U.S. patent number 3,851,140 [Application Number 05/337,005] was granted by the patent office on 1974-11-26 for plasma spray gun and method for applying coatings on a substrate.
This patent grant is currently assigned to Kearns-Tribune Corporation. Invention is credited to Robert G. Coucher.
United States Patent |
3,851,140 |
Coucher |
November 26, 1974 |
PLASMA SPRAY GUN AND METHOD FOR APPLYING COATINGS ON A
SUBSTRATE
Abstract
A method and plasma spraying device for more efficiently
depositing heat fusible materials on a substrate. The improved
efficiency referred to above is achieved by altering the flow
characteristics of a gaseous material as it enters a plasma forming
environment such as that produced by a pair of spaced-apart arcing
electrodes. The flow of gas is controllably altered by a gas
distribution ring which is capable of producing a linear or axial
gas flow in combination with a helical gas flow. As the mixed flow
of gas is converted into a plasma, its speed is accelerated and the
axial flow component is gradually converted into a spiraled or
helical flow. Whereupon, the heat fusible material introduced into
the plasma is thermally liquified and ejected at or near the speed
of sound.
Inventors: |
Coucher; Robert G. (Salt Lake
City, UT) |
Assignee: |
Kearns-Tribune Corporation
(Salt Lake City, UT)
|
Family
ID: |
23318691 |
Appl.
No.: |
05/337,005 |
Filed: |
March 1, 1973 |
Current U.S.
Class: |
219/121.59;
219/121.47; 219/76.16; 219/121.51 |
Current CPC
Class: |
H05H
1/42 (20130101); B05B 7/226 (20130101); H05H
1/3468 (20210501) |
Current International
Class: |
B05B
7/16 (20060101); B05B 7/22 (20060101); H05H
1/42 (20060101); H05H 1/26 (20060101); B23k
009/00 () |
Field of
Search: |
;219/74,75,76,121P
;239/424,428,468-472 ;313/231 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Reynolds; Bruce A.
Attorney, Agent or Firm: Trask & Britt
Claims
I claim:
1. A fluid distribution ring solely for use on an electric plasma
spraying device comprising a substantially circular ring member
having slanted tubular primary openings and at least one secondary
opening extending from the outside to the inside surfaces of said
ring, said primary openings being characterized by their ability to
direct a major portion of a fluid passing through said openings to
a focal point positioned along the axis of said ring to provide a
substantially linear flow component and said secondary opening
being characterized by its ability to direct a minor portion of
said fluid tangentially along the inner surface of said ring to
provide a substantially helical flow component.
2. The fluid distribution ring of claim 1 wherein said ring
contains an annular groove for directing said fluid into said
primary openings.
3. The fluid distribution ring of claim 2 wherein said ring
contains a second groove along its outer surface which intersects
said annular groove for directing fluid into said secondary
opening.
4. The fluid distribution ring of claim 3 wherein the secondary
opening exits from the inner surface of said ring at a point
anterior to said primary openings.
5. A plasma spraying device comprising a substantially closed
chamber, a first electrode defining a substantially elongated
nozzle outlet from said chamber, a second electrode extending into
said chamber and in spaced relation to said first electrode, a
means for introducing an arc forming electric current across said
electrodes and a means for introducing a plasma forming gas into
the area of said arc wherein said means includes a gas distribution
ring for directing a major portion of said gas along a
substantially linear flow path and a minor portion of said gas
along a substantially helical flow path which circumscribes the
linear flow path.
6. The plasma spraying device of claim 5 wherein said linear flow
component is gradually converted to an increasingly helical flow
component as said gas passes beyond said first electrode.
7. The plasma spraying device of claim 5 wherein said gas
distribution ring comprises a substantially circular ring member
having slanted tubular primary openings and at least one secondary
opening extending from the outside to the inside surfaces of said
ring, said primary openings being characterized by their ability to
direct a major portion of a fluid passing through said openings to
a focal point positioned along the axis of said ring to provide a
substantially linear flow component and said secondary opening
being characterized by its ability to direct a minor portion of
said fluid tangentially along the inner surface of said ring to
provide a substantially helical flow component.
8. The plasma spraying device of claim 7 wherein said gas
distribution ring includes an annular groove for directing said
fluid into said primary openings.
9. The plasma spraying device of claim 8 wherein said gas
distribution ring includes a second groove along its outer surface
which intersects said annular groove for directing fluid into said
secondary opening.
10. The plasma spraying device of claim 9 wherein said secondary
opening exits from the inner surface of said ring at a point
anterior to said primary openings.
