U.S. patent number 3,853,550 [Application Number 05/320,936] was granted by the patent office on 1974-12-10 for method for fabricating bimetallic members of thermoelements by sintering powdered compacts in the presence of graphite.
Invention is credited to Vladimir Ivanovich Koletvinov, Sergei Nikolaevich Ljuskin, Jury Diomidovich Nikolaev, Alexandra Semenovna Pavlenko.
United States Patent |
3,853,550 |
Nikolaev , et al. |
December 10, 1974 |
METHOD FOR FABRICATING BIMETALLIC MEMBERS OF THERMOELEMENTS BY
SINTERING POWDERED COMPACTS IN THE PRESENCE OF GRAPHITE
Abstract
A method for fabricating bimetallic members of thermoelements
from ingots of alloys based on solid solutions of Bi.sub.2 Te.sub.3
- Sb.sub.2 Te.sub.3, or Bi.sub.2 Te.sub.3 - Bi.sub.2 Se.sub.3
consisting in crushing the ingots to fines, pressing the fines in
briquettes similar in shape to the bimetallic members of
thermoelements, and annealing the briquettes in air in a
thick-walled metal vessel with a powdered graphite medium.
Inventors: |
Nikolaev; Jury Diomidovich
(Moscow, SU), Ljuskin; Sergei Nikolaevich (Moscow,
SU), Koletvinov; Vladimir Ivanovich (Moscow,
SU), Pavlenko; Alexandra Semenovna (Moscow,
SU) |
Family
ID: |
25764293 |
Appl.
No.: |
05/320,936 |
Filed: |
January 4, 1973 |
Current U.S.
Class: |
419/33; 419/56;
419/38; 420/903 |
Current CPC
Class: |
H01L
35/16 (20130101); H01L 35/34 (20130101); B22F
3/24 (20130101); Y10S 420/903 (20130101) |
Current International
Class: |
H01L
35/00 (20060101); H01L 35/16 (20060101); B22F
3/24 (20060101); H01L 35/34 (20060101); H01L
35/12 (20060101); B22f 001/00 () |
Field of
Search: |
;75/223,213,134G,134H
;29/573 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Padgett; Benjamin R.
Assistant Examiner: Hunt; B.
Attorney, Agent or Firm: Waters, Roditi, Schwartz &
Nissen
Claims
What is claimed is:
1. A method for fabricating bimetallic members of thermoelements
from ingots of alloys based on a solid solution of Bi.sub.2
Te.sub.3 - Sb.sub.2 Te.sub.3, comprising crushing said ingots to
fines, pressing said fines in briquettes similar in shape to the
bimetallic members of the thermoelements, and annealing said
briquettes in air in a thick-walled metal vessel with a powdered
graphite medium.
2. A method for fabricating bimetallic members of thermoelements
from ingots of alloys based on a solid solution of Bi.sub.2
Te.sub.3 - Bi.sub.2 Se.sub.3, comprising crushing said ingots to
fines, pressing said fines in briquettes similar in shape to the
bimetallic members of the thermoelements, and annealing said
briquettes in air in a thick-walled metal vessel with a powdered
graphite medium.
Description
The present invention relates to a method for manufacturing
thermoelements, and more particularly to a method for fabricating
bimetallic members of thermoelements.
Known in the art is a method for fabricating bimetalic members of
thermoelements from ingots of alloys based on solid solutions of
Bi.sub.2 Te.sub.3 - Sb.sub.2 Te.sub.3 and Bi.sub.2 Te.sub.3 -
Bi.sub.2 Se.sub.3 consisting in crushing the ingots to fines which
are then pressed in briquettes similar in shape to the bimetallic
members of thermoelements being produced and, finally, in annealing
the briquettes in a medium protected against oxidation. Used as
said medium are vacuum, an inert gas, or hydrogen.
A disadvantage of the prior-art method resides in the necessity to
use, for annealing, vacuum-pumping assemblies or special chambers
protecting the working medium against oxidation which substantially
complicates the process of manufacturing thermoelements.
It is an object of the present invention to improve the method for
fabricating bimetallic members of thermoelements so as to abandon
the use of vacuum-pumping assemblies or any other sophisticated
protecting chambers in the process of annealing, thus simplifying
the manufacture of thermoelement bimetallic members.
This object is achieved by annealing said briquettes in air in a
thick-walled metal vessel with a powdered graphite medium
therein.
The method for fabricating bimetallic members of thermoelements
according to the present invention does not call for the use of
sophisticated equipment for the annealing stage thereof.
The invention will now be explained in greater detail with
reference to a preferred embodiment thereof.
To fabricate bimetallic members of thermoelements of p-type
conductivity, use is made of ingots of alloys containing 76 mol
percent of Sb.sub.2 Te.sub.3, 24 mol percent of Bi.sub.2 Te.sub.3,
and 3 wt percent Te of the total weight of all the starting
components. The content of alloys used for the fabrication of
bimetallic members of n-type thermoelements is as follows: 80 mol
percent of Bi.sub.2 Te.sub.3, 20 mol percent of Bi.sub.2 Se.sub.3,
and 0.15 wt percent ZnCl.sub.2 of the total weight of the starting
components.
First, the ingots are crushed to fine particles of no more than 0.5
mm in diameter. Then, the fines thus obtained are charged into
molds and pressed at room temperature under a pressure of 9
t/cm.sup.2. Briquettes are formed which are annealed. For
annealing, the briquettes are placed in a thick-walled metal vessel
precharged with fine graphite (a layer 1 to 2 cm thick). The rest
of the vessel volume is also filled with graphite which is slightly
compressed. The vessel is covered with a lid and placed in an
annealing furnace. Temperature is controlled by thermocouple
inserted into a hole made in the vessel. Bimetallic members of
p-type thermoelements are annealed at a temperature of 375.degree.
C for 3 hours, while those of n-type thermoelements are annealed at
a temperature of 360.degree. C for 2 hours.
The thermoelectric efficiency of bimetallic members of p- and
n-type thermoelements fabricated by the novel method is
substantially higher than that of thermoelement bimetallic members
treated in vacuum by the prior-art method, as well as in air.
* * * * *