U.S. patent number 3,862,834 [Application Number 05/277,034] was granted by the patent office on 1975-01-28 for method for producing steel.
This patent grant is currently assigned to Fried Krupp Gesellschaft mit beschrankter Haftung. Invention is credited to Klaus Ermisch, Herbert Ritter Von Waclawiczek.
United States Patent |
3,862,834 |
Von Waclawiczek , et
al. |
January 28, 1975 |
METHOD FOR PRODUCING STEEL
Abstract
A method for reducing iron ore dust, including forming the dust
into a cloud, transporting the cloud in reducing gas, reacting the
cloud with the gas for enriching the dust, and introducing the
transported cloud into the plasma stream of a plasma burner whose
plasma stream is penetrating into the bath of a melting
furnace.
Inventors: |
Von Waclawiczek; Herbert Ritter
(Duisburg, DT), Ermisch; Klaus (Essen,
DT) |
Assignee: |
Fried Krupp Gesellschaft mit
beschrankter Haftung (Essen, DT)
|
Family
ID: |
27183325 |
Appl.
No.: |
05/277,034 |
Filed: |
August 1, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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240641 |
Apr 3, 1972 |
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Foreign Application Priority Data
Current U.S.
Class: |
75/10.22;
75/10.56 |
Current CPC
Class: |
C21B
13/125 (20130101); Y02P 10/134 (20151101) |
Current International
Class: |
C21B
13/00 (20060101); C21B 13/12 (20060101); C22d
007/00 () |
Field of
Search: |
;75/.5B,10-12 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rutledge; L. Dewayne
Assistant Examiner: Rosenberg; Peter D.
Attorney, Agent or Firm: Spencer & Kaye
Parent Case Text
CROSS-REFERENCE TO RELATED APPLICATION
This is a continuation-in-part application of parent application
Ser. No. 240,641, filed Apr. 3, 1972 and now abandoned.
Claims
We claim:
1. A method for reducing iron ore dust, comprising
a. forming said dust into a cloud;
b. transporting said cloud in reducing gas to a plasma stream of a
plasma burner;
c. reacting said cloud with said reducing gas during transporting
to enrich said dust and reduce said ore;
d. introducing the transported cloud containing reduced ore into
the plasma stream of a plasma burner to melt the reduced ore and
form liquid particles; and
e. directing the plasma stream to penetrate into a liquid metal
bath of a melting furnace to pass said liquid particles into and
mix the liquid metal bath.
2. A method as claimed in claim 1, further comprising continuously
draining metal from said bath and subjecting the drained metal to
further refining.
3. A method as claimed in claim 1, further comprising producing
said reducing gas by transferring heat from a nuclear reactor to a
cracking tube containing a material selected from the group
consisting of coal, oil, and natural gas.
4. A method as claimed in claim 1, further comprising producing
said reducing gas by transferring heat used for carrying out the
step of reacting into a cracking tube containing natural gas and
exhaust gas.
5. A method as claimed in claim 1, wherein the step of reacting is
carried out by heating said gas and dust with heat transferred from
hot exhaust gas.
6. A method as claimed in claim 1, further comprising continuously
feeding to said bath a liquid slag-building means and continuously
removing slag from the top of said bath.
7. A method as claimed in claim 6, wherein said slag-building means
is calcium carbide.
8. A method as claimed in claim 1, wherein said reducing gas is
directed at said dust for effecting the forming of the dust into a
cloud.
9. A method as claimed in claim 1, wherein said iron ore dust
initially contains at least 63% by weight iron.
Description
BACKGROUND OF THE INVENTION
The present invention relates to a method for making steel from
finely ground rich ores using a plasma burner. The method operates
continuously.
There are already known methods for making steel from ore dust of
high iron content, but these methods operate to a greater or lesser
degree discontinuously. Usually, the ore dust is reduced in
fluidized beds using reducing gases and the resulting powder of
high iron content is briquetted for further processing in a usual
refining unit. The briquetting is necessary, because the iron
powder would not penetrate through the slag in a refining unit, not
even if it were blown onto the slag with high pressure. Here, the
process is not only disadvantageous because of the interposed,
uneconomical step of briquetting; the subsequent conventional
refining processes operate batch-wise and thus discontinuously.
It has already been proposed a number of times that plasma burners
should be used for making steel. Thus German Democratic Republic's
Pat. No. 28,822, teaches equipping usual metallurgical equipment,
such as the Siemens-Martin furnace, converters, and electric arc
furnaces, with plasma burners for heating, and preferably for
auxiliary heating. Here, the usual inert gases used for producing a
plasma can be mixed with a reducing gas. Additionally, the gas can
be mixed with known, powdered, reactive materials for cleaning the
melt and for alloying.
