U.S. patent number 3,850,785 [Application Number 05/388,309] was granted by the patent office on 1974-11-26 for reinforced carbon fabrics.
This patent grant is currently assigned to The United States of America as represented by the Secretary of the Army. Invention is credited to Gilbert N. Arons, Allan J. McQuade.
United States Patent |
3,850,785 |
McQuade , et al. |
November 26, 1974 |
REINFORCED CARBON FABRICS
Abstract
Activated carbon fabrics, having poor textile properties in
terms of tens strength, abrasion resistance and flex performance,
are substantially upgraded by laminating the carbon fabric to at
least one other fabric having significantly better textile
properties. Lamination is effected without substantial loss of
fabric air permeability or excessive increase in weight by using a
hot-melt adhesive fabric or netting as the binding medium. The
invention described herein may be manufactured, used and licensed
by or for the Government for governmental purposes without the
payment to us of any royalty thereon.
Inventors: |
McQuade; Allan J. (Ashland,
MA), Arons; Gilbert N. (Newton Highlands, MA) |
Assignee: |
The United States of America as
represented by the Secretary of the Army (Washington,
DC)
|
Family
ID: |
26887165 |
Appl.
No.: |
05/388,309 |
Filed: |
August 14, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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191557 |
Oct 21, 1971 |
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Current U.S.
Class: |
442/2; 55/DIG.43;
55/527; 156/291; 156/306.6; 442/244; 55/DIG.45; 156/290; 156/295;
428/408; 428/902 |
Current CPC
Class: |
A62D
5/00 (20130101); B32B 17/02 (20130101); D06M
17/00 (20130101); Y10S 428/902 (20130101); B32B
2037/1215 (20130101); B32B 2367/00 (20130101); Y10T
442/102 (20150401); Y10S 55/45 (20130101); B32B
2262/106 (20130101); B32B 2377/00 (20130101); Y10T
442/3512 (20150401); Y10T 428/30 (20150115); Y10S
55/43 (20130101) |
Current International
Class: |
A62D
5/00 (20060101); D06M 17/00 (20060101); B32b
007/14 (); B32b 031/00 () |
Field of
Search: |
;55/514,527
;156/290,295,309 ;117/46CC ;161/85,88,92,146,156 ;264/29 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Van Horn; Charles E.
Assistant Examiner: Dawson; Robert A.
Attorney, Agent or Firm: Stevens, III; Eugene E. Labadini;
Lawrence E. Rainey; Charles C.
Parent Case Text
This is a continuation of application Ser. No. 191,557 filed Oct.
21, 1971 and now abandoned.
Claims
We claim:
1. A reinforced activated-carbon fabric formed by laminating an
activated-carbon fabric constructed of activated-carbon yarns
having a breaking strength of less than 1 gm/denier to at least one
other non-carbon fabric in such a manner as not to poison the
activated-carbon and so as not to substantially reduce the
permeability of the fabric layers wherein the lamination is
accomplished by
a. placing a layer of hot-melt adhesive fabric or netting between
said activated-carbon fabric layer and said non-carbon fabric
layer,
b. subjecting said combined layers to sufficient heat and pressure
for such time as to cause said hot-melt adhesive to fuse and flow,
and
c. removing said source of heat and pressure whereby said fused
adhesive solidifies bonding said fabric layers together to produce
a laminated fabric having substantially the same air permeability
as the original fabric layers.
2. A reinforced activated-carbon fabric wherein said hot-melt
adhesive fabric or netting has a weight of from 0.1 to 3.0
oz/yd.sup.2.
3. A reinforced activated-carbon fabric wherein said bonded fabric
layers have an air permeability of at least 25 ft.sup.3
/min/ft.sup.2.
Description
BACKGROUND OF THE INVENTION
Activated carbon is a material that finds widespread use because of
its unusual ability to adsorb significant quantities of gaseous or
liquid matter. This property is attributable to the extensive
surface area and developed pore structure of the carbon material.
Activated carbon in the form of powder or granules is widely used
for the removal of odors, selected gases and vapors, especially
toxic gases and vapors from the atmosphere, for decoloring liquids
and for solvent recovery. Recent developments have made it possible
to obtain activated carbon as fibers in fabric form. As fabrics,
activated carbon can be used for applications not possible with
powder or granules, e.g., as clothing to provide protection against
toxic liquid, vapor or gaseous agents, as filters or screens in air
systems to eliminate odors and pollution without restricting the
flow of air, etc. A serious drawback, however, exists in connection
with the use of such carbon fabrics, in that such fabrics have
extremely poor textile properties, notably, low tensile strength,
poor abrasion resistance and poor flex performance. Improvement in
the foregoing properties without any substantial impairment of the
sorption or air permeability properties of the carbon fabric would
greatly enhance the suitability of such fabrics for any of the
described uses.
