U.S. patent number 3,860,521 [Application Number 05/236,349] was granted by the patent office on 1975-01-14 for soap based chain conveyor lubricant.
This patent grant is currently assigned to BASF Wyandotte Corporation. Invention is credited to Otto T. Aepli, Harold L. Conaway, Malachy E. Sorgenfrei.
United States Patent |
3,860,521 |
Aepli , et al. |
January 14, 1975 |
**Please see images for:
( Certificate of Correction ) ** |
SOAP BASED CHAIN CONVEYOR LUBRICANT
Abstract
Chain Conveyor Lubricant: A. water base B. fatty acid soap C.
sequestering agent D. alcoholic coupling agent E. anionic
surfactant F. nonionic surfactant G. monostearyl acid
phosphate.
Inventors: |
Aepli; Otto T. (Southgate,
MI), Sorgenfrei; Malachy E. (Trenton, MI), Conaway;
Harold L. (Wyandotte, MI) |
Assignee: |
BASF Wyandotte Corporation
(Wyandotte, MI)
|
Family
ID: |
22889135 |
Appl.
No.: |
05/236,349 |
Filed: |
March 20, 1972 |
Current U.S.
Class: |
508/438;
508/440 |
Current CPC
Class: |
C02F
9/005 (20130101); C10M 173/02 (20130101); C10M
2217/06 (20130101); C10M 2209/103 (20130101); C10M
2207/129 (20130101); C10N 2040/32 (20130101); C10M
2207/022 (20130101); C10N 2040/44 (20200501); C10N
2010/02 (20130101); C10M 2219/044 (20130101); C10M
2207/021 (20130101); C10M 2217/046 (20130101); C10N
2050/01 (20200501); C10N 2040/38 (20200501); C10M
2215/042 (20130101); C10M 2215/044 (20130101); C10M
2207/046 (20130101); C10M 2209/107 (20130101); C10M
2223/042 (20130101); C10M 2209/108 (20130101); C10M
2215/26 (20130101); C10N 2040/50 (20200501); C10M
2209/104 (20130101); C10M 2223/04 (20130101); C10N
2040/00 (20130101); C10M 2207/125 (20130101); C10M
2201/02 (20130101); C10M 2209/109 (20130101); C10M
2215/04 (20130101); C10M 2221/043 (20130101); C10N
2040/34 (20130101); C10M 2209/105 (20130101); C10M
2209/106 (20130101); C10N 2040/30 (20130101); C10N
2040/42 (20200501); C10M 2207/289 (20130101); C10N
2040/36 (20130101); C10N 2040/40 (20200501); C10N
2070/02 (20200501); C10M 2215/16 (20130101); C10M
2207/18 (20130101); C10M 2219/042 (20130101) |
Current International
Class: |
C10M
173/02 (20060101); C02F 9/00 (20060101); C10m
003/40 (); C10m 003/18 (); C10m 003/04 () |
Field of
Search: |
;252/34.7,42.1,49.3,49.5,33.6,49.8,41,33.3 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Gantz; Delbert E.
Assistant Examiner: Vaughn; I.
Attorney, Agent or Firm: Swick; Bernhard R. Michaels; Joseph
D. Dunn; Robert E.
Claims
Having thus described the invention, what it is desired to claim
and secure by Letters Patent is:
1. In an aqueous lubricating composition concentrate for
lubricating continuously moving conveyor systems wherein said
concentrate consists essentially of by weight of about 30 to about
70 percent water, about 2 to 15 percent sequestering agent, about 2
to 30 percent anionic surface active agent, about 4 to 20 percent
fatty acid soap selected from the group consisting of fatty acid
alkali metal soap, fatty acid alkanol amine soap and fatty acid
ammonia soap, zero to 20 percent coupling agent selected from the
group consisting of propylene glycol, isopropyl alcohol and
ethylene glycol, and about 2 to 10 percent nonionic surface active
agent, the improvement comprising adding monostearyl acid phosphate
to said concentrate in an amount from about 0.15 to about 1.75
weight percent of said concentrate whereby improved defoaming
properties are obtained.
