U.S. patent number 3,834,529 [Application Number 05/219,221] was granted by the patent office on 1974-09-10 for device and method of density measurement and control of flotation systems.
This patent grant is currently assigned to The Dow Chemical Company. Invention is credited to Porter Hart.
United States Patent |
3,834,529 |
Hart |
September 10, 1974 |
**Please see images for:
( Certificate of Correction ) ** |
DEVICE AND METHOD OF DENSITY MEASUREMENT AND CONTROL OF FLOTATION
SYSTEMS
Abstract
Two open-end tubes are vertically immersed, open-end down at
substantially the same level, one near the place of entrance of a
liquid in process in a series of treating vessels and the other
near the outlet of the liquid whereby densities of the liquid at
the respective locations are measured by means of a suitable
pneumatic assembly, the density values are translated to and
recorded as a pneumatic pressure differential and the pneumatic
pressure differential is either (1) automatically converted to and
recorded in meaningful values and the indicated adjustments
manually made to restore and tend to maintain the optimum density
differential, or (2) directed to an optimizer whereby optimum
adjustments are automatically made to restore and tend to maintain
a maximum density differential. Where a fluctuating level of liquid
exists, two probes immersed at different depths to define a fixed
stratum may be used in cooperation to obtain one density value.
Inventors: |
Hart; Porter (Lake Jackson,
TX) |
Assignee: |
The Dow Chemical Company
(Midland, MI)
|
Family
ID: |
22818376 |
Appl.
No.: |
05/219,221 |
Filed: |
January 20, 1972 |
Current U.S.
Class: |
209/1; 210/96.2;
209/166 |
Current CPC
Class: |
B03B
13/005 (20130101) |
Current International
Class: |
B03B
13/00 (20060101); B03b 009/00 (); B03b
013/00 () |
Field of
Search: |
;209/162,164,172.5,166,168,169,170 ;210/96,42 ;73/438,439 |
References Cited
[Referenced By]
U.S. Patent Documents
Other References
Chem. Abst., 64, 1966, 15444c. .
Chem. Abst., 68, 1968, 89182K. .
Chem. Abst., 69, 1968, 37996e..
|
Primary Examiner: Halper; Robert
Attorney, Agent or Firm: Ancona; A. Cooper
Claims
Having described my invention, what I claim and desire to protect
by Letters Patent is:
1. In the recovery of mineral values from an ore slurry employing
flotation principles wherein conditioning agents are admixed with
water and pulverulent ore to make a treated slurry and said slurry
is subjected to flotation by passing air upwardly through the
agitated slurry in successive connected cells whereby the mineral
sought to be recovered is collected in a froth which is overflowed
and recovered from the thus provided overflow, the improvement
comprising:
continuously measuring the density values of at least two of said
cells, continuously converting the density values to a pressure
differential which is proportional to the differential of density
values;
causing a pneumatic impulse in accordance with variations in the
pressure differential to be relayed to a continuous registering
instrument to provide a continuous pressure differential record
which is calibrated to show density differential;
adjusting at least one additive of the flotation process in
accordance with the recorded density differential to tend to
maintain said differential at a maximum.
2. The method according to claim 1 wherein the electrical potential
(EMF) value of the slurry prior to its being subjected to flotation
is continuously recorded so that, for purposes of process control,
said electrical potential can be adjusted in accordance with
changes in said density differential.
3. The method according to claim 2 wherein the electrical potential
(EMF) is calibrated into pH values.
4. The method according to claim 1 wherein a pneumatic impulse in
accordance with said pressure differential, as controlled and
determined by said density differential, is continuously sent to an
optimizer which automatically seeks the maximum density
differential which is continuously recorded.
5. The method according to claim 4 wherein said maximum density
differential is continuously converted to pH values and such values
used to guide the amount of an ingredient which, when admixed with
the slurry, modifies the electrical potential (EMF) thereof.
6. The method according to claim 4 wherein a series of pneumatic
impulses provided by said optimizer are sent to the feed control of
an ingredient which modifies the electrical potential (EMF) in the
slurry and increases or decreases the rate of said feed to cause
the potential to trend at predetermined time intervals in the
direction of maximum density differential in the slurry bath in the
two cells being measured.
7. The method according to claim 6 wherein the optimum
positive-negative potential differential in the slurry bath is
recorded as well as automatic adjustment made of the rate of feed
of a positive-negative modifying ingredient to continue to modify
that rate to one which gives maximum density differential between
the density of the slurry at or near the beginning and that at or
near the end of the flotation operation.
