U.S. patent number 3,852,221 [Application Number 05/173,314] was granted by the patent office on 1974-12-03 for liquid olefin sulfonate detergent.
This patent grant is currently assigned to Jefferson Chemical Company, Inc.. Invention is credited to Floyd Edward Bentley.
United States Patent |
3,852,221 |
Bentley |
December 3, 1974 |
LIQUID OLEFIN SULFONATE DETERGENT
Abstract
Liquid detergent formulations that are based on particular
olefin sulfonates provide exceptional detersive performers that are
homogeneous, clear and stable at low temperatures.
Inventors: |
Bentley; Floyd Edward (Austin,
TX) |
Assignee: |
Jefferson Chemical Company,
Inc. (Houston, TX)
|
Family
ID: |
22631458 |
Appl.
No.: |
05/173,314 |
Filed: |
August 19, 1971 |
Current U.S.
Class: |
510/429;
510/496 |
Current CPC
Class: |
C11D
1/655 (20130101); C11D 1/523 (20130101); C11D
1/29 (20130101); C11D 1/143 (20130101) |
Current International
Class: |
C11D
1/02 (20060101); C11D 1/12 (20060101); C11D
17/00 (20060101); C11d 001/14 (); C11d
001/831 () |
Field of
Search: |
;252/536,548,555,556
;260/513R |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
|
|
|
|
|
|
|
1,961,963 |
|
Dec 1970 |
|
DT |
|
1,139,158 |
|
Jan 1969 |
|
GB |
|
Other References
Marquis et al., "Alpha-Olefin Sulfonates from a Commercial SO -Air
Reactor," JOACS, SEPT. 1966, pp. 607-614..
|
Primary Examiner: Kendall; Ralph S.
Assistant Examiner: Willis; P. E.
Attorney, Agent or Firm: Bailey; James L. Kirk, Jr.; John
R.
Claims
I claim:
1. A detergent composition consisting essentially of a clear
homogeneous liquid of (A) 19 to 30 wt. percent of an olefin
sulfonate component; (B) 8 to 15 wt. percent of an alcohol ether
sulfate component; (C) 3 to 7 wt. percent of a substituted fatty
acid amide component; (D) 1 to 8 wt. percent of a sulfonated
hydrotrope component; (E) 1 to 8 wt. percent of a monohydric
water-miscible alcohol; and (F) 32 to 68 wt. percent water; wherein
said component (A) consists essentially of (1) 7 to 60 wt. percent
of a C.sub.14 alpha-olefin sulfonate, and (2) 93 to 40 wt. percent
of a vinylidene-olefin sulfonate, wherein said vinylidene-olefin
sulfonate (2) consists essentially of C.sub.14 or C.sub.16
vinylidene-olefin sulfonate, and admixtures thereof, provided
however that the total amount of said vinylidene olefin sulfonate
component (2) shall not exceed 80 wt. percent of said component (A)
when said vinylidene-olefin sulfonate contains 95 wt. percent or
more C.sub.16 vinylidene-olefin sulfonate; wherein said component
(B) is a sulfated 2 to 5 mole polyethoxylate of a monohydric
C.sub.10 to C.sub.18 alcohol; wherein said component (C) is a fatty
acid monoethanolamide, a fatty acid isopropanolamide, a fatty acid
diethanolamide, or a fatty acid glyceryl amide and wherein the
fatty acid portion is a C.sub.10 to C.sub.16 aliphatic acid, and
admixtures thereof, and wherein said component (D) is an alkali
metal salt of xylene sulfonate, toluene sulfonate, benzene
sulfonate, or admixtures thereof.
2. The composition of claim 1 wherein said detergent composition
consists essentially of 20 to 24 wt. percent of said component (A),
10 to 13 wt. percent of said component (B), 4 to 6 wt. percent of
said component (C), 2 to 6 wt. percent of said component (D), 2 to
6 wt. percent of said component (E), and 45 to 61 wt. percent of
said component (F).
3. The composition of claim 1 wherein said component (A) consists
essentially of 30 to 60 wt. percent of said alpha-olefin sulfonate
and 70 to 40 wt. percent of said vinylidene-olefin sulfonate.
