U.S. patent number 3,819,524 [Application Number 05/311,721] was granted by the patent office on 1974-06-25 for cosmetic composition for thermal dispensing.
This patent grant is currently assigned to Colgate-Palmolive Company. Invention is credited to James Richard Marshall, Warren Robert Schubert.
United States Patent |
3,819,524 |
Schubert , et al. |
June 25, 1974 |
COSMETIC COMPOSITION FOR THERMAL DISPENSING
Abstract
An aqueous cosmetic composition for thermal dispensing
containing (a) a compound capable of exothermic oxidation-reduction
reaction with hydrogen peroxide selected from the group consisting
of ascorbic acid, its salts and esters and (b) a metal salt
catalyst to accelerate the reaction. The composition may be
pressurized in one compartment of a two compartment container
provided with a co-dispensing valve with hydrogen peroxide in the
other compartment so that, upon actuation of valve, the liquids
from the two compartments are thoroughly mixed as they are
discharged, react and release the heat of reaction to warm the
discharged product.
Inventors: |
Schubert; Warren Robert
(Somerset, NJ), Marshall; James Richard (Pittsford, NY) |
Assignee: |
Colgate-Palmolive Company (New
York, NY)
|
Family
ID: |
26978032 |
Appl.
No.: |
05/311,721 |
Filed: |
December 7, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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834144 |
Jun 17, 1969 |
|
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Current U.S.
Class: |
424/47;
252/188.1; 510/120; 510/140; 510/372; 510/137; 424/73 |
Current CPC
Class: |
A61K
8/02 (20130101); A61Q 5/04 (20130101); A61Q
9/02 (20130101); C11D 17/0043 (20130101); A61K
2800/242 (20130101) |
Current International
Class: |
A61Q
5/04 (20060101); A61Q 9/02 (20060101); C11D
17/00 (20060101); C11d 009/42 () |
Field of
Search: |
;252/90,105,188
;424/73 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Other References
Rose, The Cond. Chem Dict., 1966, Vol. 7, Reinhold Publ. Co., p.
87..
|
Primary Examiner: Schultz; William E.
Attorney, Agent or Firm: Cornell; Ronald S. Sylvester;
Herbert S. Grill; Murray M.
Parent Case Text
This is a continuation-in-part of application Ser. No. 834,144, now
abandoned, filed June 17, 1969.
Claims
We claim:
1. A package comprising (a) a container having two compartments for
a co-dispensing valve; (b) a shave cream composition for thermal
dispensing which comprises 5 to 15 percent by weight of stearic
acid, 5 to 25 percent by weight of an ascorbic acid compound
selected from the group consisting of ascorbic acid, ascorbyl
palmitate, ascorbyl myristate, ascorbyl stearate, and
triethanolamine ascorbate, a metal salt catalyst selected from the
group consisting of palladium chloride, ammonium 6-molybdoferrate,
ammonium 6-molybdonickelate, ammonium 6-molybdocobaltate, and
sodium, potassium, and triethanolamine molybdate, the ratio by
weight of said metal salt catalyst to said ascorbic acid compound
being 1:6 to 1:31, to pH of said shave cream composition being
adjusted with sodium and potassium hydroxides to a pH ranging from
9 to 10.5, and a balance of water; (c) hydrogen peroxide; and (d) a
propellant; said ascorbic acid compound being capable of an
exothermic oxidation-reduction with said hydrogen peroxide, and
said metal salt catalyst being capable of accelerating said
reaction; said shave cream composition being in one compartment of
said container, and said hydrogen peroxide being in the other; said
propellant being present to dispense said shave cream composition
and said hydrogen peroxide through said valve, whereby when said
co-dispensing valve is actuated said hydrogen peroxide is mixed
with the ingredients of the other compartment as they are
discharged, and said ascorbic acid compound reacts with said
hydrogen peroxide in the presence of said catalyst to release the
heat of reaction to warm the shave cream composition being
discharged.
2. A package comprising (a) container having two compartments and a
co-dispensing valve; (b) a composition comprising a shaving cream;
a compound capable of an exothermic oxidation-reduction reaction
with hydrogen peroxide said compound being selected from the group
consisting of ascorbic acid, ascorbyl palmitate, ascorbyl
myristate, ascorbyl stearate, and triethanolamine ascorbate; a
metal salt catalyst capable of accelerating said reaction selected
from the groups consisting of palladium chloride, ammonium
6-molybdoferrate, ammonium 6-molybdonickelate, ammonium
6-molybdocobaltate, and sodium potassium and triethanolamine
molybdate; and water; (c) hydrogen peroxide; and (d) propellant;
said shave cream composition being in one compartment, and said
hydrogen peroxide being in the other compartment, with said
propellant being present to dispense both said shave cream
composition and the hydrogen peroxide, whereby when said
co-dispensing valve is actuated, said hydrogen peroxide is mixed
with the ingredients of the other compartment as they are
discharged and said compound and hydrogen peroxide react in the
presence of said catalyst and release the heat of reaction to warm
the aqueous shaving composition being discharged.