8. An apparatus for continuously measuring, recording and
controlling an ore flotation process which comprises in
combination:
1. at least two independently operating vertically positioned
elongated hollow probes, open at the lower end, each immersed to
substantially the same depth in a body of ore slurry, each probe
being located at one of selected successive flotation stages and
filled with a non-turbulent gas, substantially chemically
unreactive with the slurry;
2. a tube extending from the upper end of each of said probes
leading to opposite sides of a closed bi-chambered
pressure-sensitive instrument, the chambers being formed by a
dividing flexible membrane, thereby providing entrapped
substantially dead gas in each probe-tube chamber combination, the
pressure of which increases or decreases directly in response to
the density of the liquid at the level of the lower end of each of
said probes and deflects said membrane in accordance with the
pressure differential and therefore in accordance with the density
differential;
3. means for continuously measuring the electrical potential (EMF)
of the ore slurry at a location prior to the first flotation stage
and means for recording and adjusting said electrical potential;
and
4. a peak-seeking optimizer responsive to the pressure differential
provided by said pressure-sensitive instrument and which adjusts
the said electrical potential (EMF) of the slurry at said location
prior to the first flotation stage at the optimum necessary to
maintain the pressure differential (and thus the ore recovery) at a
maximum.
Description
BACKGROUND OF THE INVENTION
In many processes conducted in liquid phase, it is essential for
control thereof to ascertain and control the density at various
stages. Density differential very often is also indicative and
sometimes an accurate measurement of the efficiency of the process.
Illustrative of the latter are ore flotation systems wherein a
mineral is separated by passing an aqueous slurry of finely ground
ore containing conditioning agents through a series of open-top
chambers or vessels (usually called cells), positioned
substantially horizontally to each other, each provided with an
upwardly directed air supply and troughs or trays along the upper
edges thereof to collect and drain away the desired mineral which
is frothed off, sometimes aided by additional water supplied to the
collection system, and usually thereafter thickened and dried. For
specific consideration the separation of fluorite (which term will
herein be used interchangeably with substantially pure CaF.sub.2)
from fluorspar ore is illustrative. Fluorite which is the principal
component of the ore and which is of greatest density, is frothed
off as the slurry moves through the vessels, commonly called
rougher cells. Accordingly, the density of the slurry is lessened
as it passes from cell to cell. The efficiency of the system is
indicated by the difference in density of the slurry in the
successive cells and particularly between the first and last cells
of a series. In general, the greater the difference in density, the
more of the desired heavier mineral is being floated off.
Heretofore, density values have been obtained by manually taking
samples of the slurry as it enters the first cell and again as it
leaves a subsequent cell, weighing the samples, and calculating the
density differential. Although this has long been done by a
convenient liter vessel attached to one end of a balance arm and
having a calibrated spring scale attached to the other, such
measurements are only roughly accurate, and also provide only
periodic values; they do not provide adequate information for
satisfactory control of the system. Not only is such method of
measurement done only at intervals so that conditions between
measurements are unknown, but the time lag between the time that
awareness of an undesirable change in density is known and a
correction is made and becomes effective leads to erratic
results.
A need, therefore, exists for a method of continuous density
differential measurement and for prompt correction and particularly
for automatic correction to effectuate the greatest differential
conducive to frothing off a high quality product. The invention
fulfills this need to a most gratifying extent.
SUMMARY OF THE INVENTION
Broadly, the invention is a method of continuously measuring
density, and particularly the concurrent measurement of density
values at two stages of progress in a liquid system to ascertain
the density differential, and the apparatus necessary for
performing such method. The preferred mode of practicing the
invention consists of a method and apparatus which measures such
densities and density differential and promptly and automatically
corrects the density differential to provide optimum conditions.
Particularly the invention is a method and apparatus which
continuously measures the differential between density values,
converts such values instantly to a pressure differential,
optionally relates the density differential to a calibrated
recording instrument, to guide manual changes if desired, and/or
simultaneously makes proper changes in one or more components of
the source material being introduced into the system, whereby the
density differential is optimized to maintain maximum recovery of
product of improved quality.
Although the term pH (which strictly means only the reciprocal of
the logarithm of the hydrogen ion concentration) is used herein to
designate E.M.F. or electric potential produced in the slurry, it
is to be borne in mind that such potential may be due in part to
other contributing causes.
DESCRIPTION OF THE INVENTION
The invention is an improvement in flotation processes generally,
and apparatus necessary for the practice thereof. To better
understand the invention, conventional flotation, applicable to the
recovery of CaF.sub.2 product from fluorspar, is set out below.
Ore is pulverized, as by passing it through a rock-crusher,
grizzly, or the like and then, after admixture with water to
produce a slurry, some or all of the following treating agents are
admixed therewith: a surface tension improving agent (known
sometimes as a collector) to increase surface tension and to
encourage bubble formation and stabilized froth, a suppressant to
lessen the tendency of undesirable minerals present in the ore to
rise in the froth, and an alkalinity-control agent to maintain
desirable ionic potential in the slurry, and passing the so treated
slurry in sequence: through a ball mill to reduce particle size;
from the ball mill to a conditioning tank (conditioner) for
thorough mixing and usually admixture of additional treating agents
to attain a desired slurry composition for processing conditions;
from the conditioner to a series of rougher cells wherein the
slurry is agitated and into which are fed upwardly directed air to
produce a mass of bubbles or froth, to which the desired mineral is
attracted and adheres and which is caused to overflow out into
collecting troughs positioned along the outer edges of the cells;
from the collecting troughs (usually some additional water being
admixed with the froth at this point) optionally into a second
series of similarly designed cells (often called cleaners) by which
the so collected foam is again subjected to air flotation and
refined to a higher content of desired mineral; from the cleaners
(or directly from the roughers) into a slowly agitated moderately
heated tank (usually called a thickener) during which entrapped air
escapes and considerable water separates as an upper layer and
overflows to waste (or is recycled back to the ball mill to be used
to slurry additional ore) leaving in the thickener a high viscosity
but easily pumpable slurry; from the thickener the so thickened
slurry of recovered mineral passes from the bottom thereof to a
filter system which is preferably a vacuum dewatering type which
comprises envelopes connected to an internal vacuum system to
provide interior low pressure, arranged on a wheel which rotates on
a horizontal axis so as to define an arc passing below the upper
surface of the body of the thickened mineral slurry, causing slurry
to adhere to the outside as a wet cake and water to be removed
therefrom through the internal vacuum system, and to rotate through
a second arc above the surface of the slurry where the envelopes
scrape against fixed blades which remove the cake as wet crumbles;
from thence the cake crumbles drop onto a conveyor and are conveyed
to dryers which produce a dehydrated commercially acceptable
CaF.sub.2 product.
