U.S. patent number 3,819,525 [Application Number 05/282,072] was granted by the patent office on 1974-06-25 for cosmetic cleansing preparation.
This patent grant is currently assigned to Avon Products, Inc.. Invention is credited to David L. Hattenbrun.
United States Patent |
3,819,525 |
Hattenbrun |
June 25, 1974 |
COSMETIC CLEANSING PREPARATION
Abstract
A cleansing composition comprising a soap or detergent base in
which substantially completely hydrolyzed water-soluble polyvinyl
alcohol particles are uniformly dispersed therein to form a
composition which imparts a mild abrasive action found especially
useful in cleansing the skin.
Inventors: |
Hattenbrun; David L. (New
Hampton, NY) |
Assignee: |
Avon Products, Inc. (Suffern,
NY)
|
Family
ID: |
23079989 |
Appl.
No.: |
05/282,072 |
Filed: |
August 21, 1972 |
Current U.S.
Class: |
510/139; 134/7;
510/152; 510/396; 510/475 |
Current CPC
Class: |
C11D
9/225 (20130101); C11D 3/3753 (20130101); A61K
8/8129 (20130101); A61Q 19/10 (20130101); A61K
2800/28 (20130101) |
Current International
Class: |
C11D
9/04 (20060101); C11D 9/22 (20060101); C11D
3/37 (20060101); C11d 009/26 (); B08b 007/00 () |
Field of
Search: |
;252/122,92,134,130,132,DIG.2 ;260/91.3VA,91.3R ;134/7
;51/310,313,298,295 ;15/320 ;424/73 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Scovronek; Joseph
Assistant Examiner: Marcus; Michael S.
Attorney, Agent or Firm: Pennie & Edmonds
Claims
What is claimed is:
1. A mildly abrasive cleansing composition comprising a
substantially uniform dispersion of particles of a soap base and
from about 0.1 to about 10 percent by weight, based on the weight
of the composition, of solid particles of a water-soluble polyvinyl
alcohol, said polyvinyl alcohol is at least 85 percent
hydrolyzed.
2. The cleansing composition of claim 1 wherein the composition is
in the form of a bar of a soap base material and particles of a
water-soluble polyvinyl alcohol substantially uniformly dispersed
therein.
3. The cleansing composition of claim 1 wherein the polyvinyl
alcohol is in particle sizes ranging from 50 mesh to 200 mesh.
4. The cleansing composition of claim 1 wherein the particles of
polyvinyl alcohol are about 1 percent of the total composition.
Description
BACKGROUND OF THE INVENTION
Cleansing compositions in the form of blocks, tablets or powders
which contain various abrasive materials have been used in the
past. The abradant material is added to the composition to enhance
the effectiveness in the removal of foreign matter from the surface
being cleaned.
Compositions found useful in accomplishing this cleaning purpose
have been various abrasive materials used alone or with some
additional inert filler material in conjunction with a soap or
detergent base. The incorporation of various abradants into soap
and detergents are well known as illustrated by such early patents
as U.S. Pat. Nos. 11,097 and 173,136 in which sawdust was used.
More recently other finely-divided water-insoluble materials, such
as silica, felspar, pumice, keiselguhr, emery or carborundum have
been used to produce the abrasive action desired. Synthetic
water-insoluble polymeric materials have also been incorporated as
abradants into some detergent compositions.
The inorganic, water-insoluble materials which are natural products
often vary in quality and, therefore, do not yield uniform results
when used. Although the synthetically formed abradants heretofore
known may be formed of uniform consistency, they, like their
natural counterparts, are normally harsh abradants even when in
fine particle form. Also, all of the water-insoluble abradants when
used leave residue particles in the wash basin, drains, etc., which
are hard to clean out and tend to clog the drain system.
Furthermore, the strong abrasive action formed by these water
insoluble materials are normally too harsh for cosmetic cleansing
of such tender surfaces as the human skin.
SUMMARY OF THE INVENTION
It has now been susprisingly found that cleansing compositions
which have mild but effective abrasive action can be formed by
utilizing certain water-soluble material.
Briefly, the present invention comprises cleansing compositions in
the form of bars, tablets, or powders comprising water-soluble
polyvinyl alcohol granules of uniform or varying particle size in
standard or superfatted soap bases or detergent bases. When
cleansing compositions of this nature are used, the polyvinyl
alcohol particles are subjected to and absorb water and thus swell
and remain solid for a time sufficient to form a mild abrasive
material which is cosmetically suitable for use in cleansing the
skin, before becoming completely solubilized in the water.
DETAILED DESCRIPTION OF THE INVENTION
The polymeric material which has been found useful in forming the
cosmetically suitable cleansing composition of this invention is a
water-soluble polyvinyl alcohol. This synthetic resinous material
is commercially available and is normally formed by the hydrolysis
of polyvinyl acetate. It is well known that even "completely
hydrolyzed" polyvinyl alcohol contains small residue amounts of
acetate groups which have not been replaced by the hydroxy group.
It has been found that materials which are substantially completely
hydrolyzed, that is polyvinyl alcohols having at least 85 percent
of the acetate groups replaced by hydroxyl groups, are most
suitable as abrasive materials in skin cleansing preparations. It
is further contemplated that in certain instances polyvinyl
alcohols which are hydrolyzed to a lesser degree may be found
effective within the scope of the invention. The amounts of
polyvinyl alcohol found useful ranges from about 0.1 to about 10
per cent of total composition with concentrations of about 1 per
cent useful in most instances.
