U.S. patent number 3,815,602 [Application Number 04/889,607] was granted by the patent office on 1974-06-11 for disposable diaper.
This patent grant is currently assigned to E. I. du Pont de Nemours and Company. Invention is credited to Martha Marie Johns, John Andrew Lynch, Jr..
United States Patent |
3,815,602 |
Johns , et al. |
June 11, 1974 |
DISPOSABLE DIAPER
Abstract
Improvements in disposable diapers of the type having
moisture-absorbing cellulosic material sandwiched between a
waterproof backing sheet and a cover fabric worn next to the body.
The cover fabric is a light-weight apertured nonwoven of unbonded
polyester fibers hydraulically entangled into a strong fabric
having durability in use, rapid transmission of fluid to the
absorbing layer without wicking, and a dry feeling when the
absorbing layer is wet.
Inventors: |
Johns; Martha Marie
(Wilmington, DE), Lynch, Jr.; John Andrew (Chadds Ford,
PA) |
Assignee: |
E. I. du Pont de Nemours and
Company (Wilmington, DE)
|
Family
ID: |
25395435 |
Appl.
No.: |
04/889,607 |
Filed: |
December 31, 1969 |
Current U.S.
Class: |
604/366; 604/372;
604/375; 604/370; 604/374 |
Current CPC
Class: |
A61F
13/513 (20130101); A61F 13/49001 (20130101); A61F
13/51121 (20130101); A61F 13/512 (20130101); A61F
13/49413 (20130101) |
Current International
Class: |
A61F
13/15 (20060101); A41b 013/02 () |
Field of
Search: |
;128/287,296,290 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rosenbaum; Charles F.
Claims
We claim:
1. A disposable diaper comprising in combination a waterproof
backing sheet of rectangular shape, a moisture-absorbing layer of
cellulosic material which is smaller in length and width than the
backing sheet, and an apertured, nonwoven cover fabric of unbonded
staple fibers having an entanglement completeness of at least 0.5,
the cover fabric weighing about 0.5 to 1.0 oz./yd..sup.2, having
dimensions substantially the same as the backing sheet, and
consisting of 80 to 90 percent of polyester fibers and from 20 to
10 percent cellulosic fibers, both side edges of the rectangular
diaper being infolded and then outfolded along lines substantially
parallel to the center longitudinal axis of the diaper to provide a
pair of double folds which are secured in place with adhesive.
2. A diaper as defined in claim 1 wherein said polyester fibers are
about 1.5 denier and about 0.75 to 3 inches in length.
Description
BACKGROUND OF THE INVENTION
The invention relates to disposable diapers which are discarded
after a single use.
One of the major problems in using diapers is the wetting of
clothes either by leaking or by wicking from the wet
moisture-absorbing layer through the cover fabric. It has been
proposed to seal the moisture-absorbing layer and the cover fabric
with an extension of the waterproof backing sheet, but such contact
of the body and the backing sheet is undesirable and can cause a
rash. The use of a margin of cover fabric beyond the
moisture-absorbing layer can reduce the wicking from the layer, but
conventional cover fabrics of cellulose fibers, such as wood pulp
or rayon, wick liquid fairly readily.
Papers used as cover sheets may lack integrity so as to leave loose
fibers on the body, generally have an unpleasant papery feeling and
usually wick liquids readily.
Another requirement of a satisfactory diaper is rapid transmission
of fluid from the cover fabric to the absorbing layer so that the
fluid does not leak from the diaper area. This has been
conventionally attained by the use of moisture-absorbing fibers
such as wood pulp, cotton, or rayon. However, the use of such
fibers causes the surface of the diaper to feel wet when the
absorbing layer is wet.
DEFINITION OF THE INVENTION
A preferred product of the present invention is a diaper comprising
in combination:
1. a waterproof backing sheet of rectangular shape;
2. a moisture-absorbing layer of cellulosic material which is
smaller in length and width than the backing sheet and is centrally
disposed on it and covered by
3. an apertured, nonwoven cover fabric of unbonded staple fibers
having an entanglement completeness of at least 0.5, the fabric
weighing about 0.5 to 1.0 oz./yd..sup.2, having dimensions
substantially the same as the backing sheet; and consisting of
75-100 percent of polyester fibers and from 0 to 25 percent of
cellulosic fibers. Preferably the cover fabric contains less than
about 10 percent cellulosic fibers and has an elongation at the
break of less than about 90 percent.
