U.S. patent number 3,833,951 [Application Number 05/347,036] was granted by the patent office on 1974-09-10 for cigarette burn resistant mattresses having aluminized polyurethane foam layer.
This patent grant is currently assigned to Rohm and Haas Company. Invention is credited to Melvin D. Hurwitz.
United States Patent |
3,833,951 |
Hurwitz |
September 10, 1974 |
CIGARETTE BURN RESISTANT MATTRESSES HAVING ALUMINIZED POLYURETHANE
FOAM LAYER
Abstract
This invention is concerned with flameproofed mattresses,
pillows and sleeping bags, pads, cushions for chair or sofas, and
so on. The flameproofed materials of the present invention may be
formed of (1) a close-woven fabric attached to (2) a thick layer
(e.g., 0.1-1 inch) of resilient self-extinguishing polyruethane
cushioning foam having (3) a metallized heat-conductive layer, such
as of aluminum, which dissipates heat rapidly, thereupon, the
metallized foam being secured to (4) filling or padding with (5) a
backing fabric secured thereto. The parts are suitably locally
secured together by tying means such as stitching, tufting,
dielectric welding or the like. The object is to protect the main
body of highly combustible filler material in cushions, pillows,
mattresses, sofas, upholstered chairs, and the like from fire in
case of the dropping of a match, cigarette, or the like on the
cover fabric or ticking by someone, such as a careless smoker. Even
though the foam is self-extinguishing relative to a lighted
cigarette, when not compressed, when it is compressed by tying as
by stitching, the heat may be conducted therethrough and ignite the
filling or stuffing, if no metal layer is present.
Inventors: |
Hurwitz; Melvin D.
(Southampton, PA) |
Assignee: |
Rohm and Haas Company
(Philadelphia, PA)
|
Family
ID: |
23362063 |
Appl.
No.: |
05/347,036 |
Filed: |
April 2, 1973 |
Current U.S.
Class: |
5/698; 297/5;
297/DIG.5; 428/171; 428/920; 428/162; 428/319.1; 428/921 |
Current CPC
Class: |
D06M
23/18 (20130101); B32B 5/26 (20130101); B32B
5/245 (20130101); A47C 27/22 (20130101); B32B
5/024 (20130101); D06Q 1/04 (20130101); B32B
5/18 (20130101); B32B 27/12 (20130101); B32B
2305/188 (20130101); B32B 2601/00 (20130101); B32B
2266/0278 (20130101); B32B 2305/022 (20130101); B32B
2307/3065 (20130101); Y10T 428/24529 (20150115); B32B
2255/102 (20130101); B32B 2255/205 (20130101); B32B
2038/008 (20130101); Y10S 428/921 (20130101); Y10T
428/24999 (20150401); Y10S 297/05 (20130101); Y10T
428/24603 (20150115); Y10S 428/92 (20130101); B32B
2375/00 (20130101) |
Current International
Class: |
A47C
27/22 (20060101); D06M 23/00 (20060101); D06Q
1/04 (20060101); D06Q 1/00 (20060101); D06M
23/18 (20060101); B44d 005/00 (); B44d 001/36 ();
C09k 003/28 (); A47c 027/22 () |
Field of
Search: |
;5/345,355 ;297/DIG.5
;117/136,137 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Nunberg; Casmir A.
Attorney, Agent or Firm: Strobaugh; Terence P.
Claims
I claim:
1. A mattress, pad, or the like comprising a lightweight woven or a
damask fabric, a soft, flexible layer secured thereto formed of a
resilient, self-extinguishing plastic heat-insulating and
cushioning foam of about 0.1 to 1.0 inch in thickness, and a
metal-containing coating on the resilient foam layer, the metal
content of which serves to conduct heat rapidly away from any point
to which heat is applied, said metal-coated foam being adjacent a
combustible padding or filling body, in turn lying upon a fabric
backing, all of the recited elements being secured to one another
by tying means which locally compress said cushioning foam thus
diminishing its heat insulating properties at said compressed
locations, whereby heat from a heat source at the ignition
temperature of the padding or filling which is applied to said
compressed locations is dissipated by said metal-containing
layer.