2. The concentrate according to claim 1 wherein the amount of
monostearyl acid phosphate is from about 1/2 to about 1.5 weight
percent.
3. The concentrate according to claim 1 wherein said fatty acid
soap is obtained by incorporating in said concentrate a fatty acid
in an amount from about 2 to 30 weight percent along with an agent
selected from the group consisting of alkali metal hydroxide,
ammonium hydroxide and alkanolamines in amount sufficient to react
with the fatty acid to produce the fatty acid soap.
4. A lubricating composition consisting essentially of the
concentrate according to claim 1 and water in a volumetric
proportion of concentrate to water of about 1:50 to about
1:500.
5. The lubricating composition according to claim 4 wherein said
concentrate contains from about 1/2 to about 1.5 weight percent of
monostearyl acid phosphate.
6. The lubricating composition according to claim 4 wherein said
concentrate fatty acid soap is obtained by incorporating in said
concentrate a fatty acid in an amount from about 2 to about 30
weight percent along with an agent selected from the group
consisting of alkali metal metal hydroxide, ammonium hydroxide and
alkanolamines in an amount sufficient to react with the fatty acid
to produce the fatty acid soap.
Description
BACKGROUND
1. Field of the Invention
This invention relates to the improved soap based chain conveyor
lubricants and more particularly to lubricants which are aqueous
compositions containing fatty acid soaps and surfactants.
2. Description of the Prior Art
In breweries, soft drink bottling operations and food processing
plants, conveyor belts are used to move the bottles, jars, cans and
the like along the bottling line. In order to keep the conveyor
chains clean and provide lubrication, it is customary to use a
lubricant such as a soap based lubricant. However, these lubricants
have often tended to foam to such an extent that the labels affixed
to the bottles are wetted by the foam thereby giving them a poor
appearance and/or are partially removed. Additionally, the use of
these lubricants have resulted in the accumulation of unsightly
amounts of foam on the floors and other areas.
In view of the prior art, it is an object of this invention to
provide a soap based chain conveyor lubricant having improved
defoaming properties. It is still another object of this invention
to provide a soap based chain conveyor lubricant having improved
lubricating properties.
These and other objects will become apparent from the following
detailed description.
SUMMARY OF THE INVENTION
In accordance with this invention, there is provided an aqueous
lubricating concentrate for lubricating continuously moving
conveyor systems wherein said concentrate contains a fatty acid
soap and a surfactant, the improvement comprising the addition to
said composition of monostearyl acid phosphate in an amount from
about 0.15 to about 1.75 weight percent of the concentrate. The
concentrate when diluted with water is then ready for use as a
lubricating composition.
DESCRIPTION OF THE PREFERRED EMBODIMENT
The typical chain conveyor lubricant for convenience and economy in
transporting and storing is manufactured and sold as a concentrate
which is then diluted with water in proportions by volume of from
about 1:50 parts concentrate to water to about 1:500 parts
concentrate to water for usage. The lubricant concentrate typically
consists of from about 20 to about 80 percent water, about 0 to 15
percent sequestering agent, about 0 to 30 percent anionic surface
active agent, about 2 to 40 percent fatty acid soap, about 0 to 40
percent coupling agent, about 0 to 15 percent nonionic surface
active agent. Usually it is more preferred that the concentrate
contain about 30 to about 70 percent water, about 2 to 15 percent
sequestering agent, about 2 to 30 percent anionic surface active
agent, about 4 to 20 percent fatty acid soap, about 0 to 20 percent
coupling agent and about 2 to 10 percent nonionic surface active
agent.
According to this invention monostearyl acid phosphate is added to
the foregoing composition to obtain the objects of the present
invention. Typically the monostearyl acid phosphate is added in an
amount from 0.15 to 1.75 percent of the concentrate exclusive of
the water present. More preferably the amount of monostearyl acid
phosphate will be from about one-half to about 1.5 weight
percent.
