U.S. patent number 3,823,676 [Application Number 05/296,147] was granted by the patent office on 1974-07-16 for method of reducing sulphur dioxide emissions from coal.
Invention is credited to Webster Warren Cook, James A. Maitland.
United States Patent |
3,823,676 |
Cook , et al. |
July 16, 1974 |
METHOD OF REDUCING SULPHUR DIOXIDE EMISSIONS FROM COAL
Abstract
A method of reducing sulphur dioxide emissions from coal by
adding an effective amount of Wyoming Trona to the coal for
combining with sulphur in the coal to form a relatively heavy ash
which is collected with other heavier ash for removal in the usual
way.
Inventors: |
Cook; Webster Warren (Monee,
IL), Maitland; James A. (Monee, IL) |
Family
ID: |
23140814 |
Appl.
No.: |
05/296,147 |
Filed: |
October 10, 1972 |
Current U.S.
Class: |
110/342;
423/244.05; 423/552; 423/551; 423/206.2 |
Current CPC
Class: |
C10L
9/10 (20130101); F23K 3/00 (20130101); F23K
2203/008 (20130101) |
Current International
Class: |
C10L
9/10 (20060101); C10L 9/00 (20060101); F23K
3/00 (20060101); F23b () |
Field of
Search: |
;110/1J,1K,106 ;44/1R,4
;201/17 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Sprague; Kenneth W.
Assistant Examiner: Schwartz; Larry I.
Attorney, Agent or Firm: Olson, Trexler, Wolters, Bushnell
& Fosse, Ltd.
Claims
The invention is claimed as follows:
1. A process of reducing sulphur dioxide emissions substantially to
or beneath a predetermined level when oxidizing coal containing
sulphur in a furnace, comprising adding an effective amount of
Wyoming Trona to said coal, and causing the Trona to be combined
with at least a portion of the sulphur in said coal to provide an
ash.
2. A process as defined in claim 1, comprising the step of adding
the Trona in a particulate form to coal particles and mixing the
Trona throughout the coal particles.
3. A process as defined in claim 1, comprising adding the Trona in
a particulate form as a layer generally on top of a bed of coal
particles.
4. A process of reducing sulphur dioxide emissions to or below a
predetermined level when burning coal containing in excess of one
percent by weight of sulphur in a furnace, comprising adding an
effective amount of Wyoming Trona to particles of said coal to be
burned, subjecting the coal and Trona to heat and causing the Trona
to combine with at least a portion of the sulphur to form as ash
readily separable from gaseous products of combustion.
5. A process as defined in claim 4, wherein the coal contains up to
about 6 percent by weight of sulphur and Trona is added in amounts
up to about 20 percent by weights of the coal.
6. A process, as defined in claim 5 wherein the Trona
comprises:
7. A process, as defined in claim 6, wherein the Wyoming Trona is
at least partially refined prior to being added to the coal by the
removal of part or substantially all of the inerts.
8. A process, according to claim 5, wherein the effective amount of
Trona added is sufficient for reducing sulphur dioxide emissions in
combustion gases to about 1 percent or less by weight.
Description
The present invention relates to a novel process of eliminating or
substantially reducing to acceptable levels sulphur dioxide
emissions which normally result from the burning of sulphur
containing coal.
It has long been recognized that one serious contributor to the
problem of air pollution is the emission of sulphur dioxide from
burning coal used in furnaces or boilers such as in power plants
and the like. The amount of such emissions varies with the sulphur
content of the coal being used. The sulphur content varies widely
in accordance with the type and source of the coal and may, for
example, range from about 0.5 percent to 5 percent or 6 percent by
weight. In general, much of the more economical and readily
available coal, particularly in the midwest, is a relatively soft
coal having a rather high sulphur content.
Numerous attempts have been made to eliminate or reduce to
acceptable levels the sulphur dioxide emissions such as by
pre-treating the coal or by mixing an additive with the coal. For
environmental purposes, it is usually desired to keep sulphur
dioxide emissions at a level of about one percent or less of the
gaseous emissions resulting from oxidation or combustion of the
coal. Prior attempts to achieve this goal, particularly with high
sulphur coal, have not been generally successful since they have
either been too costly or have resulted in unacceptable side
effects. For example, attempts have been made to use limestone as
an additive with coal, but this results in the formation of an
unacceptable coating on the interior of the furnace or boiler.
