U.S. patent number 3,853,750 [Application Number 05/316,523] was granted by the patent office on 1974-12-10 for method and device for the collection of particles in a gas with particle-size separation.
This patent grant is currently assigned to Commissariat a L'Energie Atomique. Invention is credited to Robert Volsy.
United States Patent |
3,853,750 |
Volsy |
December 10, 1974 |
METHOD AND DEVICE FOR THE COLLECTION OF PARTICLES IN A GAS WITH
PARTICLE-SIZE SEPARATION
Abstract
Particles suspended in polluted gas or atmospheric air to be
analyzed are collected and separated according to their effective
size by means of an electrostatic device comprising an inlet duct
for the supply of "clean" gas, means for damping-out turbulent
motion within said duct, and a conduit comprising at least one
ionizer through which the polluted gas or air is injected into the
clean gas stream. The charged particles are collected as the stream
flows between two conductive plates which are substantially
parallel to each other and between which is applied a
direct-current potential difference.
Inventors: |
Volsy; Robert (Brignoud,
FR) |
Assignee: |
Commissariat a L'Energie
Atomique (Paris, FR)
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Family
ID: |
9088495 |
Appl.
No.: |
05/316,523 |
Filed: |
December 19, 1972 |
Foreign Application Priority Data
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Dec 31, 1971 [FR] |
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71.47800 |
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Current U.S.
Class: |
209/127.1;
55/DIG.14; 55/DIG.29; 55/418; 73/28.02; 138/37; 209/10; 250/432R;
96/63; 95/78; 96/417; 324/71.4 |
Current CPC
Class: |
B03C
3/019 (20130101); B03C 3/383 (20130101); B03C
3/12 (20130101); Y02A 50/2357 (20180101); Y10S
55/29 (20130101); Y10S 55/14 (20130101); Y02A
50/2351 (20180101) |
Current International
Class: |
B03C
3/12 (20060101); B03C 3/38 (20060101); B03C
3/34 (20060101); B03C 3/00 (20060101); B03C
3/04 (20060101); B03C 3/019 (20060101); B03c
003/12 (); B03c 003/43 (); B03c 003/08 () |
Field of
Search: |
;55/146,150,151,152,128,129,120,270,4,97,102,123,138,145,209,418,DIG.14,DIG.2
;138/37 ;324/32,33,71R,71PC ;310/8.1 ;317/3,4
;73/23,28,433,421.5R,421.5A,422R,432PS
;250/281,282,283,284,288,423,424,428,432,435,436,437,438
;209/127R,129,133,134,135,121,10 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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833,798 |
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Mar 1952 |
|
DT |
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833,799 |
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Mar 1952 |
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DT |
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Primary Examiner: Talbert, Jr.; Dennis E.
Attorney, Agent or Firm: Cameron, Kerkam, Sutton, Stowell
& Stowell
Claims
What we claim is:
1. A method for the collection of particles in a polluted gas with
particlar-size separation comprising the steps of charging the
suspended particles of polluted gas in an ionizer, injecting into a
gas stream in non-turbulent regime a flow of said charged polluted
gas and collecting said charged particles by passing said gas
stream between two substantially parallel conductive plates
parallel to the axis of propagation of the gas stream and applying
a direct-current potential difference between said plates.
2. A method according to claim 1, including the steps after the gas
stream has passed between said conductive plates, of again charging
the particles remaining in said stream in a second ionizer and
precipitating the particles.
3. A method according to claim 1 including the steps of
automatically weighing the deposits as collected and corresponding
to each particle size.
4. A device for the collection of particles in a polluted gas with
particle size separations comprising:
a conduit for the admission of polluted gas; at least one ionizer
in said conduit;
a duct of larger cross-sectional area than said conduit, said duct
having the shape of an aerodynamic converging cone for the supply
of a gas stream, means in said duct for damping-out the turbulence,
said conduit opening into said means, an orifice for said conduit
oriented in the same direction as the downstream portion of said
converging cone;
a tubular chamber having the same longitudinal axis as said duct
and connected at one end to the downstream portion of said
converging cone, at least two conductive surfaces in said chamber
extending in the longitudinal direction of said chamber, means for
applying a direct-current potential difference between said
surfaces;
and means for circulating the two gas streams between said
surfaces.
5. A device according to claim 4, including a suction means
connected to said chamber, and means for regulating the suction
power of said suction means to produce within said chamber a flow
having small and damped-out turbulence.
