U.S. patent number 3,838,977 [Application Number 05/228,903] was granted by the patent office on 1974-10-01 for catalytic muffler.
This patent grant is currently assigned to Ethyl Corporation. Invention is credited to Joel A. Warren.
United States Patent |
3,838,977 |
Warren |
October 1, 1974 |
CATALYTIC MUFFLER
Abstract
Catalytic muffler containing a catalyst bed between a perforate
catalyst retainer and a movable pressure plate. The pressure plate
applies pressure on the catalyst bed preventing it from becoming
fluidized. The required pressure can be supplied by springs or by
pneumatically actuated bellows. By preventing fluidization of the
catalyst bed during thermal expansion and contraction, the muffler
functions to prevent catalyst attrition.
Inventors: |
Warren; Joel A. (Birmingham,
MI) |
Assignee: |
Ethyl Corporation (Richmond,
VA)
|
Family
ID: |
22859022 |
Appl.
No.: |
05/228,903 |
Filed: |
February 24, 1972 |
Current U.S.
Class: |
422/179; 55/475;
210/351; 210/352; 422/176 |
Current CPC
Class: |
F01N
3/2846 (20130101); F01N 3/2892 (20130101); F01N
3/2885 (20130101); F01N 2230/04 (20130101); F01N
2240/20 (20130101); F01N 2330/08 (20130101); F01N
2350/08 (20130101) |
Current International
Class: |
F01N
3/28 (20060101); F01n 003/14 (); B01j 009/04 () |
Field of
Search: |
;23/288F,288R
;423/213,214 ;60/299 ;210/20,350,351,352 ;55/475 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
|
|
|
|
|
|
|
1,079,595 |
|
Apr 1960 |
|
DT |
|
439,766 |
|
Dec 1935 |
|
GB |
|
Primary Examiner: Richman; Barry S.
Attorney, Agent or Firm: Johnson; Donald L. Linn; Robert A.
Odenweller; Joseph D.
Claims
I claim:
1. A catalytic muffler comprising a muffler housing having an inlet
at one end and an outlet at the other end, a transverse perforate
fixed catalyst retainer member proximate to said outlet, a
transverse perforate movable pressure plate proximate to said inlet
and in spaced relationship to said retainer member defining a
catalyst compartment between said retainer member and said pressure
plate, a particulate catalyst bed within said catalyst compartment,
pressure means connected to said movable pressure plate and adapted
to move said pressure plate in response to a change in the volume
of said catalyst bed to continuously maintain a force on said
pressure plate in line with the direction of exhaust gas flow
through said catalyst compartment said pressure means comprising a
substantially cylindrical spring housing mounted externally of said
muffler housing on the outer surface of said muffler housing, a
coil spring within said spring housing, an opening in said muffler
housing at the location of said spring housing, actuating means
connecting said coil spring through said opening to said pressure
plate whereby said coil spring applies pressure on said pressure
plate in line with the direction of exhaust gas flow through said
catalyst compartment.
Description
BACKGROUND
Catalysts have been developed which function to reduce carbon
monoxide, hydrocarbons and nitrogen oxide content of the exhaust
gas of internal combustion engines. These are generally used by
placing a bed of the catalyst in a container and passing the
exhaust gas through the catalyst bed. These containers come in a
variety of designs and are referred to collectively as "catalytic
mufflers." A few examples of these devices are shown in U.S. Pat.
Nos. 3,146,073; 3,149,925; 3,149,926; 3,154,389; 3,380,810;
3,495,950; 3,503,714; 3,503,715; 3,567,403 and 3,600,142.
A major problem in reducing exhaust emission using a catalytic
muffler is catalyst attrition. This is the physical loss of
catalyst due to the catalyst breaking up during use. The powdered
catalyst is either blown out the exhaust pipe or packs into a dense
bed, resulting in excessive back pressure.
One cause of catalyst break up is that the catalyst bed becomes
loosely packed after being used for a short time and tends to
fluidize in the pulsating exhaust gas stream. This abrades the
catalyst granules, leading to premature break up.