11. A method for producing a high temperature plasma in an electric
plasma spraying device, comprising introducing a major portion of a
plasma forming gas into an area of a plasma producing electrical
arc in a path which provides a substantially linear flow component
and concomitantly introducing a minor portion of said plasma
forming gas into a plasma producing arc along a path which provides
a substantially helical flow component.
12. The method of claim 11 wherein the linear flow component is
gradually converted into a helical flow component as the plasma
forming fluid is being converted into a high temperature plasma.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention is directed generally to plasma guns and
particularly to an improved means and method for introducing a gas
into a plasma-forming environment.
2. State of the Art
The use of plasma guns for converting a gaseous medium through
electrical energy into heat and thereby achieving a high
temperature, high velocity, gaseous stream suitable for applying a
coating on a substrate is well known (e.g., U.S. Pat. Nos.
3,676,638 and 3,312,566 and British Pat. No. 1,087,173).
In such plasma guns, a coating material is introduced into a high
temperature plasma stream (8,000.degree.F and higher), thermally
liquified and ejected from the gun on the substrate at or near
sonic and supersonic speeds.
The plasma's high temperature is obtained by applying a voltage
sufficient to cause arcing between a pair of spaced-apart
electrodes. In so doing, electrons are released from one of the
electrodes (cathode) and as the electrons gain kinetic energy from
the field, they move at accelerating velocities toward the other
electrode (anode).
When a free electron field has been developed, the atoms and/or
molecules of the plasma forming material (normally a gas), which
has been introduced therein, collide with the free electrons.
During these collisions some of the kinetic energy of the electrons
is transformed and absorbed by the molecules as heat energy. As the
temperature of the gas increases, some of the molecules or atoms
are ionized yielding additional electrons. As ionization continues,
the collisions become more frequent increasing the conversion of
kinetic energy to energies of heat and ionization. Eventually the
gaseous material will take on a characteristic which is normally
referred to as a "high temperature plasma" state.
In order for this high temperature plasma state to be sustained, it
is necessary that a continuous source of electrons be provided and
that a continuous supply of plasma-forming material be made
available. U.S. Pat. No. 2,960,594 identifies these prerequisities
as (1) minimum power requirements (for providing the necessary
electrons), and (2) minimum gas flow (for providing the
prerequisite number of ions).
This patent further states, in effect, that if the power
requirements and/or if the gas flow falls below these minimums the
plasma-forming environment will not be sustained and a "flash back"
condition occurs. Flash backing will normally result in a severe
drop in temperature and loss of the plasma state.
With plasma guns currently available, relatively high power and gas
flow requirements are required to sustain a plasma-producing
environment. This, of course, results in a relatively high cost of
operation. As a result, the use of plasma guns has been limited in
commercial operations. In order for plasma guns to gain broader
acceptance and in order that they may bcome more economically
competitive with other spraying means, it would be highly desirable
if the above minimum requirements could be lowered. In so doing,
the cost of operation would not only be reduced but the life of the
electrodes could also be extended thus reducing the down time and
expense incurred for replacement.
SUMMARY OF THE INVENTION
A reduction in power and flow requirements for operating a plasma
gun has been achieved by the apparatus and methods of this
invention which comprise generally a substantially closed chamber
wherein a first electrode (anode) defines a nozzle outlet from the
chamber and a second electrode (cathode) extends into the chamber
in spaced relationship to the first electrode. A means is provided
for introducing an arc forming electric current across the
electrodes. A plasma forming gas is introduced into the arc area in
a particular manner such that the kinetic energy of the electrons
emanating from the electrodes is effectively transformed into
energies of heat for absorption by the plasma forming gas. In one
embodiment, this is achieved by means of a specially designed gas
ring which is capable of providing a substantially linear gas flow
in combination with a helical or vortical gas flow. As the gas
travels through the nozzle towards the outlet, the axial gas flow
is gradually converted into a helical or vortical gas flow.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a cross-sectional side view of the plasma spraying
device;
FIG. 2 is an exploded cross-sectional side view of the main
elements of the spraying device;
FIG. 3 is an isometric of the brass housing shown in FIG. 1;
FIG. 4 is an isometric of the insulated housing shown in FIG. 1;
and
FIG. 5 is an enlarged partially cut away isometric of the gas
distribution ring wherein the gas flow components emanating
therefrom are illustrated.
