U.S. patent number 3,852,152 [Application Number 05/271,355] was granted by the patent office on 1974-12-03 for resilient cushion.
This patent grant is currently assigned to Akzona Incorporated. Invention is credited to Hans Stapp, Helmut Werner.
United States Patent |
3,852,152 |
Werner , et al. |
* December 3, 1974 |
RESILIENT CUSHION
Abstract
This invention relates to a resilient filamentary cushioning
unit or pad and a process for its production wherein a plurality of
substantially amorphous thermoplastic filaments, e.g.,
fiber-forming polyamide filaments, are melt-spun into a liquid
cooling bath in such a manner that they lie in the form of
predominately helical to sinuous loops randomly bonded at their
points of intersection as the filaments are completely solidified
in the bath. The resulting looped and bonded filaments form a
cohesive resilient structure which is useful as a spring core or
cushioning unit.
Inventors: |
Werner; Helmut (Elsenfeld,
DT), Stapp; Hans (Momlingen, DT) |
Assignee: |
Akzona Incorporated (Asheville,
NC)
|
[*] Notice: |
The portion of the term of this patent
subsequent to September 12, 1989 has been disclaimed. |
Family
ID: |
27181375 |
Appl.
No.: |
05/271,355 |
Filed: |
July 13, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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807301 |
Mar 14, 1969 |
3687759 |
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Foreign Application Priority Data
|
|
|
|
|
Mar 21, 1968 [DT] |
|
|
1778026 |
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Current U.S.
Class: |
428/338; 156/181;
264/178F; 428/371; 156/167; 264/168; 264/282 |
Current CPC
Class: |
D04H
3/16 (20130101); Y10T 24/27 (20150115); Y10T
428/2925 (20150115); Y10T 442/68 (20150401); Y10T
428/268 (20150115) |
Current International
Class: |
D04H
3/16 (20060101); B32b 005/02 (); D04h 003/16 () |
Field of
Search: |
;161/47,70,140,142,143,146,150,156,157,148,166,168,169,173
;5/351,361B ;156/167,181,306 ;264/168,178F,282 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Lesmes; George F.
Assistant Examiner: Lipsey; Charles E.
Attorney, Agent or Firm: Johnston, Keil, Thompson &
Shurtleff
Parent Case Text
This is a division of application Ser. No. 807,301, filed Mar. 14,
1969, now U.S. Pat. No. 3,687,759.
Claims
The invention is hereby claimed as follows:
1. A resilient cushioning unit consisting essentially of a
plurality of continuous melt-spun filaments of a substantially
amorphous synthetic thermoplastic fiber-forming polymer with a
filament diameter of between about 0.1 and 1 mm., each of said
continuous filaments extending side by side in the direction of
compression of the cushioning unit in the form of filamentary
springs having substantially periodic helical to sinuous loops
which coil around parallel vertical axes corresponding to said
direction of compression, said loops of each filamentary spring
spreading laterally in overlapping relationship with the
corresponding loops of the next adjacent filamentary springs with a
random adhesive bonding of the filaments at their points of
intersection to form a cohesive structure substantially more
resilient in the vertical direction than in the direction
transverse thereto.
2. A resilient filamentary cushioning unit as claimed in claim 1 in
which the individual filament diameter is from about 0.3 to 0.5
mm.
3. A resilient filamentary cushioning unit as claimed in claim 1
wherein the polymer is a synthetic fiber-forming polyamide.
4. A resilient filamentary cushioning unit as claimed in claim 1
wherein the polymer is polycaprolactam.
5. A resilient filamentary cushioning unit as claimed in claim 1
wherein the polymer is polyhexamethylene adipamide.
6. A resilient filamentary cushioning unit as claimed in claim 1
wherein the parallel axes of the filamentary springs are spaced
about equidistantly from each other corresponding approximately to
the linear path of the freshly spun filaments, said axes being
separated by a distance of about 3 to 10 mm.
Description
Various kinds of resilient materials are employed for the padding
of chairs, automobile seats, or as mattress cores or similar bulky
cushioning elements. In addition to foamed elastomeric polymer
units, which can be supplied in any desired thickness, density and
softness or hardness, the use of coiled metal springs as cushioning
inserts still plays an important role, particularly as mattress
cores. Such cushioning units have many very desirable properties
but also have the disadvantage that cleaning them is difficult.
Furthermore, cushioning units with coiled metal springs and even
thick foamed elastomers are comparatively heavy.
