U.S. patent number 3,818,533 [Application Number 05/179,190] was granted by the patent office on 1974-06-25 for treated paper and non-woven material for wiping surfaces and method therefor.
This patent grant is currently assigned to Alustikin Products, Inc.. Invention is credited to Fred F. Scheuer.
United States Patent |
3,818,533 |
Scheuer |
June 25, 1974 |
**Please see images for:
( Certificate of Correction ) ** |
TREATED PAPER AND NON-WOVEN MATERIAL FOR WIPING SURFACES AND METHOD
THEREFOR
Abstract
Tissue type paper and non-woven material are uniformly
impregnated with a non-aqueous liquid carrier selected from liquid
hydrocarbons, glycols, and pine oils containing an agent uniformly
distributed therein automatically, by applying a predetermined
quantity of treating fluid to any portion of the non-treated
material. The agent is selected from waxes, silicones, and
materials producing a predetermined odor. The agent does not
separate from the carrier until at least the treated material is
substantially impregnated, and the carrier and agent remain in the
material substantially as when it was impregnated and are deposited
in the same proportions as a thin film on a surface wiped by the
material.
Inventors: |
Scheuer; Fred F. (New York,
NY) |
Assignee: |
Alustikin Products, Inc.
(Bronx, NY)
|
Family
ID: |
26875092 |
Appl.
No.: |
05/179,190 |
Filed: |
September 9, 1971 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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843223 |
Jul 18, 1969 |
3619280 |
|
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|
475234 |
Jul 27, 1965 |
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Current U.S.
Class: |
15/104.93;
427/391; 427/395; 427/387 |
Current CPC
Class: |
A61Q
19/00 (20130101); A61K 8/0208 (20130101); A61K
2800/75 (20130101); A61Q 19/005 (20130101) |
Current International
Class: |
A61K
8/02 (20060101); B08b 001/00 () |
Field of
Search: |
;117/112,154,158,168,120
;15/104.93,29R ;161/82,209,235 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Van Horn; Charles E.
Assistant Examiner: Wityshyn; M. G.
Attorney, Agent or Firm: Miskin; Howard C.
Parent Case Text
This application is a continuation of my copending application Ser.
No. 843,223, filed July 18, 1969, now U.S. Pat. No. 3,619,280,
which in turn is a continuation of application for Ser. No.
475,234, filed July 27, 1965, now abandoned.
Claims
What is claimed is:
1. A wiping and polishing pad for wiping surfaces as is, without
the addition of water or other substances, and which remains
permanently in a condition such that it can deposit a thin film on
the wiped surfaces, comprising tissue paper or a non-woven material
uniformly impregnated with a fluid consisting essentially of a
non-aqueous liquid carrier and a composition uniformly distributed
in said carrier, said carrier and composition comprising at least
about 7.5 to about 70 percent by weight of said impregnated tissue
paper or non-woven material, there being no separation of the
carrier and composition until at least the paper is substantially
impregnated, said carrier being selected from the class consisting
of a liquid hydrocarbon, a glycol, and a pine oil which are
substantially nonvolatile at room temperature, said composition
consisting essentially of a wax and a silicone, said wax comprising
about 1 to 40 percent by weight of said carrier, and said silicone
comprising at least 0.1 percent by weight of said impregnated
tissue paper or nonwoven material, said carrier and composition
releasably remaining in said tissue paper or non-woven material
during the normal life of the article in the state substantially as
when said tissue paper or non-woven material was impregnated and
capable of being deposited as a thin film on a surface wiped by
said tissue paper or non-woven material, said impregnated tissue
paper or non-woven material being dry to the touch.
2. A wiping and polishing pad according to claim 1 wherein said wax
comprises about 7 to about 15 percent by weight of said fluid
impregnated in said paper and said silicone comprises about 2 to
about 8 percent by weight of said fluid impregnated in said
paper.
3. A wiping and polishing pad according to claim 2 wherein said wax
is selected from the class consisting of carnauba, beeswax,
candelilla, paraffin, ceresin, esparto, ouricuri, and rezowax.
4. A method for impregnation of a tissue paper useful in polishing
and/or cleaning which comprises applying to only one spot or part
of a surface of said tissue paper at ambient temperature, a fluid
consisting essentially of a non-aqueous liquid carrier containing a
composition uniformly distributed in said carrier, said carrier and
composition comprising about 7.5 to about 70 percent by weight of
said impregnated tissue paper, said carrier being selected from the
class consisting of a liquid hydrocarbon, a glycol, and a pine oil
which are substantially non-volatile at room temperature and said
composition consisting essentially of a wax and a silicone, said
wax comprising about 1 to about 40 percent by weight of said
carrier and said silicone comprising at least about 0.1 percent by
weight of said impregnated tissue paper, and letting said tissue
paper with said fluid stand so that said fluid penetrates every
part of said tissue paper to provide a uniform distribution of said
fluid throughout said tissue paper.
