U.S. patent number 3,864,251 [Application Number 05/435,515] was granted by the patent office on 1975-02-04 for treatment of middlings stream from hot water process for recovering bitumen from tar sand.
This patent grant is currently assigned to Atlantic Richfield Canada, Ltd., Canada-Cities Service, Ltd., Gulf Oil Canada, Imperial Oil Limited. Invention is credited to Lubomyr M. O. Cymbalisty.
United States Patent |
3,864,251 |
Cymbalisty |
February 4, 1975 |
Treatment of middlings stream from hot water process for recovering
bitumen from tar sand
Abstract
This process relates to treating the middlings stream from the
primary separation cell used in the hot water process for
extracting bitumen from tar sand. The middlings stream is diluted
with hot water and settled in a quiescent zone. Froth is formed in
the settler; this froth is surprisingly low in solids and water.
The tailings stream from the settler is recycled to the front end
of the extraction process, thereby conserving water. The invention
provides an alternative to the conventional sub-aeration cell used
for treatment of the middlings stream.
Inventors: |
Cymbalisty; Lubomyr M. O.
(Edmonton, Alberta, CA) |
Assignee: |
Canada-Cities Service, Ltd.
(N/A)
Atlantic Richfield Canada, Ltd. (N/A)
Imperial Oil Limited (N/A)
Gulf Oil Canada (N/A)
|
Family
ID: |
23728711 |
Appl.
No.: |
05/435,515 |
Filed: |
January 22, 1974 |
Current U.S.
Class: |
210/703; 208/391;
208/435 |
Current CPC
Class: |
B03D
1/1468 (20130101); B01D 21/00 (20130101); B03B
9/02 (20130101); B03D 1/24 (20130101) |
Current International
Class: |
B03D
1/24 (20060101); B03D 1/14 (20060101); B01D
21/00 (20060101); B03B 9/00 (20060101); B03B
9/02 (20060101); B01d 021/00 () |
Field of
Search: |
;210/44,145,50,56,63,67,72,73,83,84,221,220 ;208/11 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Adee; John
Attorney, Agent or Firm: Johnson; Ernest Peter
Claims
What is claimed is:
1. In a continuous process for recovering bitumen from tar sand
comprising combining the tar sand with air and hot water in a
tumbler to disintegrate the tar sand and produce a hot slurry,
diluting the slurry with water, introducing the dilute slurry into
a separation cell wherein coarse solids settle out to form a
tailings product, aerated bitumen rises to the surface of the cell
contents and forms a froth product, and a middlings stream is
withdrawn from the cell, said stream comprising bitumen, fine
solids and water, the improvement which comprises:
diluting the middlings stream with hot water; and
introducing the diluted middlings stream into a settler vessel and
holding it therein for a sufficient period of time to allow the
major portion of the bitumen in the stream to rise to the surface
of the vessel contents and form a froth product;
withdrawing the froth product; and
withdrawing a tailings stream from the base of the vessel, said
tailings stream comprising the major portion of the fine solids and
water introduced into the vessel.
2. The process as set forth in claim 1 wherein:
at least part of the tailings stream from the settler vessel is
recycled for repeated treatment in the separation cell.
3. The process as set forth in claim 1 wherein:
the middlings stream is aerated prior to entry into the settler
vessel to facilitate bitumen flotation.
Description
BACKGROUND OF THE INVENTION
This invention relates to a hot water process for recovering
bitumen from tar sand.
The invention has been developed using tar sand from the Athabasca
deposit at Fort McMurray, Alberta, Can. While it is described with
reference to that feed stock, the invention may find beneficial
application to tar sands present in other deposits.
Athabasca tar sands comprises sand grains which are each sheathed
in a thin layer of water. Bitumen is trapped in the void space
between the water-wet grains. By way of example, the composition of
the tar sand might be 10 percent by weight bitumen, 4 percent
water, and 86 percent solids.
Athabasca tar sands are presently processed using a method commonly
referred to as the hot water method. In accordance with this
process, tar sand is mixed in a conditioning drum or tumbler with
hot water and steam. While in the tumbler, the tar sand
disintegrates and at the same time liberated bitumen is aerated. By
"disintegrate" is meant that the sand and bitumen particles are
dispersed one from another in preliminary way. The tumbler product
is a porridge-like slurry which typically might comprise 9.5
percent bitumen, 22.00 percent water and 68.5 percent solids, at a
temperature of 185.degree.-190.degree.F.
The slurry is flooded with additional hot water to further disperse
the sand and bitumen. This flooding operation is usually carried
out at a screen positioned at the outlet from the tumbler. The
flooded slurry typically might have a composition of 7 percent
bitumen, 43 percent water, and 50 percent solids, and a temperature
of 160.degree.F.
The flooded slurry is introduced into a separation cell at about
its longitudinal midpoint; this cell is a cylindrical vessel having
a conical bottom. The major portion of the solids, particularly the
coarse sand particles, settle to the bottom of the cell; most of
the bitumen particles, which have preferentially become attached to
bubbles of air, rise to the top surface of the cell contents, where
they collect in the form of a froth. The sand leaves the vessel
through a bottom outlet and is discarded as tailings. The froth
overflows the vessel wall into a launder and is removed for further
treatment.
