U.S. patent number 3,844,920 [Application Number 05/417,724] was granted by the patent office on 1974-10-29 for air fuel ratio sensor.
This patent grant is currently assigned to General Motors Corporation. Invention is credited to Richard R. Burgett, Bruce W. Holleboom.
United States Patent |
3,844,920 |
Burgett , et al. |
October 29, 1974 |
AIR FUEL RATIO SENSOR
Abstract
This invention relates to a sensor that can be used in an
exhaust system for sensing the relative presence of oxygen in the
exhaust stream. The sensor includes a hollow zirconia element that
is conical in shape, and is closed at one end with the zirconia
element having platinum electrodes on the inside and outside
surfaces. A mounting device that is constructed of easily assembled
parts supports the zirconia element. The sensor is constructed and
adapted to be mounted in the automobile exhaust stream so as to
expose the outside of the zirconia element to the exhaust stream
and the inside to atmosphere. A shield that protects the outside of
the zirconia element is attached to the mounting device to prevent
erosion of the electrode coating. Because of the diverse thermal
expansion rates of the components that make up the sensor, a mica
insulator is included as an essential element in the assembly to
maintain a tight seal between the different component parts and
assure electrical continuity.
Inventors: |
Burgett; Richard R. (Grand
Blanc, MI), Holleboom; Bruce W. (Grand Blanc, MI) |
Assignee: |
General Motors Corporation
(Detroit, MI)
|
Family
ID: |
23655165 |
Appl.
No.: |
05/417,724 |
Filed: |
November 21, 1973 |
Current U.S.
Class: |
204/428; 60/285;
60/276; 60/289 |
Current CPC
Class: |
G01N
27/4077 (20130101) |
Current International
Class: |
G01N
27/26 (20060101); F02M 7/00 (20060101); F01N
3/00 (20060101); G01n 027/46 (); F02m 007/00 () |
Field of
Search: |
;60/276,285,289
;123/119R,119E ;204/1T,195S |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Tung; T.
Attorney, Agent or Firm: Taucher; Peter A.
Claims
1. An exhaust gas sensor for measuring the relative presence of
oxygen in an exhaust system comprising: a hollow metal shell having
a shoulder therein, a first metal gasket on said shoulder, a
conically shaped hollow zirconia element positioned within said
hollow metal shell on said gasket having one end closed and thin
walls tapering from the thinnest section that begins at the closed
end and terminates in a thicker section at the opposite end, which
end has an enlarged diameter that forms a top shoulder and a bottom
shoulder, said zirconia element having a platinum coating on the
inside and outside surfaces including the top and bottom shoulders
to form inner and outer electrodes on said zirconia element with
the enlarged diameter portion between the top and bottom shoulders
being uncoated, said bottom shoulder of said zirconia element being
in contact with said first metal gasket to form a first electrical
contact means between said outer shell and said outer electrode, a
second metal gasket on the top shoulder of said zirconia element
that provides electrical contact with the inner electrode on said
zirconia element and a metal body member placed thereon forming a
second contact means with a terminal on said body member, said
outer metal shell including clamping means to retain said zirconia
body, said gaskets and said body member in a gas tight
relationship, and mica means between said body member and clamping
means to compensate for the different expansion and contraction
rates of the different components assembled in gas tight
relationship to maintain such relationship through
2. An exhaust gas sensor for measuring the relative presence of
oxygen in an exhaust system comprising: a hollow metal shell having
a shoulder formed on the inner surface thereof intermediate its
ends and being adapted to be mounted in an exhaust gas conduit, a
first metal gasket on said shoulder, a conically shaped hollow
zirconia element positioned within said hollow metal shell and
having its small diameter end closed and adapted to be exposed to
the exhaust gas, the large diameter open end of said zirconia
element being joined with an enlarged diameter portion on the outer
surface thereof to form a top shoulder and a bottom shoulder, a
platinum coating provided on the inside and outside surfaces of
said zirconia element including the top and bottom shoulders to
form inner and outer electrodes thereon, the surface of said
enlarged diameter portion between said shoulders being uncoated,
the bottom shoulder of said zirconia element being positioned in
contact with said first metal gasket to complete an electrical path
between said metal shell and said outer electrode, a second metal
gasket on the top shoulder of said zirconia element to complete an
electrical path between the inner electrode and a metal body member
positioned thereon, said body member having an electrical terminal
provided thereon, the open end of said zirconia element being
positioned within the end of said metal shell, clamping means
provided on the end of said shell to retain said zirconia element