Description
This invention relates to a disposable treated tissue and non-woven
material. More particularly, it relates to a treated tissue or
non-woven material, which may be used as is, to wipe a
predetermined surface and deposit a thin, invisible film on such
surface, and which material is then discarded; and a process for
treating the tissue and material. The treated tissue and material
may be used for a variety of personal and cleaning purposes, such
as toilet tissue, facial tissue, and dusting and polishing cloths,
and wipers.
Treated paper is old. However, all of the treatments to these
materials are directed solely to affecting the paper or material.
Hence, paper has been treated with ingredients that inhibit mold
growth, bacteria growth, sticking of candy and the like on or to
the treated paper. These treated materials are incapable of
transmitting that treatment to another surface, since the treating
material is dried or hardened after application. Further, the
manner of treatment for paper on one hand, and tissue or non-woven
material on the other hand, is entirely different. Heretofore,
paper, cloth, or the like was treated with the desired ingredients
by coating the surface by rollers or other mechanical means, or the
paper or cloth was pulled through the treating liquid. While this
method is feasible for strong papers and cloths, it is not
practical, or is too expensive, for thin materials or multiple
tissue paper. Similarly, for certain purposes an agent, such as a
water-repellant, was distributed over the surface of cloth by
dissolving the agent in a solvent, spreading the solution on the
surface, and evaporating the solvent, thereby leaving the agent
attached to the surface. This treatment also was with respect to
the cloth itself, i.e., water-proofing it.
The present invention is directed to treating relatively weak paper
materials, such as tissue papers and non-woven materials. These
materials are inexpensive and are intended to be disposable. The
paper and non-woven materials are treated not for affecting the
properties of the paper and material, but to apply the treating
fluid in the same proportions as originally applied to the paper,
to another surface that is wiped with the treated paper or
material, in a thin layer, in which the agent is uniformly
distributed. In effect, the treated tissue or material acts as an
applicator for the treating fluid, even while performing its
primary function as a facial tissue or wiper or toilet tissue or
duster.
The different end uses of the material treated in accordance with
the present invention require different agents, all of which are
completely dispersed in a non-aqueous carrier. The total quantity
of treating fluid is applied to any portion of the tissue paper and
distributes itself throughout the paper uniformly, in the same
proportion of agent to carrier as originally applied, so that a
surface wiped with one portion of the treated paper will have the
same quantity of agent remaining on it as another surface wiped
with a different portion of the treated paper.
It is an object of the present invention to provide a disposable
treated tissue or non-woven material, which is useful for many
purposes, including personal, toilet, and dusting and polishing of
furniture and glass surfaces, and which is simple and convenient to
use.
It is another object of the present invention to provide a treated
paper, which is disposable, economical and effective in polishing
delicate surfaces, such as furniture, cars, metal, plastic and
glass, when wiped with any part of this treated paper. The treated
paper applies a non-drying film in a thin layer, so as to provide a
maximum polish and high gloss without leaving any smearing
film.
It is a further object of the present invention to provide a
treated tissue, which is dry to the touch and having an emollient
feel, which is usable as toilet tissue by sufferers of piles and
other irritations of the anus.
It is still a further object of the present invention to provide a
treated tissue having an emollient feel and a long shelf life,
which can be applied to the nose by sufferers of colds and other
respiratory afflictions, which provides a desired characteristic
odor to relieve the distress caused by these ailments, as well as
applying a soothing film for preventing chapping and irritation of
the skin.
It is another object of the present invention to provide a method
for preparing such treated paper in a simple manner.
Treated paper and non-woven material prepared in accordance with
the present invention is useful for many purposes, such as
cleaning, polishing and dusting various types of surfaces,
including furniture, automobiles, glass, mirrors and the like. The
treated paper besides polishing collects and retains the dust in
the air with resulting respiratory dangers, as well as the
resettling of the dust on the surfaces cleaned. The treated tissue
made in accordance with the present invention is emollient and can
be used dry on the most delicate and fine wood finishes, and
deposits an invisible thin film on the surface wiped without the
need of further additional material, liquid, or additional
polishing or rubbing. The present treated paper is easy to use and
provides a high gloss on the wiped surface.