It is preferred to employ as the sequestering agent salts of
ethylene diamine tetracetic acid. These sequestering agents may be
added to the composition in the form of the salts or the acid may
be added along with a sufficient amount of metallic hydroxide or
alkanolamine to neutralize the acid.
Any sequestering agent which will complex calcium and magnesium
ions from water may be employed in this invention. Additional
suitable sequestering agents are trans-1,2-diaminocyclohexane
tetracetic acid monohydrate, diethylene triamine pentacetic acid,
sodium salt of nitrilotriacetic acid, pentasodium salt of
N-hydroxyethylene diamine triacetic acid, trisodium salt of
N,N-di(beta-hyroxyethyl) glycine, and sodium salt of sodium
glucoheptonate.
Where the formula is diluted in tap water, conventional metallic
soap dispersants may be necessary or desirable in addition to the
sequestering agents.
Anionic surface active agents which may be employed include linear
alkyl benzene sulfonic acids, alpha-olefin sulfonates, alkyl
diphenyl oxide disulfonates, sodium N-methyl-N-alkyl-taurate, alkyl
sulfonated amides, di(2-ethylhexyl) sulfosuccinate, dioctyl sodium
sulfosuccinate, sodium sulfonate of oleic acid, anionic phosphate
esters, alkyl ether sulfates, alkyl polyethyleneoxy esters, alcohol
sulfates such as sodium lauryl sulfate, the product of
chlorosulfonation of paraffin hydrocarbons, e.g., octadecenyl
sulfonate and the condensate of a fatty acid chloride with an
amine.
For the sake of simplicity in formulating the composition, instead
of adding fatty acid soap as such it is preferred to simply add
fatty acid in amount from about 2 to 30 weight percent for the
broad composition or 4 to 15 percent by weight in the preferred
composition and then add a sufficient amount of an alkali metal
(from the first column of the periodic table) hydroxide, ammonium
hydroxide or an alkanolamine to neutralize the fatty acid to
produce the fatty acid soap. Where the sequestering agent is also
added in the acid form, the foregoing hydroxide or alkanolamine is
added in sufficient amount to neutralize both the sequestering
agent acid and the fatty acid. Preferred fatty acids for this
purpose are tall oil fatty acids with low rosin content of about
0.5 to 0.9 percent by weight and which generally comprise
approximately 52 percent by weight oleic acid, 45 percent by weight
linoleic acid, 1 percent by weight linolenic acid, and 2.3 percent
by weight saturated acid. Coconut oil fatty acids, generally
comprised of 50 percent lauric, 20 percent myristic, 10 percent
oleic, 10 percent palmitic, 8 percent of other saturated fatty
acids, and about 2 percent unsaturated fatty acids are also
desirable for this purpose. Additional useful fatty acids include
those derived from tallow, soya beans, corn, cottonseed, palm, and
blends or hydrogenated forms of the basic type of fatty acid to
give desired characteristics such as low solubilization
temperature, viscosity, and reduced corrosion tendency.
Sodium, ammonium or potassium hydroxide and mono, di, and
triethanolamine or isopropanolamine are the preferred source used
for neutralizing and converting fatty acids and sulfonic acid
derivatives to soap or amides. Potassium hydroxide and
monoethanolamine are preferred for their ability to produce
compounds with a pH and foam generating capacity suitable for
conveyor lubricants.
The nonionic surface active agents which are advantageously
employed in the compositions of the invention are generally the
polyoxyalkylene adducts of hydrophobic bases wherein the
oxygen/carbon atom ratio in the oxyalkylene portion of the molecule
is greater than 0.40. Those compositions which are condensed with
hydrophobic bases to provide a polyoxyalkylene portion having an
oxygen/carbon atom ratio greater than 0.40 include ethylene oxide,
butadiene dioxide and glycidol, mixtures of these alkylene oxides
with each other and with minor amounts of propylene oxide, butylene
oxide, amylene oxide, styrene oxide, and other higher molecular
weight alkylene oxides. Ethylene oxide, for example, is condensed
with the hydrophobic base in an amount sufficient to impart water
dispersibility or solubility and surface active properties to the
molecule being prepared. The exact amount of ethylene oxide
condensed with the hydrophobic base will depend upon the chemical
characteristics of the base employed and is readily apparent to
those of ordinary skill in the art relating to the synthesis of
oxyalkylene surfactant condensates.