SUMMARY OF THE INVENTION
This invention relates to a reinforced, activated-carbon, fabric
constructed by laminating an activated-carbon fabric having poor
textile properties to at least one other fabric having good textile
properties and bonding said fabrics together by means of a hot-melt
adhesive fabric or netting. The resulting laminate composite has
textile properties that far exceeds those of the carbon fabric
alone and is suitable for most textile applications. The use of
hot-melt adhesive fabric or netting rather than conventional
adhesive coatings to effect bonding results in an inherently more
air permeable fabric composite than would otherwise be obtained,
does not excessively increase the weight or stiffness of the fabric
composite, and does not significantly reduce the sorptive
properties of the activated carbon by solvent poisoning.
DETAILED DESCRIPTION
The objective of this invention, to prepare an activated-carbon
fabric having textile properties suitable for typical textile
applications, is achieved by lamination of an activated-carbon
fabric to one or more non-carbon fabrics having significantly
better textile properties. Such laminate composite is formed in a
manner which does not result in any substantial loss of air
permeability characteristics or sorptive capacity. Conventional
adhesives require solvents and solvents will poison the activated
carbon material.
Carbon fabrics are known and commercially available and may vary
from weakly activated to highly activated. The activity of carbon
is a function of the surface area and pore development of the
carbon material. The more highly active carbon materials adsorb
greater quantities of materials and depending on pore size and
development can selectively adsorb certain gases, vapors or
liquids. For purposes of this invention, it is necessary that the
activated carbon have a surface area of at least 100m.sup.2 /g and
have micropores with an effective diameter of less than 30
A.degree. for gas and vapor sorption and preferably a transitional
pore structure with an effective diameter ranging from 30 A.degree.
up to 2,000-4,000 A.degree. for liquid sorption. While activated
carbon materials are produced by techniques well known in the art
and constitute no part of this invention, U.S. Pat. Nos. 3,253,323
and 3,484,183 may be referred to as illustrating or describing
techniques for the fabrication of certain carbon fabrics.
Activated carbon fabrics are known to have relatively poor textile
properties which properties further decline with increase in
activation. The poor or weak textile properties of activated carbon
fabrics are typified by low breaking (tensile) strength, poor
abrasion resistance, and poor flexing properties. Carbon yarns, for
example, normally have a breaking strength of less than 1
gm/denier. The expression "carbon fabric," as used herein, refers
to fabrics whose yarns are composed of fibers having a carbon
content of from 50% up to 99+%. Carbon fabrics can be produced by
pyrolysis of any fabric made from non-melting organic fibers.
Activation is usually accomplished with a heated oxidizing gas,
e.g., CO.sub.2, H.sub.2 O, or O.sub.2. Because of the weakness of
the carbon yarns, it is usual and preferred that the finished
fabric be pyrolyzed to the carbon derivative and then activated,
although it is possible to form fabrics from activated carbon
yarns. The expression "fabric," as used herein, refers to woven,
knitted or felt materials.
The fabrics which are laminated to the activated-carbon fabrics to
improve the textile properties of the latter are light in weight
and woven or knitted from common, commercial, yarns (containing
man-made or natural fibers) having a breaking strength in the range
of 2 to 5 gm/denier. These fabrics, which may be referred to as
"non-carbon fabrics," i.e., they are composed of yarns containing
less than 50% carbon, include such materials as wool, silk, cotton,
viscose, acetate, acrylic, modacrylic, nylon, Nomex, a product of
E. I. DuPont de Nemours and Co., and other special polyamides,
polyester and blends of the same. Nylon tricot, nylon-cotton
(50/50), poplin or sateen, Nomex muslin, Nomex twill and acetate
taffeta are but some examples of suitable lightweight fabrics.
Lamination of the activated carbon fabric to the non-carbon fabric
is accomplished by use of a hot-melt adhesive fabric or netting as
the bonding agent. Such hot-melt adhesives are well-known and
include thermoplastic materials, such as polyamides, polyesters and
polyolefins that melt at temperatures that range from 300.degree.F.
to 400.degree.F. The adhesive fabric or netting is an open type
structure and weighs from 0.1 oz/yd.sup.2 to 3.0 oz/yd.sup.2.
Unlike conventional adhesives, hot-melt adhesives do not require
solvents to effect bonding. The temperture applied to the fabric
layers for the lamination step to activate the adhesive will vary
with the adhesive material employed but will oridinarily range from
325.degree.F. to 375.degree.F. Pressures applied will ordinarily
range from 2 to 20 p.s.i. and the dwell time is such as to permit
the adhesive to fuse and wet the fabric layers. The open fabric or
net nature of the adhesive means that more of the surface area of
the laminated composite will be free of adhesive material. As a
consequence, the air permeability of the fabric assembly is not
affected to any significant degree.
