U.S. patent number 3,849,236 [Application Number 05/368,493] was granted by the patent office on 1974-11-19 for flock-texturing method and product.
This patent grant is currently assigned to Pervel Industries, Inc.. Invention is credited to Richard P. Bourdon.
United States Patent |
3,849,236 |
Bourdon |
November 19, 1974 |
FLOCK-TEXTURING METHOD AND PRODUCT
Abstract
The invention contemplates a method and product whereby, for
certain densities of flock-finish on fabric, the fabric can have a
texture, appearance and hand closely akin to and resembling that of
natural-leather chamois or suede. The technique relies upon soaking
a suitable flock-finished fabric with a dilute solution of
compatible adhesive, wringing out and drying the soaked fabric, and
then curing the adhesive.
Inventors: |
Bourdon; Richard P. (Claremont,
NH) |
Assignee: |
Pervel Industries, Inc.
(Plainfield, CT)
|
Family
ID: |
23451464 |
Appl.
No.: |
05/368,493 |
Filed: |
June 11, 1973 |
Current U.S.
Class: |
428/90; 156/305;
427/369; 156/72; 427/206 |
Current CPC
Class: |
D04H
11/00 (20130101); Y10T 428/23943 (20150401) |
Current International
Class: |
D04H
11/00 (20060101); D03d 027/00 () |
Field of
Search: |
;161/64,88
;156/72,305 |
References Cited
[Referenced By]
U.S. Patent Documents
|
|
|
3547749 |
December 1970 |
White et al. |
3565742 |
February 1971 |
Stephens et al. |
3772132 |
November 1973 |
Dullin, Jr. |
|
Primary Examiner: Van Balen; William J.
Attorney, Agent or Firm: Sandoe, Hopgood and Calimafde
Claims
What is claimed is:
1. The method of treating a flock-finished fabric wherein the flock
consists of synthetic fibers of uniform denier and length bonded at
corresponding ends to at least one side of a fabric base and
uniformly distributed over the base and oriented normal to the
base, the flock density being less than maximum and at least such
that the average fiber-to-fiber spacing is substantially less than
projecting flock-fiber length, which method comprises soaking the
flock-finished fabric with a dilute aqueous solution of a
heat-curable adhesive to which the flock is compatible, randomly
folding the soaked fabric, wringing from the folded fabric a
substantial fraction of the fabric-adhered solution, spreading the
wrung-out fabric, drying the spread and wrung-out fabric, and then
heating the dried fabric to a temperature and for a period
sufficient to cure the adhesive.
2. The method of claim 1, in which the volume of wrung-out solution
is approximately one half that which is fabric-adhered after
removal from the soaking solution.
3. The method of claim 1, in which the flock is viscose rayon and
the adhesive is an acrylic-resin adhesive.
4. The method of claim 1, in which the soaking solution includes a
fabric delustrant.
5. The method of claim 4, in which the delustrant includes titanium
dioxide.
6. The method of claim 1, in which the soaking solution includes an
an-ionic softening agent.
7. The method of claim 3, in which the proportion by weight of
adhesive in the solution is in the order of 2 percent.
8. The method of claim 4, in which the proportion by weight of
fabric delustrant is in the order of 5 percent.
9. The method of claim 6, in which the proportion by weight of
an-ionic softening agent in the solution is in the order of 5
percent.
10. As an article of manufacture, a flock-finished fabric
comprising a woven-fabric sheet having front and back faces, an
adhesive layer covering one of said faces, precision-cut flock of
synthetic fiber of predetermined length and denier rooted at one
end to said adhesive layer and projecting normal thereto, the flock
density being less than that to produce a full coat of said one
face and at least such that the average fiber spacing is
substantially less than the projecting length of individual flock
fibers, random groups of adjacent flock fibers being adhesively
bonded to each other along their adjacent edges in randomly
distributed bent-over alignments wherein the orientation of bonded
adjacent flock fibers is angularly offset from the local normal to
said one face.
11. The article of claim 10, in which the average fiber spacing is
in the order of magnitude of the flock-fiber diameter.
12. The article of claim 10, in which the flock is viscose
rayon.
13. The article of claim 12, in which the adhesive layer consists
essentially of an acrylic adhesive.
