U.S. patent number 3,813,677 [Application Number 05/333,482] was granted by the patent office on 1974-05-28 for heat-sensitive record.
This patent grant is currently assigned to Matsushita Electric Industrial Co., Ltd. Invention is credited to Wataru Shimotsuma.
United States Patent |
3,813,677 |
Shimotsuma |
May 28, 1974 |
HEAT-SENSITIVE RECORD
Abstract
A heat-sensitive recorder using a thermal head, which is
furnished with power in accordance with the speed of its movement
relative to the recording sheet for the thermal control so as to
obtain a uniform record quality.
Inventors: |
Shimotsuma; Wataru (Hirakata,
JA) |
Assignee: |
Matsushita Electric Industrial Co.,
Ltd (Osaka, JA)
|
Family
ID: |
27520051 |
Appl.
No.: |
05/333,482 |
Filed: |
February 20, 1973 |
Foreign Application Priority Data
|
|
|
|
|
Feb 23, 1972 [JA] |
|
|
47-18613 |
Mar 8, 1972 [JA] |
|
|
47-23852 |
May 2, 1972 [JA] |
|
|
47-44000 |
May 16, 1972 [JA] |
|
|
47-48757 |
Sep 8, 1972 [JA] |
|
|
47-90820 |
|
Current U.S.
Class: |
347/193;
346/135.1; 347/172; 219/501 |
Current CPC
Class: |
G01D
15/10 (20130101) |
Current International
Class: |
G01D
15/10 (20060101); G01d 015/10 () |
Field of
Search: |
;346/76R,76L
;219/216,501 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Tomsky; Stephen J.
Assistant Examiner: Miska; Vit W.
Attorney, Agent or Firm: Stevens, Davis, Miller &
Mosher
Claims
What we claim is:
1. A heat-sensitive recorder comprising
a. a thermal head furnished with electrical power for heating,
b. a heat-sensitive recording sheet disposed in contacted with a
heat generating surface of said thermal head,
c. means to move said thermal head and said heat sensitive
recording sheet respectively,
d. first detecting means to detect the distance traveled by said
thermal head and to produce first trigger signals at intervals
proportional to said detected distance,
e. second detecting means to detect the distance traveled by said
heat-sensitive recording sheet and to produce second trigger
signals at intervals proportional to said detected distance,
f. a pulse generator receiving said first and second trigger
signals and producing a pulse output at controlled average pulse
frequencies, and
g. means to control power supplied to said thermal head according
to the pulse output from said pulse generator.
2. A heat-sensitive recorder according to claim 1, wherein said
thermal head consists of silicon and is provided with a superficial
heat generating resistive layer formed by selectively diffusing
such an impurity as phosphorus and boron into the silicon
material.
3. A heat-sensitive recorder according to claim 1, wherein the heat
generating surface of said thermal head is formed in the shape of a
smooth curved-surface having a U-shaped cross section.
4. A heat-sensitive recorder according to claim 1, wherein the area
of the heat generating surface of said thermal head is no greater
than about three times the area of contact between said thermal
head and heat-sensitive recording sheet.
5. A heat-sensitive recorder according to claim 1, wherein said
heat-sensitive recording sheet is capable of changing the color of
recording or record density, and which further comprises a control
means to control power supplied to said thermal head such as to
obtain records in various colors or with various record
densities.
6. A heat-sensitive recorder according to claim 5, which further
comprises means to compare the level of signals to be recorded and
a particular reference level, the output signal from said comparing
means being used to control said control means.
7. A heat-sensitive recorder according to claim 5, wherein said
heat-sensitive recording sheet is a multi-color heat-sensitive
sheet consisting of a base sheet and one or more coating layers
formed on said base sheet and containing a leuco-die and a phenol
compound or an organic acid as heat-sensitive coloring
components.
