U.S. patent number 3,824,002 [Application Number 05/312,097] was granted by the patent office on 1974-07-16 for alternating current liquid crystal light value.
This patent grant is currently assigned to Hughes Aircraft Company. Invention is credited to Terry D. Beard.
United States Patent |
3,824,002 |
Beard |
July 16, 1974 |
ALTERNATING CURRENT LIQUID CRYSTAL LIGHT VALUE
Abstract
This invention is directed to improved photoactivated liquid
crystal light valves or cells which exhibit extended lifetime. All
electrically conductive elements of the light valve are separated
from the liquid crystal layer by insulating layers. By thus
separating all electrically conductive elements from direct contact
with the liquid crystal layer, the life of the liquid crystal is
significantly extended. To accomplish photoactivation in the
presence of electrical insulating layers, the principle of
impedance matching is applied to the photoconductor/liquid crystal
combination. Three novel means of impedance matching are taught: 1)
photoresponsive heterojunction; 2) low impedance liquid crystal; 3)
metal grid.
Inventors: |
Beard; Terry D. (Westlake
Village, CA) |
Assignee: |
Hughes Aircraft Company (Culver
City, CA)
|
Family
ID: |
23209867 |
Appl.
No.: |
05/312,097 |
Filed: |
December 4, 1972 |
Current U.S.
Class: |
349/29; 250/331;
349/177; 349/30; 349/137; 349/25 |
Current CPC
Class: |
G02F
1/1354 (20130101) |
Current International
Class: |
G02F
1/13 (20060101); G02F 1/135 (20060101); G02f
001/16 () |
Field of
Search: |
;350/16LC ;250/331
;96/1R |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Bauer; Edward S.
Attorney, Agent or Firm: MacAllister; W. H. May; John M.
Claims
What is claimed is:
1. A liquid crystal light valve which is operable by alternating
current and comprises:
a. a nematic liquid crystal layer, said layer having a first face
and a second face;
b. opposite said first face, a first transparent conductive
electrode which is separated from said first face by a transparent
insulating means;
c. a first transparent plate adjacent said first electrode, said
plate forming a first exterior of said light valve;
d. opposite said second face, a second transparent insulating
means, photoresponsive means substantially matching the alternating
current impedance of said liquid crystal layer, a second
transparent conductive electrode, and a second transparent plate
respectively, said second transparent plate forming a second
exterior face of said light valve.
2. A liquid crystal light valve of claim 1 wherein said impedance
matching is achieved by means of a photoresponsive heterojunction
between a layer of a photoconductive semiconductor and a layer of
another semiconductor having a different energy band gap.
3. A liquid crystal light valve of claim 1 wherein said impedance
matching is achieved through said nematic liquid crystal layer
having an impedance at 100 Hz of less than 10.sup.5
.OMEGA./cm.sup.2.
4. A liquid crystal light valve of claim 1 wherein said
photoresponsive means comprises a conductive grid in ohmic contact
with a layer of photoconductive material, said conductive grid
being electrically connected to said first electrode and
essentially equipotential therewith.
5. A liquid crystal light valve which is operable by alternating
current and comprises:
a. a nematic liquid crystal layer, said layer having a first face
and a second face;
b. opposite said first face, a first transparent conductive
electrode which is separated from said first face by a transparent
insulating means;
c. a first transparent plate adjacent said first electrode, said
plate forming a first exterior of said light valve; and
d. opposite said second face, a dielectric mirror, photoresponsive
means comprising a photoresponsive heterojunction between a layer
of photoconductive semiconductor and a layer of another
semiconductor having a different energy band gap, a second
transparent conductive electrode, and a second transparent plate
respectively, said second transparent plate forming a second
exterior face of said light valve.
6. A light valve of claim 5 wherein said first exterior has an
anti-reflective coating.
7. A light valve of claim 5 wherein said dielectric mirror is
backed by means for blocking residual projecting light.