2. An article according to claim 1 in which the cushioning foam is
a polyurethane foam.
3. An article according to claim 1 in which the metal-containing
layer comprises crushed foam.
4. An article according to claim 1 in which the thickness of the
metal-containing coating is from 0.5 to 6 mils.
5. An article according to claim 2 in which the metal in the
metal-containing layer is selected from the group consisting of
aluminum, nickel, silver, bismuth, antimony, tin, gold, stainless
steel, brass, bronze and Wood's metal.
6. An article according to claim 5 in which the metal is aluminum
having a particle size in the range of 0.02 to 0.1 mm. in an
organic binder.
7. An article according to claim 6 in which the metal is anodized
aluminum.
8. An article according to claim 5 in which the metal is stainless
steel having a particle size in the range of 0.02 to 0.1 mm. in an
organic binder.
9. An article according to claim 5 in which the metal-containing
layer is adhered to said cushioning foam on the side thereof which
is adjacent to the filling or padding and in which said latter
material is formed of combustible fibers.
Description
DESCRIPTION OF THE INVENTION
It has heretofore been the practice in making ironing board covers
to apply a coating of metal particles, such as of aluminum, to the
face or back of the cover to provide rapid dissipation of heat.
However, ticking fabric materials are in general, relatively thin
and generally have a printed decorative design on the exposed face.
Consequently, the placing of a metal-particle-containing layer
directly on the face would obscure the design and if it were placed
on the back or inside surface of the ticking fabric, it results in
an undesirable appearance of the coated ticking because the metal
layer is visible to observers as they look at the outside of the
covered article, such as a mattress, the effect observed being
commonly referred to as "grin-through." In addition, the
metal-coated covering fabric is stiffened detrimentally.
Polyurethane foam cushioning layers between mattress ticking and
the stuffing or padding thereof is commonly used to serve as a
self-extinguishing and insulating layer between the ticking and the
stuffing for the purpose of preventing accidental ignition of the
mattress. It has been found by applicant, however, that in areas
where the polyurethane foam is compressed to a minor fraction of
its original thickness, for example, reduced in thickness from 1/2
or 5/8 inch to 1/8 or 1/16 inch or less by tying means such as
stiching or tufting, the insulating properties of the polyurethane
foam are reduced or lost, and a lighted cigarette placed on that
compressed area will often cause ignition of the cotton or other
stuffing underlying the polyurethane foam layer causing a
smoldering fire.
The present invention compensates for this deficiency by providing,
particularly in localized areas such as edges or tufted or stitched
areas where the foam is compressed, a heat conductive layer of
metallic material, usually powdered or flaked metal held together
by a binder, whereby the heat in the areas of compression of the
foam, that would otherwise be conducted to the flammable material,
is conducted away by the metal. The metal coating may be either on
the face of the foam adjacent to the ticking or on the face
adjacent to the stuffing, preferably the latter in order to prevent
"grinning" of the metal through the ticking. The ticking may be of
damask or a loosely woven rayon fabric, either having a decorative
design thereon by printing or by weaving.
The drawings illustrate the invention.
FIG. 1 shows a damask or rayon ticking 1 attached to a polyurethane
cushioning foam layer 2, in turn bearing a metallized coating 3.
The ticking and metallized polyurethane foam are secured to the
stuffing 4 by tying means such as stitching or tufting 6 through
the respective layers including a fabric backing 5 such as
muslin.
FIG. 2 illustrates essentially the same structure except that the
metallized coating 3a is on the surface of the polyurethane layer
adjacent the ticking, rather than on that surface adjacent the
stuffing. The cushioning foam is suitably about 0.1 to 1.0 inch in
thickness with a density of about 0.25 to 10 pounds per cubic
foot.