in gas tight relationship with said shell, mica means between said
metal body member and said clamping means to compensate for the
different expansion and contraction rates of the different
components assembled in gas tight relationship within said shell
and thus seal exhaust gas from the inner electrode, and a shield
provided on the end of said shell and about the small diameter end
of said zirconia element to protect the outer electrode
3. An exhaust gas sensor for measuring the relative presence of
oxygen in an exhaust system comprising: a hollow metal shell having
a shoulder formed on the inner surface thereof intermediate its
ends and being adapted to be mounted in an exhaust gas conduit, a
first metal gasket on said shoulder, a conically shaped hollow
zirconia element positioned within said hollow metal shell and
having its small diameter end closed and adapted to be exposed to
the exhaust gas, the large diameter open end of said zirconia
element being joined with an enlarged diameter portion on the outer
surface to form a top shoulder and a bottom shoulder, a platinum
coating provided on the inside and outside surfaces of said
zirconia element including the top and bottom shoulders to form
inner and outer electrodes thereon, the surface of said enlarged
diameter portion between said shoulders being uncoated, the bottom
shoulder of said zirconia element being positioned in contact with
said first metal gasket to complete an electrical path between said
metal shell and said outer electrode, a second metal gasket on the
top shoulder of said zirconia element to complete an electrical
path between the inner electrode and a metal body member positioned
thereon, said body member having an electrical terminal provided
thereon, the open end of said zirconia element being positioned on
the shoulder formed on the inner surface of said metal shell to
thereby position the top shoulder within the end of said metal
shell below the end thereof, mica means positioned on a shoulder on
said metal body member to compensate for the different expansion
and contraction rates of the different components assembled within
said shell, a nut threadably attached to said metal shell that is
in contact with the mica means to retain said zirconia element in
gas tight relationship with said shell and thus prevent exhaust gas
from reaching the inner electrode, and a shield provided on the end
of said shell that encircles the small diameter end of said
zirconia element to
4. An exhaust gas sensor for measuring the relative presence of
oxygen in an exhaust system comprising: a hollow metal shell having
a shoulder formed on the inner surface thereof intermediate its
ends and being adapted to be mounted in an exhaust gas conduit, a
first metal gasket on said shoulder, a conically shaped hollow
zirconia element positioned within said hollow metal shell and
having its small diameter end closed and adapted to be exposed to
the exhaust gas, the large diameter open end of said zirconia
element being joined with an enlarged diameter portion on the outer
surface to form a top shoulder and a bottom shoulder, a platinum
coating provided on the inside and outside surfaces of said
zirconia element including the top and bottom shoulders to form
inner and outer electrodes thereon, the surface of said enlarged
diameter portion between said shoulders being uncoated, the bottom
shoulder of said zirconia element being positioned in contact with
said first metal gasket to complete an electrical path between said
metal shell and said outer electrode, a second metal gasket on the
top shoulder of said zirconia element to complete an electrical
path between the inner electrode and a metal body member positioned
thereon, said body member having an electrical terminal provided
thereon, the open end of said zirconia element being positioned
within the end of said metal shell, mica means positioned on a
shoulder on said metal body member to compensate for the different
expansion and contraction rates of the different components
assembled within said shell, a spacer means in contact with the
mica means and held in such position by said metal shell to retain
said zirconia element in gas tight relationship with said shell and
thus prevent exhaust gas from reaching the inner electrode, and a
shield provided on the end of said shell that encircles the small
diameter end of said zirconia element to protect the outer
electrode from the direct impact of the exhaust gas.
5. An exhaust gas sensor as set forth in claim 4, wherein said
spacer means
6. An exhaust gas sensor as set forth in claim 4, wherein said
spacer means is a metal nut that is spaced from said body member
and is attached to said outer shell.
Description
A high temperature zirconia element of the electrolyte type has
been used as a sensor of unburned constituents in furnace stack
gases, and is described in Hickman U.S. Pat. No. 3,347,767 Device
for Monitoring Oxygen content of Gases, dated Oct. 17, 1967. A
similar element has also been used as an automobile exhaust gas
sensor, such a sensor being shown and described in Eddy U.S. Pat.