All necessary crushers, ball mills, conveyors, treating compound
inlet and feed lines, transfer lines, control valves and pumps,
rougher cells equipped for mechanical agitation, aerating and
collection means, conditioning and thickener tanks, vacuum
dehydration means, and dryers (all of which are known in the art)
are located in accordance with a recommended lay-out suggested by
advanced technology of ore treatment processing.
The improvement, in broad terms, of the above conventional general
procedure and equipment which is the instant invention, comprises a
method and means of continuous measurement of density differential
of a mineral slurry at selected successive stages in a flotation
system which differential is continuously recorded and serves as a
basis for judicious adjustment of at least one component or
condition of the process and provides for prompt adjustment
thereof, e.g., a component of the feed composition in accordance
with the density differential, to provide optimum recovery and
improved quality of product. This is attained inherently in the
novel system by converting the density differential to a pressure
differential which is transferred as a pneumatic impulse. This may
be done by directing the impulse to a recording instrument which is
observed and acted on. The impulse preferably, however, is directed
to an optimizer which automatically directly adjusts an ingredient
in the feed to that proportion which results in the highest per
cent recovery which is consistent with good quality. This is a
peak-seeking optimizer which continuously changes the selected
ingredient to result in optimum density differential.
The novel aspects and mode of operation of the improved process of
the invention include cooperating mechanisms (the most critical of
which are identified immediately below by small letters) for
obtaining continuous density values converted to pressure
differential employing (a) open-bottomed tubes (called hereafter
density probes) positioned substantially vertically in the slurry
at selected successive stages of the process, which connect at the
top with tubing filled with dead air which terminate in (b) a
two-chambered density cell, against a flexible diaphragm therein,
which forms the density cells where, by density variations, the
densities are converted to corresponding pressure variations in
each chamber, called herein D.sub.1 and D.sub.2, respectively, for
the selected stages. The differential between D.sub.1 and D.sub.2
is either calculated and a pneumatic impulse sent to a recording
meter for quick reading and manual adjustment made or an impulse is
sent directly to (c) an optimizer which optimizer continuously
seeks the greatest D.sub.1 -D.sub.2 or peak value possible and
automatically relays this directly to a control which adjusts a
component or condition so as to maintain the highest D.sub.1
-D.sub.2 value.
If desired, the pneumatic impulse from the density pressure cell
may go both to the recording meter and to the optimizer whereby the
potential difference in the slurry (which as aforesaid for
practical purposes may be thought of as the pH value) is made of
record but wherein the change is promptly made automatically by the
peak-seeking optimizer. To attain this latter end, an electric line
or pneumatic conduit leads from the optimizer (or continues from
the meter) to an electric motor which actuates the valves that
control that component of the feed which must be changed to result
in the desired optimum condition, viz. optimum electric potential
in the slurry being processed which in turn maintains a large
density differential which results in increased product
recovery.
It is to be understood that the invention may be practiced by
employing variations and modifications of the above procedure so
long as the concept of density measurement and automatic optimum
adjustment of density, in accordance with the invention, is
practiced.
The optimizer is available from instrument specialists e.g., Model
571 Syncro Optimizer MS-276701, as described and illustrated in
"Operating Instructions" for said model published by Moore products
Co., Spring House, Pennsylvania.
DESCRIPTION OF THE DRAWING
The drawing schematically illustrates an embodiment of the
apparatus of the invention and that used to practice the method of
the invention.
FIG. 1 shows the various parts of the assembled apparatus and the
working relationship of a flotation system for carrying out the
process of the invention.
FIG. 2 is a schematic view of an embodiment of the density
measuring instrument of the invention wherein a fixed level is
established between the lower ends of two cooperative probes which
constitute one instrument to obtain a single reading. It is used
where the surface level of the liquid under control fluctuates.
FIG. 3 is a schematic view of two instruments from which D'.sub.1
and D'.sub.2, and the differential thereof, of successive stages of
a flotation operation, including the instrumentation referred to as
(a) to (c) above, are shown.
