U.S. patent number 3,826,226 [Application Number 05/314,490] was granted by the patent office on 1974-07-30 for apparatus for coating particulate material.
Invention is credited to Raymond L. Clark.
United States Patent |
3,826,226 |
Clark |
July 30, 1974 |
APPARATUS FOR COATING PARTICULATE MATERIAL
Abstract
Apparatus and method of depositing controlled thickness coatings
on small particles including a drop tower for gravity feed of the
particles from a first hopper to a second hopper and wherein the
particles are induced to spin during fall and pass through a
vaporized coating medium; said medium comprising an ion beam
directed from an ion emitter disposed laterally offset from, and
shielded with respect to, said drop tower.
Inventors: |
Clark; Raymond L. (Hampton,
VA) |
Family
ID: |
23220170 |
Appl.
No.: |
05/314,490 |
Filed: |
December 12, 1972 |
Current U.S.
Class: |
118/716; 118/726;
118/723VE; 118/722 |
Current CPC
Class: |
C23C
14/223 (20130101); C23C 14/22 (20130101) |
Current International
Class: |
C23C
14/22 (20060101); C23c 013/12 () |
Field of
Search: |
;118/48-49.1 ;117/93.3
;222/414,DIG.1 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Kaplan; Morris
Attorney, Agent or Firm: Osborn; Howard J. Nelson; Wallace
J. Manning; John R.
Claims
What is claimed as new and desired to be secured by Letters Patent
of the United States is:
1. Apparatus for depositing a uniform thickness metallic coating on
granular material comprising:
a. a vertically disposed drop tower;
b. a feed hopper attached to the top of said tower and a hopper
attached to the bottom of said tower;
c. stirring means disposed in said feed hopper to prevent clumping
of the granular material contained therein;
d. an exit valve connecting said feed hopper to said tower and
serving to control the rate of flow of the granular material from
said feed hopper to said tower;
e. means disposed in said tower adjacent said exit valve for
scattering the granular material passing through said valve and to
impart a spinning motion to the individual granules comprising a
rotating drum, said rotating drum having knurled grooves to isolate
individual granules from each other and assist in destroying any
particle clumps that may have passed through said exit valve and
thereby permit the material grains to fall individually through
said coating chamber on the way to said collection hopper;
f. a coating chamber within said tower and substantially
intermediate said feed hopper and said collection hopper, and
g. means connected to said coating chamber to provide a coating
medium for the individual granules as they pass through said
coating chamber comprising an ion beam contained within a separate
Y branch to said drop tower, an ion emitter from which said beam is
directed and optical shielding to shield the ion emitter from the
major portion of said drop tower.
2. Apparatus as in claim 1 wherein said stirring means consist of
an electrically operated stirring mixer.
3. The apparatus of claim 1 wherein said ion emitter includes an
electrically heated high vacuum tungsten filament having
water-cooled electrodes, a bar of the metallic material to be
deposited being driven against said filament by an electric motor
drive mechanism whereby as the deposition bar metal is melted the
filament will be tinned by the deposition material and the
deposited material will thus be present simultaneously in the
solid, liquid and gaseous phases.
4. The apparatus of claim 3 including means for controlling the
rate of deposition material evaporation.
5. The apparatus of claim 1 including a vacuum system in operative
connection with said feeder hopper and said collection hopper
capable of maintaining an operable pressure of at least
10.sup.-.sup.6 mm Hg where linear streaming of the deposition
material occurs in said coating chamber.
6. The apparatus of claim 4 wherein the deposition metal is
selected from the group of metals consisting of gold, copper,
silver, aluminum and indium.
7. The apparatus of claim 4 wherein the granular particles coated
are spherical in shape.
8. The apparatus of claim 7 wherein the spherical particles are
hollow glass spheres having a size of 3 microns to 1/2 inch
diameter.
9. The apparatus of claim 7 wherein the coating chamber is an area
of from 8 to 10 centimeters' length in said drop tower.
10. The apparatus of claim 9 wherein the coating applied to said
glass spheres is approximately 200 angstroms thickness.
Description
ORIGIN OF THE INVENTION
This invention was made by an employee of the National Aeronautics
and Space Administration and may be manufactured and used by or for
the government for governmental purposes without the payment of any
royalties thereon or therefor.
