U.S. patent number 3,853,682 [Application Number 05/291,491] was granted by the patent office on 1974-12-10 for waterproofed concrete structure.
This patent grant is currently assigned to Grace, W. R. & Co.. Invention is credited to John Hurst.
United States Patent |
3,853,682 |
Hurst |
* December 10, 1974 |
WATERPROOFED CONCRETE STRUCTURE
Abstract
The concrete sublayer in a bituminous road or pavement structure
is waterproofed using a preformed sheet material made up of a
flexible sheet-like support (e.g., woven polypropylene mesh) having
on its surface placed adjacent the concrete a waterproof
pressure-sensitive adhesive membrane formed of a bituminous rubber
composition, and on the other surface, a layer of bituminous
composition to which has been added sufficient wax to render the
composition non-tacky when cold, the wax-containing layer becoming
tacky or pressure-sensitive at an elevated temperature.
Inventors: |
Hurst; John (London,
EN) |
Assignee: |
Grace, W. R. & Co.
(Cambridge, MA)
|
[*] Notice: |
The portion of the term of this patent
subsequent to June 26, 1990 has been disclaimed. |
Family
ID: |
26966817 |
Appl.
No.: |
05/291,491 |
Filed: |
September 22, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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803438 |
Feb 28, 1969 |
3741856 |
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676652 |
Oct 19, 1967 |
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Current U.S.
Class: |
428/40.3;
428/348; 156/337; 428/489; 442/46 |
Current CPC
Class: |
E01D
19/083 (20130101); E04D 7/00 (20130101); Y10T
428/31815 (20150401); Y10T 428/141 (20150115); Y10T
428/2822 (20150115); Y10T 442/178 (20150401) |
Current International
Class: |
E01D
19/08 (20060101); E01D 19/00 (20060101); E04D
7/00 (20060101); B32b 011/02 () |
Field of
Search: |
;404/66,31,67,32 ;61/1,7
;161/406,236,92,89 ;52/420,309 ;117/168,68,68.5 ;156/337 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
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249,629 |
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Dec 1962 |
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AU |
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699,950 |
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Dec 1964 |
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CA |
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Primary Examiner: Lesmes; George F.
Assistant Examiner: Roche; R. J.
Attorney, Agent or Firm: Baker; William L. Parker; C.
Edward
Parent Case Text
This application is a continuation-in-part of my copending
application, Ser. No. 803,438, filed Feb. 28, 1969 now U.S. Pat.
No. 3,741,856, which is a continuation-in-part of my application,
Ser. No. 676,652, filed Oct. 19, 1967, now abandoned.
Claims
It is claimed:
1. In combination (a) a structure comprising a flexible sheet-like
support, on one side of the support a layer of bituminous
composition comprising a mixture of a bitumen and wax, wherein the
ratio by weight of bitumen to wax is from about 1 to 10 parts
bitumen per part of wax, and on the other side of the support a
waterproof pressure-sensitive adhesive membrane formed of a
bituminous rubber composition at least 0.025 cm thick which is a
blend of a rubber selected from the grouping consisting of a
natural rubber, synthetic rubber, or combinations thereof, with a
bitumen, the ratio by weight of said bitumen to said rubber being
greater than 80:20; (b) a concrete surface to which the face of
said pressure-sensitive membrane is adherent; and (c) a layer of
load bearing, hot poured asphaltic concrete deposited over the
adherent to the bitumen-wax layer.
2. The combination of claim 1 wherein the support is a woven fabric
of polypropylene fibers.
3. The combination of claim 1 wherein a layer of bituminous or
neoprene-based primer composition is employed between said concrete
and said membrane.
4. The combination of claim 3 wherein the melting point of the
mixture of wax and bitumen is at least 115.degree.F.
5. The combination of claim 1 wherein the melting point of the
mixture of wax and bitumen is at least 175.degree.F.