FIG. 4 is a graph whereon the .DELTA.D, i.e. D'.sub.1 -D'.sub.2
density differential as read on the recorder and guided by the
optimizer, is curve (1) and as obtained manually is curve (2); and
the pH values as established by automatic adjustment according to
the invention is curve (3); and the pH values as taken manually are
curve (4).
FIGS. 5 and 6 are percent recovery values plotted against pH values
of the slurry.
In the drawing the word "conduit" is used for tube connections
filled with air which effectuate desired changes by pneumatic
impulses. The word "line" refers to flow lines for liquids.
Electric connections are referred to as wires or wiring.
In more detail, the significant members of the assembled flotation
system of FIG. 1 are represented by the following designations:
Item 2 is a moving endless apron for conveying crushed ore from a
mine or storage pile. Item 3 supplies water (which need be neither
deionized nor softened for use in the invention). Line 4 supplies a
suppressant, e.g., an aqueous solution of quebracho. Both 3 and 4
lead into line 5 which bifurcates, through control valves (a) and
(b), into lines 6 and 7, respectively. Tank 8 supplies an
alkalinity control agent, e.g., an aqueous solution of soda ash,
which connects with line 10. Lines 6 and 10 supply water and
conditioning agents to the ore as it enters, and line 7 as the ore
leaves, ball mill 12 (i.e., a drum rotating on a substantially
horizontal axis or inclined slightly towards the outlet end, and
containing freely moving steel balls for grinding ore). Item 13 is
the outlet line from 12 which by means of pump (p) powered by motor
(m) conveys slurry to 14 which is a cyclone separator of coarser
and finer grind ore (in aqueous slurry containing the additives).
Item 16 is an outlet line for finer grind ore from 14 leading
directly to further processing and line 18 is an outlet line for
coarser grind ore from 14 leading back to 12 for regrinding.
Instrument 19 positioned in line 16 is a total ore volume measuring
instrument which is connected by electric wire 20 to the first of
two pens on recording instrument 21 which records hourly total ore
volume thereon. Line 16 terminates in conditioning tank 22 known as
a conditioner for finely ground ore slurry from the ball mill,
provided with a high speed agitator (A). Positioned in 22 are
electrodes T and S comprising electrode pair 24 made of
erosion-resistant material (as described in co-pending application
Ser. No. 219,230, entitled "METHOD OF CONTINUOUS MEASUREMENT AND
CONTROL OF FLOTATION CONDITIONS", of Porter Hart, filed
concurrently herewith) which are provided with electric wiring 25
connected thereto and leading to a first recording pen which
records continuously the electrode potential, which for simplicity
may be considered to be the alkalinity of the slurry, on meter 26
(which for practical purposes may be considered a pH meter).
Electrodes 24 are not essential to the practice of the invention
but give an accurate slurry EMF (which for simplicity as indicated
may be called pH value) at any time and serve as an independent
source of knowledge of the conditions of operation.
Feeding into 22 is a surface tension improver or collector agent,
e.g., oleic acid, by means of system 27.
Also in conditioner 22 there are shown a pair of cooperating
vertical tubes 28, open at the bottom and containing air as shown
in FIG. 2. They are, as shown on FIG. 2, immersed to different
depths in the slurry, e.g., a difference in depth of about twenty
to thirty inches between the open lower ends, thereby defining a
fixed stratum or layer of slurry upon which to calculate the slurry
density. By means of conduits 29 and instrument 30 (a
pressure-density cell) there is provided an accurate density
reading D.sub.1 by reason of corresponding pressure changes. This
D.sub.1 value is conveyed through conduit 31 into three conduits,
viz: 32, 33, 34: conduit 32 leads to computer 35 where the volume
(V) value from meter 21 through conduit 36 is received and the
calculation V .times. D.sub.1 = mass flow is made and the result
sent by pneumatic signal through conduit 37 to a second pen on
meter 21 for recording mass flow thereon. Conduit 33 leads to
computer 38 to provide the D.sub.1 value to the computer. Conduit
34 leads to a first pen on meter 39 which records the D.sub.1 value
continuously. Conduit 40 leads from meter 39 to valves (a) and (b):
valve (a) provides automatic control of water containing quebracho
into line 6 for entrance to ball mill 12 and valve (b) provides
automatic control of water containing quebracho into line 7 as the
slurry leaves ball mill 12.
Line 41 leads conditioned ore from 22 to cell C-1, the first of the
series of rougher cells designated collectively item 42. Density
probe tube 44 (similar to the longer tube of 28 and described more
fully hereinbelow), is submerged in cell C-1. Via air conduit 46
the density D'.sub.1 of the slurry in cell C-1 (converted to
corresponding pressure) deflects a flexible diaphragm in accordance
therewith, in two-chambered density-pressure instrument 48. Cell
C-6, the sixth of rougher cells 42, is provided with density probe
50 (similar to probe 44 of cell C-1) which by way of conduit 52
converts the density D'.sub.2 of the slurry in cell C-6 to pressure
which also tends to deflect the flexible diaphragm in
density-pressure instrument 48 (against the opposing pressure
responsive to the density of C-1) in accordance with the pressure
changes. By means of the pressure-activated diaphragm positioned
between the two chambers in 48, a pneumatic impulse, responsive to
the pressure differential, is passed along conduit 54, sending one
signal into optimizer 56 and a second signal through conduit 58 to
a second pen on meter 26 which continuously registers the actual,
i.e., existing, D'.sub.1 -D'.sub.2 or .DELTA.D' value for purposes
of record.