Preferably the product has a waistband (the two shorter edges)
which is reinforced and stiffened by film tapes secured to the
backing sheet, or is reinforced and stiffened by a fold of the
backing sheet that is secured directly to the backing sheet by an
adhesive or by fusion.
Both side edges of the rectangular diaper are infolded and then
outfolded along lines substantially parallel to the center
longitudinal axis of the diaper to provide a pair of double folds
which are secured in place with adhesive.
BRIEF DESCRIPTION OF THE DRAWINGS
FIG. 1 is a plan view of a contoured diaper with a portion of the
cover fabric broken away.
FIG. 2 is a cross-sectional view taken along line 2--2 of FIG.
1.
FIG. 3 is a plan view of a reinforced diaper with a portion of the
cover fabric broken away.
FIG. 4 is a plan view of a rectangular diaper with a portion of the
cover fabric broken away.
FIG. 5 is an illustration of a folded rectangular diaper.
DETAILED DESCRIPTION OF THE DRAWINGS
Referring to FIGS. 1 and 2, the illustrated diaper contains a
moisture-absorbing layer 12 that rests upon waterproof backing
sheet 14 and is covered by cover fabric 10. Moisture-absorbing
layer 12 is smaller than the backing sheet and the cover fabric,
and is centrally disposed between them so that a margin 18 and 18'
is formed around the entire periphery of the diaper. This
arrangement, in combination with the low wicking properties of the
cover fabric, prevents the transmission of urine from the layer 12
to the infant's clothes. The same or slightly larger dimensions of
the cover fabric 10 assures contact of the soft, nonwoven fabric
with the body at all points of contact to avoid rash caused by the
contact of the backing sheet and the body.
The concave lateral edges of the diaper 20 and 20' afford a better
fit with the crotch. The edges may be cut in various shapes. A sine
curve s conveniently used as the layers can be cut by a rotating
cutter to give two or more row of fabric blanks with a minimum of
waste.
The assembly is conveniently held together by a line of attachment
between the cover fabric and backing sheet around the edges of the
moisture-absorbing layer.
FIG. 3 illustrates a reinforced diaper wherein a reinforcing strip
of fabric 16 having the same low-wicking properties of the cover
fabric is added to the ends of the diaper where it is pinned about
the waist of the infant.
FIG. 4 shows a diaper which is folded for use, wherein the backing
sheet and cover fabric are of rectangular shape.
As illustrated in FIG. 5, one diaper of the invention is made by
placing the unfolded diaper of FIG. 4 with cover fabric 10 upward.
Each of the side edges 28 and 28' are then folded towards the
center of the diaper. This provides a first fold 21 running along
each side of the folded diaper substantially parallel to a center
imaginary line. The infolded edges 28 and 28' are then folded back
on themselves to where the edges 28 and 28' substantially coincide
with the first folds. This provides two first folds 21 and two
second folds 22 both extending lengthwise of the diaper. The second
folds 22 may touch or be spaced from each other so as to leave a
portion 26 of the center part of the diaper open and not covered by
the folded-in sides. The cover fabric between folds 21 and 22 is
secured to its opposite cover fabric. This is preferably done at
fold 22 by an adhesive 24 placed substantially midway between the
ends of the diaper.
COVER FABRIC
The cover fabric can be made by subjecting a web of fibers
supported on an apertured plate or screen to the action of fine
columnar streams of liquid as taught in U.S. Pat. No. 3,485,706
dated Dec. 23, 1969. The treatment results in the interentangling
of the fibers to give a strong, integral fabric-like product. The
appearance of the product depends upon the nature of the supporting
plate, the weight of the web, and the intensity of the treatment.