Typical hydrophobic bases which can be condensed with ethylene
oxide in order to prepare nonionic surface active agents include
mono- and polyalkyl phenols, polyoxypropylene condensed with a base
having from about 1 to 6 carbon atoms and at least one reactive
hydrogen atom, fatty acids, fatty amines, fatty amides and fatty
alcohols. The hydrocarbon ethers such as the benzyl or lower alkyl
ether of the polyoxyethylene surfactant condensates are also
advantageously employed in the compositions of the invention.
Among the suitable nonionic surface active agents are the
polyoxyethylene condensates of alkyl phenols having from about 6 to
20 carbon atoms in the alkyl portion and from about 5 to 30
ethenoxy groups in the polyoxyethylene radical. The alkyl
substituent on the aromatic nucleus may be octyl, diamyl,
n-dodecyl, polymerized propylene such as propylene tetramer and
trimer, isoctyl, nonyl, etc. The benzyl ethers of the
polyoxyethylene condensates of monoalkyl phenols impart good
properties to the compositions of the invention and a typical
product corresponds to the formula: ##SPC1##
Higher polyalkyl oxyethylated phenols corresponding to the formula:
##SPC2##
wherein R is hydrogen or an alkyl radical having from about 1 to 12
carbon atoms, R.sup.1 and R.sup.2 are alkyl radicals having from
about 6 to 16 carbon atoms and n has a value from about 10 to 40,
are also suitable as nonionic surface active agents. A typical
oxyethylated polyalkyl phenol is dinonyl phenol condensed with 14
moles of ethylene oxide.
Other suitable nonionic surface active agents are cogeneric
mixtures of conjugated polyoxyalkylene compounds containing in
their structure at least one hydrophobic oxyalkylene chain in which
the oxygen/carbon atom ratio does not exceed 0.40 and at least one
hydrophilic oxyalkylene chain in which the oxygen/carbon atom ratio
is greater than 0.40.
Polymers of oxyalkylene groups obtained from propylene oxide,
butylene oxide, amylene oxide, styrene oxide, mixtures of such
oxyalkylene groups with each other and with minor amounts of
polyoxyalkylene groups obtained from ethylene oxide, butadiene
dioxide, and glycidol are illustrative of hydrophobic oxyalkylene
chains having an oxygen/carbon atom ratio not exceeding 0.40.
Polymers of oxyalkylene groups obtained from ethylene oxide,
butadiene dioxide, glycidol, mixtures of such oxyalkylene groups
with each other and with minor amounts of oxyalkylene groups
obtained from propylene oxide, butylene oxide, amylene oxide and
styrene oxide are illustrative of hydrophilic oxyalkylene chains
having an oxygen/carbon atom ratio greater than 0.40.
Further suitable nonionic surface active agents are the
polyoxyethylene esters of higher fatty acids having from about 8 to
22 carbon atoms in the acyl group and from about 8 to 30 ethenoxy
units in the oxyethylene portion. Typical products are the
polyoxyethylene adducts of tall oil, rosin acids, lauric, stearic
and oleic acids and the like. Additional nonionic surface active
agents are the polyoxyethylene condensates of higher fatty acid
amines and amides having from about 8 to 22 carbon atoms in the
fatty alkyl or acyl group and about 10 to 30 ethenoxy units in the
oxyethylene portion. Illustrative products are coconut oil fatty
acid amines and amides condensed with about 10 to 30 moles of
ethylene oxide.