8. A liquid crystal light valve operable by alternating current for
modulating projection light in response to changes in writing
light, said light valve comprising in sequential order:
a. a first glass plate having an antireflective coating and forming
a first exterior of said light valve;
b. a first transparent conductive electrode of tin-doped indium
oxide electrically connected to a first terminal of an alternating
current source;
c. a transparent insulating layer of silicon dioxide;
d. a layer of nematic liquid crystal;
e. a dielectric mirror consisting essentially of alternate layers
of magnesium fluoride MgF and zinc sulfide ZnS;
f. a light-blocking layer of cadmium telluride;
g. a photoconductive layer of cadmium sulfice which forms a
photoresponsive heterojunction with said cadmium telluride
light-blocking layer;
h. a second transparent conductive electrode of tin-doped indium
oxide electrically connected to a second terminal of said
alternating current source;
i. a second transparent plate of glass for forming a second
exterior face of said light valve;
wherein said insulating layer and said dielectric mirror serve
respectively to block the flow of DC current to said liquid
crystal, wherein said dielectric mirror serves to reflect said
projection light through said liquid crystal layer and in
combination with said light-blocking layer serves to block
projection light from said photoconductive layer, and wherein said
photoconductive layer in combination with said light-blocking layer
sufficiently matches the alternating current impedance of said
liquid crystal to permit said projection light to be modulated by
said liquid crystal layer in response to changes in the level of
said writing light impinging on said photoconductive layer and on
said heterojunction.
9. A light valve of claim 8 wherein said first and second
transparent conductive electrodes are electrically connected to the
respective terminals of an alternating current source having a low
frequency component for inducing dynamic scattering in selected
portions of said liquid crystal layer and a high frequency
component for varying the scattering threshold of said liquid
crystal layer.
10. A liquid crystal light valve which is operable by alternating
current and comprises:
a. nematic liquid crystal layer, said layer having a first face and
a second face;
b. opposite said first face, a first transparent conductive
electrode which is separated from said first face by a transparent
insulating means;
c. a first transparent plate adjacent said first electrode, said
plate forming a first exterior of said light valve;
d. opposite said second face, a dielectric mirror, a layer of
photoconductive material having in ohmic contact therewith a
conductive grid, a second transparent conductive electrode, and a
second transparent plate respectively, said second transparent
plate forming a second exterior face of said light valve; and
e. a source of alternating current having a first terminal thereof
connected to said first electrode and to said conductive grid and
having a second terminal thereof connected to said second
electrode.
11. The light valve of claim 10 wherein said alternating current
source provides a low frequency component and a high frequency
component.
Description
BACKGROUND OF THE INVENTION
My invention is in the field of liquid crystal light valves. In
these light valves, an electro-optical property of a liquid
crystal, such a dynamic scattering is varied in accordance with a
writing light and is used to modulate a projection light. Such a
light valve may be used to amplify the imaging light and/or to
effect wavelength conversion. Interest in this area has been
intense in the last several years. Such valves have multiple uses;
for example, in reflective and transmissive projection systems, and
in optical data processing.
A typical light valve of the prior art is disclosed in U.S. Pat.
No. 3,592,527. That valve utilizes DC current with the electrode in
direct contact with the liquid crystal, which adversely effects the
lifetime of the valve. It also uses a mosaic type of mirror, which
limits resolution.
A somewhat different embodiment is disclosed in U.S. Pat. No.
2,892,380. This valve incorporates a dielectric structure -- a
mirror -- and an alternating drive voltage to pass a current
through the dielectric mirror. Although this device incorporates an
insulating film -- the dielectric mirror -- over one electrode, it
does not teach the value of insulating films for extending
lifetime; in fact, it fails to include a second insulating film
over the opposite electrode, which exclusion leads to reduced
lifetime with liquid crystal electro-optic materials. In addition,
it fails to include means for impedance matching the photoconductor
to the electro-optic material and therefore would only be operable
for those combinations of photoconductor and electro-optic material
that are intrinsically impedance matched.
