U.S. patent number 3,854,067 [Application Number 05/403,419] was granted by the patent office on 1974-12-10 for spark plug.
This patent grant is currently assigned to Phillips Petroleum Company. Invention is credited to Thomas D. Morgan.
United States Patent |
3,854,067 |
Morgan |
December 10, 1974 |
SPARK PLUG
Abstract
A spark plug for a combustion engine or a combustion chamber in
which the electrodes have a coating of titanium dioxide
thereon.
Inventors: |
Morgan; Thomas D.
(Bartlesville, OK) |
Assignee: |
Phillips Petroleum Company
(Bartlesville, OK)
|
Family
ID: |
23595692 |
Appl.
No.: |
05/403,419 |
Filed: |
October 4, 1973 |
Current U.S.
Class: |
313/130 |
Current CPC
Class: |
H01T
13/39 (20130101) |
Current International
Class: |
H01T
13/39 (20060101); H01t 013/02 () |
Field of
Search: |
;313/130
;117/221,230,231 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Saalbach; Herman Karl
Assistant Examiner: Hostetter; Darwin R.
Claims
I claim:
1. A spark plug for a combustion engine comprising in combination a
metal shell, an insulator positioned within said shell, a first
electrode passing through said insulator and projecting from the
lower end of said insulator to form a spark-producing area, a cap
attached to the upper end of said first electrode, and a second
electrode attached to said metal shell in juxtaposition with said
first electrode to form a spark-gap and a second spark-producing
area, wherein said spark-producing areas of said electrodes consist
of a button having thereon a coating of titanium dioxide.
2. The spark plug of claim 1 wherein said electrodes are produced
with at least one hole in said spark-producing area and wherein
said button is impressed into said hole in said electrodes.
3. The spark plug of claim 1 wherein said electrodes are provided
with at least one hole in said spark-producing area and wherein
said button has a threaded portion, with said threaded portion
having been inserted into said hole in said electrodes.
Description
This invention relates to spark plugs. More particularly, this
invention relates to spark plugs having novel electrodes which
provide better ignition of the fuel-air mixture under marginal
conditions.
The modern vehicle engine, unlike its ancestors, must be all things
to all men at all times. It must deliver greater power for a given
size than heretofore achieved. It must operate at greater economy
than heretofore realized. It must accomplish all this while
emitting nothing more than carbon dioxide and water. Emissions such
as oxides of nitrogen, unburned hydrocarbons, carbon monoxide, and
lead are no longer viewed as "progress." Large sectors of the
public now demand that vehicular engines operate as free of harmful
emissions as is possible.
The route to emission-free engines has been extremely difficult. A
large amount of research effort has been expended in attempting to
create the "perfect" piston-type internal combustion engine. Many
of the results of such efforts have been less than perfect.
The installation of "emission control" devices has solved many
problems. However, such devices have also created problems. Engines
equipped with such devices must be operated at a relatively low
fuel-air ratio in order to maintain emissions of unburned
hydrocarbons and carbon monoxide at low levels. A low fuel-air
ratio (lean mixture) makes the engine hard to start and more prone
to misfire.
Lead emissions can be curtailed by using nonleaded fuels or fuels
containing low levels of lead. Such fuels, however, normally have
lower octane ratings than lead-containing fuels. The result of the
use of such fuels can be hard starting and misfiring. Until now,
there has been no simple, low cost method or device which would
allow engines to utilize lean fuel mixtures and/or low lead fuel
with no sacrifice in performance.
It is, therefore, an object of this invention to provide a spark
plug which will effect ignition of a fuel-air mixture under
marginal conditions of fuel mixture and spark intensity.
It is another object to provide a spark plug in which at least the
spark-producing areas of the electrodes are coated with titanium
dioxide.
It is a further object to provide a spark plug in which the
spark-producing areas of the electrodes are formed of a molecularly
bonded coating of titanium dioxide.
Other aspects and objects will be apparent to those skilled in the
art from the following disclosure, example, appended claims, and
the annexed drawing in which:
FIG. 1 is a view, partly in section, of a spark plug showing a
coating on the spark-producing areas.
FIG. 2 is an enlarged view, partly in section, of the lower end of
the spark plug of FIG. 1 showing more clearly this invention.
By the present invention I have found that spark plugs having
greater reliability under marginal conditions of fuel mixture and
spark intensity are provided if there is employed therein an
electrode having spark-producing areas of the electrode coated with
titanium dioxide.
Referring now to the annexed drawing, numeral 2 designates a spark
plug in its entirety and includes a metal shell or shank 4 having a
threaded portion 6 by which the spark plug is screwed into a
cylinder head. Hexagonal nut 8, an integral part of shank 4,
provides a means for driving the spark plug into and withdrawing it
from the cylinder head. The upper end of the spark plug 2 includes
a cap 10 for attaching a conductor connected to the high voltage
source, not shown. Cap 10 is positioned at the upper end of a first
electrode 12 which is insulated from shank 4 by a porcelain
insulator 14. The electrode 12 passes through the entire length of
spark plug 2. The lower end of the spark plug is extended to form a
skirt 22 which carries a second electrode 16. The skirt 22 and
threaded portion 6 provide a conductive path with the engine block
(not shown) to ground electrode 16. Electrodes 12 and 16 can be
made of ferrous metals or ferroalloys. Alternatively, the
electrodes can be titanium or a titanium alloy.
