U.S. patent number 3,866,565 [Application Number 05/427,124] was granted by the patent office on 1975-02-18 for vapor deposition apparatus with rotating drum mask.
Invention is credited to David E. U. Ridout.
United States Patent |
3,866,565 |
Ridout |
February 18, 1975 |
VAPOR DEPOSITION APPARATUS WITH ROTATING DRUM MASK
Abstract
Apparatus and method for depositing a stripe of metal on a
metallic strip, comprising a peripherally slitted wheel or drum
enclosing a vaporizing boat into which the metal to be deposited is
fed and heated to vaporization. A strip of metal of resistance
material which is to be coated along its central portion is
entrained and moved along the outer periphery of the slitted wheel
or drum so that the edges of the slit define the limits of the
coating to be deposited onto the metal strip. Both the slit wheel
and vaporizing boat are water cooled. The entire assembly
comprising the slit wheel, vaporizer and wire feeder are contained
within an evacuated container. A heating current is passed through
a length of the strip to heat it before it is coated. A
modification is to provide a wheel with peripheral holes for
depositing longitudinally spaced spots of metal, instead of a strip
of metal, onto a metallic base strip. A plurality of such wheels
may be used for simultaneously depositing metallic spots onto a
plurality of metal strips disposed side-by-side.
Inventors: |
Ridout; David E. U. (Export,
PA) |
Family
ID: |
23693579 |
Appl.
No.: |
05/427,124 |
Filed: |
December 21, 1973 |
Current U.S.
Class: |
118/718; 118/504;
118/620; 118/721; 118/725 |
Current CPC
Class: |
C23C
14/042 (20130101); C23C 14/562 (20130101) |
Current International
Class: |
C23C
14/56 (20060101); C23C 14/04 (20060101); C23c
013/12 () |
Field of
Search: |
;118/620,48-49.5,504,505,301,406 ;117/107.1,38 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Kaplan; Morris
Attorney, Agent or Firm: Ruano; William J.
Claims
1. Apparatus for depositing vaporized metal along the intermediate
longitudinal portion of an elongated base strip, comprising a drum
having central opening means extending along the entire periphery,
means for rotating said drum about its axis, a source of metallic
vapor on one side of said opening means, means for longitudinally
moving a base strip entrained on the other side of the drum
overlying said opening immediately adjacent said opening means,
said source of metallic vapor being contained within said drum and
comprising a boat-like container which is heated to vaporization
temperature of a strip of metal progressively fed into said
container, and said base strip being longitudinally driven along a
portion of the outer periphery of said drum so that the inner
surface exposed to said slit will become coated with said vaporized
metal, the edges of the slit defining the boundaries of the coated
strip, said base strip being driven by a motor and further
entrained about a plurality of idler wheels, a source of potential
being applied between a brush which contacts the shaft of one of
said idler wheels and a brush which contacts the shaft of said drum
so as to provide electric heating current to a portion of said base
strip extending between the periphery of one of said idler wheels
and of said drum, to effect preheating of said portion before
deposition of vaporized metal thereon through said slit, and means
contacting said drum beyond the area of strip contact whereby to
remove excess deposited metal
2. Apparatus as recited in claim 1, together with a back plate
rotatably mounting said drum, and together with a pivotally mounted
cover having a flexible sealing gasket about the mouth of said
cover for engaging and forming a seal with said back plate, and
evacuating means for evacuating
3. Apparatus as recited in claim 1 together with water cooling
conduits extending through a spindle on which said drum is rigidly
connected and through interior portions of said drum and back plate
on which said
4. Apparatus as recited in claim 3 together with a pair of
electrical, water-cooled terminals extending through said back
plate and to the ends of said container for passing electric
heating current through said
5. Apparatus as recited in claim 1 together with a supply roll of
strip material and means for longitudinally moving said strip
material into said
6. Apparatus as recited in claim 1 wherein said opening means is in
the form of a plurality of holes extending along the entire
periphery of said
7. Apparatus as recited in claim 6 wherein a masking strip is
longitudinally moved between the periphery of said drum and the
base strip
8. Apparatus as recited in claim 1 comprising a plurality of drums
in side-by-side relationship with said drum, each having a
circumferential slit and a plurality of base strips simultaneously
moved longitudinally outside said slits, whereby the base strips
which are moved along said
9. Apparatus as recited in claim 1 wherein said means to remove
excess deposited metal comprises knife means projecting into the
sides of said slit.