4. The composition of claim 3 wherein said vinylidene-olefin
sulfonate consists essentially of C.sub.14 vinylidene-olefin
sulfonate.
5. The composition of claim 3 wherein said component (B) is a
sulfated 2 to 5 mol ethoxylate of a C.sub.10 to C.sub.14 monohydric
alcohol, said component (C) is a fatty acid ethanolamide or fatty
acid diethanolamide, wherein said component (D) is sodium xylene
sulfonate, and wherein said component (E) is ethyl alcohol.
6. The composition of claim 2 wherein said component (B) is a
sulfated 2 to 5 mol ethoxylate of a C.sub.10 to C.sub.14 monohydric
alcohol, said component (C) is a fatty acid ethanolamide or fatty
acid diethanolamide, wherein said component (D) is sodium xylene
sulfonate, and wherein said component (E) is ethyl alcohol.
Description
This invention relates to novel liquid detergent compositions and
to a method for making liquid detergent compositions based on
olefin sulfonates.
More particularly, this invention relates to built light duty
olefin sulfonate liquid detergent compositions and to a method for
providing homogeneous, clear, low temperature stable, liquid
detergents based on alpha-olefin sulfonates and vinylidene-olefin
sulfonates.
Detergents based on biodegradable alpha-olefin sulfonates and
vinylidene-olefin sulfonates represent attractive alternatives to a
general public who have become increasingly concerned with ecology
and environmental conservation.
Heavy duty granular detergents based on said olefin sulfonates were
recently described in U.S. Pat. No. 3,544,475.
To my knowledge, however, the art has neither described any
homogeneous, clear liquid detergent compositions based on said
olefins, nor has it even addressed itself to the problems of making
light duty liquid detergent formulations based on said olefins.
I believe, therefore, that my invention represents a significant
advancement in the field of liquid light duty detergents.
Surprisingly, my invention not only provides a liquid detergent
that has improved oily-soil removing characteristics and better
foam stability than active compounds known to the art such as the
alpha-olefin sulfonates and alkylbenzene sulfonates, but my
detergents possess the superior characteristics of being clear,
homegeneous liquids that are stable with respect to separations of
solids under conditions of low temperature storage, e.g.,
30.degree.F. to 40.degree.F., and are stable with respect to
gelling during formulation and/or storage.
Therefore, in accordance with my invention, the above-described
liquid detergent composition is provided that consists essentially
of a clear homogeneous liquid of:
A. 19 to 30 wt. percent of an olefin sulfonate component;
B. 8 to 15 wt. percent of an alcohol ether sulfate component;
C. 3 to 7 wt. percent of a substituted fatty acid amide
component;
D. 1 to 8 wt. percent of a sulfonated hydrotrope component;
E. 1 to 8 wt. percent of a monohydric water-miscible alcohol;
and
F. 32 to 68 wt. percent water.
Preferably, the olefin sulfonate component (A) is employed in an
amount in the range of about 20 to 24 percent by weight thereof
based on said detergent composition.
Said olefin sulfonate component (A) consists essentially of (1)
alpha-olefin sulfonate and (2) vinylidene-olefin sulfonate which
are employed in the form of the alkali metal salts, ammonium salts,
or substituted ammonium salts, such as the sodium, potassium,
ammonium and ethanolamine salts of the respective sulfonates, and
mixtures thereof.
Said alpha-olefin sulfonate (1) is employed in an amount sufficient
to provide in the range of about 7 to 60 wt. percent, preferably 30
to 60 wt. percent, based on the total weight of said olefin
sulfonate component (A).
Said alpha-olefin sulfonate (1) consists essentially of C.sub.14 to
C.sub.16 alpha-olefin sulfonates, and mixtures thereof, wherein the
C.sub.14 alpha-olefin sulfonate is employed in an amount sufficient
to provide in the range of about 50 to 100 wt. percent, based on
the total weight of said alpha-olefin sulfonate (1) and the
C.sub.16 alpha-olefin sulfonate is employed in an amount to provide
in the range of about 0 to 50 wt. percent, preferably 0 to 20 wt.
percent, based on the total weight of said alpha-olefin sulfonate
(1).