The water-soluble polyvinyl alcohols which are useful in this
invention are solid granular materials having densities ranging
from about 1.2 to about 1.3 grams per cc. The particle size which
has been found useful in imparting the mild abrasive effect in the
soap compositions of this invention may range from about 25 to
about 300 mesh with the particle size being preferably selected
from 50 to 200 mesh. The particle size of the polyvinyl alcohol may
be all of uniform size or may be a distribution of particle size
within the described range. The type of particle size distribution
will depend upon the composition in which these abradants are
incorporated and the particular end use of the soap composition.
Particles having mesh size within the range described hereinabove
have been found particularly suited for subjection to water which
allows the particles to first absorb a certain amount of water and
thereby swelling the particles. The thus deformed particles yield
the particular mild abrasive quality desired.
In carrying out the invention the water-soluble polyvinyl alcohol
particles are mixed with various soap base materials which are
useful in cleansing human skin. The term "soap base" includes the
various surface active materials, such as detergents, or
emulsifying ingredients, such as carbonates, borates or phosphates
of alkali and alkaline earth metals, fatty acid soaps and the
like.
The incorporation of the polyvinyl alcohol material into these soap
bases can be accomplished by utilizing standard soap processing
procedures. Polyvinyl alcohol granules of a predetermined particle
size are added directly into the amalgamator along with the other
constituents of the soap batch. After thorough amalgamation, the
soap batch can be milled and plodded without any adverse effect to
the abrasiveness of the finished soap material. The finished
product may take the form of bars, tablets, as well as being ground
or cut to form particles such as powders. During the process of
forming the mild abrasive cleansing soap of this invention other
ingredients normally used in soap preparations may be included.
These ingredients include fragrances, perfumes, colorants, creams
and the like. The exact type and amount of these additional
ingredients will depend upon the particular end use of the
cleansing soap and can be chosen by those skilled in the art.
The use of water soluble polyvinyl alcohol granules in soap
compositions produces a mild abrasive quality heretofore
unobtainable by other materials. When these particles are
incorporated in soap bases in the form of bars, the particles are
substantially uniformly mixed with the soap base prior to the
formation of the finished soap bar. Upon use, the particles which
are at the surface of the bar at any one particular time are
subjected to water during the process of washing of the skin. Such
particles swell under the action of absorption of water causing
them to become raised above the surface of the bar and thereby,
form a soft abrasive surface in coordination with the soap bar.
When the water soluble particles are dislodged from the bar, they
are easily dispensed in the wash basin and drains. Even those
particles which might become lodged in crevices in such wash basins
have no tendency to remain there for long periods of time. The use
of additional quantities of water in such wash basins will, under
normal action, completely dissolve and remove the spent
granules.
The following examples are set forth for the purposes of
illustration only and are not to be construed as limitations on the
present invention except as set forth in the appended claims. All
parts and percentages are by weight unless otherwise indicated.
EXAMPLE I
Cleansing compositions are prepared from a soap base having the
following compositions:
Ingredients Parts ______________________________________ Soap Chips
(Sodium Palmitate/Sodium Laurate/Sodium Stearate 1:1:1:) 97.1
Mineral soap fragrance A-2273 2.5 Soap solution yellow 0.02 Soap
solution blaze orange 0.08 Soap solution white 0.3 Soap solution
black 0.002 ______________________________________
The above soap base composition is mixed with 0.2, 1.5, and 10
parts of 95 percent hydrolyzed polyvinyl alcohol granules in which
more than 90 percent of the polymer particles are retained on
screens ranging from between 50 and 200 mesh. The soap base
composition and the granular polyvinyl alcohol are placed in an
amalgamator and mixed until substantially uniform distribution of
the granules is achieved. The cleansing compositions thus formed
are then milled and plodded into finished soap bars.
Each of the bars formed has a mild abrasive action on the skin
without any adverse effect thereon when used for washing.
EXAMPLE II
One part of 90 percent hydrolyzed polyvinyl alcohol granules which
are substantially all retained when passed through sieve screens
ranging from 50-150 mesh is mixed with the soap base composition
described in Example I above. The soap and polyvinyl alcohol
granules are mixed in an amalgamator until there is substantially
uniform distribution of the granular material. After thorough
amalgation, the soap batch is then milled and plodded into
decorative soap balls. These decorative balls, when used, are found
to have a mild abrasive action without being harsh to the skin of
the user.
EXAMPLE III
A powdered hand cleansing composition is prepared having the
following ingredients:
Ingredients Parts ______________________________________ Dry Yellow
Powder Soap (92% c.p.s.; S.N. = 210; titre = 30.degree.C) 85
Tri-sodium Phosphate (tech. grade, powdered) 7 Polyvinyl alcohol
(85% hydrolyzed 200 mesh) 8
______________________________________
The composition is found to have a mild abrasive quality which
effectively removes foreign matter from the hands of the user.
EXAMPLE IV
A powdered detergent base of the following ingredients:
Soap (90% c.p.s.; titre = 30.degree.C) 15 Sodium Bicarbonate 30
Sodium Metasilicate 5 Trisodium Phosphate 10 Tetrasodium Phosphate
40
is mixed with 10 parts of 85 percent hydrolyzed polyvinyl alcohol
to yield a composition having a mild abrasive action useful in
removing foreign matter from the material being cleaned without
injuring the material.
It will be understood that it is intended to cover all changes and
modifications of the examples of the invention herein chosen for
the purpose of illustration which do not constitute departures from
the spirit and scope of the invention.
* * * * *