Description
This invention relates to apparatus for coating a strip of metal
onto a base metallic strip, such as one of resistance material, or,
in the alternative, for coating a series of metallic spots
thereon.
In the past, the common way of applying a coated strip of metal
onto a base strip has been by an electrolytic method by first
masking the sides of the strip and, after the electrolytic process,
dissolving the masking strips and then finally washing out the
resulting liquid. This involves considerable apparatus, chemicals,
large tanks of water and extended time for manufacture that have
made the cost of the process exhorbitant.
An object of the present invention is to overcome the abovenamed
disadvantages and high costs by eliminating the necessity of
masking the strip and using solutions for dissolving the masking
material.
An object of the present invention is to overcome the abovenamed
disadvantages and high costs by eliminating the necessity of
masking the strip and the masking material.
A more specific object of my invention is to provide a novel
apparatus for applying a strip or spots of vaporized metal to the
strip after electrically heating a portion of the strip in a vacuum
chamber.
Other objects and advantages will become more apparent from a study
of the following description taken with the accompanying drawings
wherein:
FIG. 1 is an elevational view, with the cover removed, of apparatus
for depositing vaporized metal in the form of a central strip
portion onto a metallic base strip, in accordance with the present
invention;
FIG. 2 is a side view thereof, reduced in size and showing the
cover in place, which cover is shown partly cut-away to expose the
interior parts;
FIG. 3 is an enlarged, vertical, cross-sectional view of the slit
wheel and vaporizer shown in FIGS. 1 and 2;
FIG. 4 is an enlarged, fragmentary view of a portion of the strip 9
illustrated in FIGS. 1 and 2, showing the deposited central strip
portion 36 thereon;
FIG. 5 is a vertical, plan view, partly in cross-section, showing a
modification wherein radial holes are provided to apply a series of
longitudinally spaced spots, instead of a strip, on the base
metallic strip;
FIG. 6 is an elevational view, partly in vertical cross-section, as
viewed from the left of FIGS. 5;
FIG. 7 is an enlarged, fragmentary view of a portion of the spotted
strip 61 illustrated in FIGS. 5 and 6;
FIG. 8 is a further modification showing multiple slit wheels for
applying central coated strips to a plurality of base metallic
strips, simultaneously; and,
FIG. 9 is a cross-sectional view taken along line IX--IX of FIG.
8.
Referring more particularly to FIGS. 1, 2 and 3, of the drawing,
numeral 1 generally denotes apparatus for vaporizing metal and
depositing it in the form of a strip along a central portion of a
base metallic strip of electrical resistance material. The
apparatus is mounted on a back plate or support 2 and is enclosed
by a cover 3 which may be either round, to form a bell jar, or
rectangular in shape and sealed to the back plate 2 by a sealing
strip 6 of neoprene rubber or other suitable material to enable
retention of a vacuum in the space enclosed by the cover 3. The
cover 3 is hingedly mounted on back plate 2 by a double hinge 4, 5
and may be sealed tightly thereagainst by seal 6 and by a handle
and cam lock (not shown), such as commonly used in the past on
iceboxes and the like. An evaporation boat 23 heats to vaporization
a strip of aluminum 24 or other metal to form the coating or stripe
36.