The vinylidene-olefin sulfonate (2) is employed in an amount
sufficient to provide in the range of about 40 to 93 wt. percent,
preferably about 40 to 70 wt. percent, based on the total weight of
said olefin sulfonate component (A).
The vinylidene-olefin sulfonate (2) consists essentially of
sulfonates of C.sub.14 to C.sub.16 vinylidene olefin, and mixtures
thereof, said vinylidene olefins being represented by the following
formula: ##SPC1##
wherein R and R' are independently alkyl groups and the total
carbon atoms in said groups are in the range from 12 to 14.
Further, when the said vinylidene-olefin sulfonate (2) contains 95
percent by weight or more C.sub.16 vinylidene-olefin sulfonate the
total amount of said vinylidene-olefin sulfonate (2) should not
exceed about 80 percent by weight of the total weight of said
olefin sulfonate component (A).
It should also be noted that although said olefin sulfonate
component (A) consists essentially of the above-described
components, it need not be entirely pure and can contain small
amounts, e.g., not more than 10 percent by weight of the total
weight of the olefin sulfonate component (A) of sulfonated products
of internal olefins, diolefins, olefins containing carbon atoms per
molecule greater (such as C.sub.16, C.sub.18, and the like), or
less (such as C.sub.12, and the like) than the aforementioned
components, mixtures thereof, and the like. A small quantity, of
the order 1 to 5 percent, of unsulfonated oil may also be present
in the olefin sulfonate component (A).
The alcohol ether sulfate component (B) can be represented by the
following formula:
R"--O(C.sub.2 H.sub.4 O).sub.x SO.sub.3 M
wherein R" represents a C.sub.10 to C.sub.18 alkyl group, x is an
integer of 2 to 5 and M represents a cation such as an alkali
metal, e.g., sodium, potassium, and the like, ammonium, substituted
ammonium, such as alkanolamine, e.g., ethanolamine, and the like,
or admixtures thereof.
The above-described component (B) is a sulfated monohydric alcohol
polyethoxylate and can be derived from synthetic alcohols, such as
lauryl alcohol or natural alcohol, such as those from coconut oil,
palm-kernel oil, and the like, or admixtures thereof. Said alcohol
ether sulfate component (B) can be made conventionally by the
condensation of 2 to 5 mols of ethylene oxide on to an aliphatic
monohydric alcohol having in the range of about 10 to 18,
preferably about 10 to 14, carbon atoms per molecule. The
ethoxylated alcohol is sulfated and neutralized by known methods.
Preferably, the alcohol ether sulfate component (B) comprises about
10 to 13 percent by weight of said detergent composition.
The substituted fatty acid amide component (C) comprises a fatty
acid portion and a substituted amide portion. The fatty acid
portion is derived from an aliphatic acid containing in the range
of 10 to 18 carbon atoms per molecule. The fatty acid can be
derived from a natural source, such as the fatty acids derived from
coconut oil, palm-kernel oil, and the like, and mixtures thereof,
or a synthetic acid, such as lauric, myristic, palmitic, linoleic,
and the like, and mixtures thereof. The substituted acid amide is
selected from fatty acid monoethanolamide, fatty acid
monoisopropylamide, fatty acid diethanolamide, and fatty acid
glycerylamide, and mixtures thereof. The substituted fatty acid
amide component (C) preferably is employed in an amount to provide
in the range of about 4 to 6 percent by weight thereof, based on
the total weight of said detergent composition.
The sulfonated hydrotrope component (D) is selected from the alkali
metal salts of xylene sulfonate, toluene sulfonate, benzene
sulfonate, or admixtures thereof. Sodium xylene sulfonate is
presently preferred. Preferably, said sulfonated hydrotrope
component (D) is employed in an amount to provide in the range of
about 2 to 6 percent by weight thereof, based on the total weight
of said detergent composition.
The monohydric water-miscible alcohol component (E) preferably is
employed in an amount to provide about 2 to 6 percent by weight
thereof, based on the total weight of said detergent composition.
Exemplary alcohols include ethanol, isopropanol, admixtures
thereof, and the like.