EXAMPLE I
A weakly activated carbon fabric, Pluton B-1, 6 oz/yd.sup.2, a
product of 3M Co., having a saturated carbon tetrachloride vapor
sorption capacity of 15% by weight, a surface area of 250m.sup.2
/g, and a yarn breaking strength in the warp direction of
approximately 0.4 gm/denier and in the filling direction of
approximately 0.2 gm/denier is reinforced with nylon and acetate
fabrics. Nine inch squares of the different textile fabrics are cut
and assembled in the following laminate sequence: Acetate taffeta
fabric (2.56 oz/yd.sup.2)/adhesive fabric/carbon fabric/adhesive
fabric/nylon tricot fabric (0.9 oz/yd.sup.2). The adhesive fabric
is Thermogrip 5030A, polyester-type adhesive, having a weight of
1.23 oz/yd.sup.2, a product of USM Chemical Company. The fabric
assembly is laminated at 370.degree.F., at 4 p.s.i. for 20 seconds
in a commercial press. Upon removal from the press, the laminate is
allowed to cool. The laminate has good air permeability values
ranging from 26 to 41 cubic feet per minute per sq. ft. when tested
under Method 5450 of Federal Test Method Standard 191. The laminate
also had good flexible properties and suffers no weight loss or
significant visible damage when flex tested 1,260 cycles as
specified in Federal Test Method Standard 191, Method 5320. The
laminate layers are securely bonded together and the outer fabric
layers protected the inner carbon layer from abrasive
influences.
EXAMPLE II
The carbon fabric of Example I is laminated between a nylon-cotton
poplin (50-50) fabric (5 oz/yd.sup.2), and a nylon tricot (2.0
oz/yd.sup.2). The adhesive fabric or netting employed between the
fabric layers is selected from one of the following:
1. A polyester type, Thermogrip 5030A, a product of USM Corp.,
weighing 1.23 oz/yd.sup.2.
2. A polyamide type, Thermogrip LM 5230A, a product of USM Corp.,
weighing 1.15 oz/yd.sup.2.
3. A polyolefin type, Delnet X230, a product of Hercules, Inc.,
weighing 0.53 oz/yd.sup.2.
The laminates are inserted in a commercial press and bonded at 4
p.s.i. for 16 seconds at temperatures which range from
325.degree.F. to 375.degree.F. and are allowed to cool before
testing. The laminates are tested as follows:
1. Air permeability in accordance with Method 5450 of Federal Test
Method Standard 191.
2. Stiffness in accordance with Method 5205 of Federal Test Method
Standard 191 using the standard 60.degree. angle of bend, and with
the reading in lbs.
3. Peel test of each fabric laminated to the carbon fabric using 1
inch wide by 4 inch long samples of an Instron Tensile Tester, with
reading in lbs., using 5 lbs. full scale and a separation rate of 5
in./min.
The results of the foregoing tests for each of the laminate samples
are set forth in TABLE I.
TABLE I
__________________________________________________________________________
Thermogrip Thermogrip Delnet 5030A LM 5230A X230
__________________________________________________________________________
Adhesive -- Fabric or Netting Air Permeability 25.3-31.5 23.4-29.0
26.0-32.0 (ft.sup.3 /min./ft.sup.2) Stiffness (lbs) Warp 0.67-0.149
0.132-0.202 0.08-0.115 Fill 0.072-0.81 0.081-0.126 0.052-0.067 Peel
(lbs) Nylon tricot Warp 1.7-3.10 1.47-2.56 1.29-1.64 Fill 1.40-2.1
0.60-4.1 0.89-1.03 Nylon-Cotton Poplin Warp 2.3-2.9 1.15-1.80
0.78-1.82 Fill 2.5-3.4 1.48-2.8 0.66-1.02
__________________________________________________________________________
EXAMPLE III
A moderately activated carbon fabric, Pluton H-1, 4 oz/yd.sup.2, a
product of 3M Company, having a saturated carbon tetrachloride
vapor sorption capacity of 30% by weight, a surface area of 450
m.sup.2 /g is reinforced with nylon and a selection of three other
fabrics. 24 inch by 20 inch rectangles of different textile fabrics
are cut and assembled in the following laminate sequence: Any one
of three fabrics, (1) nylon-cotton (50/50) twill, (5 oz/yd.sup.2),
or (2) Nomex muslin, (3.1 oz/yd.sup.2) or (3) Nomex twill, (4.5
oz/yd.sup.2)/ together with adhesive fabric/carbon fabric/adhesive
fabric/nylon tricot fabric (2 oz/yd.sup.2). The adhesive fabric is
Thermogrip 5030A as in EXAMPLE I. The fabric assembly is laminated
at 350.degree.F. at 41/2 p.s.i. for 20 seconds on a commercial
press and allowed to cool. The laminates have the following air
permeabilities when tested in accordance with Method 5450 of
Federal Test Method Standard 191:
Fabric Air Permeability (cu ft.sup.3 /min/ft.sup.2)
______________________________________ Nylon-cotton (50/50) twill,
31.6 5.0 oz/yd.sup.2 Nomex muslin, 55.5 3.1 oz/yd.sup.2 Nomex
twill, 4.5 oz/yd.sup.2 66.9
______________________________________
The technique described herein using a hot-melt adhesive fabric or
netting to laminate lightweight, strong fabrics to weak carbon
fabrics makes the use of such carbon fabrics possible for
conventional textile applications. Adhesion of the reinforcing
fabric to the carbon fabric is accomplished without impairment of
the activated carbon system and without any significant reduction
in the air permeability of the laminate system.
The invention described in detail in the foregoing specification is
susceptible to changes and modifications as may occur to persons
skilled in the art without departing from the principle and spirit
thereof. The terminology used is for purpose of description and not
limitation, the scope of the invention being defined in the
claims.
* * * * *