Other suitable polyoxyalkylene nonionic surface active agents are
the alkylene oxide adducts of higher aliphatic alcohols and
thioalcohols having from about 8 to 22 carbon atoms in the
aliphatic portion and about 3 to 50 oxyalkylene portion. Typical
products are synthetic fatty alcohols, such as n-decyl, n-undecyl,
n-dodecyl n-tridecyl, n-tetradecyl, n-hexadecyl, n-oxtadecyl and
mixtures thereof condensed with 3 to 50 moles of ethylene oxide, a
mixture of normal fatty alcohols condensed with 8 to 20 moles of
ethylene oxide and capped with benzyl halide or an alkyl halide, a
mixture of normal fatty alcohols condensed with 10 to 30 moles of a
mixture of ethylene and propylene oxides, a mixture of several
fatty alcohols condensed sequentially with 2 to 20 moles of
ethylene oxide and 3 to 10 moles of propylene oxide, in either
order; or a mixture of normal fatty alcohols condensed with a
mixture of propylene and ethylene oxides, in which the
oxygen/carbon atom ratio is less than 0.40 followed by a mixture of
propylene and ethylene oxides in which the oxygen/carbon atom ratio
is greater than 0.40 or a linear secondary alcohol condensed with 3
to 30 moles of ethylene oxide, or a linear secondary alcohol
condensed with a mixture of propylene and ethylene oxides, or a
linear secondary alcohol condensed with a mixture of ethylene,
propylene, and higher alkylene oxides. As couplers or hydrotropes
which may be employed in this invention, or perhaps they could be
equally described as homogenizers or phase control agents, the
following are typical examples of useful agents for this purpose:
propylene glycol, isopropyl alcohol and ethylene glycol.
The compositions of this invention are prepared by standard
well-known open kettle mixing techniques known in the industry.
The practice of this invention is illustrated by, but not limited
by, the examples given below. Unless otherwise noted, temperature
is expressed in degrees Centigrade and parts are parts by
weight.
In determining foam characteristics and lubricity (pounds gate
pressure) a 12 foot section of continuous bottle conveyor, driven
by a one-third horse power motor is loaded with 50 water-filled 6.5
fluid ounce bottles. The test lubricating composition is diluted in
a proportion by weight of 1:100. This dilute solution is then
applied at a single application point at the end of the conveyor
distal to the drive, thus simulating operating conditions of the
section of the actual bottle conveyor. The relative efficiency of
the lubricant is determined by the force in pounds of gate pressure
exerted by the stationary bottles on a spring balance at the end of
the conveyor as the chain moves under the load. Compositions with
poor lubricity will result in a higher gate pressure due to the
force transmitted to the bottle column by the friction of the chain
passing under the bottle load. Generally, a lubricant yielding a
gate pressure of greater than 12 pounds on the balance with the
standard load will exhibit poor lubricity under actual use
conditions.
The current load in watts of the drive motor is also proportional
to the lubricity of the lubricant as related to the friction
between the bottle load and the conveyor chain. The foam generating
capacity of the test formula is determined by the height of the
suds that build up between adjacent bottles. Lubricants giving a
gate pressure of less than 12 pounds and an electrical load of less
than 105 watts have been shown to perform satisfactorily in actual
conveyor systems. The results of lubricity and foam generating
capacity of the below listed compositions are indicated in Table I
below.
EXAMPLE I
A quantity of phosphate-free aqueous commercial conveyor chain
lubricant containing a non-ionic surfactant and a fatty acid soap
was divided into two parts. One portion was marked sample A and
used as a control. To the other portion, marked sample B, was added
and uniformly dispersed therein one percent by weight of
monostearyl acid phosphate (hereinafter for convenience called MSAP
in this and the following examples). Each sample was tested in the
bottle conveyor test described above.