8. A heat-sensitive recorder according to claim 5, which further
comprises one or more additional thermal heads, and means to cause
the movement of the individual thermal heads according to different
input signals and supply energy of different levels to the
individual thermal heads for recording in different colors.
9. A heat-sensitive recorder according to claim 1, wherein the rate
of pulse supply with respect to the movement of said thermal head
is within a range between 1 and 5 pulses per millimeter of movement
of said thermal head and the rate of pulse supply with respect to
the progress of said heat-sensitive recording sheet is within a
range between 10.sup.2 and 10.sup.5 pulses per millimeter of
progress of said recording sheet, the energy in each pulse being
within a range between 1 and 5 millijoules.
10. A heat-sensitive recorder according to claim 1, which further
comprises means to increase the pulse energy supplied to the
thermal head during an initial recording period until normal
recording conditions set in.
Description
This invention relates to analog measurement recorders in and, more
particularly, to recording apparatus for recording physical
quantities converted into electric signals in the observation or
recording of natural or man-made phenomena.
There are various prior art recording methods adopted in the
recording means of recorders, including one using ink,
electrostatic recording method, electrofax process and one using
light-sensitive media. One of the major purposes of the recorder is
to effect automatic recording of physical phenomema. However, this
end of automatic recording cannot be truely attained with any of
the above prior art recording methods because of the necessity of
replenishing ink or other developing agents and such
after-treatment as developing and fixing.
Further, the ink recording method, which is the most generally
employed prior art recording method, has such a drawback that the
recording sheet would be broken if a signal containing noise is
recorded at a low speed (for instance, at a recording sheet feed
speed of 5 .times. 10 .sup..sup.-3 mm/sec.). Secondly, in case of
high-density recording covering substantially the whole area of the
recording sheet, the operator's clothes as well as the instrument
are likely to be stained with slowly drying ink. Thirdly, ink is
very susceptible to the state of the ink pen and atmospheric
pressure, often resulting in excessive or insufficient ink
supply.
An object of the present invention is to provide a perfectly
automatic recorder without requiring any replenishment of ink or
developing agent and any after-treatment such as developing and
fixing.
Another object of the invention is to provide a heat-sensitive
recorder, which gives records of a uniform quality irrespective of
changes of the speed of the thermal head.
A further object of the invention is to provide a heat-sensitive
recorder, which gives records in different colors with a single
recording head.
In order for the invention to be fully understood, it will now be
described in conjunction with the accompanying drawings, in
which:
FIG. 1 is a schematic representation of the basic arrangement
according to the invention;
FIG. 2 is a schematic showing an example of the control circuit for
thermally controlling a recording head;
FIGS. 3 to 5 are perspective views, partly broken away, showing
basic structures of the head;
FIG. 6 is a view to show the state of contact between head and
heat-sensitive sheet;
FIGS. 7 to 9 show contours of the head tip;
FIGS. 10 to 12 are pictorial fragmentary sectional views showing
heat-sensitive sheet structures;
FIG. 13 is a schematic showing an example of the control circuit
for controlling pulse energy supplied to a head either according to
an external signal or manually;
FIG. 14 is a graph showing relative record density and width of the
record trace as functions of the recording speed of the recorder
according to the invention;
FIG. 15 is a graph showing relative resistance change in various
heads plotted against the record length change in various heads
plotted against the record length traced; and
FIG. 16 is a graph showing the relation between heat attenuation
time and relative heat generating layer area of various heads.
In the drawing, like reference numerals refer to like parts.
The invention is based upon the adoptation of a novel
heat-sensitive recording method for the recording means of analog
measurement recorders (hereinafter referred to as recorders).
The heat-sensitive recorder according to the invention comprises,
as its recording means, a thermal head, a heat-sensitive recording
sheet (hereinafter referred to as heat-sensitive sheet) and a
control circuit for thermally controlling the thermal head.
While the mechanism for moving the thermal head according to an
input signal supplied to the recorder is outside of the scope of
the invention, an example of such mechanism will be described in
connection with FIG. 1 for the purpose of demonstrating the basic
arrangement according to the invention.