DESCRIPTION OF THE PREFERRED EMBODIMENT
As shown in FIGS. 1-4, the plasma spraying device has a handle
housing 10 made from an insulating material such as rubber,
plastic, synthetic resin and the like. A hollow electrical
conductive cathode connector 12 runs longitudinally through the
handle. One end of the cathode connector is adapted with a
connecting means 14 for receiving a water-cooled electrical cable
16. The other end of the cathode connector is adapted with an
electrical conductive bushing 18 for receiving and holding the male
end of a bored water exit assembly 20 which in turn is adapted to
receive and hold the male end of a bored cathode holder 22. An
O-ring 24 is provided to insure a water-tight connection between
the bushing 18 and the water exit assembly 20. Another O-ring 26 is
provided to serve a similar purpose between the water exit assembly
and the cathode holder 22.
A tungsten or thoriated tungsten hollow cathode 30 has a threaded
rear section for screwing (not shown) into the cathode holder. The
front end of the cathode has a conically shaped head 32 which is
circumscribed by a gas distribution ring 34 capable of distributing
a plasma forming gas into the area around the cathode in a
particular manner. The design of the gas distribution ring and its
use shall be subsequently described in greater detail. The water
exit assembly 20, the cathode holder 22, the cathode 30 and the gas
distribution ring 34 are encompassed and held in a fixed operative
position by a bored insulated housing 36 constructed from an
electrically non-conductive material such as Nylon, Teflon, and the
like. A channel 38, traversing the insulated housing 36, is adapted
at one end with a fitting 40 for receiving a plasma inlet line 42.
The other end of the channel opens into an annular gas chamber 44
which is in communication with a plurality of slanted channel
openings 45 and with at least one other opening 46 via an
intermediate groove cut into the outer wall of the gas distribution
ring. A bored disc plate 48 constructed from a refractory material
such as aluminum oxide is mounted to the front face of the
insulated housing 36. The inner circular edge of the bored disc
plate 48 is in close proximity to the channel openings 45 and 46.
The outer edge of the bored disc is adjacent to a plurality of
water carrying passageways 50 bored axially through the insulated
housing 36.
A centrally bored copper anode 54 having a water chamber 56 formed
by an annular groove which is in communication with a plurality of
axially bored water carrying passageways 57 is held to the
insulated housing 36 by an overriding bored anode holder 58. The
copper anode 54 is held in a position such that it is in proximal
spaced relationship to the cathode 30.
The anode holder 58 is provided with a traversing conduit 60. One
end of the conduit is adapted with a fitting 62 for receiving a
water inlet line 64. The other end of the traversing conduit 60 is
in communication with the water chamber 56 of the copper anode 54.
The anode holder also contains a plurality of bored water carrying
passageways 65 for directing cooling water toward outlet 16.
Mounted to the front face of the anode holder 58 is a centrally
bored brass housing 70 having a conduit 72 radially bored therein.
One end of the conduit is adapted with a fitting 74 for receiving
an inlet line 76 for feeding a heat fusible material into a flared
chamber 77 which is in communication with the outlet end 78 of the
gun's nozzle. The outlet end 78 is formed by an open ended tubular
member 79 having a frustrum shaped flared end piece 83 extending
toward the anode holder 58 from a bored end piece 80. The flared
end piece 83 is in spaced relationship with a matching flared end
section 84 formed around the bore of the brass housing 70. The
space between the two flared pieces 83 and 84 forms the flared
chamber 77.
A plurality of axially bored water carrying passageways 86
circumscribe the bore in the brass housing 70. These passageways
are in communication with an annular cavity 88 of the bored end
piece 80. A second set of axially bored water carrying passageways
90, of larger diameter, circumscribe passageways 86 and are also in
communication with the annular cavity 88. Cooling water enters the
annular cavity 88 through passageways 86 and leaves the cavity
through passageways 90. An O-ring 91 insures a seal between the
flared chamber 77 and the water carrying passageways 86 and 88. The
bored end piece 80 is held in sealing engagement against the brass
housing 70 by means of an O-ring 92 and an annular lip 94 extending
outwardly from the bored end piece 80.
A number of threaded bolts 96 extend through a corresponding number
of matched openings positioned around the peripheral edge of the
lip 94, the brass housing 70, the anode holder 58, the insulated
housing 36 and engage a threaded opening in the handle housing 10
for holding these elements in an aligned and fixed position.
Additional O-rings 98 are provided for insuring a sealing
engagement between the above elements near the openings through
which the bolts 96 pass.
As shown in FIG. 5, the gas ring 34 earlier referred to comprises a
ceramic sleeve 100 having an annular groove 102 along one of its
end. A plurality of inwardly slanted conduits 104 extend from the
groove to the interior wall 106 of the ceramic sleeve. The conduits
are characterized in that they all converge (if extended) at a
central focal point at or near the vicinity of the conical head of
the cathode. A tangential opening 108 which is in communication
with the annular groove 102 via an intermediate surface groove 109
is positioned anterior to the exit openings of the slanted conduits
for directing a portion of the gas introduced as a spiraled
component about the gas linearly introduced through the slanted
conduits 104. With this type of gas ring a major portion of the gas
introduced into the area of the cathode possesses a linear
component while a minor portion is introduced tangentially to
provide a spiral or vortical component which in effect
circumscribes the linear component.