Additionally, said detergent composition can contain the usual
ingredients conventionally included in liquid detergents, such as
coloring agents, perfumes, bacteriocides, suspending agents, and
the like.
The water component (F) is preferably employed in an amount
sufficient to provide about 45 to 61 percent by weight thereof,
based on the total weight of said detergent composition. It should
be understood that it is not necessary to add water per se as an
individual component, but that the water can be supplied by using
aqueous solutions of the heretofore mentioned components. For
example, olefin sulfonate aqueous slurries, sulfonated hydrotrope
aqueous solutions, and the like, are customarily employed.
It is recognized that components (B) through (F), above-described,
are conventionally employed in liquid detergent formulations. This
is advantageous since these components are already favorably
recognized in the industry. Our novel compositions, therefore,
employ heretofore established components in combination with select
quantities of particular olefin sulfonates to provide a novel and
surprising olefin sulfonate based liquid detergent composition.
The fact that my liquid detergent composition, above-defined, is
stable with respect to separation of solids, even under conditions
of low temperature storage, and stable with respect to gel
formation during formulation and/or storage was completely
unexpected. This is particularly true since I found that the
C.sub.14 and C.sub.16 vinylidene-olefin sulfonates individually, or
as admixtures, were not particularly compatible with water.
Vinylidene C.sub.16 olefin sulfonate was found to be practically
insoluble in water and the vinylidene C.sub.14 olefin sulfonate
still a definite slurry consistency at 40 percent concentration.
That such vinylidene-olefin sulfonates could be employed to provide
a homogeneous and clear liquid detergent composition, a composition
I sought to prepare appeared to be seemingly impossible.
To add further discouragement to my development work, I found that
when alpha-olefin sulfonates, such as above-mentioned, were admixed
with the conventionally employed components (B) and (C), e.g., the
alcohol ether sulfonates and the fatty acid alkanolamides,
respectively, that a blob of gel immediately began to form which
thickened upon the continued addition of the components. Quite
obviously a clear homogeneous liquid detergent employing such a
combination looked hopeless.
To even further complicate the problem, I additionally found that
when components (B) through (F) were employed alone with a
vinylidene-olefin sulfonate, as above-defined, the formulation
became markedly less stable under low temperature storage.
Accordingly, it was with great surprise that I discovered that the
vinylidene-olefin sulfonates, as above-defined, when employed
together with the alpha-olefin sulfonates, as I have hereinbefore
outlined, would provide a clear homogeneous detergent composition.
Accordingly, all of the above-described problems were somehow
dispelled by using my unique olefin sulfonate component (A).
In addition, other surprising results and unexpected advantages of
my invention were also discovered. In the composition heretofore
described as preferably, i.e., wherein the vinylidene-olefin
sulfonate component (2) is employed in amounts of about 40 to 70
percent by weight thereof, based on the total weight of the olefin
sulfonate component (A) the dishwashing performance of my liquid
detergent composition is greater than one would expect from a
straight line relationship between a 100 percent vinylidene-olefin
sulfonate containing detergent and a 100 percent alpha olefin
sulfonate containing detergent. Also the ability for considerable
viscosity control in the final formulation by merely adjusting the
percentages of the various components within the parameters
hereinbefore defined was realized.
It should be further noted that smaller amounts than are
conventionally used of the more expensive components, i.e., the
alcohol ether sulfates and the substituted fatty acid amide
components need be employed when they are used with the olefin
sulfonate component (A) according to my invention. Further use of
even lesser amounts of these components when employed according to
my invention results in little or no loss in the performance of the
detergent.
The detersive performance of the liquid detergent compositions of
my invention is appreciably better than the detersiveness of
identical detergents based on linear alkylbenzene sulfonates (LAS).
The liquid detergent compositions of my invention also exhibit even
more improved detersive performance with increasing water hardness.
At the level of 150 ppm. hardness, for example, the liquid
detergent compositions of my invention give about 25 percent better
detersive performance than a liquid detergent employing LAS.