In order to function, a photoconductor activated liquid crystal
light valve must be capable of switching the voltage that drives
the device from the photoconductor to the liquid crystal layer at
the command of the photoactivation signal supplied by an external
writing light. Since the photoactivation signal alters the
impedance of the photoconductor, the device operates by the
principle of impedance match. It must be designed so that the
photoactivation signal swings the impedance of the photoconductor
from a value that was considerably larger than that of the liquid
crystal layer when the photoconductor was dark, to a value that is
considerably less than that of the liquid crystal layer in the
presence of the photoactivation signal. Thus, to make
photoconductor activated light valves operate, it is necessary to
match the impedance of the photoconductor to that of the liquid
crystal layer. In some systems this can be done directly. An
example of such a system is a photoactivated liquid crystal light
consisting of a thin film zinc sulfide photoconductor and a nematic
liquid crystal such as MBBA and operated by direct current. In this
arrangement, the high intrinsic impedance of the zinc sulfide
permits direct match of the photoconductor to standard preparations
of nematic liquid crystal. A system for which this is not true is
one in which the zinc sulfide is replaced by cadmium sulfide, a
photoconductor that is more sensitive than zinc sulfide and one
that exhibits considerable sensitivity in the visible portion of
the spectrum (which zinc sulfide does not, being sensitive
primarily in the ultra violet). In this system the bulk impedance
of the cadmium sulfide is too low to permit acceptable
photoactivation of standard nematic liquid crystals. Fortunately, a
photoactivated, diode-like heterojunction forms at the physical
interface between the liquid crystal. This heterojunction adds
sufficient impedance to the photoconductor to operate the device.
Hence, in this device an artifact is required to make the basic
device operate. In any photoconductor activated liquid crystal
light valve in which the impedance match between the photoconductor
and the liquid crystal layer is not appropriate, an impedance
matching means must be provided.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is an enlarged cross-sectional view through a liquid crystal
light valve of the present invention.
FIG. 2 is a schematic view of a reflective projection system
utilizing a liquid crystal light valve of the present
invention.
FIG. 3 is an enlarged cross-sectional view through a second liquid
crystal light valve of the present invention.
FIG. 4 is a plan view of a grid which may be used in the embodiment
of FIG. 3.
DETAILED DESCRIPTION OF THE INVENTION
This disclosure describes such means for photoconductor activated,
liquid crystal light valves that have been improved to exhibit
extended lifetimes.
The direct current liquid crystal light valve of Pat. No. 3,592,527
exhibits shortened lifetime in large part because it conducts a
non-zero direct current that promotes electrochemical reactions
between the liquid crystal and the material that forms the
electrodes of the device. To alleviate these electrochemical
reactions, a direct course is to employ two dielectric insulating
films, one over each electrode, to separate the liquid crystal from
the electrodes. In this case an alternating voltage source is
required to couple the current through the dielectric layer and
into the liquid crystal. The insulating layers limit device
performance by destroying the heterojunction between the liquid
crystal and the photoconductor and also by presenting an extra
impedance load on the photoconductor modulating element which
further reduces the voltage that is available to be modulated
across the liquid crystal. By my invention improved impedance match
in the presence of the lifetimeextending insulating layers are
provided by one of the following methods.
i. Photoresponsive Heterojunction: A heterojunction structure is
formed between the photoconductor and the light blocking layer
which allows the spatial photomodulation of the capacitive as well
as the forward and backward resistive impedance of the
photoconductor and the photo-diode heterojunction formed therewith;
thus the total AC impedance is also modulated and this provides a
change in voltage across the liquid crystal layer in response to
the light signal.
ii. Low Impedance Liquid Crystal: By the use of liquid crystal
impedances lower than that typically used in the art (10.sup.7 -
18.sup.8 .OMEGA.-cm) an improved impedance match can be obtained
between the impedance found at low frequencies (<10.sup.3 Hz) of
the photoconductor and the liquid crystal. A typical value for this
impedance is 10.sup.5 .OMEGA./cm.sup.2 at 100 Hz whereas typical
liquid crystal devices found in the state of the art have
impedances > 10.sup.6 .OMEGA./cm.sup.2.
iii. The Addition of a Metal Grid: The addition of a metal grid to
the device can also provide improved impedance matching by the
method of controlling the AC electric field penetration into the
liquid crystal layer. This is accomplished by the use of the
photoconductor as a shorting plane in regions where light is
incident while still maintaining high resistivity (and thus AC
field penetration into the liquid crystal) where no imaging light
is incident.