As the gas passes through the bore (nozzle) 77 of the anode 54 and
the bore in the brass housing 70, the linear components of the gas
gradually take on a spiraling characteristic until reaching the end
of the central bore where the flow is essentially completely
helical or vortical in nature with little if any of the linear
component remaining.
With the above gas distribution ring for introducing a plasma
forming gas into the plasma gun, a substantially lower minimum gas
flow can be realized along with lower power requirements. This
phenomenon is demonstrated by the following example in which the
operating parameters and the test results are reported in Table 1
which immediately follows the example.
A plasma gun of the type shown in the drawings and hereinabove
described possessed a nozzle having a diameter of about 0.228
inches and a length of about 1.375 inches. Approximately 20 cubic
feet per hour of plasma forming gas was introduced into the gun
through the means provided. The gas introduced comprised a mixture
of 8 cfh nitrogen and 12 cfh argon. An electrical input of 95
amperes and 47 volts was applied to the cathode having a diameter
of about 0.40 inches. A heat fusible material comprising primarily
tungsten carbide and having a particle size of about 25-50 microns
was introduced into the heated plasma at a rate of about 0.05
lbs./min. As the gas and softened heat fusible material exited from
the gun at a velocity approaching the speed of sound, they were
directed against a sheet of aluminum. Upon contact the heat fusible
material solidified forming a thin, evenly distributed coating
across the surface of the aluminum sheet.
TABLE 1
__________________________________________________________________________
Min. Nozzle Nozzle Gun Est. Cath. Dia. Length Flow Temp. Gas Mix.
Dia. Inches Inches c.f.h. F.degree. Amps Volts % N.sub.2 % Ar
Inches
__________________________________________________________________________
.25+ 1.25 19 8500.degree. 60-100+ 47 40 60 0.40 .375 1.25 19
8500.degree. 50 45 40 60 0.40
__________________________________________________________________________
To better understand the specific features of the plasma gun above
described, a more detailed presentation of certain specific
operational and design features is now presented.
OPERATION OF PLASMA GUN
In coating a substrate with a thermally fusible material, a plasma
forming gas is introduced through line 42 into the gas chamber 44
via intermediate conduit 38. The gas passes through the channels
104 and 108 of the gas distribution ring 34 and exits about the
conically shaped cathode head 32. The gas is emitted as a
substantially linear component converging at a point slightly in
front of the cathode head. Concomitantly a spiraled flow component
is also emitted about the substantially linear component.
Generally, the linear component of the gas introduced into the
plasma forming environment will constitute at least 10% of the
total volume of gas introduced.
Preferably the linear component will constitute between about 80
and 90 percent of the total gas volume and the helical or vortical
component will constitute between about 10 and 20 percent of the
total gas volume. As the gas is converted into a plasma and moves
toward the exit end of the nozzle, the linear component will
gradually take on a vortical component. About midway down the
nozzle, the vortical component constitutes between about 30 and 40
percent of the total gas flow and the linear component constitutes
between about 60 and 70 percent of the total gas flow.
A direct current is now applied to the spaced-apart electrodes 30
and 54 causing an arc to develop between them. The gas passing
through the electrical arc is thermally energized by the electrons
released from the cathode transforming the gas into a "high
temperature plasma." After the linear component of the hot plasma
is gradually converted into a substantially helical flow, a finely
divided thermally fusible material is introduced into the flow of
hot plasma through line 76 and into the flared chamber 77 via
intermediate conduit 72. Because of the chamber's flared
characteristics, the heat fusible material is introduced
countercurrent to the flow of hot plasma. The heat fusible material
is thermally liquified as it contacts the hot plasma and is ejected
with the hot plasma gas through the nozzle portion 78 upon a
substrate.
PLASMA GUN COOLING SYSTEM
During operation of the plasma gun, a flow of circulating cooling
water is introduced into the gun via line 64 and into a water
chamber 60 of anode 54. The water flows from the water chamber 60
through a number of water carrying passageways 57 in the anode and
through a series of interconnecting water carrying passageways 65
and 86 in the anode holder 58 and the brass housing 70
respectively. The water finally enters a turnaround water chamber
88 in the guns end piece 80. At this point the direction of water
flow is reversed and enters water carrying passageways 90 in the
brass housing and eventually into the hollow cathode 30 via a
number of interconnecting water carrying passageways 65 and 50
carried by the brass housing 58 and the insulated housing 36
respectively. The water exits through line 16 via water cooled
electrical cables 12 located in the handle housing 10.