SUMMARY
An object of this invention is to provide a catalytic muffler that
will hold a catalyst bed firmly, thus preventing abrasion of the
catalyst granules. A further object is to provide a catalytic
muffler that will prevent fluidization of the catalyst bed during
use in a pulsating exhaust stream. These and other objects are
accomplished by providing a catalytic muffler comprising a muffler
housing having an exhaust gas inlet and outlet. Positioned within
the housing are two opposed elements between which the catalyst bed
is held. One of these elements is a retainer which is generally
perforated to allow exhaust gas to flow to or from the catalyst
bed. The other element is a movable pressure plate which maintains
a pre-set pressure on the catalyst bed even when the bed expands or
contracts or suffers some attrition. Pressure is maintained on the
catalyst bed by pressure means connected to the pressure plate such
as spring means.
DESCRIPTION OF THE DRAWINGS
FIG. 1 is a schematic showing a typical exhaust system connected to
an internal combustion engine.
FIG. 2 is a cross section of the catalytic muffler housing showing
the catalyst granules firmly held between the retainer and pressure
plate. Coil springs located outside the muffler housing are shown
applying pressure on the pressure plate.
FIG. 3 is a cross section of an embodiment which shows the catalyst
contained in a closed screen package which is held between a lower
shaped perforated retainer and a perforate pressure plate. The
catalyst package ie replaceable. A single coil spring is shown
supplying the pressure.
FIG. 4 is a cross section of a catalytic muffler housing showing
the catalyst in a replaceable screen bag held between a dish-shaped
perforate retainer and a perforate pressure plate. Pressure is
furnished to the plate by external bellows connected to the plate
by a rod extending through an opening in the muffler housing. A
cover surrounds the external bellows forming a closed pressure
chamber in the space outside the bellows. This pressure chamber is
connected to a source of pressure which actuates the bellows and
applies pressure on the pressure plate.
DESCRIPTION OF THE PREFERRED EMBODIMENTS
Referring to FIG. 1, internal combustion engine 1 is connected by
exhaust pipe 2 to catalytic muffler 3. Conduit 4 connects the exit
port of catalytic muffler 3 to optional conventional muffler 5. The
treated exhaust is vented to the atmosphere through tail pipe
6.
FIG. 2 shows in detail the construction of one embodiment of
catalytic muffler 3. The catalytic muffler is formed by housing 20
having exhaust inlet 21 and exhaust outlet 22. Baffle 23 deflects
exhaust entering the inlet plenum zone of housing 20 through inlet
21. Located within housing 20 is perforated catalyst retainer 24
located in proximity to exit 22. The periphery of retainer 24 is
attached to housing 20 forming an exit plenum zone between retainer
24 and the bottom surface of housing 20. Also located within
housing 20 is movable pressure plate 25 arranged substantially
parallel to retainer 24. Plate 25 and retainer 24 form two surfaces
of catalyst compartment 26, which is filled with catalyst 27, only
a portion of which is shown. Screen 28 is positioned on the top
surface of the catalyst bed beneath pressure plate 25. Coil springs
29 are located outside the muffler housing in spring compartments
formed by spring housing 20A mounted on muffler housing 20. Any
number of springs may be used. Springs 29 are operatively connected
by pushrods 21A extending through an opening in housing 20 to
pressure plate 25 and tend to force pressure plate 25 toward
catalyst 27 with sufficient force to hold the catalyst firmly in
position.
In operation, exhaust gas enters housing 20 at inlet 21 and is
deflected evenly across pressure plate 25 by baffle 23. The gas
passes through the perforations in plate 25 into catalyst
compartment 26 where it contacts catalyst 27. The treated exhaust
gas then leaves catalyst compartment 26 through the perforations in
retainer 24. It then leaves housing 20 at exit 22.
Pressure plate 25 can move toward and away from catalyst 27 in
response to change in the volume of the catalyst due to temperature
effects or due to attrition of a portion of the catalyst. During
volumetric changes in the catalyst a substantially constant
pressure is maintained on the catalyst by pressure plate 25, thus
preventing it from becoming a fluidized bed which causes severe
abrasion of the catalyst granules.
FIG. 3 shows the construction of another embodiment of the
invention. The muffler housing is formed by pan-shaped upper
housing 30 and lower housing 31 which are bolted together around
their periphery. In lower housing 31 is located dish-shaped
perforated retainer 32 which is attached to lower housing 31
forming an exit plenum between retainer 32 and the inner surface of
housing 31. Located in the bottom of lower housing 31 is exit port
33.