Referring to FIG. 1, numeral 1 designates a servo motor for moving
a thermal head 6 through a stretched thread 2 attached thereto
according to an input signal. Numeral 3 designates a synchronous
motor for driving a drum 4 to feed a heat-sensitive sheet 5.
Numeral 7 designates a record trace. Numeral 8 designates a circuit
to superimpose pulses produced from servo motor and synchronous
motor 3 in accordance with the distance traveled by the thermal
head, numeral 9 a circuit to produce pulses of a constant pulse
length according to the output signal from the circuit 8, the pulse
output of the circuit 9 being supplied to the thermal head 6, and
numeral 10 a power supply circuit. A disc 1a formed with a number
of circumferentially spaced apertures is secured to the shaft of
the servo motor 1, and a photoelectric converter 1b which
co-operates with the disc 1a detects the speed of the servo motor
1. The speed of the synchronous motor 3 is detected by a detecting
means 3a.
In this system, the synchronous motor 3 is run according to an
X-axis input signal, or in an automatically balanced strip chart
recorder it is run at a constant speed for time sweeping. This
motor 3 serves to feed the recording sheet 5. The servo motor 1, on
the other hand, is controlled according to a Y-axis input to cause
the corresponding movement of the thermal head 6. The speed of the
motors 1 and 3 is respectively detected by photoelectric converter
1b and detecting means 3a, whose respective outputs are synthesized
in the circuit 8. The output signal of the circuit 8, which is
based on the combination of the speeds of the motors 1 and 3,
substantially represents the speed of the thermal head 6. This
signal is coupled to the pulse generating circuit 9 to supply power
to the thermal head 6 according to the speed thereof for the
thermal control thereof. In this way, a record with a constant
density may be obtained.
FIG. 2 shows an electric circuit used in the system of FIG. 1. A
photo-diode 11a which is provided in the photoelectric converter 1b
constitutes a photochopper 11, whose output is coupled to a shaper
amplifier 12 consisting of transistors 12a and 12b. In case where
the recording sheet 5 is fed at a predetermined constant speed, the
detecting means 3a shown in FIG. 1 may include a select switch 15a
to select a resistance under the control of a feed speed
determining operation and a unijunction transistor 15b. A group of
resistors 15c which are switched by the select switch 15a
constitutes a charging path to charge a capacitor 15d. When a
predetermined voltage is built up across the capacitor 15d, the
unijunction transistor 15b is turned "on", causing the discharging
of the capacitor 15d until the transistor 15b eventually becomes
"off." In this way, the circuit 15 provides pulses at a
predetermined frequency. The outputs of the circuits 12 and 15 are
impressed upon a mono-stable multi-vibrator 13 consisting of
transistors 13a and 13b, so that the multi-vibrator produces a
pulse output, which is power amplified by an amplifier 14 for
coupling across terminals 16 connected to the thermal head 6.
With the recorder of the above construction, it is possible to
obtain a record of a uniform quality on the recording sheet at a
recording speed ranging between 5 .times. 10.sup..sup.-3 and 3
.times. 10.sup.2 mm/sec. For multi-color recording, a multi-color
heat-sensitive sheet to be described hereinafter, a plurality of
thermal heads and the same number of thermal control circuits such
as shown in FIG. 2 may be employed.
The thermal head (hereinafter referred to as head) is an essential
element in this invention, and it will now be described in detail
in connection with examples shown in FIGS. 3 to 5.
The head may be made from silicon used as base material. In this
case, usual semiconductor techniques are used to diffuse phosphorus
or boron into a P- or N-type silicon substrate 19 having a
configuration as shown in FIG. 3, 4 or 5 to form a heat generating,
resistive layer 18 such that a substrate portion 17 constitutes a
heat generating area. The layer 18 is made to have P.sup.+-type
conductivity if the substrate 19 is of N-type, or it is made to be
of N.sup.+-type if the substrate is of P-type. The thickness of the
layer 18 is suitably 1 to 40 microns. Then, electrodes 20
contiguous to the layer 18 are formed by depositing aluminum. Then,
nickel and copper are deposited, and the resultant system is
finally electroplated with copper.