Optimizer 56 continuously and automatically seeks the greatest
density differential (D'.sub.1 -D'.sub.2), since the greater
differential in density indicates the greatest efficiency of the
rougher cells. An important condition for high recovery is the
correct amount of alkalinity control agent (usually soda ash
solution) added. Exact and quick adjustment of soda ash is
accomplished by the optimizer passing optimum desired pH value
signals, via conduit 59, to a pointer on meter 26 where they are
continuously indicated for reference purposes and which the pH
recording pen thereon tends to follow. However, by means of conduit
61, the optimizer-guided pneumatic impulses are promptly passed on
through branching conduits 62 and 63 to valves c and d,
respectively which, by means of gap controller 64, control two
branch flows from soda ash supply system, of the alkalinity control
additive (e.g., an aqueous solution of soda ash). Valve c regulates
flow through line 10 to ball mill 12 and valve d regulates flow
through line 65 to conditioner 22 in desired proportions, usually
about twice as much being directed to 12 as to 22. It should be
understood that soda ash is used here for illustrative purposes.
For some ores it is necessary that flotation be conducted in a
neutral or acid medium, i.e., at a relatively low pH and an
acidifying agent would be added.
An air supply system is represented by source 66, main conduit 67,
and branches 68, 69, and 70, which system provides available
pneumatic pressure as needed in the various conduits for automatic
control.
As the slurry is moved from cell to cell in roughers 42, leaving
each preceding cell and entering the next succeeding cell, while
being agitated and while air is blown upwardly therethrough foam is
produced which carries CaF.sub.2 to the top of the cells and froths
it off into the collecting troughs 82.
A third density probe 72 (of the type designated 44 and 50) is
immersed in cell C-8 whereby density D.sub.2 value is obtained by
means of conduit 73 leading to pressure-density diaphragm cell 74.
The D.sub.2 value of C-8 is conveyed therefrom via conduit 76 to a
second pen on meter 39 whereby D.sub.2 is recorded. Branching off
of conduit 76 is conduit 77 which feeds the D.sub.2 value into
computer 38 for calculating D.sub.1 -D.sub.2 /D.sub.1 = percent
recovery (percent R). This percent R value is conveyed by pneumatic
signal via conduit 79 to a third pen on meter 39 whereby it is
recorded.
The slurry which has not been frothed off in roughers 42 passes
from a point near the bottom of cell C-8 through line 81 and, by
means of pump p' and motor assembly m', is forced to a tailings pit
or pile.
The high CaF.sub.2 content material, i.e., concentrates, from
roughers 42 is frothed off into collecting trough system 82 from
which it ultimately passes through line 83 to cleaners designated
collectively 84, which are actually additional flotation cells (and
not always necessary) and which are very similar to 42 but which
are designed to accept the once-frothed off ore as feed which is of
much higher CaF.sub.2 content than slurried fresh ore feed. That
portion of the slurried concentrates which is not frothed off at
cleaners 84 (similarly as from roughers 42) passes out from a point
near the bottom of the last cleaner cell through line 85 into line
81 and thence to the tailings pile. The recovered froth from
cleaner cells 84 passes into collecting troughs 86 and ultimately
into line 87 leading to thickener vessel 88 under slow agitation
where a large percent of the water content thereof rises to the top
and overflows to waste (or is recycled for reuse with fresh ore) as
the concentrates settle toward the bottom and thickens. From
thickener 88, as a high viscosity fluid, the CaF.sub.2 is drawn off
the bottom of 88 through line 89 into filter system 90 comprising
envelopes which are subjected to interior vacuum, alternately being
submerged in the thickened slurry which clings thereto to form a
cake, and thence being brought out of the slurry into contact with
fixed scraper blades that remove the cake (not shown in detail).
The rotating envelopes and stationary blades are identified
schematically as items 91 and 92, respectively.
The so removed cake (now wet crumbles) is passed via conveyor 94 to
dryer 96, which in practice customarily consists of a series of
connected drying units, which produces a 97.4 percent or higher
anhydrous CaF.sub.2 powder.
Although pneumatically operated controls are shown in the
illustration, it should be understood that, other than the pressure
impulses received from the density probes by the pressure cells,
all signals may be transferred and measured by means of an electric
system.
FIG. 2 shows two tubes in combination to define a fixed depth or
stratum to obtain a single density value (where the level in the
container varies) so that the volume at which density (D.sub.1) is
measured remains the same. It is used, for example, when the
density is obtained from conditioner 22. Since air must be provided
to maintain adequate and substantially dead air in the probes, a
metering valve, opening for admission of air without objectionable
accompanying air currents, is provided in each of the two tubes
comprising the probe.