Similar technique is taught in U.S. Pat. No. 3,347,766. The
reducing gas fed to the inert gas plasma is conducted into the slag
of a metal bath in a hearth furnace in a highly reactive condition
and is thus supposed to accelerate the refining process. The anode
of the plasma burner is arranged in the hearth furnace, thus
meaning significantly larger costs and difficulties in plasma
stream regulation because of the different bath and slag
heights.
The JOURNAL OF METALS for January, 1961, describes in a general way
at pages 51 to 54 various possible applications for plasma burners
in metallurgy. Thus, they are suggested for serving as heat sources
in usual melting and refining furnaces. It is further indicated
that a reduction of difficulty reducible metal oxides is possible
in a plasma stream containing carbon and that a reoxidation of the
resulting metals can be prevented.
SUMMARY OF THE INVENTION
An object of the present invention, therefore, is to provide a
method for making steel from finely ground, rich iron ores using a
plasma burner and operating continuously from ore to finished
steel, which method reduces heat losses and makes possible a plant
of low cost and small size.
This as well as other objects which will become apparent in the
discussion that follows are achieved, according to the present
invention, by a method for reducing iron ore dust, comprising
forming the dust into a cloud, transporting the cloud in reducing
gas, reacting the cloud with the gas for enriching the dust, and
introducing the transported cloud into the plasma stream of a
plasma burner whose plasma stream is penetrating into the bath of a
melting furnace.
GENERAL ASPECTS OF THE INVENTION
The present invention lies first of all in the forming of the
charged ore into a cloud of dust, transporting the cloud by means
of reducing gas in a suitably heated device, while simultaneously
enriching the ore, and finally feeding the ore into the plasma
stream of a plasma burner whose plasma stream is penetrating into
the bath of a melting hearth. If need be, the ore can be finally
transformed into steel continuously in at least one refining unit
connected to the melting hearth.
The invention provides the advantage that the continuously
resulting, finished steel can be continuously submitted to further
working, especially in a continuous casting mold and rolling mill
trains following such a mold.
The iron oxide recovered from the exhaust gases of the refining
units and the melting hearth, so-called LD-dust, can be fed back
into the process and thus need not represent a loss.
The reduction of the ore begun in the heated transport device is
continued in the plasma stream of the plasma burner and finished in
the melting hearth or following refining unit.
In a further development of the invention, a cracked gas is used as
the reducing gas. This cracked gas is produced by means of nuclear
reactor heat loss in a heated cracking tube from coal, oil, or
natural gas. In this way, it is possible to combine the basic
process of the invention extremely economically with a nuclear
power plant.
In another development of the invention, the reducing gas is a
cracked gas produced from natural gas and furnace exhaust gas in a
cracking tube heated by the heat fed to the heated transport
device. This gives a further improvement in the heat
utilization.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a schematic view of a steel producing installation
according to the present invention.
FIG. 2 illustrates the transport section of FIG. 1 in greater
detail.
FIG. 3 is a section viewed on the cutting plane III--III of FIG.
2.
FIGS. 4 and 5 are modified transport sections.
FIG. 6 is a section viewed on the cutting plane VI--VI of FIG.
5.
FIG. 7 is an elevational section of a plasma burner for use in the
present invention.
FIG. 8 is a section viewed on the cutting plane VIII--VIII of FIG.
7.
FIG. 9 is a section viewed on the cutting plane IX--IX of FIG.
7.
FIG. 10 is an elevational section of a plasma burner for use in the
present invention.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Firstly with reference to FIG. 1, finely ground ore coming
continuously from a mill and having preferably a minimum iron
content of 63% by weight is loaded into a feed hopper 1 for feeding
the transport section 2. The finely ground ore has preferably a
size in the range suitable for fluidized bed reduction processes,
e.g., 40 microns. The lower end of hopper 1 opens into a device 3
having the structure of an atomizer, where the finely ground ore is
formed into a cloud of dust by means of hot reducing gas blown
through the atomizer device 3. The reducing gas then transports the
cloud of dust further in the direction of the longitudinal axis of
the transport section 2.