When using screens of 40 percent or less open area and up to 40
mesh, products may be prepared with actual visible holes
corresponding to the screen pattern when products are of low
weight, e.g., 1 ounce/square yard (oz./yd..sup.2) or less. With
weights of 2 oz./yd..sup.2 the screen should be 30 mesh or coarser
to give the desired apertured products. The cover fabrics of this
invention are preferably made on a 20 .times. 20 mesh or finer
screen.
The more preferred products have a slightly fuzzy surface (this is
used on the outer face of the diaper next to the skin) due to fiber
ends being driven through the fabric in its preparation.
The energy (E) expended during one passage under a manifold in the
preparation of a given nonwoven fabric, in horsepower-hours per
pound (HP-hrs./lb.) of fabric, may be calculated from the
formula:
E = 0.125 (YPG/sb)
where:
Y = number of orifices per linear inch of manifold,
P = pressure of liquid in the manifold in psig.,
G = volumetric flow in cu.ft./min./orifice,
s = speed of passage of the web under the streams, in ft./min.,
and
b = the weight of the fabric produced, in oz./yd..sup.2
It has been observed that the entanglement of the fibers is related
to the product of the energy (E) of the treatment and the impact
force (I) (in pounds) of the hydraulic stream.
I = PAK
where P is the pressure on the orifice in psi., A is the area of a
single orifice in square inches and K is the orifice discharge
coefficient (approximately 0.64).
The polyester fibers used in the cover fabric should preferably
have a denier no greater than about 2.5 and more preferably about
1.5. Any convenient fiber length can be used, e.g., up to 3 inch.
The average length should not be much less than 0.75 inch as the
tensile strength decreases with shorter lengths for a given
entangling treatment.
The length of any cellulosic staple fiber used is not critical but
is preferably about 0.75 to 1.5 inch. When rayon is used, a
relatively low denier in the range of 1 to 2 is preferred. The
cellulosic staple should comprise no more than about 25 percent of
the weight of the blend with polyester and preferably less than
about 10 percent.
MOISTURE-ABSORBING LAYER
Suitable moisture-absorbing layers are well known. A high
absorbency of water or body fluids is required. Generally, this
layer has a low order of wet strength and integrity. The layer may
comprise layers of a paper, wood pulp crepe wadding, a layer of
wood fluff, an embossed wood pulp pad or various combinations of
such cellulosic products. Wood fluff is preferred.
Fluid distribution means known in the art may be incorporated in
this layer.
WATERPROOF BACKING SHEET
Suitable backing sheets are well known in the art. It can be a thin
plastic sheet such as polyethylene or the like, or a liquid
repellant layer of a hydrophobic polymer on the bottom face of a
nonwoven fabric.
ADHESIVES
The various components of the diaper can be secured in any desired
manner as by stitching or cementing. Suitable adhesives include
produces sold under the trademarks "Thermogrip" Hot Melt Adhesive
No. 1313, which is a formulated polyethylene base adhesive sold by
the B. B. Chemical Division of United Shoe Machinery Corp. of
Cambridge, Mass., and "Sobo" which is a polyvinyl acetate/water
emulsion sold by Solomon Laboratories of Long Island City, N.Y.
Adhesive transfer tape (double-faced) is also suitable
TESTING PROCEDURES
Water-Retention Test
Diapers are assembled using the various nonwoven fabrics as the
cover fabric and the moisture-absorbing layer and plastic film
backing sheet of a commercial disposable diaper ("Newborn Pampers"
made by Proctor and Gamble Co. of Cincinnati, Ohio). The
moisture-absorbing layer comprises seven layers of 1 oz./yd..sup.2
crepe wadding (10 .times. 13.5 inch) embossed together in a
pattern. The cover fabric is placed with the surface that faced the
screen during entangling as the outer face (skin-contacting) of the
diaper.