14. The article of claim 13, in which the bonding adhesive consists
essentially of an acrylic component.
15. The article of claim 10, in which the woven fabric is cotton
drill.
16. The article of claim 10, in which the other of said faces has a
covering layer of adhesive, further precision-cut flock of said
synthetic fiber of predetermined length and denier rooted at one
end to the adhesive layer of said other face and projecting normal
thereto, the density of said further flock being less than that to
produce a full coat of said other face and at least such that the
average fiber spacing is substantially less than the projecting
length of individual flock fibers on said other face, random groups
of adjacent flock fibers on said other face adhesively bonded to
each other along their adjacent edges in randomly distributed
bent-over alignments wherein the orientation of bonded adjacent
flock fibers is angularly offset from the local normal to said
other face.
17. The article of claim 16, in which flock length on opposite
faces is the same.
18. The article of claim 16, in which flock length on one face is
greater than that at the other face.
19. The article of claim 16, in which denier of the flock on both
faces of said fabric is the same.
20. The article of claim 16, in which denier of the flock on one
face of said fabric is greater than that on the other face of said
fabric.
21. The article of claim 16, in which flock density on one face of
said fabric is substantially the same as on the other face of said
fabric.
22. The article of claim 16, in which flock density is greater on
one face of said fabric than on the other face.
23. The method of treating a flock-finished fabric wherein the
flock consists of synthetic fibers of uniform denier and length
bonded at single corresponding ends to at least one side of a
fabric base and uniformly distributed over the base and oriented
normal to the base, the flock density being less than maximum and
at least such that the average fiber-to-fiber spacing is
substantially less than projecting flock-fiber length, which method
comprises soaking the flock-finished fabric with a dilute solution
of a heat-curable adhesive to which the flock is compatible,
extracting from the folded fabric a substantial fraction of the
fabric-adhered solution by compacing the soaked fabric, spreading
out the compacted fabric, drying the spread fabric, and then
heating the dried fabric to a temperature and for a period
sufficient to cure the adhesive.
24. The method of claim 23, in which the fabric is flock-finished
on both sides, the heat-curable adhesive being selected for
compatability with the synthetic fibers of the flocks on both the
respective sides of the fabric.
Description
The invention relates to a texturized-flock fabric and to the
method of making the same, all in the specific context of
precision-cut flock of synthetic fiber.
It is an object of the invention to provide a novel
flock-texturizing method and product of the character
indicated.
A specific object is to produce an artificial chamois or suede
fabric, characterised by hand and appearance closely akin to that
of natural leather.
Another specific object is to produce such a synthetic chamois or
suede, using existing materials and equipment.
A still further specific object is to produce double-faced
synthetic sueded fabric wherein texturizing patterns correspond on
both faces of the fabric.
Another specific object is to achieve the above objects with
different texture but corresponding texture patterns on the
respective faces of the fabric.
Other objects and various further features of novelty and invention
will be pointed out or will occur to those skilled in the art, from
a reading of the following specification in conjunction with the
accompanying drawings. In said drawings, which show, for
illustrative purposes only, preferred forms and methods of the
invention:
FIG. 1 is a simplified sectional view through a flock-coated
fabric, typifying its condition in readiness for performing the
method of the invention;
FIG. 2 is a simplified diagram of steps in the method of the
invention;
FIG. 3 is a perspective view illustrating an individual bent flock
fiber, greatly enlarged, to permit identification of various
degrees of bend;
FIG. 4 is a succession of four like perspective views of single
fibers, bent to the respective extents identified at sections
a-b-c- d in FIG. 3;
FIG. 5 is a corresponding succession of sectional views taken at
the respective sections d-b-c- d of FIG. 3;
FIG. 6 is a simplified enlarged fragmentary sectional view through
a fabric texturized in accordance with the invention; and
FIG. 7 is a view similar to FIG. 6, on a lesser scale, to
illustrate the invention in application to a fabric that is
flock-finished on both sides.