6. A device according to claim 4 wherein each ionizer in the
conduit for the admission of polluted gas has three electrodes:
the first electrode having conductive surface placed longitudinally
within said conduit and connected to an alternating-current voltage
source;
the second electrode having grid, a plate covering said grid, a
slot in said plate, the generating-lines of said surface and of
said plate being substantially parallel, said grid and said plate
being disposed longitudinally within said conduit and maintained at
a direct-current potential;
and the third electrode being a wire, a cavity having an opening
opposite said slot, said cavity, receiving said wire, means for
maintaining said wire at a direct-current potential different from
that of said grid, said grid and said plate being disposed over
said opening and connecting said cavity to said conduit and through
said grid and said slot.
7. A device according to claim 4 wherein said conduit for the
admission of polluted gas is disposed coaxial with the axis of the
converging cone of said supply duct.
8. A device according to claim 4 wherein said conduit for the
admission of polluted gas is adjacent a wall of said chamber.
9. A device according to claim 4 wherein said ionizer comprises a
radioactive source.
10. A device according to claim 4 including means for automatic
weighing of the deposits of different particle size comprising
piezoelectric strips operatively associated with said collecting
conductive surfaces.
11. A device according to claim 4 including between the chamber and
the suction means an ionizer to precipitate the unseparated
particles.
12. A device according to claim 6, said ionizer to precipitate the
uncollected particles comprising a radioactive source.
Description
This invention relates to a method and a device for the collection
of particles in a gas together with particle-size separation.
More precisely, the object of the invention is to collect dust or
more generally any particles which are suspended in air or in a
polluted gas to be analyzed and to separate said particles as a
function of their effective size, that is to say as a function of
their volume, so as to permit of subsequent chemical analysis of
said particles.
Control of the aerosol content of air is a problem to which
considerable importance is attached. For this reason, devices for
control of particulate material already exist in a very wide range
of categories for the application of the different methods. Among
the principal types can be mentioned the following:
The systems for filtering through porous fabrics; these systems
retain all the particles having sizes larger than the diameter of
the pores. These filters have a disadvantage in that they cause a
very substantial drop in gas pressure and become very rapidly
clogged.
Inertial systems based on gravity settling, particle impact or
centrifugal force; these systems can permit selection of particles
according to their mass if this latter is sufficiently high to
ensure that the inertia forces are not negligible. At equal volume,
the constituents which have a lower mass per unit volume are
precipitated with lower efficiency than the others, and all
particles of less than one micron in size escape from
precipitation.
The thermal precipitation systems whereby a selection of particles
can be carried out according to the square or the cube of their
size if this latter is sufficiently small to ensure that the
particles are sensitive to the forces applied (bombardment of
photons). With this method the rate of flow of the polluted gas is
limited (a few millimeters per second), which calls for a very long
period of use in order to collect a sufficient quantity of
constituents.
Electrostatic precipitation; the particles are charged by means of
a bombardment of ions which are emitted by an ion source and
precipitated by means of an electric field, the selection of
particles being carried out according to their dimensions or the
square of their dimensions in proportion to the electric charge
acquired. In the majority of these types of apparatus, the
electrostatic pressure which results from the ion charge density
produces a turbulent electric wind which, if it exists within the
aerosol precipitation zone, disturbs the conditions of collection
of said particles and therefore prevents any possibility of
selection as a function of particle size. Devices which are not
subject to this disadvantage do in fact exist but the flow rate of
polluted gas for which they are designed is such that the quantity
of particles collected is not sufficient to permit quantitative or
only qualitative analysis of the constituents.
The precise object of the present invention is to provide a method
and a device for collecting particles in a gas with particle-size
separation which overcome the disadvantages attached to the
techniques of the prior art.
The method essentially consists in injecting into a gas stream in
non-turbulent regime a flow of polluted gas in which the suspended
particles have previously been charged within an ionizer, and in
collecting said charged particles by passing said gas stream
between two conductive plates which are substantially parallel to
each other and to the axis of propagation of the air stream and
between which is applied a direct-current potential difference.
In an alternative embodiment, after the gas stream has passed
between the conductive plates, the particles which are still
contained in said stream are charged and precipitated for
subsequent retention in a second ionizer.