The space within cover 3 is evacuated by a mechanical pump driven
by a motor, generally denoted by numeral 8, and a diffusion pump 7
of any well known type with suitable controls for allowing
roughing, that is, partial evacuation by the mechanical pump and
further evacuation by the diffusion pump. The diffusion pump has an
outlet leading through a hole 7' in the back plate 2 to evacuate
the space covered by sealed cover 3. A gate valve 46a is supported
on the back plate for controlling the flow of air exhausted from
the space in cover 3.
A strip 9 of metal, particularly metal having high electrical
resistance, such as an alloy of iron, nickel and cobalt sold under
the trademarks KOVAR and FERNICO, is unwound from a feed spool 10,
passed over a guide spool 11 and thence over a centrally slitted
drum or wheel generally denoted by numeral 15. A stripe 36 (see
FIG. 4) of aluminum or of other vaporized metal is deposited on
strip 9 through a slit in the wheel, thereafter the strip is passed
over a second guide spool 12 and finally wound onto a take-up spool
13. The slit wheel assembly comprises three essential parts: an
inner wheel 20 an outer wheel 21, and a spindle 16 on which both
are rigidly mounted and spaced apart by slit 9. This assembly is
water cooled.
The spindle 16 is essentially a piece of pipe threaded at one end
and with a flange 34 with recessed O ring attached. A small pipe 42
located concentrically carries cooling water to the inner and outer
slit wheels. The inner wheel 20 is permanently attached to the
spindle.
Both slit wheels 20 and 21 have cavities through which cooling
water flows. It enters the spindle via a rotating seal 18 outside
the vacuum chamber, and flows into a cavity in the inner slit wheel
20 through a hole 38 in the spindle. When the cavity is full the
water flows out through a radially located inlet pipe 40 connected
to the pipe 42 concentric with the spindle. Inlet pipe 37 and
outlet pipe 43 are provided for water flow.
The outer wheel 21 is similar to the inner and has a water cavity,
the chief difference being that it is drilled and tapped to fit
onto the threaded end of the spindle. By this means, the wheel is
pulled up tightly against the O ring in the spindle flange, thus
sealing in the cooling water. The outer slit wheel 21 differs in
that it has an additional water cavity 41a supplied by a radial
pipe 41 thence flowing into the pipe 42 concentric with the
spindle. Water flows into the main cavity through holes 39 drilled
in the threaded portion of the spindle. The water cavities of the
inner and outer split wheels are thus in parallel. Before taking
off the outer slit wheel 21, the water is removed by so positioning
the wheel that the radial pipe is vertically below the spindle and
applying a few pounds of pressure of compressed air.
Provision is made for adjusting the width of the aluminum stripe by
inserting washer of appropriate thickness between the outer slit
wheel 21 and the spindle flange 19. An additional O ring to that
shown is let into the outer slit wheel 21 to effect a water seal.
The spindle is supported by ball races 17 (not self-aligning) and
is insulated electrically from the back plate 2 in much the same
way as the outer spindles. The spindle is held in position by a
ring 18 on a threaded portion of the spindle outside the vacuum
chamber. A window 45 is provided to enable viewing of the interior
of the space or chamber enclosed by lid 3. A graphite brush
assembly is located on the spindle next to the rotating water
seal.
The feeder for the aluminum wire 24 consists of four separate
assemblies: (1) knurled wheel assembly; (2) Wilson seal assembly);
(3) Motor and gearbox; and (4) spool support and guide tube.
The knurled wheel assembly 30 for feeding aluminum wire into
evaporating boat 23 comprises two bars 30a, 30b, each carrying a
knurled wheel 22a on a shaft inserted in small ball races pressed
into opposite sides of the bars, which are clamped to a pivot 33 by
means of two tie rods located at opposite ends of the bars. By
adjusting the nuts on the tie rods, suitable clearance between the
knurled wheels may be obtained. The pivot 33 is extended to serve
as a support for the knurled wheel assembly and is terminated at
the end by a flange bolted to the back plate 2.