The composite of the present invention prevents burning of the
fibrous filler body of pads, cushions, pillows, mattresses, sofas,
and the like when a lighted cigarette or match comes into contact
with the cover fabric or ticking enclosing the fibrous filling
material, especially at areas where the foam is locally compressed
by tying means such as tufting or stitching to a small fraction of
its normal thickness such that the self-extinguishing properties
and insulating properties are adversely affected to an extent which
would permit ignition of the fibrous filling, absent said metal.
The lighted object may cause smoldering or burning of a small area
in direct contact with the burning segment of a cigarette, match,
or the like, but the combustion of this small area quickly brings
the metal coating into play and, as a consequence, the heat in that
small area is quickly dissipated by the metal layer, rapidly
bringing the burning or smoldering items or segments down in
temperature so that they themselves are extinguished and preventing
the rise in temperature of the highly combustible fibrous filling
material to the temperature of ignition or combustion.
The thickness of the metal coating or layer may be from about 1/2
to 6 mils, preferably 2 to 4 mils. The metal in the coating may be
a powdered metal the particles being bonded together by an organic
binder preferably of a combustion-resistant material, or the metal
may be applied by a chemical plating or an electroplating process
wherein no organic binder is used. Again, the metal may be applied
by a sputtering process or by a vacuum metallizing process wherein
a small amount of metal is vaporized in a vacuum within which the
crushed foam/ticking laminate is either disposed with the ticking
surface as well as the crushed foam surface exposed or disposed
with a removable protective film, e.g., of polyethylene, against
the front face of the ticking to prevent its being coated by the
metal, the protective film being removed after the metallizing
operation, if desired. A wide variety of metals may be used, such
as aluminum, nickel, silver, bismuth, antimony, tin, gold, and
alloys, such as stainless steel, brass, bronze, solder, woods,
metal, etc. At present aluminum is preferred.
When the metal is deposited by applying a coating composition
comprising the metal particles in a polymeric binder, the
proportion of metal should be at least about 25 percent by weight
of the binder, and preferably is at least 40 to 50 percent or more
by weight thereof. The amount of the metal-containing coating is
from about 0.5 to 4 oz./sq. yard and preferably 1 to 2 oz./sq.
yard.
The metal layer may be continuous or it may also be in the form of
a foamed or a crushed foam layer wherein it is somewhat
discontinuous, but has the advantage of being more or less
permeable, i.e., it has the quality of breathability, which makes
it more comfortable to a person sitting or lying upon the pad,
cushion, mattress, or the like, especially in hot weather.
When the metal layer is formed from a metal powder/binder
composition, the binder used should be of a flame-resistant
polymer, such as a polymer of vinyl chloride, vinylidene chloride,
or other halogen-containing vinyl monomer. Regardless of what type
of polymer is used, it should be one that is of flexible, rather
than stiff, nature.
Preferred compositions are those based on aqueous dispersions of
emulsion copolymers of monoethylenically unsaturated monomers
having a group of the formula ##SPC1##
including vinyl monomers, especially of vinyl chloride, vinylidene
chloride or mixtures thereof. Since the monomers produce hard and
rigid homopolymers, they are copolymerized with monomers which,
when homopolymerized produce polymers which are soft and flexible.
Examples of the latter type of monomer are ethylene, ethyl
acrylate, butyl acrylate, 2-ethylhexyl acrylate which are included
in the general class of acrylic acid esters of alcohols having 1 to
18 or more carbon atoms and amyl methacrylate, 2-ethylhexyl
methacrylate and octadecyl methacrylate which are included in the
general class of methacrylic acid esters of alcohols having 5 to 18
carbon atoms. The copolymers may also include appreciable amounts
of other hardening monomers, such as styrene, vinyltoluene,
acrylonitrile, and vinyl acetate provided the particular softening
monomer in the amount thereof used is able to provide the desired
flexibility for the particular laminated covering material in its
intended use without requiring a reduction of the halogenated
monomer to such an extent as to make the binder of the metal layer
too susceptible to combustion. The copolymer may also comprise
small amounts (0.1 to 2 percent by weight) of an acid such as
acrylic acid, methacrylic acid, and itaconic acid, to provide
improved stability of the emulsion polymer and ease of thickening
by adjustment of pH of the system. Small amounts (0.5 to 5 percent
by weight) of other reactive monomers may be included to provide
self-crosslinking properties to the copolymer and/or to favor
reaction of the metal layer binder with the intermediate foam layer
and thereby provide chemical bonding and the advantages of this
type of adhesion between the metal layer and the intermediate foam
layer.
