U.S. patent number 3,843,763 [Application Number 05/122,507] was granted by the patent office on 1974-10-22 for embossing rollers and method of embossing.
This patent grant is currently assigned to Stauffer Chemical Company. Invention is credited to Miguel Coll-Palagos.
United States Patent |
3,843,763 |
Coll-Palagos |
October 22, 1974 |
EMBOSSING ROLLERS AND METHOD OF EMBOSSING
Abstract
A new and useful method for modifying embossing rollers, plates
or dies is provided capable of imparting any relief pattern or
texture of the highest quality to textiles, papers, synthetic
materials including artificial leather, plastic materials including
vinyl and polyamide fabrics, sintered metals, wood, sheet metal,
and the like. In one specific embodiment of the invention, a method
is provided for modifying embossing rollers capable of imparting to
the surface of a vinyl plastic material, the appearance and texture
of smooth leather grain, and in particular the appearance of wet
leather. The process includes the steps of electroplating a deposit
of a metal having a high to medium levelling effect and high
brightness over the entire surface of the roller and plating the
roller with a metal characterized by a relatively lower levelling
effect, as a finishing coating.
Inventors: |
Coll-Palagos; Miguel (Rye,
NY) |
Assignee: |
Stauffer Chemical Company (New
York, NY)
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Family
ID: |
26820596 |
Appl.
No.: |
05/122,507 |
Filed: |
March 9, 1971 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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858136 |
Sep 15, 1969 |
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Current U.S.
Class: |
264/219; 205/151;
205/178; 264/293 |
Current CPC
Class: |
C25D
5/627 (20200801); B44F 9/12 (20130101); C25D
7/00 (20130101); B29C 33/38 (20130101); C25D
1/10 (20130101); C25D 5/12 (20130101) |
Current International
Class: |
B29C
33/38 (20060101); C25D 1/00 (20060101); B44F
9/00 (20060101); B44F 9/12 (20060101); C25D
5/12 (20060101); C25D 5/10 (20060101); C25D
7/00 (20060101); C25D 1/10 (20060101); B29c
001/02 (); B28b 011/08 (); C23b 005/56 () |
Field of
Search: |
;204/23,25,41,140.5
;264/219,284,293 ;101/32,5 |
References Cited
[Referenced By]
U.S. Patent Documents
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2217015 |
October 1940 |
Gurwick et al. |
3022231 |
February 1962 |
Broderick |
3280736 |
October 1966 |
Schafler et al. |
3478684 |
November 1969 |
Schafler et al. |
|
Foreign Patent Documents
Other References
Industrial Chromium Plating, by D. H. Bissell, Crodon publication
reprinted from the Melliand Textile Monthly, Vol. III, No. 3, June
1931. .
Crodon in Paper Mills, Jan. 10, 1933..
|
Primary Examiner: Tufariello; T. M.
Parent Case Text
CROSS-REFERENCE TO COPENDING APPLICATIONS
This application is a continuation-in-part of an application filed
Sept. 15, 1969, Ser. No. 858,136 for EMBOSSING ROLLERS in the name
of Miguel Coll-Palagos, now abandoned.
Claims
What is claimed is:
1. In the method of embossing a vinyl substrate material to
reproduce a fine or textured pattern thereon, the improvement which
comprises contacting said vinyl substrate with a master embossing
surface which has been subjected to the following succession of
steps:
a. Electroplating the surface with a brightening metal having a
high to medium levelling effect selected from the group consisting
of copper, iron, and nickel followed by
b. electroplating with a metal having a relatively lower levelling
effect selected from the group consisting of chromium and nickel
with the proviso that the metal of step (b) has a relatively lower
levelling effect than the metal of step (a).
2. A method according to claim 1 wherein the levelling action is
effected by subjecting the master surface to the electroplating
action of copper.
3. A method according to claim 1 wherein the second electroplating
step is effected by contact with chromium.