On the lower end of electrode 12, and on the upper surface of
electrode 16 in the area facing electrode 12, there is provided a
very thin coating 18 of titanium dioxide. The surfaces of the
coatings 18 are spaced to form a gap 20 across which a spark is
created when high voltage electrical charge is impressed across
electrodes 12 and 16.
Various techniques can be employed for achieving the desired
coating of the electrode. For example, the coating of the electrode
can be applied by molecularly bonding titanium dioxide to ferrous
metal or ferroalloy electrodes by a process known as "sputtering."
The coating can also be prepared by heating, in the presence of
oxygen, a titanium "button" which has previously been impressed
into or otherwise affixed to ferrous metal or ferroalloy
electrodes. Alternatively, the electrodes can be formed of titanium
or an alloy of titanium. The outer surfaces of the electrodes are
then changed to titanium dioxide by heating in the presence of
oxygen.
In a preferred embodiment, the coatings 18 are deposited by a
device known in the trade as a "sputterer." The process is known as
sputtering. Briefly, the process involves depositing molecules
dislodged from an electrode, known as the target, onto another
surface, known as the substrate. A coating formed in this manner
can have a thickness ranging from 1 to 5,000 Angstroms. As a
practical matter, a coating having a thickness ranging from about
200 to about 1,200 Angstroms is preferred.
The coatings 18 are deposited directly on the metal of the
electrode without the need for an intermediate bonding agent, such
as brazing and the like. In the preferred practice of this
invention, the metal oxide coating is deposited into the pores of
the electrodes and will not chip or peel.
Radio frequency sputtering is the most commonly used of all
sputtering techniques. The article to be coated is placed in a
vacuum chamber, which is pumped down to remove contaminants. An
inert gas, usually argon, is then introduced into the chamber.
Radio frequency power excites the gas molecules until they form a
plasma discharge. This discharge bombards the target, dislodging
atoms which deposit on the substrate. By introducing a small amount
of oxygen into the chamber along with the inert gas, the coating is
modified to form oxides of the target material.
In another embodiment, coatings can be formed by impressing solid
"buttons" of titanium or a titanium alloy into the upper and lower
electrodes. The "buttons" can be attached to the electrodes by any
means known in the art, such as by spot welding and the like. A
coating of titanium dioxide is formed on the exposed surfaces of
the "buttons" by heating the button-containing electrodes in an
oxygen atmosphere for a suitable period of time. A coating having a
thickness of from about 500 to about 2,000 Angstroms can be formed
by heating said electrodes for a period of from 12 to 36 hours at a
temperature ranging from about 350.degree.C. to about 550.degree.
C. The oxygen source can be air.
In a further embodiment, coatings 18 can be formed by heating solid
titanium electrodes in the presence of oxygen in similar
fashion.
In a yet further embodiment, electrode tips can be fabricated from
any machinable metal, then coated with titanium dioxide. The coated
tips can then be inserted into the upper and lower electrodes of
the spark plug.
The following example illustrates the present invention, which is
not to be considered as limited thereby:
EXAMPLE
Spark plug electrode tips were fabricated from stainless steel
screws in the following manner:
The screw heads were machined to provide flat spark-producing
areas. The thus-machined screws were attached to the anode of a
sputtering device. The vacuum chamber was sealed, then evaluated to
a pressure of about 10.sup.-.sup.9 torr. Pure oxygen was then
admitted to the chamber to raise the pressure to about
10.sup.-.sup.5 torr. Titanium was then sputtered from the cathode
to the screw heads. Treatment was continued about 2 weeks. The
oxygen chemically combined with the freshly sputtered titanium.
The presence of the coating on the screw heads in the form of
titanium dioxide was established by Induced Electron Emission
Spectroscopy, X-ray diffraction and by an energy dispersive X-ray
analyzer (EDAX) attachment to a Stereoscan Electron Microscope.
The coated electrode tips were inserted into drilled and tapped
holes in the ground and center electrodes of standard spark plugs.
The titanium dioxide-treated spark plugs were compared with
untreated spark plugs under the following engine test
conditions:
Engine Speed 1000 rpm Compression Ratio 6.00 Throttle 90.0% Spark
Timing set for maximum power Fuel Mixture Temperature 125.degree.
F. Engine Coolant Temperature 150.degree. F. Fuel 91 octane, lead
free
The test results are expressed in terms of "Lean Misfire Limits
(LML)." LML is defined as the leanest fuel-air mixture at which
consistent firing of the mixture can be detected with the spark
timing adjusted for maximum power. The fuel-air mixture is
expressed in terms of "percent stoichiometric fuel," which is the
ratio of the quantity of fuel actually present in the fuel-air
mixture to the quantity theoretically required to produce a
stoichiometric mixture with the same quantity of air.
Results of the tests are as follows:
Titanium Dioxide- Coated Plug Uncoated Plug
______________________________________ Lean Misfire Limits
(average) 74.1% 81.4% ______________________________________
The tests show that a significant improvement in engine combustion
characteristics can be effected by use of the spark plugs of the
present invention.
Modifications and variations of the above disclosure will be
apparent to those skilled in the art in light of the foregoing
disclosure.
* * * * *