It is also possible to use ceramics as the base material 19. In
this case, 80 to 96 percent pure alumina (Al.sub.2 O.sub.3),
forsterite (2MgO.sup.. SiO.sub.2), steatite (MgO.sup.. SiO.sub.2)
and beryllium oxide (BeO) are suitable ceramics. In manufacture,
heat generating layer 18 is formed in portion 17 by well-known
means such as spattering and vapor phase deposition. Alternatively,
the heat generating layer 18 may be a hesa coating film formed by
spraying an aquaous blend solution containing stannic chloride
(SnCl.sub.4) and antimony chloride (SbCl.sub.3) in a molarity ratio
of 5 : 1 to 40 : 1 onto the ceramic material heated to a
temperature of 400.degree. to 600.degree.C, or it may be formed by
imprinting the portion 17 with silver palladium paint (manufactured
by Du Pont Corporation) and sintering it a temperature of
600.degree. to 900.degree.C. Then, electrodes 20 contiguous to the
heat generating layer 18 may be formed in the same way as in the
above case of using silicon.
There often results a state of contact between head 21 and
heat-sensitive sheet 22 as shown in FIG. 6. In order to better the
record quality it is effective to prepare heads having round tips
as shown in FIGS. 7 to 9. In FIGS. 7 to 9, numeral 17 designates a
heat generating surface, numeral 19 a base material, numeral 18 a
heat generating layer, and numeral 20 an electrode.
The heat-sensitive sheet is required to color or undergo a color
change only at its heated portion. Generally, the coloring agent
may be prepared by combining a leuco-die and a phenol compound or
organic acid or combining an organic metallic soap and an organic
reducing agent. As the leuco-die may be used crystal violet lactone
(coloring blue) and phenylrhodamine lactone (coloring red). As the
phenol compound bisphenol A is suitable. Suitable organic metallic
soaps are ferric stearate and silver behenic acid, and suitable
organic reducing agents are gallic acid and protocatechuic acid. As
the dispersion medium and binder may be used polyvinyl alcohol,
polyvinyl acetate and acrylate-vinyl acetate copolymers.
FIGS. 10 to 12 show examples of the heat-sensitive sheet structure.
In these examples, the coloring agents are prepared from the
combination of leuco-die and phenol compound.
In FIG. 10, numeral 23 designates a base sheet of fine quality
paper of the order of 20 to 70 g/m.sup.2, and numeral 24 a binder
such as mentioned above. Bisphenol A and crystal violet lactone are
dispersed in the binder layer as respectively designated at 26 and
at 25. The particles of the components 25 and 26 range between 1
and 5 microns in diameter, and their parts ratio is 1 : 10 to 1 :
25. The total quantity of coating is 3 to 7 g/m.sup.2. This example
is a single-color heat-sensitive sheet, and it is rendered blue by
one-second heating of it at a temperature of 90.degree.C.
The example of FIG. 11 is a two-color heat-sensitive sheet. It
colors red when the one-second heating temperature is 90.degree.C,
and it becomes green at a temperature of 100.degree.C. The particle
diameter, parts ratio between leuco-die and phenol compound and
total quantity of coating of the individual coating layers are
similar to those in the FIG. 10 example. In FIG. 11, numeral 27
designates leuco-phenylrhodamine R (coloring red), and numeral 28
leuco-malachite green.
The example of FIG. 12 is a combination of the FIG. 11 and FIG. 10
examples. It is a three-color heat-sensitive sheet coloring blue at
90.degree.C, red at 100.degree.C and green at 110.degree.C.