6. The combination of claim 1 wherein said wax is paraffin wax.
7. A waterproofing structure comprising a flexible sheet-like
support, on one side of the support a layer of a bituminous
composition which is not normally tacky but which becomes tacky at
an elevated temperature comprised of normally tacky bitumen to
which has been added sufficient wax to render the mixture
non-tacky, and on the other side of the support a wateroroof
pressure-sensitive adhesive membrane formed of a bituminous rubber
composition at least 0.025 on thick which is a blend of a rubber
selected from the group consisting of a natural rubber, synthetic
rubber or combinations thereof and a bitumen, the ratio by weight
of said bitumen to said rubber being greater than 80:20.
8. The structure of claim 7 wherein said support is a woven
polypropylene mesh.
9. In combination (a) a structure comprising a flexible sheet-like
support, on one side of the support a layer of a bituminous
composition comprising a mixture of a bitumen and a wax wherein the
ratio by weight of bitumen wax is from about 1 to 10 parts bitumen
per part of wax, and on the other side of the support a waterproof
pressure-sensitive adhesive membrane formed of a bituminous rubber
composition at least 0.025 cm thick which is a blend of a rubber
selected from the group consisting of a natural rubber, synthetic
rubber, or combinations thereof with a bitumen, the ratio by weight
ofsaid bitumen to said rubber being greater than 80:20 and/less
than 95:5; (b) a concrete surface to which the face of said
pressure-sensitive adhesive membrane is adherent; and (c) a layer
of load bearing, hot poured asphaltic concrete deposited over and
adherent to the bitumen-wax layer.
10. A waterproofing structure comprising a flexible sheet-like
support on one side of the support a layer of a bituminous
composition which is not normally tacky but which becomes tacky at
an elevated temperature comprised of a normally tacky bitumen to
which has been added sufficient wax to render the mixture
non-tacky, and on the other side of the support a waterproof,
pressure-sensitive adhesive membrane formed of a bituminous rubber
composition at least 0.025 cm thick which is a blend of a rubber
selected from the group consisting of a natural rubber, synthetic
rubber, or combinations thereof with a bitumen, the ratio by weight
of said bitumen to said rubber being greater than 80:20, the face
of said membrane remote from said support being covered with a
protective covering easily removable from the membrane without
damage thereto.
11. The structure of claim 10 wherein said protective covering is
paper having a layer of release coating on its surface adjacent
said membrane.
Description
This invention relates to the sealing of the concrete layer in a
composite building or civil engineering structure in which a layer
of concrete is employed. More particularly, this invention pertains
to the waterproofing of the concrete layer in such a structure
using a waterproofing which is in the form of a preformed
sheet-like structure. The sheet-like structure is designed in a
particular manner to receive, and be bonded to, a layer of hot
poured bituminous or asphaltic material such as a wear course of
asphaltic concrete.
It is desirable to waterproof the concrete mass employed as a
sub-base in a road or pavement structure, especially an
above-ground road or pavement structure which is particularly
susceptible to freezing. Bridge decks, for example, due to their
elevation, tend to freeze faster than on-ground structures and
consequently receive a comparatively larger application of the
widely used de-icer, calcium chloride. Calcium chloride is,
however, corrosive of the structural steel employed in the deck
and, therefore, its penetration into and through cracks occuring in
the concrete sublayer to the structural steel supporting the deck
should be prevented.
The waterproofing of such a concrete layer is realized according to
the invention by the use of preformed structures of
pressure-sensitive adhesives. Such structures can be produced on a
large scale in a factory and then used on site.
Reference is made to the accompanying drawing wherein
FIG. 1 is an enlarged cross sectional view of the structure of the
invention, and
FIG. 2 is a sectional view in perspective of the structure of FIG.
1 installed in a road or pavement construction.
FIG. 2 is a sectional view in perspective of the structure of FIG.
1 installed in a road or pavement construction.
The structure comprises a sheet-like substrate and contiguous
thereto, a membrane 2 of a waterproofing pressure-sensitive
adhesive comprising a mixture of rubber and a bituminous material.