The invention utilizes flock-finished fabric wherein precision-cut
synthetic fibers of uniform denier and length are bonded at one end
to a woven fabric base, such as a piece of cotton drill 10. A first
set of such fibers 11 is shown distributed over and bonded to one
side or face of the fabric 10, being rooted in an adhesive coat 12
on said side; a second set of such fibers 13 is shown distributed
over and bonded to the other side or face of the fabric, being
rooted in an adhesive coat 14 on said other side. The flock fibers
11 are of the same material, denier and precision-cut length, and
are distributed over the fabric with substantial uniformity, at
less than maximum density, meaning that space exists between
adjacent fibers; preferably, such space S.sub.1 is very
substantially less than the fiber length L.sub.1 which projects
free of its root to the adhesive layer 11 and is in the order of
magnitude of the fiber diameter D.sub.1 ; generally, the rooted
portion is in the range of 15 to 30 percent of the fiber length
L.sub.1. A similar relationship exists for the flock fibers 13 on
the other side of the fabric, as to the spacing S.sub.2, diameter
D.sub.2 and free length L.sub.2 of such fibers 13. It will be
understood that fibers 11-13 may be formed and spaced and projected
in precisely the same manner on both sides of the fabric, or the
quantities S, D and L may be selected for different values on
opposite sides of the fabric, depending upon appearance effects
desired, as will later be clear.
In accordance with the method of the invention, flock-finished
fabric as described in connection with FIG. 1 is subjected to
processing in a succession of steps, in one embodiment of which
FIG. 2 may be considered illustrative. First, such fabric is
subjected to soaking in a dilute solution of a curable adhesive
which is compatible with the flock-fiber material and preferably
also with the existing adhesive layer 12 (14), thus coating all
flock fibers 11-13 with adhesive. The material is then crumpled,
crushed, compacted, wrung or otherwise folded on itself, preferably
at random and therefore without any particular pattern. Such
compaction is carried to the extent of extracting approximately one
half the soaking solution which is carried with the fabric upon its
removal from the soaking bath. It is then dried, as by tumbling in
a rotating drier, but preferably by spreading out the fabric and
allowing it to dry, without use of an iron or other flattening
means. When fully dried, the fabric is subjected to a heat cycle
appropriate to the curing of the particular adhesive, so that
adjacent flock fibers which may have been adhesively "tacked" to
each other in the crushing step will become permanently bonded in
the orientation in which they were adhesively "tacked."
I have yet to develop a completely satisfying explanation of the
actual mechanics of my process, but FIGS. 3 to 7 are presented to
impliment an approach to understanding. FIG. 3 serves to illustrate
a single length or partial length of a flock fiber, for different
degrees of bend of its central axis 20. In FIG. 3, section a--a is
taken at the outer surface of the adhesive layer 12 in which the
fiber is rooted and from which it projects in a direction normal to
the local surface region of layer 12. The bend beyond section a--a
progresses to a point at section b--b where axis 20 is inclined
30.degree. from the normal, thence to section c--c where axis 20 is
inclined 45.degree. from the normal, thence to section d--d where
axis 20 is inclined 60.degree. from the normal, and so on, as far
as it is desired to carry the analysis.
Each of the sections a--a, b--b, c--c, d--d, is taken in a plane
parallel to the local fabric 10 or adhesive 12 surface orientation,
the respective sections being displayed in FIGS. 5 a-b-c-d. From
these sections, it can be seen that what started as circular
becomes elliptical, with growth only in the major axis; for
example, for the 60.degree. bend situation depicted for section
d--d, the major axis is twice the fiber diameter D. FIG. 4 depicts
at a-b-c-d the appearance of individual fibers if frozen or bonded
at the respective degrees of bend represented by the different
sections taken in FIG. 3; in all cases, the fiber length L.sub.b,
L.sub.c, L.sub.d which projects beyond the bend is straight and is
oriented at the particular indicated angle of bend.
FIG. 6 illustrates how adjacent bent fibers 21-22-23-24 of diameter
D and spacing S come to be bonded to each other, by reason of
adhesive "tacking" along adjacent surface regions of the
straight-projecting outer ends, such regions being identified
25-26-27. Such bonds become "tacked" when the soaked fabric is
wrung, and the "tacking" becomes permanent upon adhesive cure.