ELECTRODES
The cathode preferably has a conical head as shown in the drawings;
however, a rounded or blunt head can also be advantageously
used.
Normally, the cathode's conically shaped head will have an included
angle of between 45.degree. and 60.degree. and a diameter of
between 0.10 inches and 0.125 inches. The length of the cathode can
be varied or adjusted to provide a distance betweeen the two
electrodes which will produce an arc best suited for a particular
use. In instances where a temperature of about 8,000.degree.F is
desired and where the gun is to be utilized for spraying a material
on a substrate, the distance between the two electrodes will
normally be between about 0.015 inches and 0.100 inches.
The second electrode or the anode nozzle preferably has a length of
between 1.125 inches and 1.375 inches and an internal diameter of
between 0.200 inches and 0.250 inches. Normally the anode will be
constructed from an electrical conductive material such as
copper.
POWER PARAMETERS
With electrodes of the type above described and with a gas
distribution ring of this invention, a direct current of between 30
and 200 amperes and a voltage of between 30 and 90 volts are
normally used. The power requirements may vary to a degree
depending on the type and amount of plasma producing gas that is
introduced into the electrode area. For example, a diatomic gas
will normally require lower power requirements than a monotomic
gas. Further, the degree of ionization and the gas temperatures
desired are also factors which must be taken under consideration in
determining the optimum power requirements. In most cases, the most
suitable conditions can be imperically determined for the
particular use intended. In all cases, though, substantially lower
power requirements are required when the gas distribution ring or
if the gas flow characteristics wherein described are employed.
PLASMA FORMING GASES
To achieve operating parameters wherein a minimum gas flow of
around 20 and 30 c.f.h. and an average amperage input of between 50
and 100 amperes are used, a plasma producing gas comprising a
volume ratio of between 2 to 1 and 1 to 1 of monotomic gas to
diatomic gas is preferred. Excellent results have been obtained
wherein a mixture containing 60 percent of argon and 40 percent of
nitrogen have been used. As a general rule, argon is more easily
ionized than nitrogen at relatively low energy levels. Mixtures of
the above two gases will normally require an energy level of
between those required for the individual gases. Certain gas
combinations also appear to be more suitable for achieving a
particular temperature, especially if the temperature is below
10,000.degree.F. For example, if temperatures of under
1,000.degree.F are desired, a mixture of gases comprising 60
percent argon and 40 percent nitrogen is preferred. However, if a
temperature in excess of 10,000.degree.F. is desired, a mixture
comprising 50 percent argon and 50 percent nitrogen can be used to
advantage.
COOLANTS
Generally a coolant such as water will be circulated through the
gun as earlier described. However, other coolants such as glycol,
refrigerants, etc., can also be used. In some cases, circulated air
or other heat absorbing gases may also be used.
Normally the amount of liquids circulated will vary depending on
the degree of cooling desired. In order to maintain optimum
electrode life, it is preferred that the electrodes be maintained
at a low temperature.
Generally, as the power requirements are increased, the volume of
coolant introduced or recirculated is likewise increased assuming
that the other operating parameters remain relatively constant.
SPRAYING HEAT FUSIBLE MATERIALS
Finely divided heat fusible materials are introduced into the
plasma stream and emitted on a substrate in the manner earlier
described.
Generally, though, the distance between the nozzle and the
substrate is about 6 to 8 inches when the gun is being operated at
an amperage of between 50 and 100 amperes. The distance is normally
longer if the heat fusible material has a relatively low melting
point and at a shorter distance if it has a relatively high melting
point. The heat fusible material will melt or be softened upon
contact with the heated plasma and will then be accelerated to
speeds approaching sonic or supersonic speeds.
Most all of the synthetic thermoplastic materials such as
polyethylene, polypropylene, polyamides, polyvinylchloride,
polystyrene or polytetrafloroethylene are particularly suitable for
coating either alone or in combination. Other materials such as
glass, ceramics, resins, cellulose butyrate, and the like may also
be used. The material to be deposited is usually introduced as fine
particulates having a particle size of between -125 mesh and -200
mesh.
Any conventional material may be used as a substrate such as the
metals, woods, plastics, ceramics, glass and the like.
While the invention has been described with reference to specific
embodiments, it should be understood that certain changes may be
made by one skilled in the art and would not thereby depart from
the spirit and scope of this invention which is limited only by the
claims appended hereto.
* * * * *