The water retention of each diaper cover is tested by placing the
diaper flat on a surface with the cover fabric up, adding 100 ml.
of water to the diaper through the cover fabric, covering with a
plastic film, and pressing with an aluminum plate loaded to give
0.1 psi. pressure on the diaper for 30 minutes. The damp cover
fabric is then removed from the moisture-absorbing layer and
weighed. Water retention is the weight in grams of the water
retained by the 10 .times. 13.5-inch cover fabric. The higher the
water retention, the less desirable is the fabric due to the wet
feeling.
Fluid Run-Off Test
Another important function of a diaper assembly is its ability to
quickly absorb liquid. This is measured by a fluid run-off test
wherein 30 ml. of water is added from a burette at a rate of 4
ml./second to a 6 .times. 6-inch portion of a diaper assembly of
the cover fabric and the above commercial moisture-absorbing layer.
The diaper assembly is supported at a 15.degree. angle to the
horizontal, and the fluid that runs off the surface of the cover
fabric is measured.
In use, the cover fabric may be wet with baby oil, lotions, etc.,
from the babies' skin, so the test is also run on a diaper section
that has had 1 gram of baby oil (Johnson's Baby Oil) spread evenly
over its surface by transfer from a plastic sheet. Strip tensile
strength and elongation at break are measured on an Instron Tester
at 70.degree.F. and 65 percent relative humidity using 1.0-inch
wide samples with a 2-inch distance between jaws and elongating at
50 percent per minute. The results are given in pounds/inch
(lb./in.) for machine direction (MD) and cross direction (XD) as
MD/XD.
Wickability Test
The wickability of a fabric is determined by fastening the ends of
a 2 .times. 5.5-inch strip to a perforated metal plate with rubber
bands, resting the end of the plate under about 0.5 inch of
distilled water at about 25.degree.C. at an angle of 25.degree. to
the level of the water and noting the time in minutes and distance
in inches at which the sample wicks. The wicking should be measured
on samples cut in 2 directions at 90.degree. to each other (machine
and cross directions) and the results averaged. A soluble dye may
be added to the water to assist in determination of the level on
the fabric.
A typical commercial nonwoven fabric of resin-bonded rayon fibers
(Item G of Example I) has a wickability of 1.5 inches in 20
minutes. An entangled nonwoven fabric of rayon staple fibers (Item
B of Example I) has a wickability of about 4 inches in 4
minutes.
ENTANGLEMENT COMPLETENESS TEST
In this test, nonwoven fabrics are characterized according to the
completeness of the fiber entanglement in non-bonded fabric, as
determined from strip tensile breaking data using an "Instron"
tester.
Entanglement completeness is a measure of the proportion of fibers
that break (rather than slip out) when a long and wide strip is
tested. It is related to the development of fabric strength.
Durable non-bonded products have an entanglement completeness of at
least 0.5
Entanglement completeness is calculated from strip tensile breaking
data, using strips of the following sizes:
---------------------------------------------------------------------------
Strip Strip "Instron" Gauge Elongation Rate Width Width (in.)
Length (in.) (in./min.) Symbol
__________________________________________________________________________
w.sub.o 0.8 0 0.5 w.sub.1 0.3 1.5 5 w.sub.2 1.9 1.5 5
__________________________________________________________________________
In cutting the strips from fabrics having a repeating pattern of
ridges or lines of high and low basis weight, integral numbers of
repeating units are included in the strip width, always cutting
through the low basis weight portion and attempting in each case to
approximate the desired widths (w.sub.o, w.sub.1, w.sub.2) closely.
Ten or more specimens are tested a w.sub.1, and five or more at
w.sub.2 and w.sub.o using an "Instron" tester with standard rubber
coated, flat jaw faces and the gauge lengths and elongation rates
listed above. Average tensile breaking forces for each width
(w.sub.o, w.sub.1 and w.sub.2) are correspondingly reported as
T.sub.o, T.sub.1, and T.sub.2. From these a value (c) is calculated
as follows:
c = (T.sub.2 - T.sub.1)/(w.sub.2 - w.sub.1) .multidot. w.sub.o
T.sub.o
For patterned fabrics, strips are cut in two directions: (a) in the
direction of pattern ridges or lines of highest basis weight (i.e.,
weight per unit area), and (b) in the direction at 90.degree. to
the direction specified in (a). For unpatterned fabrics any two
directions at 90.degree. will suffice. The value (c) is determined
separately for each direction and the arithmetic means of the
values for both directions, (c) is calculated. The value (c) is
called the entanglement completeness.