Additionally, tissue paper may be treated in accordance with the
present invention with a non-aqueous liquid carrier vehicle and a
chemical which produces an odor, which alleviates the distress
occasioned by nasal, throat or bronchial ailments. One such
chemical is menthol, represented by the formula C.sub.10 H.sub.19
OH and its homologues. Other chemicals are thymol, represented by
the formula CH.sub.3 (C.sub.3 H.sub.7)C.sub.6 H.sub.3 OH and its
homologues, and camphor, represented by the formula C.sub.10
H.sub.16 O and its homologues. Menthol and thymol and their
homologues have properties in common and may be classified under
the broad group of phenols and their corresponding carbocyclic
products of varying degrees of saturation. The chemical
homogenously mixed with the carrier retains its odorforming
properties, even for a long period of shelf life, and produces a
slow, continuous release of the odor for a relatively long period
of time, much longer than if the chemical were applied directly,
and the present invention not used.
In use the treated tissue is used in the conventional manner in
wiping the nose. The odors of the chemical used provides relief to
the user and the pliable treated tissue deposits a thin film of oil
and odor-producing chemical on the sensitive skin about the nose
and lips of the user, which oil prevents irritation and chapping of
the skin, and the odor remains for a relatively long period. After
use the tissue is discarded.
Also, other chemicals can be used to provide desired odors to the
impregnated paper, including "essential oils" and artificial
scents, which produce animal, tree, plant, flower, astringent and
medicinal odors, which are well-known in the cosmetic and perfumery
field. "Essential oils" are volatile oils derived from the selected
plants and flowers carrying the characteristic odor or flavor of
the plant or flower used. (See "The Condensed Chemical Dictionary"-
7th Edition, Reinhold Publishing Corp. 1961, 1966.)
Similarly, toilet tissue may be impregnated with a liquid
hydrocarbon and a silicone, in accordance with the present
invention, which will sooth the irritated skin by depositing a thin
layer of oil on the skin of the user without any greasy
feeling.
Heretofore, in the manfuacture of treated facial and toilet tissues
and polishing and dust cloths made of paper, cotton and the like,
it has been customary to impregnate the material with an aqueous
solution containing the treating ingredients by spraying, soaking
and the like, which ingredients were then air-dried on the
material. Because of the nature of the structure of the cloth or
special types of paper, these could be subjected to treatment with
an aqueous solution for long periods of time without deleterious
effect. In attempting to apply these aqueous processes to the
treatment of conventional paper, such as tissue paper, it was found
that the results were not satisfactory. It was found that paper
treated with an aqueous solution could not absorb more than one
percent of water without altering its structure. The absorption of
this small amount of water would not result in the deposition of
adequate amounts of the treating material, such as polishing agents
on the paper. It was thus necessary to devise a method to deposit
an adequate amount of the treating material on the paper without
altering the structure of the paper. Also, the dried paper required
wetting in some manner from an outside source before using, in
order to be effective.
In accordance with the present invention, the paper being treated
will absorb sufficient treating material, such as a polishing
agent, menthol or other ingredients, to render the paper useful for
the purpose intended, such as polishing and dusting, a toilet
tissue or a facial type of tissue, without altering the structure
of the paper if the paper is treated with a non-aqueous liquid
vehicle, in which the treating material is substantially uniformly
distributed. The treating liquid is self-spreading throughout the
entire sheet and is spread evenly over the entire surface of the
paper. No separate drying operation is required, as was necessary
previously.
A variety of non-aqueous liquid vehicles are known, which are
useful for the purpose of the present invention. Among these may be
mentioned liquid hydrocarbons, glycols and pine oils. The preferred
liquid vehicles are the normally liquid hydrocarbons, e.g.,
normally light liquid hydrocarbon oils, aliphatic naphthas,
Stoddard solvents, kerosenes (refined), paraffinic hydrocarbons,
natural mineral oil and white mineral oil.
Since the products of the present invention generally come in
contact with the skin, the non-aqueous liquid vehicles generally
employed are those that are non-toxic or non-irritating when the
paper contacts the skin.
All of the ingredients are preferably completely dispersible in the
non-aqueous vehicle, and remain so, so that subsequent agitation is
not needed to redisperse the ingredients in the vehicle before use.
By using the proper percentage of liquid vehicle, a total all-side
surface treatment is assured. This is especially important when
tissue paper is being used, which comes in one-, two-, three-,
four-ply, or more.
For some purposes, certain agents should be incorporated in the
paper. Thus, for example, there may be added to the liquid vehicle
a silicone, wax or menthol, scent, perfume or other agent or
combination of these, which will be absorbed by the paper when the
paper is processed in accordance with this invention.