4. A method according to claim 1 wherein the texture, grain and
effect of a natural leather, wet leather, or a patent leather is
reproduced on a vinyl fabric by engraving the surface of a roller
with a natural leather grain, subjecting the roller to a copper
flash, electroplating the resulting surface with bright copper to
obtain a deposit high ductility, brightness and hardness,
subjecting the surface thus obtained to electroplating with
chromium and then embossing a vinyl fabric with the resulting
modified roller.
5. A method according to claim 4 wherein the roller is subjected to
a copper flash in an alkaline cyanide bath prior to electroplating
with copper.
6. A method according to claim 1 wherein the engraved master
surface is a roller, plate or die.
Description
FIELD OF THE INVENTION
The present invention relates to a new and improved embossed
roller, plate or die which is obtained by electroplating a deposit
of a suitable metal having a high or medium levelling effect, such
as copper, over the entire surface of an engraved roller and a
second plating with a metal having a lesser levelling effect such
as chromium, as a finishing coating. The new and improved roller
thus obtained is capable of reproducing designs from an original
pattern thereby providing a uniform pattern of high lustre without
employing a fluorocarbon, polyester or like film lamination in the
reproduction operation.
DESCRIPTION OF THE PRIOR ART
For many years, the embossing industry has searched for new methods
and procedures to create and reproduce faithfully, embossing and
graining rollers, plates or dies so as to impart, on suitable
substrates such as paper, leather, artificial leather, synthetic
materials such as thermoplastic materials, synthetic fibers, vinyl
fabrics, metal foil, and the like, relief patterns or textures of
the highest quality and appearance. Unfortunately, these attempts
have met with limited success since the copy or result is not
generally as detailed and as bright as desired. In many instances,
additional steps are required such as, for example, buffing or
other finishing steps but even such added efforts do not create a
reproduction comparable to or simulating the texture, appearance,
or quality of the original material. This is particularly true when
a high lustre is desired for the final product as, for example,
when a shiny or wet leather finish is desired on vinyl or leather
materials. In order to achieve the desired shiny or wet appearance,
it has been the practice to use a fluorocarbon or polyester film
lamination, particularly Mylar films, in the embossing step.
Although this Mylar processing yields the desired wet look, it is
economically unattractive since large amounts of Mylar are consumed
in the processing.
Conventional procedures whereby the industry attempted to impart
embossing effects on different materials included, for example,
machine engraving and electroforming. Machine engraved embossing
rollers do not however possess the surface finish quality which is
required, for instance, to impart the brilliance and richness of
leather grains on vinyl fabric material. Electroforming, on the
other hand, has not yet developed the mold-making technique that
would assure a successful and accurate reproduction of a seamless
embossing roller or cylinder which is required to emboss patterns
and textures that are required and demanded for example, in
footwear, wearing apparel, fine upholstery fabrics, and the
like.
Thus, conventional embossed rollers, even when used with Mylar
film, could not successfully reproduce articles of clothing such
as, for example, leather products. The reproductions of natural
leather usually obtained were characterized by streaks and a very
hazy overall effect and such products did not possess the elegant
appearance of the original leather. Furthermore, the reproductions
were also marred by undesirable lines and sharp edges, and an
undesirable feel. Such products did not even resemble the
appearance or elegance of good quality leather. Thus, using
conventional engraved embossing rollers, it was not possible to
obtain a surface finish quality such as that required, for
instance, to impart the brilliance and richness of fine leather
grains on vinyl fabrics. Up to the present time, it was not
possible to reproduce faithfully embossing and graining plates to
impart on substrates such as paper, leather, artificial leather,
plastics, metal foil, and the like, relief patterns or textures of
a high and delicate quality. Furthermore, it has been heretofore
impossible to obtain vinyl or leather substrates which while
faithfully reproducing the grain of the original leather, possess
the high lustre and brightness of the so-called wet look without
employing a Mylar film lamination in the embossing step.
DETAILED DESCRIPTION OF THE INVENTION
The present invention provides a new and useful procedure for
modifying embossing rollers, plates or dies so as to produce
articles having the desired surface patterns or designs which are
characterized by the brightness and feel of natural leather grains.