The ore dust is enriched at the same time as it is being
transported in the transport section, which is maintained at a
reducing temperature by heat transferred from hot gas. The
enrichment may be by any of the fluidized-bed reduction processes
such as H-Iron, Nu-Iron, and Esso-Fior. The iron content of the ore
dust as it leaves transport section 2 is preferably in the range of
93 to 97 weight-percent. Finally, the ore dust is conducted into
the plasma stream of an electric arc plasma burner 4, which is
connected as close as possible to the end of the transport section
2. The flow rates of dust and reducing gas, are determined by the
thermodynamic and kinetic conditions of the reduction process in
the transport section, i.e., conditions such as reduction velocity,
temperature range, pressure and particle size of the ore. The
particular plasma stream used for the present invention is
preferably not affected by variations in the flow rates.
For the purpose of forming the plasma stream of the plasma burner,
furnace exhaust gas is conducted through lower cleaner 14,
compressor 70b, and pipeline 5 to the electric arc plasma burner 4.
The exhaust gas is thus first cleaned, in order to prevent
short-circuit-causing bridges.
The cloud of dust is sucked into the plasma stream as a result of
the pressure drop caused by the movement of the stream. The dust is
strongly heated once in the stream, and is further reduced to a
small extent. The dust particles are turned into liquid particles
and pass into a liquid metal bath of a melting hearth 6 along with
the plasma stream which penetrates into the bath. The plasma
stream, which maintains the temperature of the ore particles at
about 1,700.degree. C, is adjusted such that it penetrates into the
melt far enough, for example a few millimeters, to provide a
sufficient and thorough mixing of the melt. Since the reduced ore
dust never comes in contact with oxygen all the way down into the
melt, a reoxidation of the melted particles is prevented.
The plasma arc temperature depends primarily on the particular
plasma gas being used, and on the place where the temperature is
measured in the arc. The temperature can reach up to 20,000.degree.
C. At the point of penetration of the plasma stream into the bath,
the temperature shall not, however, exceed electric arc temperature
since otherwise too much material is evaporated.
The technology of the plasma arc per se has been well developed for
the welding and cutting of metals and for the space reentry
simulation experiments of NASA.
The melt in the melting hearth 6 is continuously fed liquid calcium
carbide of low acetylene rate through pipeline 7 coming from a
calcium carbide oven 8 where the calcium carbide is melted. This
slag-building additive, which is a mixture of calcium carbide and
calcium oxide producing only small quantities of acetylene gas when
mixed with water, serves primarily for a good desulphurizing of the
melt; it can also serve simultaneously for raising the carbon
content of the melt. For purpose of renewing the slag, the melting
hearth is provided at the level of the top of the bath with at
least one overflow cup closure 9, in the form of a skimmer, through
which excess slag is continuously removed. Calcium carbide smelting
practice is known per se and is in worldwide use in electric
submerged arc furnaces.
Preferred technique for obtaining a suitable calcium carbide in
oven 8 is melting down a mixture of 36% by weight of calcium
carbide and 64% by weight calcium oxide in temperature range of
theoretically 1,600.degree.-1,800.degree. C depending on the
desired viscosity of the melt. One to four weight-percent of the
resulting calcium carbide is added to the melt in hearth 6,
depending on the sulphur content of the melt.
Since there is a small amount of refining which takes place in the
melting hearth 6 due to the action of the plasma stream, the
process can be ended here, should a lower quality steel be
acceptable. Sometimes, no undesirable elements get into the melt on
hearth 6, and especially then it is possible to end the process
here. The characteristics of the melt in the hearth 6 are mainly
determined by the materials charged into the hearth, by their
chemical compositions (i.e., their content of sulphur and
phosphorus) and gangue, and by the composition of the plasma gas.
Plasma gases consisting mostly of hydrogen and nitrogen can lead to
a hydrogenation and nitrogenation of the melt; this is
undesirable.
Exemplary for the hearth 6 practice per se is the melting down of
sponge iron in the electric arc furnace practice at the Mexican
Hylsa works.
For the purpose of making steels of higher quality by removing
tramp elements, one or more refining units are connected right at
the outlet of the melting hearth. Suitable refining processes are
all those which can be carried out in hearth furnaces. In the
example of FIG. 1, the refining unit is a furnace 10 of the type
including the blowing of oxygen onto the steel to be refined. In
one example of the invention, steel qualitites at least as good as
those obtained in open hearth practice result. Furnace 10 is in
communication with the melting hearth 6 by way of a channel 11
located in the floor of the furnace. Molten metal from hearth 6
continuously drains through this channel into furnace 10. Furnace
10 refines continuously in conventional manner by means of an
oxygen lance 10' used for blowing oxygen onto the melt. Lime dust
is added for slag formation. A molten steel product is continuously
withdrawn from furnace 10. The LD-dust coming off in the exhaust
duct 12 connected to furnace 10 and in the corresponding exhaust
duct 13 of the melting hearth 6 is collected in the gas-cleaning
installation 14 and then fed into the feed hopper 1. The used slag
in furnace 10 is likewise continuously withdrawn. It may be
advantageous for the continuous operation of the process to divide
the melting hearth 6 and the refining unit by means of dividing
walls or chicanes running transversely to the flow direction of the
melt.