With the present invention, waxes, scents, pine alcohols, essential
oils and/or silicones can be added to the required degree and the
resulting admixture remains clear indefinitely without separation.
This will permit the production of the treated paper for the many
different purposes intended in the invention.
Some waxes, which are suitable for use, are carnauba, beeswax,
candelilla, paraffin, ceresin, esparto, ouricuri, rezowax and other
known waxes.
A feature of the present invention is the fact that no separation
of the essential constituents of the treating composition occurs.
This is true of the treating liquid before it is applied to the
non-woven material or tissue, as well as the treating composition
disposed on the paper or tissue. Since the treatment of the paper
in accordance with the present invention may involve contacting the
paper with a treating solution for several days, it is very
important that the components of the treating liquid do not
separate out during this period. Furthermore, since it may take
several days for the treating fluid to reach the deeper plies of
paper, it is essential for the proper treatment of these deeper
plies that the constituents of the treating fluid do not separate
out.
The relative proportions of the ingredients contained in the
impregnating liquid may be varied considerably without departing
from the spirit of this invention. In the preferred practice of the
invention, the ratio of the treating liquid to the weight of
treated paper will vary in the range of from about 10 to 70 parts
by weight of the treated paper. For example, a multiple of paper
sheets, size 12 .times. 24", requires for end use a 25 percent
treatment. The weight of the paper unit untreated is 10 grams;
therefore, 2.5 grams of the solution is applied to any part of this
paper unit, which distributes itself throughout the paper evenly in
a relatively short time.
The range of wax or combination of waxes added can vary from 1
percent to 40 percent of the impregnating liquid, with about seven
percent to fifteen percent (7-15 percent) being preferred; the
silicone added should not be less than one-tenth of a percent and
the range of the odor-producing chemical can vary from about
fifteen-hundredth of a percent to about seven-tenths of a percent,
all percentages being by weight of the impregnated sheet.
The following examples are further illustrative of the present
invention. It is to be understood, however, that this invention is
not limited thereto.
Example 1
The percentages of the materials indicated below in this example,
are based on the total weight of the treating liquid made in
accordance with the present invention.
7 percent of carnauba wax and 3 percent paraffin wax was mixed with
a solution containing 87 percent hydrocarbon distillate.sup.(1) and
3 percent silicones.sup.(2) until fully and uniformly dispersed.
Paper treated with this liquid is useful in dusting and
polishing.
Example 2
A solution was prepared by mixing 1 percent menthol and 1 percent
lavender with 97 percent of hydrocarbon distillate.sup.(1) and 1
percent cosmetic silicones.sup.(3) . This solution is used in
treating facial tissues. The percentages of materials indicated
above in this example, are
The above solutions were affixed onto two test samples of paper.
The treating solutions were free-flowing and a predetermined amount
was applied locally to one spot or part of the surface of the paper
to be treated. Within a few days, the solution penetrated every
part of its corresponding paper to provide a uniform distribution
of the treating solution throughout the paper and over the entire
surface. For the purpose of this invention, a permanently dispersed
and uniform distribution of the vehicle throughout the paper is
necessary.
In preparing the treated sheet constituting the product of this
invention, the sheet is treated in any convenient manner with a
predetermined quantity of the non-aqueous treating solution from
about 71/2 percent to about 70 percent of the weight of the treated
paper product applied locally to any spot or part of the surface
thereof. The entire quantity of treating liquid applied to the
paper is absorbed and retained by the paper. Advantageously, the
treated paper or tissue is packaged in the normal manner and within
a relatively short time, i.e., several hours to a few days, the
treating solution spreads by itself to penetrate every part of the
paper without any further act being necessary to provide a uniform
and homogeneous distribution of the treating solution throughout
the paper. The treated paper feels dry to the touch.
An impregnated paper sheet made in accordance with the present
invention is soft and cloth-like, so that it covers all of the
areas or surfaces to be wiped or contacted. The treated paper is
pliable and soft, so that the most sensitive skin surface or
furniture surface rubbed with it will not be irritated, marred or
scratched. Dust or loose dirt on the furniture adheres to the
surface of the treated sheet when the furniture is wiped by the
sheet used as a polishing or dusting cloth. In view of the large
surfaces of the sheet, a large amount of dust can be collected. If
smearing or transferring a heavy layer of oil to the surface wiped
is to be avoided, care should be taken as to how much treating
liquid is applied to the paper. Further, the added agents,
especially the odor-producing compounds, such as menthol, are
retained on the sheets and on the surface wiped, for long periods
of time, with little or insignificant loss of effective power.
Thus, the present invention provides long shelf life for the
treated paper.
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