In the top surface of upper housing 30 is inlet port 34. Mounted
inside the housing directly below inlet port 34 is baffle 35
attached at several points to upper housing 30 by spacers 36. Coil
spring 37 is attached to the lower surface of baffle 35 and the
upper surface of perforated pressue plate 38.
Positioned between pressure plate 38 and retainer 32 is a
replaceable screen container 39 filled with exhaust gas catalyst
30A, only a portion of which is shown. In operation, exhaust gas
enters the muffler housing at inlet port 34 and is diverted
throughout the upper zone above the catalyst bed by deflector 35.
The exhaust gas enters catalyst container 39 through and around
pressure plate 38 wherein it contacts catalyst 30A. The treated
exhaust gas leaves the catalyst bed through the perforations in
retainer 32 and then out through exit port 33.
As the dimensions of the muffler housing and catalyst change due to
temperature or catalyst attrition, pressure plate 38, in response
to spring 37, compensates by moving up and down as required to
maintain a substantially constant pressure on catalyst 30A in
container 39.
When catalyst 30A is no longer sufficiently active it can readily
be replaced by detaching lower housing 31 from upper housing 30 and
removing replaceable screen container 39. The spent catalyst can be
reactivated by chemical treatment, discarded, or extracted to
remove valuable constituents such as palladium, platinum, and the
like. A new or reactivated screen container of catalyst
appropriately shaped to fit the catalyst cavity is then inserted
and lower housing 31 is re-attached to upper housing 30.
The embodiment in FIG. 4 comprises a muffler housing formed by
pan-shaped upper housing 40 and lower housing 41, which are
attached around their periphery to form the muffler housing. Entry
port 42 is located in upper housing 40. Mounted on upper housing 40
outside of the muffler housing are pressure housings 43. Inside
pressure housing 43 are bellows 44, the open end of which is
sealably attached to the upper surface of upper housing 40 forming
an air-tight pressure chamber 48 between bellows 44 and pressure
housing 43. Bellows 44 are operatively connected by pushrods 45
extending through openings 46 in upper housing 40 to pressure plate
47. Pressure chamber 48 is connected to an air pressure source such
as an air tank or an engine-mounted air pump.
Inside lower housing 41 is dish-shaped perforate retainer 49
attached at its periphery to the inner surface of lower housing 41
forming plenum 40A. Exhaust gas exit 41A is located in the bottom
of lower housing 41. Fitted within the cavity formed by pressure
plate 47 and retainer 49 is screen container 42A filled with
exhaust gas catalyst 43A, only a portion of which is shown.
In operation, exhaust gas enters the muffler housing at inlet port
42. It then passes through and around pressure plate 47 into screen
container 42A wherein it contacts exhaust gas catalyst 43A. It then
passes through the openings in perforate retainer 49 into plenum
40A and then out through exit port 41A.
As the catalyst volume changes in use, pressure plate 47 moves up
or down in response to such volume change. Plate 47 maintains a
substantially constant pressure on the catalyst bed as a result of
pneumatic pressure in pressure chamber 48 tending to compress
bellows 44 which is operatively connected by push-rod 45 to
pressure plate 47. The pressure within chamber 48 should be
adjusted such that the pressure on the catalyst bed is sufficient
to hold it firmly and prevent substantial movement within the
bed.
Preferably, means are provided to adjust the pressure on the
catalyst bed. For example, a screw may be placed in the top of
spring housing 20A which serves to move a disk located within the
spring housing on top of coil spring 29. To increase pressure on
the catalyst the screw is turned down, causing the coil spring to
compress, thus increasing pressure on the catalyst bed.
A large variety of exhaust gas catalysts can be used in the present
catalytic muffler. Examples are supported copper oxide, copper
oxide-palladium, copper oxide-chromium oxide-palladium, vanadium
oxide, vanadium oxide-platinum, platinum, manganese oxide,
manganese oxide-iron oxide, vanadium oxide-chromium oxide, nickel
oxide, copper oxide-nickel oxide, and the like. Suitable supports
include alumina, silica, silica alumina, magnesia, zirconia,
kieselguhr, and the like. Some representative exhaust gas catalysts
are described in detail in U.S. Pat. No. 3,226,340; 3,433,581;
3,271,324; 3,207,704; 3,447,893; 3,428,573; 3,224,981; 3,540,838;
3,224,831; 3,425,792; 3,524,721; 3,545,917 and 3,374,183.
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