For the two-color, three-color and other multicolor sheets, it is
desirable from the standpoint of improving the color separation to
provide between adjacent coating layers an intervening layer
containing bisphenol A, stear amide, etc., dispersed in a
binder.
It is the basic concept underlying the thermal control of the head
according to the invention to make the quantity of heat supplied to
a unit area of the heat-sensitive sheet constant irrespective of
the recording speed. This end seems to be achievable by supplying
thermal energy in the form of pulses to the head at a fixed rate,
for instance 1 to 5 pulses per 1 mm of the relative movement of the
head in both Y and X directions in FIG. 1. However, from the laws
of the conduction of heat it is impossible to have all energy
supplied to the head transferred to the heat-sensitive sheet.
Accordingly, it is considered to supply pulses at a greater rate
with respect to the relative movement of the heat-sensitive sheet,
for instance, in the X direction in FIG. 1 than that in the Y
direction. By so doing, the energy supplied to a unit area of the
heat-sensitive sheet may be eventually held constant irrespective
of the recording speed. The pulse supply rate with respect to the X
direction is, for instance, set to 10.sup.2 to 10.sup.5 pulses per
one millimeter of progress of the heat-sensitive sheet, which is
fed at a speed ranging between 5 .times. 10.sup..sup.-3 and 3
.times. 10.sup.2 mm/sec. The requisite pulse energy differs with
the record color. By way of example, with the sheet of FIG. 12, 1
to 2 millijoules per pulse is necessary for coloring blue, 2 3
millijoules per pulse for red, and 3 to 5 millijoules per pulse for
green.
The thermal energy transferred to the heat-sensitive sheet is
insufficient for a certain initial period until a saturation is
reached. This is inevitable even if the head is furnished with
pulse energy at a constant rate under fundamentally excellent
thermal control of the head insofar as the heat capacity of the
head is not zero. The initial time until reaching of the stauration
differs with the supplied pulse energy, and it is 5 to 20 seconds
with the energy supply of 5 millijoules per pulse and 100 to 500
seconds with 1 millijoule per pulse. The variation of the record
density due to this staturation time is negligible in the
continuous use of the recorder, but where the recorder is used
intermittently the instability of the record quality would give
rise to various problems.
According to the invention, the record quality is stabilized
through pulse length compensation based on the saturation curve. An
example of such compensation for the record quality is illustrated
in FIG. 13.
Referring to FIG. 13, block 13 is a circuit the same as the circuit
13 shown in FIG. 2 for controlling the length of pulses supplied to
the head. Here the pulse length is determined by the resistances of
resistor 32 and thermistor 29. The thermistor 29 is provided to
obtain the compensation, and otherwise an ordinary resistor may be
used in its place. When the power source voltage is applied to the
circuit, the thermistor is heated by a heater 30, so that its
resistance is reduced with time. The relation between resistance
and time is adapted to make up for the aforementioned saturation
time. In effect, the pulse length is increased for an initial
stage, and it ultimately settles to a predetermined value when the
saturation is reached.
This compensation method, unlike other methods such as one based on
the detection of the head temperature and one where a thermistor
heater is inserted in series with the head, requires no lead of any
movable part and enables free adjustment of the saturation
curve.
In addition to the capability of ensuring a constant record quality
independently of the recording speed, it is possible with the
thermal control of the head according to the invention to
selectively switch different colors of recording with the same
head. This function of switching recording colors will now be
described in connection with the circuit of FIG. 13. In the Figure,
numeral 31 designates a comparator to receive external color switch
signals, and numeral 33 an amplifier.
