U.S. patent number 3,830,173 [Application Number 05/213,140] was granted by the patent office on 1974-08-20 for tuyere formed by cementing a ceramic liner in a metal tube.
This patent grant is currently assigned to United States Steel Corporation. Invention is credited to David Henry Hubble, Joseph George Yount, Jr..
United States Patent |
3,830,173 |
Hubble , et al. |
August 20, 1974 |
**Please see images for:
( Certificate of Correction ) ** |
TUYERE FORMED BY CEMENTING A CERAMIC LINER IN A METAL TUBE
Abstract
A method of bonding a high density, low-porosity,
abrasion-resistant, ceramic liner in a metal tube, such as a tuyere
or an oxygen lance. The method comprises applying a sodium
silicate-refractory aggregate cement to one of the surfaces to be
joined, and inserting the liner in the tube. The cement need not be
dried, as it does not run. Therefore, the tube can be used
immediately, even in high-temperature applications.
Inventors: |
Hubble; David Henry (Franklin,
PA), Yount, Jr.; Joseph George (Plum Boros, PA) |
Assignee: |
United States Steel Corporation
(Pittsburgh, PA)
|
Family
ID: |
22793884 |
Appl.
No.: |
05/213,140 |
Filed: |
December 28, 1971 |
Current U.S.
Class: |
138/114;
118/DIG.10; 118/105; 138/145; 156/294; 266/222; 428/34.6; 106/313;
138/141; 138/146; 156/325; 266/267 |
Current CPC
Class: |
C23C
24/00 (20130101); C04B 28/26 (20130101); C04B
14/303 (20130101); C04B 35/10 (20130101); C04B
18/023 (20130101); C04B 14/10 (20130101); F16L
9/14 (20130101); Y10S 118/10 (20130101); Y10T
428/1317 (20150115) |
Current International
Class: |
C04B
28/26 (20060101); C04B 28/00 (20060101); C23C
24/00 (20060101); C04B 35/10 (20060101); F23l
005/00 (); F16l 009/14 (); C21b 007/16 () |
Field of
Search: |
;106/84,313,38.27,38.3
;138/145,146,141 ;118/105,DIG.10 ;161/207 ;266/34L,41 ;110/182.5
;156/325,294 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Van Horn; Charles E.
Assistant Examiner: Dawson; Robert A.
Attorney, Agent or Firm: Dougherty; Ralph H.
Claims
We claim:
1. A composite tube comprising a metal tube, a high-density,
low-porosity, abrasion-resistant ceramic tube substantially
concentric with said metal tube, a refractory cement layer between
said tubes bonding said tubes together, said cement consisting
essentially by weight of:
about 1 to 10 percent of water-soluble alkali metal silicate
mixture having an alkali metal oxide content of about 19 to 51
percent and a silica content of about 24 to 80 percent, balance
water of crystallization and incidental impurities; and
about 90 to 99 percent of an alumina-silica refractory aggregate
which has a particle size of about -20 mesh and is selected from
the group consisting of calcined clay, raw clay, kyanite, mullite,
bauxite, alumina and mixtures thereof.
2. A composite tube according to claim 1 wherein said metal tube is
steel.
3. A composite tube according to claim 1 wherein said metal tube is
stainless steel.
4. A composite tube according to claim 1 wherein said metal tube is
copper.
5. A composite tube according to claim 1 wherein said ceramic tube
is alumina.
6. A composite tube according to claim 1 wherein said ceramic tube
is mullite.
7. A composite tube according to claim 1 wherein said alkali metal
is sodium.
8. A composite tube according to claim 7 wherein said sodium
silicate mixture has a sodium oxide content of from 22 to 32
percent and a silica content of from 50 to 60 percent.
9. A composite tube according to claim 7 wherein said cement
consists essentially of about 3 to 6 percent of said sodium
silicate mixture and about 94 to 97 percent of said refractory
aggregate.
10. A composite tube according to claim 7 wherein the particle size
of said refractory aggregate is -100 mesh.
11. A tuyere comprising:
a composite tube according to claim 1,
an outer tube surrounding said composite tube and forming an
annular space therebetween, and
spacing means between said tubes to maintain said tubes in
substantially concentric relation.
12. A tuyere according to claim 11 wherein said outer tube is
steel.
13. A tuyere according to claim 11 wherein said outer tube is
stainless steel.
14. A tuyere according to claim 11, wherein said outer tube is
copper.
Description
In bottom blown oxygen steelmaking processes, dual concentric
tuyeres are often installed in a removable bottom which is then
installed in a furnace prior to charging of a heat. The inner and
outer tubes of the tuyere are usually made of stainless steel, but
can be made from a number of other materials such as ordinary
carbon steel, special alloy steels or even copper. Oxygen is
injected into the steelmaking furnace through the central tube of
the tuyere, and a jacket gas, which can be an inert gas such as
argon or nitrogen or a hydrocarbon such as propane, butane, methane
or natural gas is injected through the annular space formed by the
central and outer tubes. When lime or other flux is to be injected
with the oxygen, either in a bottom blown or a top blown process,
it is desirable to provide a ceramic liner to prevent erosion of
the central tube by granular particles of flux.