Using the modified roller of the present process, there is obtained
a reproduction of the burnished leather effect, i.e., a high lustre
leather grain, that is difficult to distinguish from the original
design. The modified rollers of the present process can also be
used to obtain substrates having the so-called wet look without
employing a Mylar film lamination.
Any conventional design or any new design or pattern found in
nature or made by man, in whatever fashion, can be reproduced not
only in appearance but also in feel and textural reflexion. The
modified embossed roller obtained by the process of this invention
may also reproduce any design or pattern such as that found on the
surface of a natural leather, reptile or animal skin, wood, crinkle
foil, and the like.
In accordance with the process of the present invention, there is
obtained a new and improved embossed roller by subjecting a machine
engraved or electroformed roller to a combination of plating steps.
Firstly, the embossed roller is subjected to a bright metal plating
step with a metal characterized by a high or medium levelling
effect, to produce a combined brightening and smoothing effect on
the roller. Illustrative metals are copper, iron, nickel, and the
like. There is thus obtained a deposit of a metal having the
aforesaid smoothing and brightening effect over the entire surface
of the embossing roller. This is followed by a second plating step
which is used as a finishing coating for the roller and the second
plating is suitably effected by the use of a metal having a
relatively lower levelling effect such as chromium or nickel. The
second plating step provides a hard coating surface which is
resistant to corrosion and erosion while at the same time enhancing
the textured pattern of the end desired product.
The shape and configuration of the embossing rollers, plates or
dies employed in conjunction with the new method of the present
invention is not critical and it is to be understood that any
roller, plate or die of practically any shape suitable for
imparting the desired grain or texture to the material which is to
be embossed is acceptable for use in conjunction with the present
process. The roller, plate or die can be made of a wide variety of
materials including ferrous or non-ferrous metals such as aluminum
and aluminum alloys. The advantages of aluminum rollers are that
such rollers are characterized by better heat transfer, easier
machining and less weight than steel rollers. Further, it is also
possible to utilize effectively plastic rollers having a metal
coating on the surface and illustrative plastic rollers are those
fabricated from ABS, polycarbonates, polyvinyl chloride, rigid
urethanes, and the like.
The procedures used in engraving embossing rollers, dies, plates
and the like, are conventional and the particular method employed
for engraving is not critical to the success or operability of the
present process. Thus, the embossing rollers, plates or dies, can
be engraved by many procedures and illustratively, by hand, by
machine, chemical or photochemical techniques.
Using the present procedure, quite surprisingly, it is now possible
to obtain a modified roller, plate or die which can successfully
impart a natural grain to paper, aluminum foil, synthetic materials
such as polypropylenes, urethanes, cellulose, synthetic fabrics,
and the like, and even to a material such as wood. Surprisingly,
the modified rollers obtained by the present process can be applied
to any material that can be embossed whether such material is a
synthetic or a natural substance. Thus, for example, modified
rollers of the present process, when applied, for example, to the
reproduction of natural leather, the resulting product is
characterized by a glossy and shiny brilliance, an excellent "feel"
or "touch;" the product looks like a skin which has actually been
blended in. It has also been found that by employing the modified
rollers of the present invention, the wet leather look can be
imparted to the vinyl or leather substrate without the use of
conventional Mylar film lamination in the embossing process.
The present invention accordingly represents an important
improvement in the art since it avoids the disadvantages associated
with the use of conventional embossed rollers. The new and improved
process of the present invention involves a combination of steps
including modifying the roller with (1) a bright metal plating and
(2) a second metal plating step. In the first plating step, the
metal used is generally ductile and bright having a high or medium
levelling effect on the surface of the roller. Suitable metals
include, for example, copper, nickel or iron. It has been found
that the use of copper is most suitable. In the second plating
step, generally a metal having a relatively lower levelling effect
such as, for example, chromium or nickel, is used.