The amount of powdered metal in such compositions should be at
least about 20 percent by weight, based on the total solids weight
of the composition, and is preferably 40 to 50 percent or more by
weight of the total solids.
The dry weight of the powdered metal-containing coating layer
should be in the range of 0.5 to 4 ounces per square yard, per
coating, using a single or double coating. The metal particles may
have a wide range of sizes. Metal particles of sizes in the range
of 0.02 to 0.1 mm., preferably 0.03 to 0.05, are quite practical.
The selection of size is made to assure extensive contact between
the metal particles to provide for rapid conduction of heat from
one area to another in the coating.
In the metal coatings obtained by chemical or electrical plating,
by sputtering, or by vacuum metallization, it is only necessary to
provide adequate weight of metal deposit to obtain essential
continuity of the metal coating film deposited, but much heavier
thicknesses of the metal are permissible. Generally, a metal
deposit of about 0.1 ounce of more, e.g., to 0.5 oz./sq. yard is
adequate. In this situation, the upper limit of thickness or weight
of metal is determined by the amount of flexibility necessary in
the particular use. While a metal foil may be used, it is
preferable to avoid it because of the tendency to develop a
crackling noise when the composite cover fabric is flexed.
The present invention is applicable to provide a wide variety of
materials adapted to serve as pads, sleeping bags, mattresses,
pillows, cushions, upholstered chairs, beds, sofas, and so
forth.
In the following examples, which are illustrative of the invention,
parts and percentages are by weight and temperatures are .degree.F.
unless otherwise specified.
EXAMPLE 1
a. An aluminum powder (25 parts) containing metal particles of
about 0.02 to 0.04 mm. size is mixed with 100 parts of a 46 percent
solids aqueous dispersion of an 80/20 weight ratio mixture of (1)
an emulsion copolymer of about 66 vinylidene chloride, 29 percent
butyl acrylate, 0.5 percent itaconic acid, about 3 percent
acrylamide, and about 2 percent N-methylolacrylamide, and (2) an
emulsion copolymer of about 96 percent of butyl acrylate, 2 percent
of methacrylamide and 2 percent of N-methylolacrylamide, 2 parts of
methylene-bis-diamylphenoxypoly(9)ethoxyethanol, 8 parts of a 25
percent aqueous solution of diammonium hydrogen phosphate, 15 parts
of a 50 percent aqueous solution of a copolymer of about 60 percent
ethyl acrylate, 39.5 percent methyl methacrylate and about 0.5
percent of diallyl phthalate, and 42.5 parts of water. The mixture
is thoroughly stirred, yielding a 40 percent solids coating
composition.
b. The resulting 40 percent solids composition obtained in part (a)
is coated onto the exposed surface of an uncompressed, resilient
polyurethane foam to provide a 6-mil thick layer thereon. The
coated assemblage is then dried 4 minutes at 280.degree.F.,
yielding a deposit of about 2 oz./sq. yard.
c. A simulated mattress for testing purposes is made by placing a
piece of cotton wadding (such as is used as mattress stuffing) 6
inches wide 15 inches long and 4 inches thick in the center of an
80.sup.2 cotton ticking fabric 12 inches wide by 15 inches long so
that the 15-inch dimensions of the wadding and the fabric extend in
the same direction. Then a 12-inch by 15-inch piece of the
polyurethane foam cover fabric is laid on top of the batting with
its 12-inch and 15-inch dimensions coinciding with the
corresponding dimensions of the bottom fabric layer and with its
metal-coated face in contact with the wadding, followed by an
overlay of damask ticking. The two fabrics are sewn together along
the 15-inch edges of the wadding to compress the wadding and the
foam along the edges. Also, the wadding and foam are compressed
along a central line parallel to the sewn edges by sewing the
assemblage together along such central line. The resulting
simulated pad or mattress may then, if desired, be stretched taut
by fastening the extended edges of one or both cotton fabrics to
opposite sides of a square frame having a square opening within the
four edge members thereof. The resulting pad has a trough formed by
the central sewn line between two parallel bulged ridges one on
each side of the central line. For testing, a burning cigarette is
placed on the pad, either on top of one of the ridges, but
preferably in the groove between them. The cigarette is allowed to
burn itself out; if the wadding ignites, the ticking is a failure
but if the wadding does not ignite before the cigarette burns out,
the ticking passes the test.