Description
The present invention relates to a cosmetic composition for thermal
dispensing. It is intended that the composition will be placed in
one compartment of a two compartment container provided with a
co-dispensing valve and the hydrogen peroxide will be placed in the
other compartment. The composition contains a compound capable of
an exothermic oxidation-reduction reaction with the hydrogen
peroxide and a metal salt catalyst to accelerate the reaction. When
the valve is actuated the two liquids are thoroughly mixed as they
are discharged, which brings the compound, catalyst and hydrogen
peroxide into intimate contact so that they react and release the
heat of reaction to warm the discharged product. The materials from
both chambers are discharged by suitable means such as a liquefied
gaseous propellant which can be in both chambers, or, as when a
flexible barrier of known type is used between chambers, then only
in one chamber of the two compartment container. In some instances
the liquefied gaseous material has a second function such as
causing a product to foam. In such products, as in shave cream
formulations, it is appropriate to include liquefied gaseous
material in the chamber containing the material to be foamed.
Products of the general character are known in the dispensing art
and have been described in the literature. An article entitled HOT
SHAVE TECHNOLOGY in AEROSOL AGE, March 1968, pages 19-21 described
an aerosol shave cream containing potassium sulfite which is
pressurized in one compartment of a two compartment container
provided with a co-dispensing valve and having hydrogen peroxide in
the other compartment. When the valve is actuated to discharge the
product, the shave cream liquid and the hydrogen peroxide are
thoroughly mixed so that the hydrogen peroxide and potassium
sulfite are brought into intimate contact and react. The heat of
reaction which is released warms the shave cream. AEROSOL AGE,
October 1968, page 97, describes a hot foam hair conditioner which
is similarly packaged. Each of these articles also describes
suitable propellants, containers and valves for a product of this
type. Various other known systems can be used such as that
described in U.S. Pat. No. 2,973,883 which discloses a container
having a flexible tube therein with the propellant only in the
space surrounding the tube. The pressure around the tube causes its
collapse when the valve is opened, thereby forcing the ingredients
from the tube as well as from the surrounding chamber. U.S. Pat.
No. 3,451,593 discloses a package in which both compartments are
pressurized. All of the above prior art is incorporated herein by
reference.
The use of inorganic sulfites, e.g. sodium and potassium sulfites,
in cosmetics emulsion systems creates problems of compatability
which rather seriously limit the freedom to formulate these
products as desired. Moreover the sulfites and their reaction
products with hydrogen peroxide may cause irritation to the skin of
many users of the products.
The present invention is based upon the discovery that ascorbic
acid, its salts and esters, together wih a metal salt catalyst to
accelerate the reaction with hydrogen peroxide, can be used in
cosmetic compositions for thermal dispensing. The organic ascorbic
acid, its salts and esters, have better compatability in emulsion
systems used in cosmetics than inorganic alkali metal sulfites so
that freedom of formulation is greatly expanded as compared with
composition containing potassium or sodium sulfite. These organic
compounds, moreover, also have the distinct advantage of being much
less irritating to the skin than the inorganic compounds.
The pH of cosmetic compositions may vary from about 5 to about 10.
Many cleansing compositions, skin creams and the like, are
formulated on the slightly acid side, e.g. at a pH within the range
of about 5 to 7, so as to approximate the natural pH of normal skin
which is on the slightly acid side. Compositions containing anionic
surfactants, such as many shave creams contain, are formulated on
the alkaline side, e.g. within a pH range of about 9-10.5. Shave
creams and other cosmetic compositions containing non-ionic
surfactants have a greater range of possible latitude of pH and may
be formulated to have a pH on the slightly acid side, or they may
be approximately neutral having a pH of about 7 or they may be on
the alkaline side within a pH range from 7 to about 10.
The ascorbic acid esters may be used in cosmetic compositions
within the entire pH range from about 5 to 10. If the cosmetic
composition is formulated on the slightly acid side, ascorbic acid
may also be used. On the other hand if the formulation has a pH on
the alkaline side, ascorbic acid salts may be used as well as the
esters.