The electroplating procedures used are conventional and involve
utilizing the roller as the cathode in an electrolytic bath. The
electroplating enhances the surface characteristics of the roller,
plate or die so that said roller imparts to the material to be
embossed, a lustrous leatherlike finish. Any suitable or
conventional electrolyte can be used in the electroplating bath. As
indicated above, a plurality of electroplating steps is employed in
order to secure the desired surface characteristics comparable to
those of the original material. Thus, for example, in the
production of an embossed vinyl material possessing the
characteristics of a natural leather which is highly desirable, for
example, in the footwear industry, the first electroplating step is
effected by use of a metal having a high or medium levelling effect
such as copper followed by a second electroplating step using a
metal having a relatively lower levelling effect such as
chromium.
It has been found particularly useful to conduct the first plating
step by initially flash-coating the metal having the high or medium
levelling effect by well known periodic reverse current plating
techniques to the roller followed by electroplating that metal on
the roller. The conventional copper cyanide periodic reverse
current solutions which are well known in the art are particularly
useful for this flash-coating. This method insures complete and
even coverage of the roller.
In order that the invention may be more fully understood, the
following Example is given by way of illustration only.
EXAMPLE
A 6-foot embossing roller was engraved with a leather grain effect.
The embossing effects previously obtained on a polyvinyl chloride
fabric were unsatisfactory since the fabric was characterized by a
dull-plastic look and did not possess the lustre of the wet
look.
The embossed roller composed of a conventional steel such as SAE
1035 was stripped of metals previously plated. After the stripping
of the roller, the roller was subjected to a copper flash from a
cyanide bath having the following composition and under the
following conditions:
Copper cyanide 3.0 oz/gal Sodium cyanide 4.5 do. Sodium carbonate
2.0 do. Sodium hydroxide to a pH of 12 to 12.6 Cu by analysis 2.1
do. Free cyanide 1.0 do. Temperature 90-110.degree.F. Cathodic
current density 10-15 Amp/sq.ft. Plating thickness 0.05-0.1
thousands of an inch
On this copper flash, a bright acid copper was electrodeposited and
the composition of the plating bath as well as the conditions are
as follows:
Copper sulfate 30 oz/gal Sulfuric acid 5.5 fl. oz/gal Chloride ion
30 mg/l UBAC Make-up additive 0.75% (by wt) UBAC-R1 Additive 0.25%
(by wt) Temperature 90.degree.F. Cathode current density 100
Amp/sq.ft. Agitation: Air 1-2 cfm per sq. ft. of soln surface
Plating thickness: 3-6 mills (for our roller)
The electrolyte was subjected to a moderate agitation as, by
stirring, in order to keep the deposit surface free from hydrogen
bubbles.
A final chromium plate is deposited on the bright copper surface
and a standard hard chromium bath was used having the following
composition and under the indicated conditions:
Chromic acid 33.0 oz/gal Sulfuric acid 0.33 do. Bath ratio
CrO.sub.3 /H.sub.2 SO.sub.4 100:1 Temperature 110-120.degree.F.
Cathode Current Density 0.7-1.5 Amp/sq.ft. Plating thickness 0.5
mills (for our roller)
The plating bath determines the levelling effect. i.e., the ability
to deposit in recessed areas.
The product obtained by use of a modified roller prepared by the
foregoing combined electroplating steps is characterized by the
glossy, shiny brilliance of the wet leather look while possessing
the "touch" and feel of natural leather. The product is also
characterized by an elegant appearance and simulates, in every
detail, the appearance and texture of vinyl fabric which has been
embossed with the aid of Mylar film.
It is, of course, to be understood that the present invention is by
no means limited to the particular methods and devices set forth
above, but also comprises any modifications within the scope of the
intended claims. Thus, the rollers, dies, and the like, can be made
of any material having a conductive surface.
Further, the embossing rollers, molds or dies can be used on many
material substrates such as synthetic materials, paper, wood,
metal, and the like. Still further, as electrolytes, various
substances can be suitably employed.
* * * * *