FIG. 3 shows in some detail the assembly comprising density probes
44 and 50, conduit 46 leading from probe 44 and conduit 52 leading
from probe 50 to opposing chambers D'.sub.1 and D'.sub.2 of
density-pressure differential instrument 48. The probes, as
aforesaid, are elongated hollow cylinders which are open at the
bottom and closed at the top to form dead-end systems terminating
at the flexible diaphragm which separates 48 into D'.sub.1 and
D'.sub.2 chambers. The diaphragm responds to slight changes in
pressure differential thereagainst which changes are promptly
transferred from instrument 48 via conduit 54 to optimizer 56 and
thence via conduit 59 to meter 26. The pneumatic impulses recorded
on meter 26 are passed on via conduit 61 to gap controller 64 and
valves c and d. Stirring and air supply assemblies are
schematically represented and so labeled. Ample air is provided in
tube probes 44 and 50 by air entering the cell bottoms for
flotation.
FIG. 4 clearly demonstrates the improved control leading to assured
improved efficiency and higher percent recovery attained by the
practice of the invention.
FIG. 5 shows the percent CaF.sub.2 recovered at increasing slurry
pH values to show that recovery is substantially zero at too low or
too high slurry EMF, herein referred to as pH values.
FIG. 6 shows that the percent CaF.sub.2 recovered remains high as
the pH values are clustered about the optimum value as
automatically set by the optimizer as it receives the signals from
the pressure-density cell, the signals being in prompt response to
the density differential based on densities measured by the probes
in accordance with the invention.
The density probe for D'.sub.2 need not be positioned in the cell
selected in FIG. 1, although such is preferred. Any succeeding cell
after cell C-1 can be used. Since by far the major portion of the
flotation has been consumated by the time the slurry has passed
from cell C-6, that cell is selected for illustration. The
remaining cells, viz. cells C-7 and C-8 of FIG. 1, often called
scavenger cells, froth off very little additional CaF.sub.2 and
sometimes none. However the D'.sub.2 probe could be satisfactorily
placed in cell C-8 rather than cell C-6 to provide for automatic
adjustment of the additament required to maintain optimum
conditions. C-1 and C-6 are selected for D'.sub.1 and D'.sub.2
density values because a preponderance of the flotation is attained
therebetween within a relatively short time and therefore automatic
adjustments based thereon are made as promptly as possible.
The principal use of D.sub.1 density, i.e., the density of the
unfrothed slurry, is for the purpose of controlling the total
solids, (i.e., amount of water added to the ore) in the ball mill.
D.sub.2 is the density of the tailings. Both values are used for
the calculation: D.sub.1 -D.sub.2 /D.sub.1 to give the overall
percent CaF.sub.2 recovery.
EXAMPLES
To illustrate the practice of the invention in comparison with
conventional practice employing as nearly as possible the same mill
lay-out, ore, and processing techniques except that, in the
practice of the invention, the hereinafter claimed density-pressure
probes and optimizer control of soda ash were employed whereas
control was exercised in the conventional or comparative example in
accordance with the most efficient techniques known prior to the
instant invention.
The most significant operating conditions and results obtained for
illustrative and comparative examples are shown in Table I.
Comparative
This example was conducted to illustrate the recovery of CaF.sub.2
from fluorspar ore in accordance with conventional practice.
Complete daily records were maintained for a prolonged period of
continuous operation. The procedure followed consisted of feeding
crushed fluorspar ore by way of conveyor 2 into ball mill 12 as
shown in FIG. 1 into which were also fed 10 percent by weight
aqueous solutions of quebracho and soda ash and sufficient water to
provide the desired solids. The ore was thereby converted to a
conditioned slurry of fine particle ore. From 12 the slurry was
passed into a cyclone separator of the type designated 14 in FIG.
1. Therein particles coarser than 200 mesh size were returned to
the ball mill and the finer particles were pumped to a highly
agitated conditioning tank (e.g., conditioner 22) into which
concurrently were fed oleic acid and additional aqueous soda ash
solution controlled as needed.
From the conditioner the substantially uniformly mixed treated ore
slurry was caused to flow to the series of flotation (rougher)
cells as represented by 42 of the drawing.
Air was released into each cell near the bottom center by way of an
annular opening about the shaft of a rotating stirrer-centrifugal
pump assembly (illustrated in FIG. 3) vertically positioned in each
cell to produce froth. The CaF.sub.2 being attracted to the froth
in the cells, rose to the top thereof, was caused to overflow, and
was collected as a slurry in troughs positioned along the outer
edges, where, aided by limited additional water flow, it was
drained away, and thereafter subjected to a second flotation
treatment in similar series of cells known as cleaners, e.g., 84 of
FIG. 1 of the drawing. The uncollected portion of the slurry in
rougher cells 42 was drained away to a tailings pond as also was
the uncollected portion of cleaner cells 84. The recovered froth
from the cleaners 84, usually aided by more additional water for
satisfactory flow, was pumped to a relatively large moderately
heated tank 88, called a thickener, provided with very slow
agitation wherein an appreciable amount of the water present
continued to rise and was separated by its overflowing. From 88 the
thickened paste-like slurry was flowed at a controlled rate from
the bottom thereof to filter (dewatering) system 90 comprising
exhausted envelopes, i.e., envelopes 91 having a vacuum applied to
the interior causing the thickened slurry to cling to the exterior,
whereby moisture was drawn inwardly from the slurry by the vacuum
leaving a cake-like layer on the envelope exteriors. This layer was
removed by causing the envelopes to rotate against fixed scraper
knives or blades 92 (or if more convenient the knives may be moved
across the envelopes) causing the wet recovered mineral to fall in
crumbles on a conveyor, e.g., 94, and be taken into the first of a
series of dryers represented by 96. The dryer produced an anhydrous
CaF.sub.2 product.