No. 3,616,274 Method and Apparatus for Monitoring Exhaust Gas,
dated Oct. 26, 1971.
In the general operation of such sensors, air passes or flows into
the center of the zirconia element and when the zirconia element is
activated by the heat of the exhaust gases passing around it,
oxygen ions conduct through the element from atmosphere to the
outer electrode, the overall effect being to create a simple
electrochemical cell which develops a potential difference between
the two electrodes. The cell output voltage indicates the partial
pressure of oxygen at the surface exposed to the exhaust gas. In
use in an automobile, as the air-fuel ratio becomes leaner, the
oxygen concentrate in the exhaust gas increases, and the ratio of
partial pressures between the outside and inside of the cell
approaches unity whereupon the output voltage drops to near zero.
When the air-fuel ratio becomes richer, oxidizable gases such as
carbon monoxide and hydrogen exist. With such conditions, it is
convenient to think of the sensor as a miniature electrochemical
fuel cell in which these gases become a fuel source for the cell.
At the exhaust side of the sensor the platinum electrode
catalytically enhances chemical oxidation reaction which in turn
depletes the concentration of oxygen at that surface. A low surface
concentration of oxygen results and the sensor voltage rises to
generate an EMF signal logarithmically proportional to the relative
concentrations of combustible gases in the exhaust. This signal is
used in combination with other components to adjust and maintain
desired engine air fuel mixtures.
Prior art devices, constructed similar to that of the present
invention and used in automobile exhaust systems generally include
a mounting means to hold the zirconia element wherein the zirconia
element extends the full length of and beyond the ends of the
mounting means, with the end of the zirconia element exposed to the
exhaust stream extending substantially beyond the lower end of the
mounting means. With such an arrangement, the zirconia element
requires a substantial amount of zirconia and platinum to make up
the element and electrodes, and in addition the prior art devices
use a rather expensive and complex mounting system of sleeves and
insulators to retain the zirconia element within the mounting
means.
The present invention uses a zirconia element as an air-fuel ratio
sensor in an automobile exhaust system to detect rich and lean
air-fuel conditions that does not extend the full length of the
mounting means, and therefore requires less material than prior art
devices and therefore provides a cost savings in the zirconia base
element as well as a savings in the platinum used to make the
electrodes. Also the mounting means is made up of parts that are
relatively inexpensive to manufacture and are more easily assembled
than those of the prior art and includes a material such as mica
not found in the prior art devices to compensate for the expansion
and contraction of the several diverse materials used, to thereby
assure a tight seal between the zirconia element and mounting
means. A tight seal is necessary to assure that there are no
exhaust gases introduced into the center of the sensor to
contaminate the air that passes onto the inner electrode in the
center.
It is therefore an object of this invention to provide an exhaust
gas sensor that includes a zirconia element that is shorter in
length than prior art devices and therefore less expensive to
manufacture.
A further object is to provide an exhaust gas sensor that includes
a zirconia element that is easily adaptable for mounting in a
compact, easily manufactured and assembled mounting system.
A further object is to provide an exhaust gas sensor in which the
zirconia element is easily adaptable to an interchangeable mounting
means.
Another object is to provide a mica gasket in the sensor that will
compensate for the expansion and contraction of the several
different parts having different coefficients of thermal expansion
that make up the sensor to thereby provide and maintain a gas-tight
seal and electrical contact between the parts.
FIG. 1 is a side view of the preferred embodiment of the invention
showing the sensor in partial cross section mounted in an exhaust
pipe;
FIG. 2 is a view in the direction of line 2--2 of FIG. 1, showing
the configuration of the openings in the shield;
FIG. 3 is a side view of a second embodiment showing the sensor in
partial cross section; and
FIG. 4 is a sectional view taken along line 4--4 of FIG. 3, showing
the configuration of the openings in a second embodiment of the
shield.
Referring to FIG. 1, the sensor 10 includes a hollow outer metal
shell member 12, with the upper section of the interior being
larger in diameter than the lower section, thereby forming a
shoulder 14 within the shell. The shoulder thus is generally
located intermediate the ends. Threads 16 are used to mount the
sensor to the exhaust pipe 18.
A zirconia element 20 is positioned on and supported by shoulder
14. Element 20 is hollow and has a thin wall construction 24 that
tapers from the thinnest section of the element that begins at a
closed small diameter end 22 generally bulbous in shape, and
terminates in a thicker section at the opposite end, which end has
an enlarged diameter section 26 that forms upper and lower
shoulders 27,29 respectively thereon with the zirconia element
thereby having a generally conical shape. The lower shoulder 27 is
positioned on a metal gasket 28 that is located on shoulder 14.