SUMMARY OF THE INVENTION
It is an important object of the present invention to provide a
novel process of eliminating or reducing to an acceptable level
sulphur dioxide emissions when burning sulphur containing coal in a
manner which is relatively economical and which has no unacceptable
side effects.
A more specific object of the present invention is to provide a
novel process for eliminating or reducing to an acceptable level
sulphur dioxide emissions by introducing an additive at an
effective point in the combustion of the coal so as to cause the
sulphur in the coal to combine with the additive in a manner which
facilitates subsequent removal and which does not result in an
unacceptable side effect such as coating or corrosion of the
interior of the furnace or boiler.
In order to accomplish the objects of this invention, dry Wyoming
Trona in powder or granular form is applied to or mixed with the
coal. Preferably the Trona is mixed intimately with the coal prior
to initiation of combustion. An amount of Trona is used which is
effective to reduce the sulphur dioxide emissions to or below the
desired level of 1 percent. The amount of Trona required to be so
effective will vary in accordance with the amount of sulphur in the
coal. In addition the amount of Trona required will vary in
accordance with the moisture content of the coal. In general, the
amount of Trona which is effective to reduce the sulphur dioxide
emissions to a given level increases with the sulphur content of
the coal and also increases with the moisture content of the coal.
For example, relatively high sulphur (about 4 to 5 percent by
weight) and high moisture coal from Kentucky requires the addition
of about 15 percent by weight of Trona to reduce sulphur dioxide
emissions to 1 percent or less while relatively dry coal having
lower sulphur contents (about 2 to 3 percent sulphur) usually
requires the addition of only about 10 percent by weight of Trona
to reduce the sulphur dioxide emissions to 1 percent or less.
The Trona used in the present invention is a mineral mined from
known deposits in the State of Wyoming and has an average
composition as follows: INGREDIENTS % BY WEIGHT
______________________________________ Silicates 0.21 Aluminum 0.24
Iron Oxide 0.045 Magnesium Oxide 0.23 Potassium 0.03 Chloride 0.02
Soda Ash (Na.sub.2 CO.sub.3) 57.65 Inerts 41.575
______________________________________
The chemical reaction which takes place is not fully known, but it
is known that the Trona binds with and neutralizes the sulphur and
forms a relatively heavy ash which is readily collected with other
ash material and does not pass up the stack with the gaseous
combustion products. The ash is then removed from the furnace or
boiler in the usual manner.
Other objects and advantages of the invention will become apparent
from the following description and accompanying drawings.
Wherein
FIG. 1 is a schematic view of an installation which may be used in
carrying out the process in the present invention.
While it is to be understood that the process of the present
invention may be utilized in known types of coal burning equipment,
FIG. 1 schematically shows one typical installation. In this
installation a furnace or boiler is provided with the usual
combustion chamber into which pulverized or powdered coal is
injected by a blower 12. The coal is delivered to the blower from a
pulverizer 14 which serves to reduce the coal particles or lumps to
the desired pulverized or powdered condition. The pulverizer in
turn is fed from hopper 16 which received the fuel from a conveyer
18 extending from a suitable source of supply.
In accordance with the present invention Trona in dry powdered or
granulated or sand-like form is added to the coal, preferably prior
to the introduction to the combustion chamber. For example, the
Trona may be delivered from a suitable source of supply by conveyer
means 20 into a hopper 22 from which it may be directed to the coal
at any one of a number of locations as indicated by the arrows 24,
26 and 28. In other words, the Trona may be introduced into the
coal at any desired location such as the conveyer 18, the coal
hopper 16 or even the blower 12. Preferably the Trona is introduced
so that it is intimately mixed throughout the coal for the best
results, but if the apparatus is such that such intimate mixture
cannot be obtained or the coal is burned on a grate rather than in
pulverized form, adequate results can be obtained by introducing
the Trona as a layer on top of the coal. The Trona combines with
the sulphur in the coal to form an ash which falls to the bottom of
the combustion chamber along with other ash materials and may be
removed by any suitable means such as a conveyer 30.