Also, upon cure, the remaining film of adhesive which may not have
been involved in such "tacking" becomes a stiffening shell around
the individual fibers, particularly upon curing, thus tending
further to retain the particular set of the bend for the tacked
adjacent fibers 21-22-23-24. It will be appreciated that for the
fiber alignment shown in FIG. 6, the bend to achieve "tacking" at
25-26-27 is approximately 45.degree., by reason of the spacing S
being approximately 70 percent of the fiber diameter D.
For section alignments other than that depicted in FIG. 6, the
spacing S may bear a different relation to the diameter D, i.e.,
other than 70 percent. For example, in certain areas of the fabric
the spacing S will substantially equal D, in which case the fibers
thus arrayed are susceptible to "tacked" bending at 60.degree.; and
for still other areas and alignments, the spacing S may be still
other fractions of the diameter D, with different "tacked"
orientations determined thereby.
FIG. 7 illustrates that for fibers 11 (on one fabric side) of
different denier or spacing than those 13 on the opposite side,
there will be different angles at which "tacking" interference
occurs, when the fabric is subjected to wringing.
The foregoing explanation is intended to show how the various
regions of the flock-finished fabric may be caused to retain the
clustering of locally tacked bent fibers, occasioned by wringing
the wetted fabric. After drying and curing, the fabric surface has
a unique texture which, in certain cases can resemble
natural-leather chamois or suede as to hand and appearance. In a
specific example, the fabric of FIG. 1 was a piece of cotton drill,
coated at 12 (14) with a water-base acrylic adhesive to which
viscose-rayon flock 11 (13) had been applied. The flock 11 was 1
denier, precision-cut to 0.030-inch length, imbedded to the extent
of approximately 25 percent of its length in the adhesive layer 12,
and applied to the density achieved by 1.5 ounces per square yard
on a given side of the fabric; on the other side, the flock 13 is
of the same or a different denier, within the preferred range 0.5
to 2.0, depending upon the desired sameness difference in
appearance.
For flock-finished fabric as thus described, I use an acqueous
soaking solution in which adhesive, fabric delustrant and an
an-ionic softening agent are present in dilute proportions.
Specifically, an acqueous solution producing highly satisfactory
results, consists essentially of the following:
a. 2 percent acrylic-resin adhesive, for compatibility with the
viscose-rayon flock.
b. 5 percent fabric delustrant, such as titanium dioxide; being a
commercially available product such for example as that known as
RADUL-S*, the same being selected for light or dark coloring
depending upon the dye of the flock.
c. 5 percent an-ionic softening agent or agents, being preferably
the same as used in initial preparation of the flock-finished
fabric (FIG. 1).
d. 88 percent water.
Generally, I prefer that the solution should be warm, for example
at 160.degree.F., and soaking which proceeds as much as ten minutes
has produced excellent results. For a fabric treated in accordance
with the invention, and using the above soaking solution, about 5
percent of the initial weight of the solution ingredients remain as
part of the cured ultimately texturized product. Also, for fabric
that has been soaked in the indicated solution, curing of the wrung
and bone-dry fabric requires curing temperatures in the range of
300.degree. to 400.degree. Fahrenheit, the exposure time being in
inverse relation to temperature; for example, about 3 minutes at
300.degree.F., or 2 minutes at 325.degree.F.
In another satisfactory soaking solution, the proportions and
ingredients were even more dilute:
0.8% adhesive 0.8% delustrant 0.4% softener 98% water
The described process and article are found to achieve all stated
objects, the product exhibiting a soft chamois-like hand, for the
case of 1-denier viscose-rayon flock applied in the indicated
density. The thus-texturized material exhibits the luxury-look of
suede and exhibits exceptionally long wear, particularly at cuff
and other garment regions of great abuse; such wear, hand and
texture are retained in spite of machine-laundering with water and
conventional household soaps or detergents. Such wear
characteristics also apply for other texture configurations which
result from substantial departures of flock proportions. For
example, 1.5-denier viscose-rayon flock, cut to 0.055-inch length,
and otherwise applied and treated as described, will produce a
texturized fine-grain or small-scale "wet-dog" or "shag-rug"
appearance, with the same exceptional wearing characteristics.
While the invention has been described in detail for the preferred
forms and steps indicated, it will be understood that modifications
may be made without departure from the invention.
* * * * *