Element 20 has a platinum coating 30 on the inside surface and a
platinum coating 32 on the outside surface, with the coatings
extending respectively only up to the ends of the upper and lower
shoulders. The area 34 between shoulders 27,29 is not platinum
coated and thus separates the two platinum coated areas to form an
inner electrode 33 and an outer electrode 35 on the zirconia
element out of direct electrical contact with each other. The outer
electrode 35, metal gasket 28, and grounded outer shell 12 provide
for one electrical contact means or circuit portion.
A body member 37 is held within the outer shell by the crimped or
rolled over top 36 of the shell and ceramic insulator 40, these
members being considered as clamping means. A washer or gasket 38
may be positioned between crimp 36 and insulator 40. Body 37 is
positioned on a metal gasket 42, located on the upper shoulder 29
and inner electrode 33 of zirconia element 20 to provide a second
electrical contact means or circuit portion through terminal
connector 44. The contact means are insulated from each other by
the ceramic insulator 40 and the circumferential space 46 between
the body 37 and the shell. Centerbore 45 is provided in the body
member 37 extending therethrough to provide a passage for
introducing air into the hollow zirconia element.
An essential feature of this invention is to include a mica
insulating gasket 47 between the bottom of the ceramic insulator 40
and shoulder 49 formed on the body member 37. The mica solves a
problem that has been experienced in the past in maintaining a
satisfactory mechanical gas-tight seal between the parts. It is
essential to preclude any exhaust gases from entering the interior
of the zirconia element to avoid contamination of the air within
the zirconia element and give a false signal, and further to assure
good electrical contact between the electrodes on the zirconia
element and the other parts of the sensor. Mica has a thermal
expansion coefficient on the order of 5 to 10 times that of the
zirconia element, and thereby compensates for the lower expansion
of the zirconia element relative to the other metal members.
A shield 48 as best seen in FIG. 1 is attached by any convenient
means to the outer shell and has a plurality of struck out vane
shaped openings 50 that are positioned in the exhaust stream to
cause the exhaust gases to reach the zirconia element in an
indirect manner, so as not to erode the outer platinum coating. The
areas 52 adjacent and leading into the struck out openings are
concave to direct the exhaust gases into the openings in a
tangential or circular flow path.
A second embodiment 60, similar in most respects to that shown in
FIG. 1, is shown in FIG. 3 and includes a hollow outer shell 62,
that also includes threads 64 to mount the sensor to the exhaust
pipe 66. Outer shell 62 includes a shoulder 68 within the shell to
position the zirconia element 20. As in the embodiment of FIG. 1, a
metal gasket 70 is inserted within the grounded outer shell between
the shoulder 68 and shoulder 27 of zirconia element 20 to form a
first electrical contact means.
A body member 72 having an air entrance opening 77 is inserted
within outer shell 62 and rests on a second metal gasket 74 and the
upper shoulder 29 of zirconia element 20 to form a second contact
means with terminal 73. Body member 72 and zirconia element 20 are
clamped within the outer shell member by a nut 75 or similar means
that allows easy interchangeability of the zirconia element. A mica
insulating gasket 76 that performs the same function as mica
insulating gasket 47 is located on a shoulder on body member
72.
As an alternative to that shown in FIG. 1, a shield 78 is attached
to the outer shell member 62 and is placed in the exhaust stream in
the same manner as the shield described and shown in FIG. 1 and
generally has the same configured openings 50 and concave portions
52 leading into openings 50. Shield 78 may be constructed in two
sections, a bottom section 80 that is inserted into and attached to
the circular body section 82 by welding or edge crimping.
Air sensors of the types described above are useful for the
operation of equipment that will adjust air-fuel ratios very
quickly readily as they become richer or leaner during operation of
an automobile. Since such a sensor may be used on most automobiles,
it is essential that the item be made as economically and simply as
possible. The sensor as described in the claims is easy to
manufacture, is economical and is a simple device that accomplishes
the desired objects.
While the embodiments of the invention as herein disclosed
constitute a preferred form, it is to be understood that other
forms could be adopted within the scope of the claims which
follow.
* * * * *