended to define that group of liquid developers which are
water compatible and which therefore include liquid compositions
based upon water, glycerin and suitable water compatible alcohols,
glycols, polyols and other well known polar liquids. Any suitable
developer from this class may be employed. Typically, the
developers for which this cleaning system is effective have a
conductivity of from about 10.sup..sup.-4 (ohm-cm).sup..sup.-1 to
about 10.sup..sup.-10 (ohm-cm).sup..sup.-1. Typical developer
vehicles within this group providing these properties include:
glycerol; polypropylene glycol; 2,5 hexanediol; methanol; ethanol;
propanol; isopropanol; 1,4 dioxane; acetic anhydride; formic acid;
glyoxal; mono, di and tri ethanol amine; butyl formate; eugenol;
acetyl acetone; and diethylene glycol mono ethyl ether and
glycerin. In addition, as is well known in the art, the developers
may contain one or more secondary vehicles, dispersants, pigments
or dyes, viscosity controlling agents or additives which contribute
to fixing the pigment on the copy paper.
As stated above, the liquid cleaning material is miscible with the
liquid developer. Any suitable cleaning liquid which is miscible
with the developer may be employed. Typical cleaning liquids
include the water compatible or aqueous liquids discussed above and
any additional liquid which is miscible with the particular
developer employed in any development system. Typical materials
include: water; methanol; ethanol; propanol; isopropanol; ethylene
glycol; 2,5, hexanediol; and glycerin. The cleaning liquids should
be so selected that they do not have a deleterious effect on either
the imaging surface which they are to clean or on any of the
materials or machine components with which they come in contact and
particularly should not chemically attack the absorbent fibrous
material which applies the cleaning liquid to the imaging surface.
Additionally, the cleaning liquids preferably are nonodorous and
nontoxic.
To facilitate complete removal of the cleaning liquid from the
imaging surface, it is preferred to provide a cleaning liquid which
is readily evaporated or removed from the imaging surface. To this
end, it is preferred to provide a cleaning liquid which has a
medium range volatility or will evaporate at a temperature below a
temperature which may thermally degrade any of the other materials,
and in particular, the imaging surface. In a particularly preferred
embodiment using a vitreous selenium photoconductor, it is
preferred to provide a cleaning liquid which has a boiling point
below about 130.degree. C. To minimize waste due to evaporation
during idle machine periods, it is preferred to provide a cleaning
liquid with a boiling point of between about 45.degree. C. to about
100.degree. C. Optimum conservation of cleaning liquid while
maintaining adequate removal ability without degradation of imaging
materials is obtained with the cleaning liquids having boiling
points from between about 60.degree. C. to about 80.degree. C. When
employing a material of medium to high range volatility, a simple
heating lamp such as depicted in FIG. 1 may be employed to provide
adequate removal of the cleaning liquid. Any residual cleaning
liquid containing aqueous developer dispersed therein remaining on
the imaging surface may be removed, however, with the use of a
highly absorbent, porous material.
The cleaning liquid may be applied to the imaging surface in any
suitable manner. Typically, an absorbent porous material such as
porous sponges and fibrous materials may be employed. Particularly
effective application of cleaning liquid is obtained with highly
absorbent fibrous materials. While the absorbent fibrous materials
may be employed in the configuration of felt tips or wicks, they
preferably are in the form of continuous webs to facilitate the
rapid continuing resupply of new cleaning and applicating surfaces
and to provide both applicating and removal surfaces. Since the
fibrous material may function as a liquid cleaning applicator to
the imaging surface and may also function as an absorbent sheet,
the fibrous material should have sufficient wet strength that it
does not rip or part when it is wet by the cleaning liquid. The
fibrous material is preferably softer than the imaging member so as
not to abrade it; is lint free so as not to offset lint or other
particulate matter to the imaging surface; and is not chemically
reactive with either the liquid developer or the imaging surface.