In one specific example, the circuit of FIG. 13 was incorporated
together with the circuit of FIG. 2 in a recorder having the
mechanism of FIG. 1, and the silicon head of FIG. 3 and the
two-color heat-sensitive sheet of FIG. 11 were employed. The pulse
length of the pulse energy supplied to the head was controlled with
thermistor 29 and variable resistor 32 shown in FIG. 13 such as to
obtain recording in red color with 1.5 millijoules and recording in
green color with 3.0 millijoules. In this example, the thermistor
29 suitably offers a resistance of 80 kiloohms at normal
temperature and a resistance of 50 kiloohms after the saturation
time is elapsed, and the resistance of the resistor 32 is suitably
50 kiloohms.
In operation, without any signal at input terminal 34 of the
comparator the recording proceeds in red color. When a voltage
higher than the voltage coupled to the comparator through voltage
divider 35 appears at the input terminal 34, transistor 33 is cut
off, so that the recording color becomes green. The recording
colors may be freely switched by means of manual switch 36. Where a
plurality of heads are used in a recorder, this switching function
may of course be provided for all the heads.
With the heat-sensitive recorder as has been described in the
foregoing, the aims of the recorder mentioned before in connection
with the objects of the invention may be attained.
The heat-sensitive recorder having the basic construction as
described before in connection with FIGS. 1 and 2 has the important
feature that no maintenance is required at all until the recording
sheet is used up. In addition, the record quality obtainable with
it is superior to that obtainable with any other heat-sensitive
recorder.
The recorder refers to the clearness of the record trace and
uniformity of the width of the record trace within a recording
speed range of 5 .times. 10.sup..sup.-3 to 3 .times. 10.sup.2
mm/sec. By way of example, it may be represented in terms of
relative record density and width of the record trace related to
the recording speed, as shown in FIG. 14. In the Figure, curves 38
and 40 represent characteristics of well-known heat-sensitive
recorders employed for electrocardiographs and the like and using
nichrome wire heaters, whereas curves 37 and 39 represent
characteristics obtained in accordance with the invention. With
these latter characteristics recording with constant resolution and
density can be ensured irrespective of whatever changes occur in
the magnitude of the signal to be recorded and recording speed.
As have been mentioned earlier in connection with FIGS. 3 to 5,
there are various types of heads to be used in the preceding
embodiment, and they are classed on the basis of material and
structure. Of these heads, those made from silicon and formed with
a heat generating superficial resistive layer are superior to
others in the half-wave period, which will be described
hereinafter.
The half-wave period is an index of the rising performance of the
head. It is determined by setting the recorder such that a record
density of 1.0 is obtained with the blue-color heat-sensitive sheet
of FIG. 10 and the controlled head such as ones listed in Table 1
and at a recording speed of 60 mm/sec. and by interrupting and
resuming the recording operation. It is the time required until the
reaching of a record density of 0.5 from the instant of resuming
the recording after the head has been cooled down to normal
temperature.
Table 1 lists heads of various materials and configurations and
their half-wave period. The half-wave period depends not only upon
the head material but also upon the head structure. In average, it
is about 3.2 seconds with the head configuration of FIG. 3, 7.7
seconds with the configuration of FIG. 4 and 10.2 seconds with the
configuration of FIG. 5. Considering the average half-wave period
with regard to the material of the head, it is 1.4 seconds in case
of silicon heads having the configuration of FIG. 3 while it is 5.1
seconds in case of ceramic heads of the same configuration. Thus,
superiority of the silicon heads in this respect is evident.
In the light of the fact that the performance of the head depends
upon the thermal conductivity of the material of the head, the
combination of the silicon material having the configuration of
FIG. 3 and the heat generating layer formed by spraying is
desirable from the standpoint of improving the performance of the
head. However, the manufacture of such a head is industrially
difficult. ##SPC1##
Remarks:
1. The material is what is indicated at 19 in FIGS. 3 to 5.
2. The heat generating layer is what is indicated at 18 in FIGS. 3
to 5.
3. The resistance between electrodes 20 in FIGS. 3 to 5 at normal
temperature is meant.
4. The half-wave time is the time required until the reaching of
half the normal value of the record density.