The boat 23 is preferably made of boron nitride or other conducting
material. The aluminum strip is electrically heated in the boat by
power lead-ins comprising copper bars 28 extending through and
insulated to back plate 2 and connected to the boat through copper
delivery tubes 26, 27 which are constricted at the point of entry
35 through the slit between wheels 20 and 21. The bars 28 are
cooled by passing cooling water in pipes 26, 27 therethrough.
A length of strip 34 between idler wheel 11 and drum 15 may be
electrically preheated by a source of voltage V connected to their
shafts through brushes B. Such preheating improves adherence of
stripe 36.
FIGS. 5, 6 and 7 show a modification for applying spaced spots of
vaporized metal, instead of a strip of metal, onto the base
metallic strip 61. Numeral 1' denotes a back plate on which is
mounted apparatus generally denoted by numeral 50 for depositing
spots of vaporized metal onto strip 61, such as an electrical
heater strip, for example, one of an iron, nickel cobalt alloy,
such as KOVAR. The wheel or drum 51 is rotatably mounted on a
tubular shaft or pipe 52 by means of a pipe flange 53 bolted to the
drum 51. A plurality of sprockets 54 project radially outwardly
from the peripheral surface of the drum for guiding the strip 61,
that is, by projecting sprockets 54 through holes 54' extending
along the edges of the strip. A plurality of circumferentially
spaced holes 55 are provided through which vaporized metal is
passed and deposited on strip 61 in the form of spots, such as 60,
shown in FIG. 7.
A water cooling pipe 57 is provided with an inlet pipe 58 to allow
the flow of cooling water through boat 56 which contains the
vaporizing metal, such as gold, which is fed into vaporizing boat
56 in the form of a strip through tube 58. A masking strip 59,
entrained about idler wheels 64 and 65, will mask the sides of the
strip (or any other portion).
FIG. 7 shows the resultant design. The strip 61 is entrained about
guide spools 62 and 63 and underneath arcuate guide 66 so as to be
laid onto masking tape 59 before vaporized metal is deposited
thereon. The iron-nickel stamped lead frame strip 61 may have
cut-out portions such as 61a which provide inwardly projecting
fingers 61b whose inner extremities would be coated with gold
spots, -- four in number, corresponding to the peripheral portions
of a single spot 60.
FIGS. 8 and 9 show a modification of the invention illustrated in
FIGS. 1 to 4 inclusive for depositing a stripe of metal 36 onto a
metallic strip 9, preferably of resistance material. As shown in
FIGS. 8 and 9, a plurality of wheels 70 may be provided with
V-shaped slots and arranged side-by-side and guided by locating
wheels 74 and a spring loaded locating wheel 73. A supply spool
feeds aluminum wire 77 into a evaporating boat 76 serving all of
the slit wheels. A water cooled shield is provided between each
slit wheel. Radiation shields 78 are provided on the outside of the
slit wheels at the ends of the gang assembly. Thus a plurality of
metal strips 9, when entrained about the slits between the
respective wheels, will be coated simultaneously with stripes 36
centrally and longitudinally of the strip, as shown in FIG. 4.
Such deposited stripes may be used for numerous purposes, including
the making of a bimetallic strip, such as, by depositing a
silver-copper eutectic stripe on a strip 9 of 0.01 inch iron-nickel
cobalt alloy. This comprises a significant improvement over the
common method of bonding by rolling a silver-copper eutectic foil
about 2 mils thick onto a nickel-iron strip. Foil is difficult to
roll, particularly thinner than 1 mil.
It will be readily apparent to those skilled in the art that
variations may be made in the illustrative embodiments heretofore
described. For example, instead of putting the vaporization boat
inside the slit wheel, it may be put on the outside and under it
while passing the metallic strip 9 inside the wheel adjacent the
periphery. A plurality of such units may be provided side-by-side,
as illustrated in FIGS. 8 and 9.
* * * * *