Also the fibrous material preferably does not contain any solubles
which may be dissolved in the cleaning liquid or cleaning system
and has adequate absorbent capacity to absorb the liquid residue
resulting from the smearing of the residual liquid developer and
the cleaning liquid on the imaging surface. The most important
characteristics of the fibrous material, however are the ability to
transmit cleaning liquid from a cleaning liquid supply to the
imaging surface and a good absorption and retention of cleaned
material after the cleaning has been accomplished. Any suitable
fibrous material may be used. Typical fibrous cleaning materials
include those made from cheesecloth, flannel, rayon, cotton,
Dacron, polyester fibers, polypropylene fibers, paper and
cellulosic fibers, Nylon, combinations of rayon and cotton and
mixtures thereof. Particularly satisfactory cleaning is obtained
with those fibrous webs which are substantially homogenous and
thick and have a high absorbent capacity.
The liquid cleaning material may be supplied to the absorbent
fibrous material in any suitable manner. Typical means of supplying
the cleaning liquid from a liquid reservoir to the absorbent fibers
is by means of an absorbent, porous wet sponge roll rotating in
contact with one side of the absorbent web which delivers the
cleaning liquid to the imaging surface on the other side of the
absorbent web. Additional means to supply the cleaning liquid to
the absorbent web include dipping the absorbent web in the cleaning
liquid to virtually saturate the absorbent web. Typical sponge
rollers include polyurethane foams and rubber sponges which may be
rotating in a bath of cleaning liquid or which may be fed
internally from some cleaning liquid reservoir at a remote site.
The cleaning liquid may also be applied to the absorbent fibrous
material by means of a porous belt applicator or by means of
brushes, capillary tubes, gravure roller, metallic sponge, unglazed
porcelain or felt tips. The liquid cleaning material may be
supplied to the imaging surface in any suitable amount. Preferably,
sufficient cleaning liquid is added to assist in loosening residual
developer from the imaging surface, in uniformly distributing it
over the imaging surface and in removing all particulate and
dissolved colorant. Typically, to achieve these results, the
cleaning liquid is applied to the imaging surface in an amount of
from about 0.2 to about 3 cubic centimeters per one hundred square
inches.
In operation an electrostatic latent image is placed on an
electrostatographic imaging surface in conventional manner. The
latent image is thereafter developed with a liquid developer
according to any of the techniques previously discussed.
Development preferably is obtained with the use of a patterned
surface applicator roller wherein a liquid developer is present in
the depressed portions of the applicator while the raised portions
are substantially free of developer and the developer is pulled
from the developer applicator to the imaging surface in image
configuration. After transfer of the developer from the imaging
surface to a receiver sheet in image configuration the residual
developer remaining on the imaging surface is removed from the
imaging surface according to the technique of this invention.
According to this technique and particularly according to the
preferred embodiment illustrated in FIG. 1, a cleaning liquid is
applied to an absorbent fibrous web material on one side from a
rotating porous sponge roll rotating in a bath of cleaning liquid
in an amount sufficient to provide a cleaning amount on the
opposite side of the absorbent fibrous web. While the cleaning web
and the imaging surface may be moved in the same direction, minimum
contact length and greater cleaning efficiency have been found to
occur when the web and the plate are moved in substantially
opposite directions. By applying the cleaning liquid to the
absorbent fibrous web at a point during the cleaning contact
between the web and the imaging surface intermediate the beginning
and terminating cleaning portions, a three section cleaning station
is provided. The imaging surface first encounters a wet section of
the web saturated with relatively dirty or developer contaminated
cleaning liquid containing dissolved residual liquid developer
vehicle and dispersed residual developer solids. The residual
liquid developer on the imaging surface is smeared or distributed
over the surface with excessive quantities of liquid developer
being removed. The imaging surface then passes against
progressively cleaner, but still wet sections of the web up to the
point of application of initial cleaning liquid and initial
formation of cleaning liquid and developer mixture; and finally
encounters a dry web which absorbs any remaining liquid developer
or cleaning liquid. It should be emphasized that the contact
between the cleaning web when wet and the imaging surface provides
the necessary smearing of cleaning liquid and residual developer to
remove substantially all residual developer from the imaging
surface including any particles which may have adhered rather
tightly to the imaging surface. As also depicted in FIG. 1, if
necessary or desired, any residual liquid cleaner or developer may
be removed by the application of heat.