In investigating the effect of the addition of Trona on sulphur
dioxide emission during the combustion of high sulphur content
coals, the following test was conducted. An amount of untreated
coal was oxidized as a control reference followed by oxidation of a
like amount of coal to which was added the Trona. The same
conditions for all experiments were maintained and in these
experiments the term oxidation is used to signify the chemical
reaction and at no time were the samples observed to be burning
with an open flame. The Trona used was acquired from a Texas Gulf
Sulphur Company mine in Wyoming.
The untreated coal was first pulverized and sieved to be in the
size range of 0.033 inch and 0.066 inch and was dried at
115.degree.C for 1 hour to remove moisture. Two 2.000-gram samples
of pulverized coal were weighed. Both were spread uniformly over
the bottom of alundum combustion boats 31/2 inches long 1/2 inch
wide and 5/16 inch deep. One was oxidized as is. To the second,
0.400 grams of Trona was either spread on top of the coal or mixed
with it.
The samples were placed in a horizontal tube furnace with a Vycor
combustion tube which contained alundum crucible during a two-hour
heating cycle. A thermocouple at the crucible indicated the
temperature in the oxidation zone. Each run began with the furnace
at ambient temperature. It required about 1 hour to reach
700.degree.C with a final temperature of about 740.degree. C. Air
flowing at 1 liter per minute was introduced at one end of the
Vycor tube, flowed over the sample and swept the effluent gases
into an absorbing tray. Three iced absorbers in a series were used
to make certain that all gases were trapped. Each absorber
contained 50 ml of H.sub.2 0.sub.2. The results of several runs are
shown in table 1. From this table it is concluded that the sulphur
dioxide emissions were reduced about 10-fold by the use of Trona
additive. The manner in which the additive was applied to the coal
affected the oxidation characteristics with mixing producing more
complete oxidation compared to the layering method.
TABLE 1
__________________________________________________________________________
SUMMARY -- SO.sub.2 EMISSIONS FROM COAL Oxidation Time, 2 Hrs. Max
Temp., 740.degree.C (1364.degree.F) Air Flow, 1 liter/min.
__________________________________________________________________________
Coal Sample Weight grams Additive Weight Position of Additive
S0.sub.2 Weight Grams S0.sub.2 of %ontrol
__________________________________________________________________________
Southern Illinois 2 None -- 0.0173 -- Southern Illinois 2 0.40 on
top 0.0016 9.3 East Kentucky 2 none -- 0.0148 -- East Kentucky 2
0.40 on top 0.0019 12.8 East Kentucky 2 0.40 mined 0.0013 8.8
__________________________________________________________________________
The process of the present invention has been carried out in actual
furnace installations and has been found effective to reduce
sulphur dioxide emissions without providing any adverse side
effects. The Wyoming Trona is preferably used in the condition
received from the mine and without refinement. However, it is
contemplated that some or substantially all of the inert material
may be removed from the Wyoming Trona. While the Trona thus refined
will function in the process of the present invention, such
refinement increases the cost of the material and thus the
process.
As previously indicated, the amount of Trona added during the
process should be sufficient to reduce the sulphur dioxide
emissions to one percent or less by weight of the flue gases. The
quantity of the Trona additive necessary to accomplish this result
will vary in accordance with the sulphur and moisture content of
the coal. In general, the amount of Trona required increases with
the amounts of sulphur and moisture in the coal so that for
relatively high sulphur coals of about five percent sulphur, about
15 percent by weight of Trona should be added. On the other hand
for relatively dry lower sulphur coals having the sulphur content
of about two to three percent by weight, and an amount of Trona
equal to about ten percent by weight of the coal should be added to
reduce the sulphur dioxide emissions to the desired acceptable
level of 1 percent or less.
While the preferred embodiment of the present invention has been
shown and described herein, it is obvious that many changes may be
made without departing from the spirit of the scope of the appended
claims.
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