(The terms "bituminous material" and "bitumen" are used in this
specification inclusive of compositions and materials containing
asphalt, tar or pitch). The surface of the substrate remote from
the pressure-sensitive adhesive is coated with a layer 3 of a
bituminous adhesive composition which is not pressure-sensitive
adherent or tacky when cold but becomes tacky at elevated
temperature, as when a hot bituminous or asphaltic mix 4 is poured
thereon. Such an adhesive composition comprises a mixture of a
normally tacky or pressure-sensitive bituminous material to which
has been added an amount of a normally solid wax component
sufficient to reduce the tackiness thereof. The rendering of this
layer non-tacky by the addition of the wax permits, for example,
asphalt-laying equipment to be driven thereover during the
application of the hot asphaltic mix, following which the adhesive
layer becomes tacky due to the elevated temperature of the
asphaltic wear-layer. Activation of the tacky or pressure-sensitive
quality of the adhesive composition by the hot asphaltic layer
enables a strong bonding between the wax-containing adhesive layer
of the waterproofing structure and the asphaltic wear course.
The bituminous material-rubber waterproofing adhesive layer is
formed of natural or synthetic rubber, virgin or reclaimed, or
mixtures thereof, blended into bitumen to provide a smooth mix. The
ratio by weight of bitumen to rubber is suitably greater than
80:20, preferably up to 95:5, especially about 90:10. If desired,
the membrane may be reinforced with asbestos fibers or other types
of fillers. Generally, suitable compositions have softening points
(measured by the Ring and Ball method) of 60.degree. to
140.degree., preferably 60.degree. to 110.degree.C. and penetration
values of 50 to 400, preferably 150 to 300 at 25.degree.C. (100 g.
5 secs -- I.P. method). In order to give utmost sealing ability,
especially after movement of the concrete layer, the waterproofing
adhesive membrane layer should be least 0.025 cm. (0.010 inch)
thick, preferably 0.063 to 0.50 cm. (0.025 to 0.20 inch) thick.
A wide variety of materials can be used as the sheet-like support.
It is generally desirable that the support should be substantially
impermeable to water. For many purposes, it is desirable that the
support should be such that after application to the surface it is
capable of stretching with movement of the concrete or other
material, e.g., as a result of shrinkage, with maintenance of a
moisture and moisture-vapor-proof seal. To this end, it is
desirable that the combined structure of the support and the
membrane should have, at 20.degree.C., an elongation at break of at
least 300%, a tensile strength of at least 100 lb. per foot width
(at least 1.5 kg. per cm. width) and an Elmendorf tear strength of
at least 750 gm. However, where stretchability and flexibility are
less important than other properties, supports not fulfilling these
requirements can be utilized. For example, it is desirable for some
purposes to use a metallic foil, particularly, of copper or
aluminum, as the support.
The supports are generally films of natural rubber or of a
synthetic organic polymer such as polyethylene, e.g., that
commercially available under the trade name Polythene,
polypropylene or other polyolefin, a polyamide, a polyester, e.g.,
polyethylene terephthalate, a polyurethane, polyvinyl chloride, a
copolymer of vinyl chloride and vinylidene chloride, a synthetic
rubber such as polychloroprene or butyl rubber, regenerated
cellulose, cellulose ethers or cellulose esters. Inorganic or
metallic supports can also be used. The support should be such that
hot asphalt can be poured directly onto it without deleterious
effect on the waterproof seal. For this purpose, the support should
be able to resist, or be made able to resist, a temperature of at
least 150.degree.C., preferably at least 175.degree.C., for asphalt
mixes such as sand course asphalt, and even higher temperatures for
hot asphalt (mastic), which is applied at temperatures up to
250.degree.C. A particularly suitable material for this purpose is
one consisting of a woven fabric of polypropylene fibers. While
cellular films can be used as supports, the supports are generally
substantially incompressible and have a thickness of a most 0.25
inch (0.6 cm). Other sheet-like supports include woven and
non-woven fabrics of inorganic or organic natural or synthetic
fibers (i.e., staple fibers or continuous filaments), e.g., a woven
fabric of fibers of one of the synthetic organic polymers already
referred to, glass tissue, hessian, cotton or other fiber scrim or
bituminous roofing felt.