When the components, as herein outlined, are employed, the
particular manner in which my detergent composition is formulated
is not critical. For example, the components can be admixed in any
order that is convenient to the practitioner. It is presently
preferred, however, to admix the olefin sulfonate component (A)
with the alcohol component (E) and the sulfonated hydrotrope
component (D) and at least a portion of the water (F) prior to
admixing the alcohol ether sulfate component (B) and the
substituted fatty acid amide component (C). Regardless of the order
of mixing, however, the olefin sulfonate component (A) of this
invention will surprisingly dissolve readily with the other
components of the formulation to provide a clear homogeneous liquid
detergent composition.
As an illustration of the foregoing discussion and description, and
not to be interpreted as a limitation on the scope thereof, or on
the materials herein employed, the following examples are
presented.
EXAMPLES I-VIII
Although many formulations were made, the following detergent
formulation, as reported in Table 1, is typical and exemplifies my
novel light duty liquid detergent composition when the heretofore
described components are employed in accordance with my invention.
Typical examples are, therefore, recorded in Table 2 which
demonstrate the results obtained by using the formulation reported
in Table 1 with varying amounts of the olefin sulfonate component
(A) of my invention. Likewise reported are typical examples that
demonstrate the relative instability of other olefin sulfonate
based formulations.
TABLE 1 ______________________________________ FORMULATION
Component %, By Weight A. Olefin sulfonate .sup.(a) 23.0 B. Alcohol
ether sulfate .sup.(b) 12.5 C. Substituted fatty acid amide
.sup.(c) 4.8 D. Sulfonated aryl hydrotrope .sup.(d) 5.0 E.
Water-miscible alcohol .sup.(e) 5.0 F. Water 49.7
______________________________________ .sup.(a) Sodium salt - see
Table 2 .sup.(b) 60%, By weight C.sub.14, 40%, by weight C.sub.12,
alcohol - 3 mo ethylene oxide adduct - ammonium salt .sup.(c)
Coconut acid monoethanolamide .sup.(d) Sodium xylene sulfonate
.sup.(e) Ethyl alcohol
TABLE 2
__________________________________________________________________________
Example Olefin Sulfonate Component (A), %, By Weight Results
__________________________________________________________________________
Alpha Olefin Vinylidene Olefin Viscosity, 40.degree.F. Storage
Plates Sulfonate.sup.(a) Sulfonate.sup.(b) cps. at 25.degree.C.
Stability Washed.sup.(d)
__________________________________________________________________________
1. 100 0 Gel -- 27 2. 75 25 Gel -- 31 3. 62.5 37.5 Partial Gel --
-- 4. 50 50 143 Stable 36 5. 30 70 90 Stable 37 6. 10 90 53 Stable
35 7. 5 95 -- Unstable.sup.(c) -- 8. 0 100 -- Unstable.sup.(c) 36
__________________________________________________________________________
.sup.(a) C.sub.14 alpha-olefin sulfonate .sup.(b) 50/50 mixture, by
weight, C.sub.14 and C.sub.16 vinylidene olefi sulfonate .sup.(c)
Solids separate and, generally, separation is evident within 24
hours-48 hours .sup.(d) As reported by Anstett and Schuck, J. Am.
Oil Chem. Soc. 43, 576(1964)
EXAMPLES IX-X
Similar experiments to those reported above were performed using a
detergent formulation such as reported in Table 1. Accordingly,
storage stable (at 40.degree.F.) detergent compositions which were
clear homogeneous liquids and did not gel during formulation or
storage were also made wherein the olefin sulfonate component (A)
consisted of 93% C.sub.14 vinylidene-olefin sulfonate and 7%
C.sub.14 alpha-olefin sulfonate. Another stable, clear homogeneous
detergent composition was made wherein the olefin sulfonate
component (A) consisted of 80% C.sub.16 vinylidene olefin sulfonate
and 20% C.sub.14 alpha-olefin sulfonate.
The preceding examples can, of course, be repeated with similar
success by substituting the generically and specifically described
reactants and conditions of this invention for those employed in
the examples. As will be evident to those skilled in the art,
various modifications of this invention can be made or followed in
light of the discussion and disclosure herein set forth without
departing from the spirit or the scope thereof.
* * * * *