BACKGROUND OF THE INVENTION
This invention is concerned with an apparatus for applying thin
controlled thickness coatings on small particles. Controlled
thickness coatings on many small particles such as glass spheres,
chopped strands of fiberglass, solid granules of propellant fuels,
and the like, have proved of increasing importance in ordnance and
aerospace research projects. For example, metallic coated filled
and hollow glass spheres have been employed in sandwich structures,
ablative shielding compositions, and the like, as filler material
to control the density of the compositions and to alter the other
properties thereof. Similarly, coated propellant fuel granules are
employed in various propellant compositions. Some of the known
processes for applying coatings to small particles have required
increased temperature environments for the coating step and the
thickness of the coating applied has been difficult to adjust with
uniformity and accuracy.
It is therefore an object of the present invention to provide a
novel apparatus for coating small particles with a uniform coating
material.
Another object of the present invention is an apparatus for
applying a fusible coating material to small particles.
Another object of the present invention is to provide an apparatus
for uniformly coating small particles in an ambient temperature
environment.
Another object of the present invention is to provide an apparatus
for applying a uniform fusible coating to small particles under
vacuum conditions.
BRIEF SUMMARY OF THE INVENTION
According to the present invention, the foregoing and other objects
are attained by providing a vertically disposed drop tower having a
feeder hopper at the upper end thereof, a collection hopper at the
lower end and a coating chamber area intermediate the ends of the
tower. The feeder hopper contains a quantity of small granular
particles to be coated and is provided with a valve for releasing
the particles at a controlled rate for free fall through the
coating chamber into the collection hopper. A motor-driven stirrer
serves to break up any clumps of material which may form in the
hopper and provides a steady supply of the granular material at the
bottom of the hopper. A high speed rotating drum having a knurled
surface is provided near the top of the tower and adjacent the exit
valve of the feeder hopper. This drum receives the granular
material exiting the feeder hopper and effectively scatters the
material further destroying particle clumps and allows the material
grains to fall individually through the tower. An additional and
more important purpose of the drum is to impart a spinning motion
to the particles so that they will be completely coated as they
pass through the deposition beam.
An ion beam is contained in a separate Y-branch to the main
apparatus so as to be optically shielded from the coating chamber.
In addition, by positioning the ion emitter a distance from the
coating chamber the coating process is conducted in a relatively
cold environment. The entire drop tower is maintained under a
suitable vacuum during the coating process.
BRIEF DESCRIPTION OF THE DRAWINGS
A more complete appreciation of the invention and many of the
inherent advantages thereof will be more clearly understood by
reference to the following detailed description when considered
with the accompanying drawings wherein:
FIG. 1 is a part sectional, part schematic representation of the
coating apparatus according to the present invention; and
FIG. 2 is a part exploded view of the ion emitter assembly of the
present invention.
DETAILED DESCRIPTION
Referring now to the drawings and more particularly to FIG. 1 there
is shown the coating apparatus of the present invention generally
designated by reference numeral 10. Coating apparatus 10 includes a
vertically disposed drop tower 11 having a feed hopper 13 attached
to the upper end thereof and a collection hopper 15 connected to
the lower end thereof. Feed hopper 13 is adapted to receive a
qUantity of granular material 17 therein that is to be coated in
drop tower 11. A cover 19 is provided for feed hopper 13 and is
attached thereto in hermetically sealed relationship by a plurality
of bolted clamps, one of which is designated by reference numeral
20, in a conventional manner.
Cover 19 is also provided with a vertical extension 21 to serve as
an attachment for a support clamp or the like, not shown, for
stabilizing coating apparatus 10 during a coating operation. A
small electric motor 23 having leads 25 connected to a suitable
current source (not shown) is provided in cover 19 and serves to
rotate a shaft 27 at a controlled rate. A stirring mechanism 29 is
secured to shaft 27 and serves to prevent clumping of the granular
particles 17. In the embodiment illustrated stirring mechanism 29
is in the form of a horizontal bar with a plurality of dependent
spring segments integrally attached thereto. Other conventional
stirring apparatus may be employed as so desired.
An exit valve 31 is disposed at the base of feed hopper 13 and is
manually or other selectively controlled to meter the flow of
granular particles 17 into drop tower 11. As the particles 17 leave
valve 31 they contact a rotating drum 33 and are scattered thereby.
A shaft 35 leading to a suitable electric motor 37 serves to rotate
drum 33 at a controlled speed during a coating operation. Drum 33
is provided with a knurled surface with the knurling grooves being
approximately 100 times as large as the particles 17. The primary
purpose of drum 33 is to scatter the granular material to further
destroy any particle clumps and to impart a spinning motion to the
individual particles so that they will become completely exposed to
the deposition beam as they pass through the coating medium.