The normally non-tacky layer deposited on the surface of the
support remote from the bitumen-rubber waterproofing adhesive
membrane is, as mentioned above, formed of a normally tacky or
pressure-sensitive bituminous material to which has been added
sufficient wax to render the bituminous matterial non-tacky. The
precise amount of wax employed will vary depending upon the type of
wax employed and the degree of reduction in tackiness desired.
Generally from 1 to 10, preferably from about 2 to 5, parts by
weight of bituminous per part by weight of wax is employed.
The wax employed are normally solid and possess melting points such
that when mixed with the bituminous material, the coating will melt
at the temperature of the bituminous or asphaltic wear coat mix
deposited upon it. The wax-bitumen mixture preferably possesses a
melting point of at least about 115.degree.F., preferably
174.degree.F. The waxes may be selected from any suitable source,
for example, carnauba or candelilla or a mineral wax, e.g., montan
wax or petroleum waxes such as paraffin and microcrystalline waxes.
Normally solid synthetic waxes having the requisite melting point
may also be employed such as the ethylenic polymers, e.g.,
"Carbowax," chlorinated naphthalenes and hydrocarbon type waxes
such as prepared via the Fischer-Tropsch synthesis.
The thickness of the bitumen-wax layer may be varied, but in all
cases the thickness should be at least sufficient to form a bond
with the asphaltic mix deposited thereon. Generally, a thickness of
at least about 0.001 inch, preferably at least about 0.002 inch is
employed.
The waterproofing structures useful in the invention may be
produced in the factory in the form of laminates of the various
layers described above. The widths of the structures may vary
widely, e.g., from 1 to 48 inches (2.5 to 120 cm.); generally they
will be at least 2 inches (5 cm.) wide, e.g., 6 to 36 inches (15 to
90 cm.) wide, with widths in the upper part of this range, e.g., 24
to 36 inches (60 to 90 cm.), being preferred. The thickness of the
novel structures can also vary widely but will generally be from
0.01 to 0.25 or 0.35 inch (0.025 to 0.6 or 0.9 cm.).
To permit storage and handling, the normally pressure-sensitive
adhesive layer may be covered with a protective covering or coating
which can be removed at the job site without damage to the
membrane. A wide variety of materials can be used to provide
protective coatings in the novel structures of the invention. Paper
having a release coating thereon, e.g., siliconized paper or
suitable material formulated from or with polytetrafluoroetylene,
is satisfactory. Other materials include treated or modified films
of organic polymers.
In use, the protective coating is simply removed from the
waterproofing structure and the structure applied to the concrete
layer 5, e.g., the concrete sublayer which is supported by the
structural steel members. A primer coat, for instance, liquid
bituminous composition or neoprene-based composition may first be
applied if desired, to the concrete layer. The waterproofed
structure is then in position for deposition of the hot asphaltic
wear course mix directly upon the wax-bitumen coating which renders
the coating sufficiently tacky or pressure-sensitive to form a
strong bond with the wear coat.
The invention is illustrated by the following example.
EXAMPLE
To one side of a sheet (10 mils thick) of woven polypropylene mesh
is applied a coating (60 mils thick) of a pressure-sensitive
bituminous adhesive composition containing 7 parts by weight of
rubber and 93 parts by weight of asphalt. To the other side of the
mesh sheet is applied a hot coating (2 mils thick) of an
asphalt-paraffin wax mixture. The mixture was prepared by blending
50 gallons of asphalt with 120 pounds of paraffin wax. The
wax-asphalt mix had a melting point of about 180.degree.F. When
cooled, the wax-bitumen coating is non-tacky to the touch and will
bear traffic, e.g., asphalt laying equipment over it without the
coating being lifted from the sheet.
The resulting waterproofing laminate structure is applied to the
concrete sublayer of a conventional bridge deck construction, with
the rubber-asphalt adhesive surface adjacent the concrete. A primer
coat of, e.g., neoprene-based compound can be applied to the
concrete before applying the laminate if desired. A wear-course
comprised of one or two coats of hot (180.degree.F.) asphaltic
concrete is then layed down over the wax-asphalt layer forming a
strong unitary bond between the waterproofing membrane structure
and the wear course.
* * * * *