The invention will now be described by reference to the
drawings.
FIG. 1 discloses a reflective light valve of the present invention.
The drawing is greatly enlarged and not necessarily in proportion.
The basic structural support of the light valve is provided by
transparent cover plates 1 and 1a which are preferably made of
glass. Transparent electrodes 2 and 2a are located on the inner
faces of cover plates 1 and 1a, respectively. I have used tin doped
indium oxide with from 100 to 1,000 .OMEGA./sq. resistivity for the
electrodes 2 and 2a. Said electrodes are electrically connected to
alternating current sources through leads 12 and 12a. Insulating
films 3 and 3a are placed on either side of liquid crystal 13 to
provide electrical and chemical isolation between liquid crystal 13
and electrodes 2 and 2a. Liquid crystal 13 being a fluid, spacers 4
and 4a are employed to maintain a suitable gap between insulating
films 3 and 3a and to prevent liquid crystal 13 from escaping.
Positioned on the side of liquid crystal 13 from which writing
light 10 enters the cell are, respectively, dielectric mirror 5
which in my preferred embodiment is backed by a light blocking
layer such as cadmium telluride film 6, and cadmium sulfide
photoconductor 7. Dielectric mirror 5 is an insulating multilayer
structure providing a reflective element; due to its insulating
properties, use of separate insulating film 3a may be avoided.
Dielectric mirror 5 may be made from alternating layers of
transparent materials of high and low optical index of refraction
such as MgF and ZnS. The cadmium telluride film 6 blocks any
residual projection light 9 which might otherwise leak through the
dielectric mirror. It also forms a so-called heterojunction with
the combination of photoconductor 7 and this photo-responsive
heterojunction enhances the spatial modulation of the alternating
current voltage across the cell by both photoconductive and
photocapacitive effects. This heterojunction provides improved
impedance match to the liquid crystal.
When the light valve includes dielectric mirror 5, it is a
reflective unit. If the light valve does not include dielectric
mirror 5 and light blocking layer 6, it is a transmissive unit (not
shown). In the latter configuration, use of insulating film 3a is
essential in order to separate the liquid crystal from electrode
2a.
I have used as photoconductor 7 cadmium sulfide films ranging in
thickness from 2 to 12 microns and have obtained the best results
with 2 micron films. Cadmium sulfide is thermally deposited on a
heated substrate and subsequently baked in an H.sub.2 S atmosphere
to bring about a more nearly stoichiometric film.
Cadmium telluride (CdTe) film 6 is deposited in a vacuum onto a
heated substrate that already contains the cadmium sulfide. A CdTe
film 2.mu. thick is very opaque to light to which cadmium sulfide
is photo-sensitive. It is also sufficiently electrically insulative
to preclude image degradation due to electrical field
spreading.
Dielectric mirror 5 is deposited in a vacuum, using known
deposition techniques. It typically comprises fifteen alternate
layers of ZnS and MgF, which results in an average reflectivity
greater than 90 percent across the visible spectrum.
The insulating layers 3 and 3a, such as silicon dioxide, are also
laid down by commonly used deposition techniques. The thickness
ranges from 1,000 to 5,000 A.
I have found it advisable to put an anti-reflective coating on the
surface of cover plate 1 facing projection light 9. This coating is
typically a 1,000 A film of MgF, and it improves the projected
image contrast ratio.
Liquid crystal 13 may be any of a number of nematic liquid crystals
including MBBA. I prefer those liquid crystals which have very low
resistivity; i.e., 10.sup.7 - 10.sup.8 .OMEGA./cm range. The film
formed by liquid crystal 13 is extremely thin, e.g., 6 to 12
microns. The 6 micron films provide the best response time and
resolution.