As have been mentioned above, there are heads of various materials
and configurations that may be prepared for use in accordance with
the invention, and those made of silicon are advantageous in view
of the half-wave time. However, the heads of ceramic materials have
a certain merit as will be described hereinafter.
The recorder according to the invention features freedom from
maintenance other than the replacement of the recording sheet
during recording. However, the tip of the head wears with increase
of the number of replacements of the recording sheet, and the
resistance of the head is ultimately increased to such an extent
that the recording is no longer possible.
The service life of the head before the reaching of this state may
be increased by covering the heat tip with a hard material such as
silicon carbide and alumina. By so doing, no practical problem will
be encountered even after the head has traced beyond a record
length of 100 km.
However, it is difficult to know the remaining lifetime of the head
in use. Toward the end of the life of the head, the resistance
thereof increases progressively sharply, as shown in FIG. 15. This
sharp change of the resistance is controllable since it is related
to the thickness of the heat generating layer, and in the case of
using ceramic materials a heat generating layer with a thickness of
up to about 500 microns may be readily formed.
Curves 41 to 43 in FIG. 15 represent characteristics of respective
heads, whose respective heat generating layers are 5 microns, 100
microns and 500 microns thick in the mentioned order and are all
covered with spattered silicon carbide to a thickness of 4 microns.
The resistance of all these heads begins to change when a record
length of 102 km is covered, but the lifetime of or record length
traced by the head until the recording is no longer possible
differs with the thickness of the heat generating layer; the
greater the thickness the ss the more the head is useful for the
recorder. However, it is practically impossible to form as thick a
heat generating layer as mentioned above in the case of silicon
heads because of impurity diffusion techniques. In contrast, with
ceramic materials it is very easy to form a heat generating layer
having a sufficient thickness. By way of example, a heat generating
layer with a thickness of 0.5 mm, which had been obtained by
sintering a 0.58 -mm thick dry film of silver palladium
(manufactured by Du Pont Corporation) formed by the screen printing
method on alumina, showed the characteristic of curve 43.
The service life of the head may also be greatly extended by
rounding the tip of the head. This effect has no bearing upon the
material of the head, and this aspect will now be discussed in
connection with FIGS. 7 to 9 and the graph of FIG. 15.
Curve 44 in FIG. 15 represents the characteristic of a silicon head
having the configuration of FIG. 3 and a heat generating layer with
a thickness of 1 micron. On the other hand, curve 45 represents the
characteristic of different silicon heads, whose heat generating
layer is also 1 micron thick, but which are manufactured by shaping
the substrate into the contours of FIGS. 7 to 9 by the well-known
electrolytic polishing technique before the impurity diffusion
treatment. It will be evident from these curves 44 and 45 that the
service life of the head greatly differs with the shape of its tip.
It is thought that this effect depends for its analysis upon the
state of contact between head and heat-sensitive sheet. With the
head shape of FIG. 3 a contact state as shown in FIG. 6 would
result, and only the edges of the heat generating surface would
selectively wear, whereas with the head shapes of FIGS. 7 to 9 the
whole heat generating surface will uniformly wear. This could be
readily observed by magnifying the weared head tip.
In the grading or evaluation of the performance of the head in the
recorder, the heat attenuation time at the time of suddenly
reducing a certain high recording speed to zero is an important
factor. It is a time interval from the instant of cutting the input
to the head in use with the basic construction according to the
invention by reducing the chart bias to the head to zero, in other
words, only applying a trigger corresponding to the speed of the
head and not applying a trigger corresponding to the speed of the
recording sheet, until the record density in the normal recording
at the recording speed, V = 200 mm/sec is reduced to one half. The
shorter this time interval is, the higher the thermal efficiency of
the head and hence the easier the thermal control of the head.