The only process control practiced in the above conventional
operation, other than observation and "hand feel" consisted
essentially of ore analyses, periodic sampling for manual
determinations of both pH and density, and laboratory analyses of
the periodic samples of the CaF.sub.2 product.
The conditions and results of the conventional examples are shown
in Table I.
Example of the Invention
The following example is illustrative of the practice of the
invention. As aforesaid, the rate of feed of ore, the additives,
and flotation principles applied and the general flow pattern were
substantially the same as in the above comparative example except
that the techniques applied to the control of the process were
those of the invention.
Fluorspar ore, quebracho, soda ash, oleic acid, and water were fed
into the system similarly as in the example of conventional
practice hereinabove. However, meter 19 was positioned in line 16
so that, as the ore slurry moved therethrough, the total ore mass
thereof was measured and a correlated signal transmitted by wire 20
to recording instrument 21. Complete daily records were maintained
for the same period of time as in the above example of conventional
practice.
By the term positive-negative electrical potential as used herein
is meant any variation in electrode potential in a liquid.
In accordance with the invention the pair of density probe tubes 28
in conditioner 22 were positioned so that the vertical distance
between their lower open ends was 25 inches, thus giving a fixed
stratum or layer of slurry for measurement of density. Likewise, by
inserting single density probe tubes 44 and 50, respectively, in
rougher cells C-1 and C-6, so that their open ends were 15 inches
above the bottom of the cells, a fixed stratum of slurry was
defined since the cells are maintained full of liquid at all times
during the flotation operation. The top of tubes 44 and 50 led into
smaller flexible tubing lines 46 and 52, respectively, which
dead-ended on opposite sides of the diaphragm in D'.sub.1 -D'.sub.2
meter 48 which converted the density values of the contents of
cells C-1 and C-6 to a pressure differential which was transmitted
via conduit 54 to optimizer 56 which translated the pressure
differential to the desired EMF potential (which may be considered
pH value) corresponding to maximum pressure differential. Conduit
59 carried the pneumatic impulse to 26 where it was indicated as
the optimizer-guided desired pH value. Conduit 61 further relayed
the pneumatic impulses from optimizer 56 via conduit 62 and 63 to
motor valves c and d whereby adjustments were automatically made in
soda ash feed, by means of gap controller 64, which tended
continuously to maintain an optimum feed composition. The cells 42,
cleaners 80, thickener 88, filter assembly 90, and dryers 96, were
employed as in the conventional examples.
By means of the peak-seeking optimizer 56, that pH was maintained
which caused the .DELTA. density, and hence percent CaF.sub.2
recovered, to remain at the top of the curve shown in FIG. 6. The
optimizer attains this objective by continuously adjusting the rate
of aqueous soda ash solution flow toward maximum density, i.e.,
whenever increments in soda ash continue to increase the .DELTA.
density, such increments continue to be made but when such
increments result in a decrease in .DELTA. density, the optimizer
immediately calls for a reduction in soda ash and continues to make
such reductions until the .DELTA. density again is not improved by
such decreases.
TABLE I
__________________________________________________________________________
Kgm/ 10% min. aq. 10% of sol. aq. % CaF.sub.2 CaF.sub.2 of soda
CaF.sub.2 Product Ore avail- que- ash Oleic pro- based % CaF.sub.2
Feed % CaF.sub.2 able bracho sol'n. acid duct on CaF.sub.2 in Kgm/
in in ml/ ml/ ml/ Conditioner Kgm/ ore CaF.sub.2 Min. Ore Ore min.
min. min. * % T.S. Temp..degree.C. min. Content Product
__________________________________________________________________________
Comparative (conventional) Examples 140.28 58.0 81.4 500-900
1200-4300 3-5 32-33 110-130 50.00 61.5 97.4 130.50 67.3 87.7
500-1000 1100-4500 3-5 32-33 110-130 55.50 63.3 97.4 Example 1 of
the Invention 148.50 69.5 103.2 500 1400-2000 0.3 32 120 68.00 65.8
97.4 151.40 69.2 104.8 500 1500-1800 0.3 32 120 68.00 64.9 97.5
__________________________________________________________________________
* % Total solids
Reference to Table I clearly shows a number of significant
advantages due to the practice of the invention. Although exactly
the same mill was employed for all examples, except for the use of
the instrumentation of the invention, the following benefits of the
invention are clearly realized:
1. the amount of ore, i.e., the rate of feed, that can be put
through the mill is far greater;
2. the amount of quebracho (suppressant) required was steady;
3. the amount of soda ash was controlled within narrower
limits;
4. the amount of oleic acid (collector agent) required was
less;
5. the temperature in the conditioner was held more steady;
6. the percent of CaF.sub.2 product (of the same purity) recovered,
based upon the CaF.sub.2 available in the ore, was considerably
higher. (It is estimated that 1 percent greater recovery has a
money value of about $500 per 100 tons of ore processed).