The method is therefore divided into two parts; in a first step,
the particles contained in the gas to be analyzed are charged and
said gas is injected into a gas stream while ensuring a flow regime
having very low turbulence within the duct. In a second step, the
particles are precipitated on a conductive plate as a result of the
application of the transverse electrostatic field which arises from
the direct-current potential difference. This precipitation takes
place at a greater or lesser speed according to the charge
conferred on the particles and therefore according to the effective
size of these latter. A separation of particles as a function of
their size is thus obtained on the receiving plate. In an
alternative embodiment, a second ionizing field can be applied to
said particles, with the result that the particles of very small
size which had not been collected on the first plate can
accordingly be retained on the receiving plate of the ionizer.
The device is characterized in that it comprises:
a conduit for the admission of polluted gas, which is provided with
at least one ionizer;
a duct of larger cross-sectional area and having the shape of an
aerodynamic converging cone for the supply of a gas stream, which
is fitted with means for damping-out the turbulence and in which
said conduit is placed, the orifice of said conduit being oriented
in the same direction as the downstream portion of the converging
cone ;
a chamber of tubular shape having the same longitudinal axis as
said duct and connected at one end to the downstream portion of the
converging cone, said chamber being provided in the longitudinal
direction with at least two conductive surfaces to which is applied
a direct-current potential difference and between which the two
gases are circulated ;
means for circulating the two gas streams.
In a first alternative embodiment, the other end of the chamber is
connected to a suction device, the suction power of which is
regulated so as to produce within said chamber a flow having small
and damped-out turbulence.
A second alternative embodiment consists in placing between the
chamber and the suction device, a second ionizer which is intended
to precipitate the unseparated particles.
In a first form of construction, the conduit for the admission of
polluted gas is placed in the axis of the converging cone of the
supply duct.
In a second form of construction, the admission conduit is placed
in the vicinity of a wall.
By virtue of the separation between the ionization of the particles
and the reception of said particles, and also by virtue of the
precautions taken to ensure that the gas stream does not have any
turbulence at the moment when this latter passes between the
receiving plates, deposition of the particles on the receiving
plate depends only on the charge acquired by each particle.
Separation of the particles is therefore significant.
A clearer understanding of the invention will in any case be
obtained from the following description of one embodiment of the
invention which is given by way of non-limitative example,
reference being made to the accompanying figures, wherein:
FIG. 1 is a longitudinal sectional view showing one example of
construction of the device;
FIG. 2 is a detail view of the ionizer;
FIG. 3 is a longitudinal sectional view showing an alternative form
of construction of the device.
A general view of the device for collecting particles in a gas in
accordance with the invention is given in FIG. 1. This device
comprises a chamber 2 of rectangular cross section and formed of
insulating material, the horizontal faces of said chamber being
covered with conductive metallic plates 4 and 6. An electric
generator 8 serves to apply a direct-current potential difference
V.sub.1 between the plates 4 and 6. The chamber 2 is connected at
one end to the duct 10 for the supply of clean gas through a
converging cone 12. A member 14 having a profile which is
substantially parallel to that of the converging cone 12 and placed
along the axis of this latter is provided with a conduit 16 for the
admission of polluted gas which is placed along the axis of said
member and terminates in a nozzle 18. In addition, the member 14 is
provided internally with an ionizer 20 which will be described in
detail hereinafter. In the example of construction shown in FIG. 1,
the member 14 is provided with only one ionizer 20 but it is
readily apparent that a plurality of identical ionizers could
readily be placed in series along the conduit 16. The converging
cone 12 is preceded by a series of grids 22 and has a honeycomb
structure 24 before the point of junction with the chamber 2.
The other end of the chamber 2 is connected to a duct 28 which has
the same cross-sectional area as the chamber 2.
The duct 28 is provided with an ionizer 32. Finally, the free end
of the duct 28 is connected to an adjustable suction device 34 of
known type.
The apparatus hereinabove described corresponds to one form of
construction which is given by way of example. The device for
collecting atmospheric dust particles need not be provided with the
duct 28, in which case the chamber 2 may be connected to the
suction device 34. This makes it possible to employ the atmospheric
air or the polluted gas which has previously been filtered in order
to inject it into the inlet duct 10.
FIG. 2 is a detail view of the ionizer 20; there is again shown in
this figure the member 14 which is traversed by the conduit 16. The
member 14 is formed of insulating material and provided with a
cavity 36 which is located at right angles to the axis of the
conduit 16 and communicates with this latter. The ionizer 20 proper
is made up of three electrodes: a conductive wire 38 placed along
the axis of the cavity 36; a conductive metallic grid 39 which
closes the cavity 36 and is partially covered by a sheet-metal
plate 40 in which is formed a slot 42 in directly overhead relation
to the wire 38; a conductive surface constituted in this form of
construction by a conductive sheet-metal plate 44 which is placed
on the other wall of the conduit 16 in oppositely facing relation
to the grid 39.