For quieting and alloying the molten steel, it is advantageous to
connect an alloying hearth 16 to the refining unit. Vacuum
equipment 15 communicates with hearth 16. Molten steel coming from
the oxygen-blowing furnace 10 moves through a suction tube 17 and
reaches the alloying hearth in the form of fine droplets which
distributed themselves over the surface of the alloying hearth
bath. The alloying components melted in a ferro-alloying furnace 18
and continuously fed to the alloying hearth 16 are metered on the
basis of continuously measured parameters of steel quality, for
example on the basis of spectral analyses. The bath of the alloying
hearth 16 is divided by a horizontally lying dividing wall 19 into
an upper mixing zone and a lower quieting zone. Mixing is
accomplished by a stream of nitrogen blown in through lance 20.
The molten, finished steel flows into the mold of a continuous
casting installation 21 and is then worked further in continuous
rolling trains.
It is preferred that the reducing gas be primarily cracked gas
produced from natural gas and furnace exhaust gas in a cracking
tube 35 which winds within the heated device over its transport
section 2. The furnace exhaust gas is mostly carbon dioxide and is
thus partly moving as a recirculating agent. The heat in the
exhaust gas contributes to the cracking and is thus made directly
useful for the process. The following formula gives a rough idea of
the manner in which the process operates: ##SPC1##
where the quantity in parentheses represents the portion of the
exhaust gas which is not recirculated. Thus, theoretically, half of
the carbon dioxide in the exhaust is recirculated. These values can
of course not be obtained practically speaking, since an excess of
reducing gas must be used. The exhaust gas contains more or less
large amounts of carbon monoxide; because this carbon monoxide is
produced continuously in the process of the invention, it can be
well used in a burner plant, for example for producing steam.
Another, remaining part of the furnace exhaust gases is utilized
for heating the device containing the transport section 2.
Reducing gas containing about 85 volume-percent carbon monoxide,
remainder hydrogen, and having a high degree of purity is produced
in quantity in the calcium carbide oven 8 and a direct introducing
of this through pipelines 23 and 41 into the transport section is
advantageous in all circumstances. Furnace exhaust gas used for
heating the heated device with transport section 2 leaves the
heated device through pipeline 24 and is brought by this pipeline
to the lime oven 25.
It is especially advantageous when the process of the present
invention includes utilization of heat from a nuclear reactor
installation. The reducing gas can then be produced from coal, oil,
or natural gas in a cracking tube 27 built into a reactor 26. The
cracking tube built into the heated device with transport section 2
can then be eliminated, if desired. Furthermore, the process of the
invention can be begun using hot helium gas for the purpose of
heating the heated device containing the transport section 2. The
hot helium gas is used until a sufficient quantity of exhaust gas
is available to take over the function of the helium gas. The
exhaust gas eventually drives the helium out of the heated device.
The small amount of helium that is lost due to its being driven out
by the exhaust gas is unimportant. Furthermore, a steam superheater
29 can be placed before a steam producer 28 built into the reactor
26 and the steam superheater can be run using furnace exhaust gas
forwarded from upper cleaner 14 by the compressor 70a. In the steam
circuit are located, firstly, a turbine 30 running an alternating
electrical current generator G and, secondly, a plant 31 for
producing the requisite oxygen and nitrogen. Additionally connected
to the reactor 26 is a helium supplier 32.
Instead of including a reactor in the process, it is also possible
to make other integrated facilities. To this end, it is especially
advantageous that the exhaust gases come from the process of the
invention in essentially constant quantity. This is advantageous
for all possibilites for using the exhaust gases. A not
inconsiderable quantity of steam is, furthermore, produced from the
cooling water fed to the plasma burner and this can be directed
into the steam circuit.