Any compatible metal salt catalyst capable of accelarating the
reaction between ascorbic acid, its salts and esters, and hydrogen
peroxide may be used. Platinum metal halides, e.g., palladium
chloride, are satisfactory catalysts in many applications but in
general it has been found preferable to use molybdenum salts. Among
the preferred salts are ammonium 6-molybdoferrate, -nickelate and
-cobaltate. Alkali metal molybdates, such as sodium and potassium
molybdate, are also among the preferred catalyst salts. Other
include alkanol amine molybdates, such as triethanolamine
molybdate.
The ascorbic acid esters that may be used with particular advantage
include ascorbyl palmitate, myristate, stearate and the like.
The cosmetic composition used in the present invention may be
formulated in general as heretofore with the mere addition of the
ascorbic acid compound and the catalyst. Preferred cosmetic
compositions include shaving cream, hot facials, hair conditioners,
hair waving and straightening compositions and the like.
The effectiveness of the ascorbic acid compounds to increase the
temperature of a cosmetic composition formulated in accordance with
the present invention is illustrated in the following table:
TABLE
__________________________________________________________________________
GRAMS TEA GRAMS MOLYB- GRAMS TEMPERATURES .degree.F. ASCORBATE DIC
ACID H.sub.2 O.sub.2 INITIAL AFTER TIME
__________________________________________________________________________
6 0 10 77 78 3 min. 6 1 10 77 120 88 sec. 9 1 10 77 137 70 sec. 15
1 10 77 141 45 sec. 21 1 10 76 145 30 sec. 31 1 10 78 146 20 sec.
__________________________________________________________________________
The following specific examples illustrates complete cosmetic
formulations illustrative of the present invention:
EXAMPLE I
Foaming cosmetic composition of the nonionic surfactant type are
formulated within the indicated ranges and as exemplified in the
two specific products:
INGREDIENTS RANGE % SHAVE CREAM % CLEANSING PRODUCT %
__________________________________________________________________________
Non-ionic (1) 5-15 10.0 10.0 LMDEA (2) 0-1 0.5 0.5 Stearic Acid 0-5
0.5 0.5 Glycerine 5-15 10.0 10.0 Silicone Fluid (3) 0-2 1.0 1.0
Lanolin (4) 0-1 0.5 0.5 Fatty Alcohol (5) 0-1 0.5 0.5 Mineral Oil
0-20 10.0 Ascorbic Acid 5-25 10.0 10.0 Perfume 0-1 0.5 Water
Balance Balance Balance
__________________________________________________________________________
(1) Polyoxyethylene (4) sorbitan monostearate (Atlas Tween 61) (2)
Lauric myristic diethanolamine (3) Dow Corning 472 hydrophilic
polyglycols copolymerized with hydrophobi polydimethylsiloxane
chains (4) Ethoxylated lanolin, a natural hydroxy ester of lanolin
reacted with ethylene oxide (Croda Solan) (5) Self emulsifying
stearyl/cetyl alcohol (Croda Polawax A-31)
EXAMPLE II
A shave cream of the anionic surfactant type is formulated within
the indicated ranges and as exemplified in the specific product as
follows:
INGREDIENTS RANGE % PREFERRED PREFERRED RANGE % COMPOSITION %
__________________________________________________________________________
Stearic Acid 5-15 8-10 8.60 Coconut oil fatty acids 0-5 1-5 1.20
LMDEA 0-4 0.5-3.5 1.20 Tween 61 0-3 0.5-3 1.00 Glycerine 0-10 1-10
5.00 KOH (33.01%) QS QS 3.77 NaOH (19.1% Na.sub.2 O) QS QS 1.12
Coconut Oil 0-3 0.1-3 0.30 Perfume 0-2 .5-1 0.75 TEA ASCORBATE
(70%) (Ratio TEA:Acid 4:5) QS QS 15.00 Water Balance Balance
Balance
__________________________________________________________________________
The fatty acids react with the bases to form a sodium potassium
soap.
EXAMPLE III
A hot cleansing cream is formulated within the indicated range and
as exemplified in the specific product as follows:
INGREDIENTS RANGE % PREFERRED COMPOSITION %
______________________________________ Mineral Oil (light) 10-40
30.00 Fatty Acid (1) 3-9 5.00 TEA QS 2.50 Cetyl Alcohol 0-3 1.00
Methyl parasept 0-.5 0.20 Propyl parasept 0-.1 0.05 TEA Ascorbate
(2) 5-15 10.00 Water Balance Balance
______________________________________ (1) C.sub.16 -C.sub.18,
preferably triple pressed stearic acid (2) Same as used in Example
II
The fatty acid reacts with TEA to form a tri-ethanol amine
soap.