d. The simulated mattress obtained above, when tested in the
fashion described in part (c) hereof, passes the test.
EXAMPLE 2
The procedure of Example 1 is repeated except that in part (a)
thereof, the metal-containing composition is modified by inclusion
of a foam stabilizer or agent, specifically a mixture of about 4.3
parts of a 33 percent aqueous solution of ammonium stearate and 1.4
parts of a 33 percent aqueous solution of sodium lauryl sulfate.
The mixture is beaten into a foam which is spread on the surface of
the polyurethane foam to provide a thickness of about 60 mils and
after drying for 2 minutes at 280.degree. F., the composite is
passed through squeeze rolls of a textile pad to crush the foamed
metal-containing layer after which curing is completed by heating 4
minutes at 280.degree. F., yielding a composite material in which
the metal-containing coating is present in an amount of about 3.5
oz./sq. yard. This metal-coated resilient polyurethane foam, when
made into a simulated mattress, passes the test described in
Example 1 (d).
EXAMPLE 3
Example 1 is repeated except in part (a) thereof the aqueous
dispersion is a 90/10 weight ratio mixture of (1) an emulsion
copolymer of about 69 percent vinyl chloride, 29 percent butyl
acrylate, 1 percent methylolacrylamide, 1/2 percent acrylamide and
1/2 percent itaconic acid and (2) an emulsion copolymer of about 96
percent butyl acrylate, 2 percent methacrylamide and 2 percent
methylolmethacrylamide.
EXAMPLE 4
The process of Example 1 is carried out except that in part (a) the
aluminum powder is replaced with 23 parts of stainless steel
powder, the particles of which range in size from 0.05 to 0.1 mm.
The simulated mattress passes the test.
EXAMPLE 5
The process of Example 1 is carried out except that in part (a) the
aluminum powder is replaced with 23 parts of silver powder, the
particles of which range in size from 0.03 to 0.07 mm. The
simulated mattress passes the test.
EXAMPLE 6
The process of Example 1 is carried out except that in part (a) the
aluminum powder is replaced with 23 parts of nickel powder, the
particles of which range in size from 0.03 to 0.06 mm. The
simulated mattress passes the test.
EXAMPLE 7
The process of Example 1 is carried out except that in part (a) the
aluminum powder is replaced with 23 parts of tin powder, the
particles of which range in size from 0.02 to 0.04 mm. The
simulated mattress passes the test.
EXAMPLE 8
The process of Example 1 is carried out except that in part (a) the
aluminum powder is replaced with 23 parts of anodized aluminum
powder, the particles of which range in size from 0.02 to 0.04 mm.
The simulated mattress passes the test.
EXAMPLE 9
The process of Example 1 is carried out except that in part (a) the
aluminum powder is replaced with 23 parts of bronze powder, the
particles of which range in size from 0.03 to 0.7 mm. The simulated
mattress passes the test.
While self-extinguishing polyurethane foamed plastic has been
specified, other foamed plastics having the desired cushioning,
heat insulating, and self-extinguishing properties may serve as the
functional equivalent thereof.
The term "self-extinguishing" as applied to plastic foams herein is
intended to include ordinary polyurethane foams which, because of
their uncompressed condition and porosity, will not become ignited
by a lighted match or cigarette. Also included are chemically
treated foams which will not ignite or continue to smolder when
exposed to a blowtorch flame.
* * * * *