FIG. 2 schematically portrays a projection system utilizing a
reflective liquid crystal light valve of the present invention. In
this view, cover plates 1 and 1a and reflective coating 11 are
shown, as well as electrical leads 12 and 12a. The remaining
components of the light valve, such as those shown in FIG. 1, are
grouped in assembly 20. Projecting light 9 emanating from light
source 19 is condensed through condensing lenses 21 and 22 to
reflect off mirror 23. It then passes through projecting lens 24 to
form projecting light 9, which is directed against light valve
assembly 20. Writing light source 26, meanwhile, is projected
through writing lens 25 against the opposite side of light valve
assembly 20. The system is driven with two AC voltages. AC voltage
source 27 provides from 50 to 450 Hz at 20-100V RMS. This low
frequency alternating current provided by source 27 causes dynamic
scattering in liquid crystal 13. The second AC voltage source 28
provides from 10 to 30 KHz. This high frequency voltage improves
the response time.
FIG. 3 is representative of a second liquid crystal light valve of
the present invention. This embodiment illustrates the double
function of dielectric mirror 5 as mirror and insulating means
adjacent liquid crystal 13. It also illustrates the use of grid 31
on one face of photoconductor 7, said grid 31 being separated from
transparent electrode 2a by insulating film 3a. The grid
facilitates impedance matching between the photoconductor and the
liquid crystal.
FIG. 4 is a plan view of grid 31, showing its relationship to
photoconductor 7. Grid 31 is grounded through means 32 to lead 12a.
When photoconductor 7 is off, the AC field passes through
insulating film 3a and activates liquid crystal 13. By turning on
photoconductor 7, the field is short circuited to grid 31, and
liquid crystal 13 is turned off.
I have found that the liquid crystal light valves of the present
invention are more sensitive to writing light at and below 5,150 A.
This is the band edge of the cadmium sulfide film. Useful writing
light power is from 50 to 500 .mu. watt/cm.sup.2 at 5,100 A for
continuous operation. Projection of up to 200 lumen/cm.sup.2 with
these light valves has been achieved without noticeable
interference by the projecting light. In addition, response time of
the light valve varies with operating levels and the composition of
the liquid crystal. Faster response time is achieved by applying
more high frequency voltage and more writing light.
A particularly useful liquid crystal composition for use with the
AC light valves of the present invention is a mixture of
p-methylbenzoic acid p'-n-butylphenyl ester, p-n-butoxybenzoic acid
p'-n-butoxyphenyl ester, p-n-hexoxy-benzoic acid p'-n-butoxyphenyl
ester, p-n-octoxybenzoic acid p'-n-butoxyphenyl ester in a weight
ratio of 4:1:2:2. The mixture was doped with 0.5 percent
hexadecyltrimethylammonium stearate. Such doped mixtures are low
impedance crystals. The benzoic acid esters used in this mixture
are prepared by reacting appropriately substituted benzoic acid
chloride with an appropriately substituted phenol. This reaction is
disclosed in more detail in co-pending application Ser. No.
290,198, filed on Sept. 18, 1972, said co-pending application
having a common assignee with the instant application.
The basic photocapacitive effect noted above in the reference to
the description of the heterojunction formed between the
photoconductor 7 and the light blocking layer 6 is apparently
caused by decreased width of the depletion region, resulting from
the trapping at the heterojunction of "holes" (positive charges)
that have been created by light excitation within the
photoconductor. Obviously, the dark AC impedance of the junction,
averaged over forward and backward polarities, when added to that
of the photoconductor 7, must be great enough to keep the light
crystal below its scattering threshold.
The light valves of the present invention have provided typical
response times of 10 msec turn-on and 30 msec turn-off. Resolutions
with 6 micron liquid crystal film of 50 lines/mm have been
obtained, which equates to 1,250 lines across a typical cell
aperture of 2.5 cm.
* * * * *