A plurality of vacuum ports, two of which are shown in FIG. 1 and
designated by reference numerals 39 and 41, provide further
communication between feed hopper 13 and drop tower 11 to permit
the entire apparatus to be subjected to vacuum conditions by a
suitable vacuum pump as schematically represented by block 42.
Vaccum pump 42 serves to maintain apparatus 10 at a pressure of
approximately 10.sup.-.sup.6 mm Hg where linear streaming of the
deposition material occurs. A suitable ion vacuum gage, not shown,
is built into the apparatus in order to monitor the pressure.
The ion beam is contained in a separate Y-branch 45 to the drop
tower 11 with a suitable optical shielding 46 being provided
thereon to optically shield the ion beam from the main portion of
the tower 11. As a result, the coating material is forced to follow
a longer and more linear path before reaching the area designated
by dotted lines A-B where the grains of material to be coated are
exposed to the ion beam. In addition to providing a more even
coating, this arrangement allows the placement of the hot, emitting
electrode far enough away from the coated particles to preclude
damage to the particles from heat to thus insure that the coating
process takes place in an essentially cold environment.
The filament arrangement shown more particularly in FIG. 2 is
easily adaptable to a continuous, precisely controlled operation.
The ion beam is generated by an electrically heated high vacuum
tungsten filament, designated by reference numeral 49 and connected
between two cooled electrodes designated by reference numerals 51
and 53. The water inlets for electrodes 51 and 53 are designated,
respectively, by reference numerals 55 and 57 while the outlets are
designated, respectively, by reference numerals 58 and 59. A bar of
the material to be deposited is stored on a spool 61 attached to a
dependent bracket 62 extending from cover 63 for the ion beam
container 64. In operation, cover 63 and its attachments are
fastened to container 64 by a plurality of clamps 68.
The bar material 65 passes over a free turning pully 66 and is
threaded through an electric drive motor 67 into a tubular guide 69
leading to the vicinity of filament 49. In operation, the filament
49 is operated by a suitable current source leading through water
inlets 55 and 57 of such intensity as to maintain filament 49 at a
white heat with enough of the deposition bar 65 being melted so
that filament 49 remains tinned by the deposition material. Motor
67 is selectively controlled to insure the deposited bar material
is present adjacent filament 49 in the solid, liquid and gaseous
phases simultaneously. The rate of evaporation of deposition
material 65 is controlled by the temperature of filament 49, which
can be adjusted in a conventional manner to precisely determine the
rate of deposition by adjusting the filament voltage.
Apparatus 10 is normally operated at a pressure of 10.sup.-.sup.6
mm Hg where linear streaming of the deposition material will occur
in branch 45. A suitable ion vacuum gage, not shown, is built into
the apparatus in order to monitor the pressure.
Apparatus 10 described hereinbefore has been used successfully to
deposit a metallic coating on small hollow glass spheres sold under
the trade name of Eccospheres. These glass spheres are available in
a number of sizes ranging from 3 microns to 1,000 microns in
diameter. Solid small particulate material, such as propellant
powder grains, glass balls, shot and the like having diameters of
at least one-half inch may also be coated with the apparatus
described herein. Coatings obtained using the one ion gun shown in
the illustrated embodiment have normally been approximately 200
angstroms thick under conditions where the particles fell through a
beam of 8-10 centimeters long as designated by area A-B in FIG. 1.
Additional ion guns could be readily employed in separate Y
branches where additional thickness is desired. Each gun would
deposit approximately 200 angstroms of coating material or more if
the size of the gun is also scaled up and depending on the
temperature. For example, a larger gun operating at the same
temperature or a gun of the same size operating at a higher
temperature would deposit a thicker coating.
Any suitable and conventional coating material may be employed in
the present invention. As illustrated, metallic bar material having
a diameter range of 0.0002 - 0.030 inches is readily adaptable for
dispensing via spool 61. Metals such as gold, silver, copper and
aluminum are particularly useful with the present invention
although other metals and fusible nonmetals are equally applicable
dependent upon the end use envisioned for the particulate material
to be coated. There are obviously many modifications and variations
of the present invention possible in the light of the above
teachings. It is therefore to be understood that within the scope
of the appended claims, the invention may be practiced otherwise
than as specifically described.
* * * * *