The transport section 2 illustrated in FIG. 1 will now be explained
in further detail on the basis of FIGS. 2 and 3. As above
explained, the finely ground, heated and dried ore moves into the
atomizing device 3 from feed hopper 1 and is formed into a cloud of
dust. From the atomizing device, the ore dust is maintained as a
cloud in the transport section 2, which is here in the form of a
tube-shaped turbulence bed 33, by means of reducing gas and is
transported onwards, until it leaves the transport section 2, in
enriched condition, through the exit end 34. Exit end 34 is in
communication with the electric arc plasma burner 4. Surrounding
the tube-shaped turbulence section 33 is a cracking tube 35. The
cracking tube winds helically around the section 33. Natural gas is
introduced into cracking tube 35 at its inlet 36. The natural gas
is mixed with carbon dioxide from the furnace exhaust gases. The
carbon dioxide comes in through pipeline 38 and is mixed with the
natural gas at ring nozzle 37. The resulting mixture is cracked in
the cracking tube to a reducing gas whose reducing components
consist essentially of carbon monoxide and hydrogen. The heat
required for the cracking and for maintaining a reducing
temperature in the transport section 2 is transferred to the
transport section 2 by hot furnace exhaust gases entering through
branch 39 from pipeline 38. The temperature in the transport
section is further supported by an insulating jacket 40. The still
hot furnace exhaust gases leave the transport section 2 through
pipeline 24 leading to lime oven 25. Pipeline 41 leads into the
downstream end of the cracking tube 35, just before the nozzle
section of the atomizer device 3 for the purpose of introducing as
a component of the reducing gas the reducing gases from the calcium
carbide oven 8 and for introducing gases which have been produced
in cracking tube 27 of reactor 26, if the reactor is being used in
the process.
The heated device, with transport section, illustrated in FIG. 4 is
constructed similarly to that of FIG. 2. Instead of a tube-shaped
turbulence bed 33, there is here a fluidizing bed that transports
the cloud of ore dust. The reducing gas moves through nozzles 44
located between beams 43 over the entire length of the transport
section. The nozzles 44 are tilted downstream for the purpose of
moving the one particles continuously onwards. The reducing gas
thus serves for forming and transporting the cloud of ore dust and,
in the actual reaction chamber 45 of the bed, enriches the ore.
The heated device, with transport section 2, of FIGS. 5 and 6
likewise uses a fluidizing bed 42. Helical channel 46 conducts
heating gas entering at channel end 39'. Pipeline 47 serves for
introducing the reducing gas, which in this case is preferably made
in a nuclear reactor as above-described.
Referring now to FIGS. 7 to 9, the electric arc plasma burner 4 has
at its outlet region pairs of outlet openings 48. The openings 48
of any given pair lie opposite one another and face the channel
through which the plasma stream from cathode 49 is moving, on its
way to the melt. Openings 48 are the mouths of spiral-shaped
channels 50. Tangentially feeding into channels 50 is inlet
pipeline 51 communicating with exit end 34 of FIGS. 1 to 5 for the
mixed ore dust and reducing gas. Here, the ore dust reaches the
plasma stream laterally.
Immediately over the outlet openings 48 is the anode 52 of the
plasma burner. The cleaned furnace exhaust gas used for producing
the plasma is fed to the burner chamber 53 through a channel 54
likewise approaching tangentially. A hollow portion 55 is connected
with a cooling water circuit 56.
The annular electrode electric arc plasma burner 4' of FIG. 10,
whose electrodes are spaced from one another along an axis of
plasma stream flow, has a tube-shaped cathode 57, instead of the
solid cathode 49. Anode 52' of one or more parts is situated right
at the end where the plasma exits. The mixture of ore dust and gas
is introduced into the plasma burner through the tube-shaped
cathode 57 in the direction of the arrow and is sucked into the
plasma stream forming on the lower end of the cathode. This form of
the plasma burner is especially advantageous, because it may be
built very easily and does not have any constrictions which might
get stopped up.
Both embodiments of the plasma burner can have a three-phase or
rotational current superimposed on them. For ionizing the gas, the
burners are started up with direct current and high power, and then
the three-phase current is brought in. The cathode and anode then
have three poles, or else a multiple of three poles. The electric
arc plasma burners 4 and 4' can be made of ceramic materials of
high heat resistance. Then a special insulating of the cathodes and
anodes becomes unnecessary.
The method of the present invention can be made completely
automatic in simple manner and makes possible many variations in
the producing of the plasma stream.
It will be understood that the above description of the present
invention is susceptible to various modifications, changes and
adaptations, and the same are intended to be comprehended within
the meaning and range of equivalents of the appended claims.
* * * * *