In each case the formulation is packaged in one compartment of a
two compartment container provided with a co-dispensing valve and
having hydrogen peroxide in the other compartment. Any suitable
propellant may be used to dispense the liquid composition and
hydrogen peroxide including lower hydrocarbons, e.g. propane and
butane, and lower chlorinated and fluorinated alkanes particularly
those having up to 2 carbon atoms per molecule such as propellants
11 (trichlorofluoromethane), 12 (dichlorodifluoromethane), 113
(trichlorotrifluoroethane), 114 (dichlorotetrafluoroethane,
symmetrical), etc. The proportion of propellant to aqueous liquid
may vary from about 2 percent for propane up to 15 percent for
propellants 12 and 114 in suitable proportions to give the desired
pressure. In general the foam of the products becomes drier or less
moist as the proportion of propellant increases.
In compositions of the nonionic surfactant type, as illustrated in
Example I, the surfactant is one which is capable of forming a
foaming product on discharge from the container in which it is
pressurized as just described. The polyoxyethylene adducts of
polylydric alcohol esters of fatty acids, and particularly the one
having 4 molecules of ethylene oxide condensed with sorbitan
monooleate, are excellent nonionic surfactants for such products. A
humectant should be present in these compositions to prevent a
drying effect on the skin. In these compositions LMDEA serves as a
foam stabilizer and is a desirable, but not essential ingredient.
The higher fatty acid exemplified by stearic acid serves as a
superfatting agent and gives an emollient feel to the product when
applied to the skin. It or an equivalent superfatting agent is
preferred but not essential. The glycerine serves to control
viscosity, solubilities of other ingredients and as a humectant. It
or an equivalent solubilizer is essential. The silicone fluid,
which serves as a spreading agent in such compositions and
contributes lubricity to a shave cream, also is a desirable but not
essential ingredient. The fatty alcohol (Polawax A-31) promotes
foaming, foam stability and foam body. It is also a desirable but
not essential ingredient.
In compositions of the anionic surfactant type, as exemplified in
Examples II and III, the proportion of anionic surfactant present
in the aqueous composition may vary from about 3 to 20 percent by
weight. In general it is preferred to have a slight excess of fatty
acid over base (potassium and sodium hydroxide in Example II and
triethanol amine (TEA) in Example III) to give the lather an
emollient effect and this may be enhanced by a small proportion of
an oil such as coconut oil which is not saponified by the base.
Glycerine is a desirable ingredient to impart humectant properties
to the composition but is not essential. The Tween 61
(polyoxyethylene sorbitan monooleate) and the LMDEA, which serve as
foam improving additives, giving the product on dispensing greater
stability and body, are also desirable ingredients but may be
omitted if the particular properties they add are not considered
necessary by the formulator. Cetyl alcohol serves as an emollient
and may be used or not as the formulator chooses. The parasepts are
preservatives, used optionally as desired.
In all these compositions water is an essential ingredient since
the products are aqueous cosmetic compositions which produce foam
or discharge from a container in which they are pressurized as
described above.
Ascorbic acid itself or an ester or salts thereof is essential. The
proportion of ascorbic acid compound varies with the amount of
hydrogen peroxide used and hence is given in the tables of ranges
as QS, preferably being in slight excess so that all the hyrogen
peroxide is consumed in the reaction to prevent bleaching of the
skin. The temperature to which the product rises on discharge will
vary with the proportions of these compounds used in each package.
In general the proportion of ascorbic acid compound may vary from 5
to 25 percent. In all the formulations the percentages are by
weight.
The foregoing products are illustrative only of aqueous cosmetic
compositions that may be formulated for use in accordance with the
present invention which fundamentally involves such a composition
of any desired composition and properties which is to be dispensed
in heated condition as a result of the presence therein of material
or a compound selected from the group consisting of ascorbic acid,
its salts and esters and a metal salt catalyst capable of
accelerating the reaction thereof with hydrogen peroxide which is
admixed therewith in the dispensing operation by a co-dispensing
valve.
Although the invention has been described and illustrated in
conjunction with certain specific formulations, these have been
given by way of illustration and not limitation and it is to be
understood that the invention is not limited thereto but is of the
scope set forth in the following claims.
* * * * *