One object of the present invention is to provide a new cushioning
unit which is similar to a spring core having individual coiled or
helical springs but which has many advantages by comparison with
previously known cushioning constructions. Another object of the
invention is to provide a novel process for the production of a
resilient filamentary cushioning unit which is essentially composed
only of a large number of synthetic melt-spun filaments. Other
objects and advantages of the invention will become more apparent
upon consideration of the following detailed disclosure.
It has now been found, in accordance with the invention, that a
highly useful and unique resilient cushioning unit can be obtained
by the steps comprising melt-spinning a plurality of substantially
amorphous synthetic thermoplastic polymer filaments having a
diameter of from about 0.1 to 1 mm. downwardly into a liquid
cooling medium, preferably water, which initially supports the
filaments or exerts a sufficient buoyant force to cause the
individual filaments to extend longitudinally in the form of loops
of a helical to sinuous character which spread laterally in
overlapping relationship with the loops of the next adjacent
filaments as the filaments enter the cooling medium. The freshly
spun filaments are completely solidified only after their entry
into the cooling medium so as to adhesively bond overlapping loops
at their points of intersection on direct contact. After such
solidification, the resulting coherent mass of looped and
interconnected filaments are withdrawn from the cooling medium as a
single continuous unit, preferably without any substantial tension
being placed on the filaments as they are spun, looped and bonded
or adhered together. Especially advantageous results are achieved
with spun fiber-forming thermoplastic filaments having a diameter
of about 0.3 to 0.5 mm.
The term "substantially amorphous" as applied to the filaments is
employed herein to designate those filaments which have a
crystalline proportion which amounts to not more than about 30
percent, and preferably less than 20 percent. This amorphous
characteristic of the filaments is a well known property which can
be easily determined by conventional methods. In the conventional
melt-spinning and stretching of thermoplastic filaments, a high
degree of molecular orientation is achieved so that the initially
amorphous polymer acquires a correspondingly high crystallinity.
Since it is preferable to avoid any tension capable of stretching
the filaments during the process of the present invention, the
amorphous character of the initial polymer is largely retained.
The term "buoyant force" as used in connection with the liquid
cooling medium is intended to include not only the upward force
exerted upon an immersed body in a liquid but also surface tension
forces which may act to support the body on the surface of the
water. The generally helical looping of the freshly spun filaments
as they enter the liquid cooling medium can be attributed to one or
both of these forces, although the exact mechanism is not fully
understood. It is apparent, however, that looping begins at the
surface of the cooling liquid, and as the filaments sink below this
surface, the individual loops of a filament are most often
separated in a continuous helical to sinuous configuration. Thus,
relatively few crunodal loops are formed, i.e., where a single
filament curves back to cross itself and becomes bonded at the
crossing point. Instead, the loops are preponderantly bonded or
adhered together as between adjacent filaments.
The polymer melt can be extruded with conventional apparatus onto
the cooling liquid from at least one multiaperture spinneret,
wherein the spinneret apertures are approximately equally spaced
from one another at intervals from about 3 to 10 mm.,
advantageously about 5 to 7.5 mm. A plurality of such spinnerets
can be arranged in juxtaposition to provide additional apertures
where desired, it being understood that all apertures must be
spaced at intervals sufficiently close to each other to permit the
desired overlapping of adjacent loops as they are formed. For
practical reasons, one must employ more than just a few filaments,
e.g., on the order of at least 30 to 80 or more.
The distance between the bottom or lower face of the apertured
spinneret and the surface of the cooling liquid should ordinarily
amount to about 2 to 30 cm., advantageously about 4 to 20 cm. It is
important to avoid any substantial cooling or solidification of the
freshly spun filaments before they enter the cooling liquid since
otherwise it would not be possible to obtain an adherent
melt-bonding of the filamentary loops. Thereafter, the freshly spun
molten filaments are solidified on entering the cooling liquid as
they lie in loop form and cross over one another. After complete
solidification into a coherent cushioning unit, the product is
continuously withdrawn from the cooling liquid by any suitable
means.
The filaments forming the cushioning unit can be produced from any
melt-spinnable synthetic linear fiber-forming polymer including
polyamides, polyesters, polyolefins and the like, preferably
non-elastomeric polymers. However, it has been found to be
especially advantageous to employ conventional polyamides and
especially polycaprolactam.