Typically, the absorbent fibrous material is in the form of a web
positioned along a portion of the imaging surface. The length of
contact between the imaging surface and the absorbent fibrous web
is dependent upon many factors including, but not limited to, the
amount of cleaning liquid necessary to apply, the amount of
residual developer necessary to remove, the absorbent capacity of
the particular fibrous cleaning web, the solvent action of the
cleaning fluid, and the speed of operation. Typically with an
electrostatographic imaging surface in the configuration of a drum,
the area of contact with the cleaning web may compise from about 5
to about 50% of the imaging surface during any portion of the
cleaning cycle. To provide adequate spacing of additional imaging
stations while providing cleaning, the cleaning web may preferably
comprise from about 30 to about 40% of the imaging surface area.
While the cleaning and imaging surface may be moved in the same
direction, minimum contact length has been found to occur when the
web and plate are moved in substantially opposite directions. The
contact length may also be varied to some extent by the application
of pressure between the cleaning web and the imaging surface.
However, the pressure must be so regulated so as not to provide any
unnecessary abrading function on the imaging surface. Typically,
the pressure applied between the cleaning web and the imaging
surface in both dry and wet portions is between about 0.25 and
about 10 pounds per lineal inch of contact between the cleaning web
and imaging surface. A satisfactory balance between minimizing
abrasion effects on the imaging surface and absorbing capacity of
the cleaning web is observed with a pressure of from about 0.5 to
about 3 pounds per lineal inch at the line of contact between the
cleaning web and the imaging surface. The rate at which a web of
cleaning material is consumed is a function of the rate of plate
movement and the relative rate of the web required to yield
satisfactory cleaning has been found to vary to some degree
depending upon the particular cleaning material employed. Typically
the cleaning web is found to have a speed on the order of 1/40 to
1/1500 of the imaging surface speed. To reduce drag on the cycling
imaging surface and reduce the tendency for the web to rip, but
allowing sufficient time for adequate absorption of residual
developer and cleaning liquid the cleaning web preferably has a
speed on the order of from about 1/100 to about 1/500 of the
imaging surface speed.
Any suitable electrostatographic imaging surface may be cleaned
with the technique of this invention. Basically any surface upon
which an electrostatic charge pattern may be cyclically formed or
developed may be employed. Typical electrostatographic imaging
surfaces include dielectric materials, dielectrics coated on
conductive surfaces such as plastic coated papers or metal belts,
xeroprinting masters, electrographic recording surfaces,
photoconductors and overcoated photoconductors. Typical
photoconductors that may be employed include selenium and selenium
alloys, cadmium sulfide, cadmium sulfo selenide, phthalocyanine
binder coatings, and polyvinyl carbazole sensitized with 2,4,7
trinitrofluoronone. The electrostatographic imaging surface may be
employed in any suitable structure including plates, belts or drums
and may be employed in the form of a binder layer. For more
effective cleaning, it is preferred to provide a surface to be
cleaned which has a very smooth surface and generally the more
smooth and uniform the surface, the better will be the
cleaning.
DESCRIPTION OF PREFERRED EMBODIMENTS
The following preferred examples further define and describe the
preferred materials, methods and techniques of the present
invention. Example II is presented for comparison purposes. In the
examples, all parts and percentages are by weight unless otherwise
specified.
EXAMPLE I
An imaging system similar in configuration to that depicted in FIG.