EXAMPLE II
A conveyor chain lubricant was prepared without MSAP (sample A) and
with 1 percent by weight MSAP (sample B) by adjusting the amount of
water. The lubricants contained on a percent by weight basis:
Sample A Sample B ______________________________________ Water 43.0
42.0 Sodium salt of ethylenediamine tetracetate 4.0 4.0 Propylene
glycol 12.0 12.0 Dodecylbenzene sulfonic acid 20.0 20.0
Monoethanolamine 6.0 6.0 MSAP -- 1.0 Coconut fatty acid 10.0 10.0
Nonionic surfactant A 5.0 5.0 100.0 100.0
______________________________________
EXAMPLE III
A conveyor chain lubricant was prepared without MSAP (sample A) and
with 1 percent by weight MSAP (sample B) by adjusting the amount of
water. On a percent by weight basis the lubricant contained:
Sample A Sample B ______________________________________ Water 60.0
59.0 Sodium salt of ethylenediamine tetracetate 4.0 4.0 Tall oil
fatty acid 10.0 10.0 MSAP -- 1.0 Isopropyl alcohol 7.0 7.0
Monophosphate ester of nonionic surfactant A 10.0 10.0 Nonionic
surfactant B 3.0 3.0 Potassium hydroxide 2.0 2.0 Isopropylamine 4.0
4.0 100.0 100.0 ______________________________________
EXAMPLE IV
A conveyor chain lubricant was prepared without MSAP (sample A) and
with 1 percent by weight MSAP (sample B) by adjusting the amount of
water. On a percent by weight basis the lubricant contained:
Sample A Sample B ______________________________________ Water 57.5
56.5 Tall oil fatty acid 10.0 10.0 MSAP -- 1.0 Isopropyl alcohol
7.0 7.0 Monophosphate ester of nonionic surfactant A 10.0 10.0
Nonionic surfactant B 3.0 3.0 Potassium hydroxide 2.0 2.0
Isopropylamine 4.0 4.0 Trisodium salt of nitrilotriacetate 6.5 6.5
100.0 100.0 ______________________________________
Nonionic surfactant A is an oxyalkylated alcohol wherein the
alcohol is a mixture comprising 85% by weight of a C.sub.10
alcohol, 8.5% by weight of a C.sub.12 alcohol and 6.5% by weight of
a C.sub.14 alcohol; the oxyalkyl is a mixture of 68 parts of
ethylene oxide and 12 parts of ethylene oxide, total oxyalkyl
weight content - 80%, weight ratio of ethylene oxide to propylene
oxide 5.67 to 1.
Nonionic surfactant B is an ethylenediamine initiated oxypropylene
oxyethylene polymer wherein the molecular weight of the
poly(oxypropylene) hydrophobe portion is about 2500 and the
poly(oxyethylene) portion about 15 percent of the
poly(oxypropylene) present.
TABLE I ______________________________________ CONVEYOR LUBRICANT
TEST RESULTS (Dilution ratio 1:100) 1. Dilution water hardness zero
p.p.m. (CaCO.sub.3) ______________________________________
Lubricity (Pounds Gate Foam Example Pressure) Characteristics
______________________________________ I A 4.0-4.5 high foam I B
3.5-4.0 low-moderate foam II A 3.5-4.0 very high foam II B 3.0-3.5
moderate high foam III A 4.0-4.5 very high foam III B 3.5-4.0
low-moderate foam IV A 5.0-5.5 moderate IV B 3.0-3.5 low
______________________________________ 2. Dilution water hardness
120 p.p.m. (CaCO.sub.3) ______________________________________ I A
4.5-5.0 moderate-high foam I B 3.5-4.0 low-moderate foam II A
3.5-4.0 high foam II B 3.0-3.5 moderate foam -III A 3.5-4.0
moderate foam III B 3.5-4.0 very low foam IV A 4.5-5.0 low-moderate
IV B 3.0-3.5 low ______________________________________
In the foregoing tests the use of MSAP substantially reduced foam
build-up on the bottles on the conveyor regardless of which
lubricant was used. Additionally the lubricity of the lubricant was
usually improved by the use of MSAP.
The foregoing examples and methods have been described in the
foregoing specification for the purpose of illustration and not
limitation. Many other modifications and ramifications will
naturally suggest themselves to those skilled in the art based on
this disclosure. These are intended to be comprehended as within
the scope of this invention.
* * * * *