Such flux particles are entrained in oxygen and are blown either
into the bath of molten metal through a tuyere in a bottom blown
converter or onto the surface of the bath through an oxygen lance
in a top blown converter. The term "tuyere" is used in this
specification to mean "tuyere or lance." These flux particles can
cause early erosion of the tuyere. It is, therefore, desirable to
include a liner of a low-porosity, high-density, abrasion-resistant
ceramic material within the tuyere.
Heretofore, in bottoms manufactured for the bottom blown oxygen
steelmaking process, an alumina tube has been installed in the
metal tube of the tuyere and bonded thereto with a colloidal silica
adhesive. Use of this adhesive necessitated placing the colloidal
silica under pressure. Further, the adhesive must have been
completely dried before the tuyere was used. If the adhesive was
not completely dried, this adhesive, which is a flowable material,
would flow from between the ceramic liner and the metal tube,
leaving the ceramic liner free to be blown into the furnace when
the oxygen was turned on.
We have invented a method of cementing ceramic liners in metal
tubes, which avoids the problems that were attendant with the prior
method.
It is an object of our invention to provide a method of cementing
ceramic liners in tuyeres after the tuyeres have been installed in
a furnace bottom and the bottom has itself been installed in the
furnace, and the parts are at a relatively high temperature.
It is also an object to provide a method of cementing ceramic
liners in tuyeres which does not require drying the cement mixture
prior to use of the tuyere.
It is a further object of our invention to provide a method of
cementing ceramic liners in tuyeres that will enable the tuyere to
be used immediately after the liner is installed.
It is another object to provide a method of cementing ceramic
liners in tuyeres that does not require any special equipment,
either to handle the cement or to dry the cement after it is
applied.
These and other objects will become more apparent by reference to
the following detailed specification and the appended drawing in
which:
FIG. 1 is a longitudinal sectional view of a dual concentric tuyere
taken along line I--I of FIG. 2.
FIG. 2 is a cross-sectional view of a dual concentric tuyere having
a ceramic liner in the central tube of the tuyere, taken along line
II--II of FIG. 1.
The drawings show a dual concentric tuyere which comprises a
stainless steel outer tube 10 having nipples 12 which act as
spacers, and stainless steel inner tube 13. The inner tube has a
ceramic liner 14 of a low porosity, abrasion resistant ceramic
material, such as alumina or mullite. These materials have a very
low porosity approaching zero. The liner is held in tube 12 by a
layer of cement 16.
We prepare a cement which by weight consists essentially of about 1
to 10 percent alkali metal silicate mixture and 90 to 99 percent
refractory aggregate. The preferred range of alkali metal silicate
is from 3 to 6 percent, the balance being refractory aggregate. The
preferred alkali metal silicate is sodium silicate, although we can
use lithium or potassium silicate. In the example of sodium
silicate, the sodium oxide content by weight may be in the range of
about 19 to 51 percent, and the silica content about 24 to 80
percent, the balance water of crystallization and incidental
impurities. The preferred range is about 22 to 32 percent sodium
oxide and 50 to 60 percent silica, and the optimum about 27 percent
sodium oxide and 55 percent silica. The sodium silicate is water
soluble, and it may be either in powdered or liquid form, i.e.,
water glass. The sodium silicate is mixed with an alumina-silica
refractory aggregate, such as calcined clay, raw clay, kyanite,
mullite, bauxite, alumina, and mixtures thereof. The aggregate
should have a thermal expansion that approximates that of the
ceramic liner. The particle size of the refractory aggregate must
be -20 mesh and preferably will be -100 mesh. Next we add
sufficient water to sodium silicate - refractory aggregate cement
to obtain a trowelable consistency. The percentages of sodium
silicate and aggregate are on a water free basis, that is, are
measured prior to adding water to obtain a trowelable
consistency.
Ceramic liner 14 is installed in tube 12 by applying an excess of
the prepared cement to one of the two surfaces to be joined, that
is, to the exterior surface of the ceramic liner or to the interior
surface of the metal tube. The ceramic liner is then inserted into
the tube in a manner to effect substantially complete contact of
the cement with both of the surfaces being joined. We have found
that insertion with a rotary motion will effect such substantially
complete contact. The consistency of the cement being such that it
does not run, the tuyere may be used immediately after it is
installed in a furnace, or the liner may even be installed in a
tuyere which has already been installed in a furnace, and used
immediately, even at high temperatures. However, inasmuch as there
is no requirement that the tuyere be used immediately, it may first
be dried, if desired.
One of the advantages of our invention is that the external
diameter of the ceramic liner need not be within any particularly
close tolerances. The cement layer can be as thick as or even
thicker than the thickness of the ceramic liner.
It is readily apparent from the foregoing that we have invented a
method of cementing ceramic liners in tuyeres before or after such
tuyeres are installed in a furnace, which method requires neither
special cement handling equipment nor cement drying apparatus, and
which method provides a resulting ceramiclined tuyere that can be
used immediately without drying the cement.
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