I but without the heat lamp is assembled. A photoconductor in the
form of a drum comprising a surface layer of selenium about 20
microns thick on a conductive aluminum substrate is positively
charged to about 450 volts and exposed to a light-and-shadow image
in conventional manner. The electrostatic latent image is developed
by moving a patterned surface applicator roll having developing
quantities of developer in the depressed portions thereof past the
image bearing surface so that liquid developer is pulled out of the
depressed portions to the image bearing surface in image
configuration. The speed of development is about 12 inches per
second. The developer employed is of the following composition by
weight: Glycerol 76 parts by weight Nigrosine J 4 parts by weight
Sorbitol 19 parts by weight Santicizer 160 2 parts by weight
Nigrosine J is a dye available from American Cyanamid Company.
Santicizer 160 is a butyl benzyl phthalate plasticizer available
from Monsanto Company. The developer on the photoconductor is
transferred to bond paper in image configuration. A cleaning liquid
applicator comprising polyurethane foam, wrapped on a steel core to
provide a roll about 1 to 11/2 inches in diameter is independently
driven partially submerged in a cleaning liquid bath of two parts
by weight n-propyl alcohol and one part by weight water on the one
side and in contact with a fibrous absorbent web on the other side.
The web is made of rayon and is available from the Kendall Company
under the designation Webrils T3529. The cleaning liquid applicator
sponge roll is positioned about midway between two idler rollers
which position the cleaning web in contact with the selenium drum
along about 30% of its area. The cleaning web is advanced in the
direction opposite to the selenium drum at a speed of about 1/150
.sup.th that of the drum speed and in contact under a pressure of
about 2 pounds/lineal inch. The first print obtained with this
apparatus is free of background and has a resolution of about 10
line pairs per millimeter. After repeated cycling of 50 prints no
significant change in print quality is observed. Furthermore, the
machine components are substantially dry and free from liquid
developer and cleaning fluid.
EXAMPLE II
The procedure of Example I is repeated except that the polyurethane
cleaning liquid applicator roll is disengaged from the cleaning web
so that only a substantially dry web cleaning is provided. The
first print obtained has a resolution of about 10 line pairs per
millimeter. No further images are obtained on further cycling
because the residual conductive ink film dissipates the electrical
charge on the photoreceptor.
EXAMPLE III
An overcoated photoconductor about 9 inches by 14 inches in
dimension comprising a one quarter mill film of polyethylene
terephthalate (obtained from E. I. DuPont de Nemours & Company
under the trade name Mylar) overcoated on a 20 micron thick layer
of selenium or an aluminum substrate prepared according to the
procedure of Example I in U.S. Patent No. 3,251,686 is charged and
exposed to a light-and-shadow image in conventional manner. The
electrostatic latent image is developed with a developer of the
following composition by weight:
2,5-Hexanediol 98 parts by weight Butvar B-78 1 part by weight
Irgacet Black RL 1 part by weight
Butvar B-78 is polyvinyl butyrol sold by Shawinigan Resins
Corporation. Irgacet Black RL is a dye sold by Geigy Chemical
Corporation. The developer on the overcoated photoconductor is
transferred to bond paper in image configuration. The overcoated
photoconductor is contacted with a 120 line per linear inch
patterned gravure roll carrying a cleaning liquid comprising by
weight about 90 parts water and about 10 parts acetylacetone.
Thereafter, the overcoated photoconductor is contacted with a web
of Miracloth Type 9243, a nonwoven Rayon fabric sold by Chico pee
Mills Incorporated under a pressure of about 0.75 pound per lineal
inch and moving at a rate of 1/500 .sup.th of the photoreceptor.
The first print has a resolution of about 7 line pairs per
millimeter. After repeated cycling of 35 prints no significant
change in print quality is observed and no residual developer film
is present on the overcoating.
EXAMPLE IV
A xeroprinting master 9 by 14 inches is prepared by placing a thin
insulating coating of epoxy resin about 0.0005 inches thick in
image configuration on a conductive plate of aluminum by means of a
silk screen stencil, and then hardening the resin in known manner.