In most instances, it is desirable for all of the filaments of a
cushioning unit to have the same diameter within the above-noted
limits, although it is feasible to vary the individual diameters to
some extent and still obtain a useful product. With smaller
diameter filaments the resulting loops are also smaller while
larger diameter filaments produce larger loops, other conditions
being equal. Therefore, the interval between spinning apertures is
in part dependent upon the diameter of the individual filaments
since one must ensure a lateral overlapping of the loops as they
are formed by adjacently parallel freshly spun filaments entering
the cooling liquid.
Certain variations are possible and often desirable within the
process conditions according to the invention, depending in part on
the nature and properties of the polymer itself. The properties of
the final product can be considerably influenced by certain
modifications of the working conditions. This is important, since
upholstery or cushioning materials of widely varying softness or
hardness are required for various uses such as in the use of
upholstered furniture and mattresses. Apart from the polymer
material being used for the production of the cushioning unit, the
following factors influence to a greater or lesser degree the
properties of the end products: the distance of the spinneret
apertures from one another, the distance between spinneret and bath
surface, the spinning speed, the withdrawal speed and the
temperature of the cooling liquid. Since all these conditions can
be exactly adjusted and can be kept constant during the process, it
is readily possible to manufacture both very soft cushioning units,
i.e., those which can be highly compressed, and also hard
cushioning units, i.e., those which can be compressed only to a
relatively small extent.
It is important to maintain certain processing conditions according
to the invention within rather critical limits. Thus, for example,
it has been found best to maintain the distance of the spinneret
apertures from one another within the above-noted limits of about 3
to 10 mm., advantageously 5 to 7.5 mm., so that the cushioning unit
is given a sufficiently dense but not too compact structure.
Moreover, the distance from the spinning apertures at the bottom of
the spinneret to the bath surface may only be varied within the
indicated limits of about 2 to 30 cm., advantageously 4 to 20 cm. A
smaller distance is unsuitable on account of the great temperature
difference between the spinneret and cooling liquid, while on the
other hand, it is not usually possible to guarantee the required
loop formation of the filaments with a spacing greater than 30 cm.
Within the broadest limits of these designated ranges, the required
results cannot be produced under all circumstances, but the process
of the invention does offer the possibility, when working at the
extreme ends of these broad ranges, of producing useful cushioning
units by alteration of other processing conditions, for example,
the spinning speed, the withdrawal speed and/or the temperature of
the bath. The dependence of the properties of the resilient
cushioning products according to the invention on such individual
factors or conditions is explained in greater detail by means of
the examples and tables set forth below.
The temperature of the cooling liquid is not particularly critical
and is of relatively lesser significance. Nevertheless, it should
be adapted to the particular polymer. By way of example, bath
temperatures between about 20.degree. and 45.degree.C. are
particularly suitable for polycaprolactam, whereas
polyhexamethylene adipamide, i.e., polyamides of adipic acid and
hexamethylene diamine, are preferably spun into baths maintained at
about 40.degree. to 50.degree.C. Suitable means such as a heat
exchanger are provided for keeping the temperature of the bath
constant during the process. Highly turbulent circulation of the
bath liquid should be avoided, i.e., it is preferable to employ a
relatively deep tank in which agitation or circulation is kept to a
minimum. Also, it is preferable to continue the vertical travel of
the spun and looped filaments within the bath until they have been
completely solidified and interconnected or adhered to each other.
The resulting product can then be turned to one side and withdrawn
gradually upwardly until it emerges from the bath.
For reason of economy, water is advantageously used as the cooling
liquid, but other inert liquids can also be employed.
The spinning and the withdrawal speeds also influence the
properties of the cushioning unit being formed. Generally speaking,
both values are advantageously so adapted to one another such that
as far as possible no tension or only a slight tension is exerted
on the cushioning unit while it is being formed and while it passes
through the bath. If too great a tension is exerted, it can be
transmitted back to the point where the loops are being formed so
as to draw them out completely or at least sufficiently that
overlapping of adjacent loops cannot occur. In some instances
however, a slight tension can be exerted by increasing the
withdrawal speed, e.g., for producing a somewhat less dense
product.