EXAMPLE 1
Random webs of staple fibers are made by the air deposition of
polyester fibers (1.5 dpf. and 1.5-inch length), or rayon fibers
(1.5 dpf. and 0.75-inch length), or blends of these fibers.
Each web is hydraulically entangled into an integral, strong,
nonwoven fabric by passing it while supported on a 24 .times. 24
mesh screen (16 percent open area) under rows of fine columnar
streams of water jetted under pressure from rows of orifices in
manifolds located about 12 mm. above the web. The orifices are
similar to those shown in FIG. 3 of U.S. Pat. No. 3,403,862 to
Dworjanyn, have an upper cylindrical section of 0.005-inch diameter
with a lower frusto-conical section as an exit, and are spaced 40
per inch in each row.
The compositions of the webs and the entangling conditions are
given in Table I. Items A, C, D, and E are products useful in this
invention. Items A through F are entangled nonwovens. Item G, a
cover fabric used in a commercial diaper and made by resin bonding
of a carded web of rayon fibers, is included for comparison.
Diapers are assembled from the various fabrics and tested as
described in the section on Testing Procedures. It is noted in
Table II that entangled rayon fabric (Item B) and the commercial
fabric have relatively high water retentions as compared to the
fabrics containing polyester fibers and display a very wet
hand.
From the results in Table II, it can be seen that the preferred
cover fabrics of polyester fibers with a minor proportion of
cellulose fibers and having an adequate degree of entanglement as
judged by c (Items C, D, and E) have relatively low values of fluid
run-off on plain or oiled fabrics. These fabrics are further
characterized by patterns of distinct apertures and by the presence
of fiber ends (substantially all polyester fibers) that project
from about 0.5 to 1 mm. beyond the downstream face of the fabric
(the face of the fabric next to the screen during formation).
Item F is unacceptable as a cover fabric because an excessive
amount of loose fibers are left on the infant's skin in use, and it
is also readily stretched out of shape in use. These deficiencies
are presumably due to the low c and high elongation-at-the-break of
Item F.
The thickness of the fabrics are given in Table II is measured
under about 0.16 pound per square inch load with a plunger of about
0.75-inch diameter (Federal Gauge made by Federal Products Corp. of
Providence, R.I.). It is considered that the superior dry hand of
the diapers of this invention is due in part to the thickness of
the entangled nonwoven fabrics. The fabrics will preferably have a
thickness of at least 10 mils, and more preferably at least 15
mils, even at the lowest fabric weights. ##SPC1## ##SPC2##
EXAMPLE 2
Fabric A of Example 1 is used as a cover fabric for a diaper. The
fabric has a wickability of less than 0.1 inch in 20 minutes.
ASSEMBLY OF A DIAPER
Diapers are assembled as shown in FIG. 4 using the above nonwoven
fabric as the cover fabric, polyethylene film (about 1.0 to 1.5
mils thick) as the waterproof backing sheet and plies of a
composite moisture-absorbing layer consisting of one layer of wood
fluff (4 or 6 ounces/square yard as indicated below) with two
layers of crepe wadding (1 ounce/square yard per layer) on each
face, which has been embossed together with a grid pattern. Typical
dimensions of width (W) and length (L) in inches are given below:
##SPC3##
When assembling a given type, the larger of the moisture-absorbing
layers is centered on the film, the smaller absorbing layer is
centered on top of that. A strip of 0.75-inch wide transparent
adhesive plastic tape is placed at each end of and adjacent to the
two shorter edges of the larger layer running for the entire width
of the diaper as reinforcement and the nonwoven fabric is placed on
top of the assembly with the fuzzy (downstream) face up. The cover
fabric is secured to the film in a line around the perimeter of the
moisture-absorbing layer by strips of 0.25-inch wide adhesive
transfer tape.
* * * * *