A middlings stream is continuously withdrawn from the separation
cell at a point intermediate its upper and lower ends. This is done
for two reasons. Firstly, a relatively large quantity of water must
be added in the flooding stage to ensure that the bitumen and
solids particles are sufficiently dispersed from one another in the
separation cell to obtain reasonable froth product quality and
bitumen recovery. Some of this water must be removed from the cell
in the form of a middlings drag stream-- otherwise it will report
to the bottom tailings stream. If too much water leaves with the
sand tailings, bitumen is carried out with it and oil recoveries
drop accordingly. Secondly, the solids known as "fines" (i.e., -325
mesh), present in the tar sands, tend to accumulate in the central
portion of the cell. If the fines are present in too high a
concentration, they tend to form a thick blanket, through which the
aerated bitumen particles have difficulty in passing to reach the
froth layer. It is therefore conventional to withdraw some of these
fines in the middlings stream to relieve the congestion within the
cell.
The middlings stream typically comprises 2 percent bitumen, 15
percent solids and 83 percent water.
The bitumen particles in the middlings stream are a mixed lot --
some are non-buoyant, perhaps because they are non-aerated or
because they are attached to both solids and air; others are
buoyant but were withdrawn through the middlings outlet before
reaching the froth layer.
Conventionally, the middlings stream from the separator cell is
passed through a sub-aeration cell to recover contained bitumen. In
this latter secondary recovery cell, the middlings are turbulently
mixed with air to bring the bitumen to the surface of the cell as a
froth. This froth is badly contaminated with solids and water -- a
typical composition might be 16 percent weight solids, 54 percent
water and 31 percent bitumen.
Once the bitumen has been extracted from the tar sand in this
fashion, the primary and secondary froths are combined, diluted
with a specific gravity-altering diluent, such as naphtha, and
treated in a centrifuge circuit to separate the solids and water
from the bitumen. Erosion of these centrifuges, particularly by the
fines present in the froth, is a serious problem. Therefore any
reduction in fines content in the feed to the centrifuge circuit is
desirable.
SUMMARY OF THE INVENTION
It is therefore one object of this invention to provide a process
for treating middlings whereby a product which is comparatively
lower in solids content is obtained.
It is another object to provide a process wherein the middlings are
diluted by the addition of hot water, to improve secondary froth
quality and in which the water added is conserved by recycling to
the front end of the process.
In accordance with the invention, the middlings stream is diluted
with hot water, preferably contacted with minute air bubbles to
aerate non-buoyant bitumen, and introduced into a settler vessel.
In the quiescent and dilute environment within this vessel, the
buoyant bitumen forms a froth product which is reduced in solids
and water content in comparison to the prior art secondary recovery
froth obtained by sub-aeration flotation. Solids, water and traces
of bitumen are withdrawn from the vessel through the tailings
outlet. Part of this tailings stream may be recycled to the front
end of the process for repeated treatment in the separation cell.
In this manner, hot water is conserved within the process. The
remainder of the tailings stream may be discarded or otherwise
processed for recovery of contained bitumen. The froth product from
the settler is preferably combined with the primary froth from the
separation cell and forwarded on to the froth treatment
circuit.
DESCRIPTION OF THE DRAWINGS
FIG. 1 is a block diagram illustrating the steps of the process;
and
FIG. 2 is a schematic illustration of the equipment used in the
process.
DESCRIPTION OF THE PREFERRED EMBODIMENT
The invention and its benefits are illustrated in the following
example;
1360 pounds per hour of Athabasca tar sand, comprising 11 percent
by weight bitumen, 4 percent water, and 85 percent solids,
including 12 percent fines, is fed to a tumbler 1. Sufficient fresh
hot water, approximately 290 pounds per hour, is added to the tar
sand in the tumbler 1 to produce a slurry containing 22 percent by
weight water. The product slurry is observed to have a temperature
of 160.degree.F. The residence time in the tumbler is approximately
31/2minutes.
The slurry is fed from the tumbler 1 into a separation cell 3.
Water at 180.degree.F is added to the slurry at the screen 4 to
raise the water content to approximately 42 percent. The separation
cell 3 and settler 5 are both filled with clear water at
180.degree.F at the time that the test run is initiated. Froth,
comprising 70 percent bitumen, 6 percent solids, 24 percent water,
is produced at the surface of the separation cell at a rate of 170
pounds per hour. A tailings stream, comprising 70 percent solids,
0.8 percent bitumen and 29.2 percent water, is produced from the
cell at a rate of 1,180 pounds per hour.
A middlings stream, comprising 2 percent bitumen, 15 percent
solids, and 83 percent water, is withdrawn from the separation cell
by a pump 6 at a rate of 900 pounds per hour. This stream is mixed
with 200 pounds per hour of water and approximately 0.1 CFH air in
a mixer 7 and is then pumped to the settler.
The diluted middlings stream is introduced to the central portion
of the settler through a rotating, perforated distribution pipe 8.
A froth product is continuously formed and withdrawn at the rate of
19 lbs. per hour from the settler. This froth product comprises 77
percent bitumen, 5 percent solids, and 18 percent water. A stream
of dilute solids and water is continuously withdrawn through the
tailings outlet of the settler vessel and is recycled to the front
end of extraction.
By way of comparison, the same middlings stream, when fed directly
to a sub-aeration secondary recovery cell, gives a froth product
comprising 52 percent bitumen, 13 percent solids and 35 percent
water.
Obvious variations in the specific details described may be made
without departing from the spirit of the invention and such
embodiments of the invention as come within the scope and perview
of the appended claims are to be considered as part of this
invention.
* * * * *