The external form or shape which is imparted to the cushioning unit
depends on the size of the spinnerets, the number thereof and their
relative arrangement, and also on the distribution or pattern of
the spinneret apertures on the spinneret base plate. It is thus
possible to produce cushioning units which have a substantially
cylindrical form or an approximately rectangular cross-section. The
cushioning material with its longitudinally extending filamentary
coils or loops is initially withdrawn as an endless unit from the
bath and can then without any difficulty be trimmed or cut in
sections to the required size. A plurality of relatively small
cushioning units or a single large unit produced to conform to the
desired shape can be stuffed or inserted into the article to be
cushioned, such as mattresses, chair upholstery or the like. The
padded components such as a fabric or leather coverings filled with
the cushioning material according to the invention are extremely
light in weight and can be very easily washed in suitable washing
machines. The cushioned articles are extremely resilient and
dimensionally stable.
In order to provide a more complete understanding of the invention,
the following explanation is offered in conjunction with the
accompanying drawings wherein:
Fig. 1 is a schematic representation of a side view of the most
essential components of the apparatus employed in the process of
the invention;
FIG. 2 is an enlarged view of that portion of FIG. 1 which includes
the spinneret or spinning head and the liquid bath located directly
below;
FIG. 3 is a bottom plan view or face view of the spinneret or
nozzle plate to illustrate one arrangement of spinning apertures
therein;
FIG. 3a is a cross-sectional view of the final product, e.g., as
taken on line A--A of FIG. 1, having a circular shape as achieved
by the spinneret of FIG. 3;
FIG. 4 is a bottom plan view of the spinneret to illustrate another
arrangement of spinning apertures therein;
FIG. 4a is a cross-sectional view of the final product, e.g., as
taken on line A--A of FIG. 1, having an approximately rectangular
shape as achieved by the nozzle plate of FIG. 4;
FIG. 5 is a side view of an elongated section of the final product
approximately as it would appear when using any regular
cross-sectional shape; and
FIG. 6 is an enlarged view of a typical individual filament after
it has been looped and solidified but shown apart from the
remaining filaments of the final product.
Referring first to FIGS. 1 and 2, a conventional extruder 1
equipped with a spinning head 2 conveys the molten polymer to the
spinneret or nozzle plate 3 containing a plurality of equidistantly
spaced bores 12 emerging as the spinning apertures 13 at the lower
face 11 of the nozzle plate. The spun filaments 4 are permitted to
fall freely downwardly through an air gap 5 to initially enter the
surface 6 of the water bath 7 contained in a suitable vessel. The
liquid level in the vessel can be maintained constant by any
conventional means. As shown in FIG. 2, the initially parallel and
equidistantly spaced molten or highly softened extruded filaments
begin to form loops of a helical or sinuous configuration
immediately upon entry into the cooling liquid. As the overlapping
loops solidify, they become adhesively bonded at random points of
intersection and the entire mass of filaments tends to continue
falling downwardly in the bath of its own weight so that the
individual loops are partly drawn out to provide a longitudinally
expanded helical or sinuous configuration of each individual
filament. Although the individual filaments are extensively looped
or curved laterally back and forth in overlapping relationship with
immediately adjacent filaments, each tends to continue in the same
longitudinal path as the freshly spun filament. In other words, the
resulting helical to sinuous loops or coils are formed around
parallel vertical or longitudinal axes corresponding approximately
to the linear path of the freshly spun filaments.
The looped and overlapping filaments become sufficiently solidified
and firmly melt-bonded together after a relatively short distance
of vertical travel in the bath 7 so that the coherent product can
be continuously drawn around a pin or roller 8 and conveyed out of
the bath through the nip rollers 9 and 10 and finally collected as
a continuous roll and/or cut into appropriate lengths. The speed of
the rollers 9 and 10 should preferably be adjusted to just take up
any slack in the conveyed product, i.e., at about the speed at
which the initially solidifying mass of filaments falls vertically
down to the roller 8. The spinning velocity is of course more rapid
than this falling rate between surface 6 and roller 8. The most
desirable spinning velocity can be readily determined by routine
tests.
In FIGS. 3 and 4, the spinning apertures or openings 13 are
arranged approximately in the form of a circle or rectangle,
respectively, with regard to the outermost circumference of the
entire group of openings. This results in cushioning units having
an approximately circular or rectangular cross section according to
FIGS. 3a and 4a, respectively. Other shapes can also be provided
although extremely thin cross-sections are not practical. FIG. 5
merely gives the general appearance from one side of any
longitudinal section of the continuous resilient product.