A direct-current potential difference V.sub.2 is applied between
the wire 38 and the grid 39; and an alternating-current potential
difference V.sub.3 is applied between the grid 39 and the plate
44.
In the example which is more especially described, the nozzle 18 of
the conduit 16 has its opening at the center of the converging cone
12 but it will be readily understood that said nozzle 18 could be
located off-center with respect to the converging cone 12 without
thereby departing from the scope of the invention.
In one particular embodiment, the potential difference V.sub.2 can
advantageously be within the range of 2 to 40 kV whereas the
potential difference V.sub.3 can be within the range of a few volts
to a few kV with a frequency between 50 and 10,000 cps. With regard
to the direct-current potential difference V.sub.1, said difference
can advantageously be within the range of 4 to 20 kV.
By way of indication, the chamber 2 can have a rectangular cross
section within the range of 5 to 50 cm.sup.2 and a length within
the range of 20 to 100 cm. With regard to the velocity of the gas
stream within the chamber 2, this can advantageously be within the
range of 20 to 400 cm/second.
The operation of the device for collecting particles in the gas is
very simple. The polluted gas which is injected into the conduit 16
is charged by the ionizer 20. By virtue of the structure of the
ionizer, the disturbances or in other words the turbulent velocity
fluctuations of the polluted gas are reduced to the width of the
slot 42. Within the chamber 2, the turbulent velocity fluctuations
of the gas stream are practically reduced to zero by means of the
device which is placed within the converging cone 12. By virtue of
this shape of ionizer, the maximum dispersion of the charge
acquired by particles having the same dimensions is within the
range of 10 to 20 percent, which represents a maximum dispersion of
20 to 30 percent of the distance over which the ionized particles
travel within the chamber 2 prior to precipitation on the
collecting plate 4. The spherical particles are thus completely
separated on the collecting plate if the diameters of these latter
are in a ratio of 1:2 and larger than 0.5 micron. The volume of
polluted gas processed in 12 hours is sufficient to permit analysis
of qualitative and quantitative spectra of pollution of atmospheric
air in an urban area. In the alternative embodiment which comprises
the duct 28, if the atmospheric air which is injected into the
inlet duct 10 is replaced by clean air, all the non-precipitated
particles within the chamber 2 (namely particles which are smaller
in diameter than 0.5 micron), can be recovered within the ionizer
32.
At the time of tests performed with Dow-Latex mixed beads having
diameters of 0.8 micron and of 2 microns, the beads were
precipitated respectively at 30 .+-. 8 cm and at 16 .+-. 4 cm from
the beginning of the receiving plate 4 and formed two perfectly
separate precipitation spots on the collecting plate 4.
There is shown in FIG. 3 one example of construction of the device
in which the duct 28 and its ionizer 32 are replaced by an
electrostatic precipitator 46 which is identical with the device
claimed in U.S. Pat. application Ser. No. 316,522, filed Dec. 19,
1972 and assigned to Commissariat a l'Energie Atomique in respect
of "Electrostatic precipitator for the collection of particles
contained in a gas."
The precipitator 46 essentially comprises a duct 48 connected to
the chamber 2 in which a conductive wire 50 is placed opposite to a
receiving plate 52. A potential difference V is applied between
these two electrodes in order to produce a corona discharge between
these two conductors. The deflectors 54 and 56 serve to define two
gas streams, one of which surrounds the electrode 50. In this type
of apparatus, the clean air is replaced by the polluted air to be
analyzed. This air, which is not ionized, passes through the
chamber 2 and deposits its particles on the plate 52.
In the complete device, there is thus carried out simultaneously a
particle-size analysis within the chamber 2 and a general
collection within the duct 48, in which there can be carried out an
automatic weighing operation by means of a piezoelectric strip, for
example, and a chemical analysis.
It is readily apparent that this invention is not limited to the
example which has been more especially described with reference to
the drawings. On the contrary, the invention extends to all
alternative forms. In particular, the ionizer as hereinbefore
described can be replaced by a radioactive source on condition that
the particles having a given polarity are trapped and the other
particles of opposite polarity are collected.
* * * * *