Although not specifically shown on the table, operation according
to the invention was much more steady: the pH reading fluctuated
over a much narrower range; the rate of ore feed and the periodic
analyses of the recovered product showed less variation. The
elimination of the man hours required for sampling the slurry and
taking the pH and density by conventional methods released
operators for other duties.
The percent of SiO.sub.2 and CaCO.sub.3 in the CaF.sub.2 product
were less than in that produced conventionally.
EXAMPLE 2
Shortly after the optimizer-density probe assembly of the invention
had been installed, calibrated, and conditions stabilized, it was
employed to guide and control a production size operation for 24
hours. The analysis of the ore being processed showed 76.80 percent
CaF.sub.2, 12.0 percent CaCO.sub.3, 7.68 percent SiO.sub.2 and
about 1,000 ppm Be. Simultaneously with the practice of the
invention, the slurry in process was sampled, the pH value and
D.sub.1 and D.sub.2 density values obtained according to
conventional procedures, and indicated changes that normally would
have been made (but in fact were not) recorded every hour. The pH
values, D'.sub.1, D'.sub.2 and hence D'.sub.1 less D'.sub.2 were
automatically regulated in accordance with the invention. (Note
that D.sub.1 is taken in conditioner 22 and D.sub.2 in cell C-8;
D'.sub.1 is taken in cell C-1 and D'.sub.2 in cell C-8).
The optimizer through its peak-seeking principle continued to
change the rate of addition of the soda ash solution at
pre-selected intervals of siz minutes, increasing the rate of flow
thereof so long as the density differential increased, but when
such increase in flow of soda ash ceased to increase the density
differential, reversing direction and decreasing the rate of flow
of soda ash so long as the density differential was not decreased
by such decreased flow.
The percent CaF.sub.2 recovery, based on the CaF.sub.2 content of
the ore, is directly related to the D.sub.1 less D.sub.2 value and
is calculated by D.sub.1 -D.sub.2 /D.sub.1.
The production unit was started at 8 a.m. and continued until 8
a.m. of the following morning, following the method of the
invention. Manual tests were taken regularly and calculations made
based thereon but such tests were not used to control the
operation.
TABLE II ______________________________________ Percent CaF.sub.2
Product Recovered Based on CaF.sub.2 Content of Ore Actual pH
Values Calculated Recovery From Recovery if Based on Optimizer-
Operation Optimizer Density Had been Density Manually Probe Guided
by Probe Time Taken Control Manual Tests Control
______________________________________ A.M. 8 9.7 9.35 52.2 59.6 9
9.4 9.35 64.2 72.6 10 9.5 9.35 60.8 68.5 11 9.3 9.30 64.2 70.3 12
9.2 9.30 74.0 71.6 P.M. 1 9.3 9.25 63.6 67.4 2 9.5 9.30 79.6 69.6 3
9.4 9.25 61.6 69.2 4 9.2 9.20 55.6 66.6 5 9.2 9.25 47.2 52.8 6 9.3
9.30 59.4 70.4 7 9.3 9.35 66.6 72.8 8 9.3 9.35 65.3 69.2 9 9.3 9.35
65.3 67.0 10 9.4 9.35 65.3 69.2 11 9.1 9.40 66.0 64.0 12 9.5 9.40
66.0 70.0 A.M. 1 9.3 9.40 64.0 70.0 2 9.5 9.40 65.0 65.8 3 9.5 9.40
55.6 65.0 4 9.3 9.40 63.2 69.8 5 9.3 9.40 63.0 70.4 6 9.4 9.40 60.6
69.6 7 9.5 9.40 60.0 78.0
______________________________________
Reference to Table II evinces convincingly the more reliable
control promptly and effectively made by the practice of the
invention.
Below is a summary showing the real recovery according to the
invention and the recovery that would have been made had
conventional practices been followed, i.e., had the manual sampling
and the pH and density values which were thereby obtained been used
to adjust the rate of flow of ore, water, and soda ash solution.
The summary shows the superior performance of the method of the
invention employing the required apparatus of the invention.
______________________________________ Average Per Cent Recovery
Manual Optimizer-Density Shifts Operation Cell Control
______________________________________ 8 a.m. to 4 p.m. 65.0% 68.6%
4 p.m. to 12 p.m. 61.3% 66.5% 12 p.m. to 8 a.m. 63.5% 69.8%
______________________________________
This increased recovery was achieved at a much higher ore
through-put than conventional control would have permitted.
The above figures show that the more accurate density readings and
the prompt changes in soda ash solution flow according to the
invention make possible a more efficient operation. Of particular
significance were the erratic density values obtained when the
samples were manually tested. Had changes been made based thereon,
compared to the relatively steady consistent density values
obtained according to the invention, the lower percent recovery
would have followed.
* * * * *