Since the individual filaments do not ordinarily form a perfect
helix or cylindrical spiral but are slightly deformed or are
sometimes sinuous, it is somewhat difficult to observe the
configuration of these filaments when combined in the final
product. However, when viewed longitudinally, i.e., in looking down
at a cross section, the axis about which each filament is looped
becomes more apparent as a larger void space which runs entirely
through a short length of the product.
FIG. 6 provides an example of a typical filament of the final
product when viewed by itself as though no other filaments were
bonded thereto. A major proportion of the loops have a generally
helical configuration 14 but occasionally the loops have a reverse
curve 15 or form a sinuous pattern 16 rather than being strictly
helical. The individual filament may also exhibit a crunodal loop
17 where it becomes bonded to itself as at point 18. However, such
crunodal loops can be substantially avoided, e.g., by placing a
slight tension on the filaments as they form the loops and become
bonded to adjacent filaments. In general, such crunodal loops
appear to occur in not more than about 5 - 10 percent of all of the
loops.
In view of these illustrations and the examples set forth
hereinbelow, the finished product of the invention can be generally
identified as a resilient cushion material composed of a large
number of helically coiled or looped filamentary springs extending
longitudinally in approximately parallel positions and
interconnected to each other at random points of intersection of
immediately adjacent filaments. More specifically, the product of
the invention can be defined as a resilient cushioning unit
consisting essentially of a plurality of melt-spun filaments of a
substantially amorphous synthetic thermoplastic fiber-forming
polymer with an individual filament diameter of 0.1 to 1 mm.,
preferably 0.3 to 0.5mm., each of the filaments extending
longitudinally within the cushioning unit in the form of loops
spreading laterally in overlapping relationship with the
corresponding loops of the next adjacent filaments with random
adhesive or melt bonding of the filaments at their points of
intersection.
It will be noted that because of the helical structure analogous to
that found in the usual metal coiled springs, the cushioning unit
of the invention provides its greatest compressibility and
resiliency in the longitudinal direction corresponding to the axes
of the helices. In the lateral or transverse direction, the
filamentary cushioning unit of the invention is more apt to bend or
be crushed although it still exhibits a large degree of resiliency,
depending in part on the density of its structure. For this reason,
however, all compressibility measurements herein have been taken in
the longitudinal direction.
The process for the production of the cushioning units is explained
in greater detail by the following examples.
EXAMPLE 1
Polycaprolactam with a solution viscosity (.eta..sub.rel) of 2.6 is
extruded at a spinning temperature of 280.degree.C. from a
spinneret with 240 apertures. The spinneret apertures have a
diameter of 250 millimicrons and are arranged spaced from one
another at regular intervals of 6.5 mm. in a pattern similar to
that shown in FIG. 3. The diameter of the outer ring of apertures
is about 105 mm. The melt is extruded at a speed of 760 g/min. At a
distance of 16 cm. from the lower face of the spinneret plate, the
extruded filaments having a diameter of about 0.35 mm. strike a
water bath, the temperature of which is kept at 40.degree.C. The
filaments initially lie or collect briefly on the surface of the
water in loop form, each filament forming approximately helical
windings. Adjacent filaments are adhesively bonded on the surface
at the points of intersection. At relatively infrequent intervals,
one and the same filament is bonded to itself to form a crunodal
loop. The cushioning unit being formed gradually sinks into the
water bath and is withdrawn from the bath at a speed of 2.75
m/min., practically no tension being exerted on the filamentary
material. An approximately cylindrical unit is formed, which is cut
or trimmed to the required length.
The same process is twice repeated, whle maintaining the conditions
explained above, but with the difference that the bath temperature
is 30.degree. and 20.degree.C., respectively.
The influence of the different water temperature is apparent from
the following Table I. A cushioning unit with a height of 18 cm.
was loaded with a weight of 5 kg. as a means of measuring the
compressibility of the unit in the present example and also in
those which follow. The .DELTA.1 value shows the change in height
under the above noted load and is a standard for the softness,
i.e., compressibility of the product. In the present example, it
will be noted that a rather wide range of bath temperature has only
a moderate influence on the compressibility.
TABLE I ______________________________________ Delivery Withdrawal
Bath .DELTA.1 g/min. m/min. temperature cm.
______________________________________ 760 2.75 40.degree.C. 1.5
760 2.75 30.degree.C. 1.8 760 2.75 20.degree.C. 2.8
______________________________________
EXAMPLE 2
The influence of different melt spinning speeds (delivery) is shown
in Table II. Apart from the respective alterations in the delivery,
the tests were carried out in accordance with Example 1.