The plate is charged to +450 volts by passing it under a corona
charging unit. The image is developed in the manner described in
Example I with a liquid developer having the following composition
by weight:
Polypropylene glycol 67 parts by weight Staybelite Ester 5 7 parts
by weight Microlith CT Black 20 parts by weight Ganex V516 7 parts
by weight
Staybelite Ester 5 is an esterified wood rosin sold by Hercules
Powder Company. Microlith CT Black is a predispersed carbon black
pigment and ester gum composition in the approximate ratio of 40%
pigment to 60% resin. Ganex V516 is an alkylated polyvinyl
pyrrolidone sold by GAF Corporation. The developer is transferred
to bond paper and the resulting print has an image density of about
0.7, background density of less than 0.01, and resolution of about
6 line pairs per millimeter. The plate is cleaned by contacting it
with a nitrile sponge rubber roll saturated with a cleaning liquid
of 2 parts ethanol and one part water by weight. Thereafter, the
xeroprinting master is wiped with a web of Webrils type T3707, a
nonwoven rayon fiber fabric sold by the Kendall Company to provide
a substantially dry imaging surface. The master is cycled 75 times
without any loss in image quality. Between cycles, the surface of
the master is substantially dry.
EXAMPLE V
The procedure of Example I is repeated with a developer liquid of
the following composition by weight:
Diethylene glycol monoethyl ether 69 parts by weight Microlith CT
Black 31 parts by weight
The polyurethane roll is rotating in contact with a bath of
cleaning liquid comprising 4 parts by weight water and 1 part
diacetone alcohol. The cleaning web is made of nonwoven polyester
fabric sold by the Kendall Company under the name Webrils 1445 and
is advanced in the direction opposite to that of the selenium drum
at a speed of about 1/375 .sup.th that of the drum speed and is in
contact with the drum under a pressure of about 1.5 pounds per
linear inch. Results comparable to those obtained in Example I are
obtained.
EXAMPLE VI
The procedure of Example I is repeated with a developer liquid of
the following composition by weight:
Glycerol 70 parts by weight Sorbitol 14 parts by weight Nigrosine J
2 parts by weight Methylene Blue 0.3 parts by weight
Triethanolamine 14 parts by weight
The first print obtained has a resolution of about 6 line
pairs/millimeter and is free of background. The residual ink
remaining on the photoreceptor is cleaned by first contacting the
photoreceptor with a cleaning web saturated with a cleaning liquid
comprising by weight 3 parts water and one part ethylene glycol
monomethyl ether. The cleaning web is made of a nonwoven Dynel
fabric sold by the Kendall Company under the name of Wibrils M
1410. (Dynel is the trademark for a modacrylic fiber sold by Union
Carbide Chemicals Company.) The cleaning web is submerged in the
bath of cleaning liquid as shown in FIG. III and applies cleaning
liquid to the photoreceptor along about 15% of its area. The
cleaning liquid on the photoreceptor is next contacted by a dry web
of the same materials as described above covering about 25% of the
photoreceptor area and effectively absorbing all of the cleaning
liquid diluted residual developer film. Both cleaning webs are
driven counter to the photoreceptor direction at a speed of about
1/450 .sup.th that of the photoreceptor and in contact with the
photoreceptor under a pressure of about 0.75 pounds per linear inch
of contact. After repeated cycling of 50 prints, no significant
change in print quality is observed. Furthermore, the machine
components are substantially dry and free from liquid developer and
cleaning liquid.
The technique provided by the instant invention provides a
substantially complete cleaning of all residual aqueous developer
from an imaging surface without any significant abrasion of the
imaging surface in a very fast and efficient manner and employs
very few mechanical moving parts. It further provides a cleaning
system which minimizes contamination of mechanical movements by the
excessive use of liquids and conserves expendible material by
applying only sufficient cleaning materials, cleaning liquid and
cleaning web, to the area to be cleaned.
Although specific materials and operational techniques are set
forth in the above exemplary embodiment using the cleaning
technique of this invention, these are merely intended as
illustrations of the present invention. There are other materials
and techniques than those listed above which may be substituted
with similar results. Other modifications of the present invention
will occur to those skilled in the art upon a reading of the
present disclosure which modifications are intended to be included
within the scope of this invention.
* * * * *