TABLE II ______________________________________ Delivery Withdrawal
Bath .DELTA.1 g/min. m/min. temperature cm.
______________________________________ 760 2.75 40.degree.C. 1.5
580 2.75 40.degree.C. 3.0 330 2.75 40.degree.C. 13.5 210 2.75
40.degree.C. 16.0 ______________________________________
It can be seen from the test results that it is not desirable for
the delivery to be reduced to less than about 400 g/min.
EXAMPLE 3
The process was carried out while maintaining the conditions of
Example 1, but with an interval between the spinneret and the bath
surface of 6 cm. and using different withdrawal speeds.
TABLE III ______________________________________ Delivery
Withdrawal Bath .DELTA.1 g/min. m/min. temperature cm.
______________________________________ 760 2.75 40.degree.C. 0.8
760 4.10 40.degree.C. 2.4
______________________________________
EXAMPLE 4
Table IV shows the results of a series of tests which were carried
out according to Example 1, but using a spinneret with an aperture
spacing of 7.5 mm. and also a spinneret with an aperture spacing of
5.0 mm. The other variations in the process can be seen from the
table.
Table IV
__________________________________________________________________________
Delivery Withdrawal Bath Space between g/min. m/min. temperature
spinneret and .DELTA.1 Aperture .degree.C. bath surface cm. spacing
__________________________________________________________________________
780 2.75 40 4 cm 4.0 7.5 mm. 600 2.75 40 4 cm 8.5 do. 400 2.75 40 4
cm 12.0 do. 180 2.75 40 4 cm 16.5 do. 780 2.75 40 16 cm 1.0 do. 600
2.75 40 16 cm 2.5 do. 400 2.75 40 16 cm 13.5 do. 180 2.75 40 16 cm
15.0 do. 780 2.75 40 4 cm 2.5 5.0 cm. 600 2.75 40 4 cm 3.5 do. 400
2.75 40 4 cm 11.0 do. 180 2.75 40 4 cm 12.5 do. 780 2.75 40 16 cm
6.0 do. 600 2.75 40 16 cm 8.5 do. 400 2.75 40 16 cm 12.5 do. 180
2.75 40 16 cm 16.5 do.
__________________________________________________________________________
EXAMPLE 5
The following Table V shows the dependency of the properties of the
cushioning unit on the withdrawal speed. In these tests, the
conditions of Example 1 were maintained, except where other data is
set forth in the Table.
TABLE V ______________________________________ Delivery Withdrawal
.DELTA.1 g/min. m/min. cm. ______________________________________
600 1.2 6.5 600 1.5 6.5 600 1.9 8.0 600 2.5 8.0 600 3.3 11.0 600
4.2 13.5 600 5.8 15.0 600 7.8 16.0
______________________________________
The results of this series of tests show that it is not desirable,
under the conditions indicated, to substantially increase the
withdrawal speed in relation to the delivery speed and thus to
exert a tension on the cushioning unit which is being formed,
unless it is desired to have a particularly soft and highly
compressible product.
EXAMPLE 6
Corresponding to Example 1, polyhexamethylene adipamide, i.e., the
polyamide of adipic acid-hexamethylene diamine salt, having a
solution viscosity (.eta..sub.rel) of 2.20 was melt spun by means
of a 398 aperture spinneret (diameter of the spinneret apertures =
250 millimicrons) with an aperture spacing of 5 mm. The other
processing conditions are set forth in Table VI.
TABLE VI ______________________________________ Bath Space between
Delivery Withdrawal Tempera- spinneret and .DELTA.1 g/min. m/min.
ture bath surface cm. ______________________________________ 780
2.75 45.degree. 4 cm 1.0 600 2.75 45.degree. 4 cm 2.5 400 2.75
45.degree. 4 cm 12.0 180 2.75 45.degree. 4 cm 16.5 780 2.75
45.degree. 16 cm 1.0 600 2.75 45.degree. 16 cm 4.0 400 2.75
45.degree. 16 cm 12.5 180 2.75 45.degree. 16 cm 16.0
______________________________________
EXAMPLE 7
Nine cylindrical padding units, formed in accordance with Example
1, were arranged in rows, each of three units, and while upright,
with a conventional upholstery covering material. These upholstered
samples were subjected to 10,000 reciprocal loadings with a weight
of 75 kg. and thereafter showed a permanent deformation of 10
percent.
* * * * *