FIG. 16 shows values of the heat attenuation time that were
obtained for various ratios of heat generating layer area to
contact area of the heads listed in Table 1. In the figure, the
number attached to each plot is the same as the rererence number of
the corresponding head listed in Table 1. The empirical upper limit
of the permissible heat attenuation time is 2.5 seconds, so that
the area ratio should be less than 3 to obtain effective
results.
Experimental two-channel and three-channel recording was conducted
with the recorder according to the invention and using the
multi-color heat-sensitive sheets of FIGS. 11 and 12. In the
two-channel recording, records in red color were obtained at the
low head temperature and records in a blend of red and green colors
were obtained at the high head temperature. In the three-channel
recording, the records obtained were in blue color at the low head
temperature, in a blend of blue and red colors at the medium head
temperature, and in a blend of blue, red and green colors at the
high head temperature. In either case, the clearness was slightly
inferior to that obtainable with two-channel or three-channel
recorder using ink. However, the record quality was excellent
because the record density and width of the record trace were
steady and stable even with changes of the recording speed as are
evident from FIG. 14.
As mentioned above, it is very advantageous to use multi-color
heat-sensitive sheets, which constitute an essential element of the
invention. It has also been mentioned earlier that leuce-dies and
organic metallic soaps are useful as the main composition of the
coloring agent used in the preparation of the uni-color or
multicolor heat-sensitive sheets. The following description will
concern with which one of these two types of materials is
superior.
As mentioned earlier, with the heat-sensitive sheets having the
structures of FIGS. 11 and 12 a particular color of recording is
selectively obtained at a corresponding head temperature. When the
recording is made at the low head temperature, only the uppermost
or outermost layer undergoes coloring, so that a clear record may
be obtained. However, when the recording is made at the medium or
high head temperature, the record obtained is in a blend or colors
of the individual excited layers, so that the clearness inferior to
that of the ink recording.
In order to prevent this blending of colors, efforts have been paid
to obtain heat-sensitive sheets, with which the uppermost layer in
case of the structure of FIG. 11 or the uppermost layer and
intermediate layer in case of the structure of FIG. 12 are
decolored so that coloring of only the lowermost layer results in
the recording at the high head temperature.
Of the two types of dies, leuco-dies are found to be effectively
susceptible to the decolorizing action of polyethylene glycol,
which is incorporated in each layer or applied between adjacent
layers. With this decolorizer excellent results were obtained. For
example, a heat-sensitive sheet having the structure of FIG. 11 and
using leuco-phenylrhodamine for the lower coating layer and crystal
violet lactone for the upper coating layer enabled to obtain clear
records in blue color at the low head temperature and in red color
at the high head temperature. Also, a heat-sensitive sheet having
the structure of FIG. 12 and using the afore-mentioned dies
respectively for the lower and intermediate layers and
leuco-methylene blue for the upper layer enabled to obtain clear
records in green color at the low head temperature, in blue color
at the medium head temperature and in red color at the high head
temperature.
As has been mentioned earlier in connection with the basic
arrangement for the heat-sensitive recorder according to the
invention, the head 6 shown in FIG. 1 is furnished with pulses
provided on the basis of the signal produced from the servo motor 1
in accordance with the speed of the relative movement of the
head.
When the size of the head is taken into consideration, the suitable
rate of the pulse supply is 1 to 5 pulses per millimeter of the
movement of the head. Meanwhile, the suitable width of the record
trace is in a range of 0.3 to 0.5 mm. This means that the size of
the heat tip, which may be either square or circular, is about 0.4
mm on the side or in diameter, respectively. With this size, solid
record trace may be obtained at a pulse supply rate within the
afore-mentioned range of 1 to 5 pulses per mm. At a pulse supply
rate below this range, for instance at a rate of 0.5 pulse per mm,
a broken record trace would result. On the other hand, at a pulse
supply rate of 6 pulses per mm or above the output frequency of the
photo-chopper 11 in FIG. 2 would reach 1.8 KHz at a head speed of
300 mm/sec. Such a high frequency, to which the head cannot
respond, would lead to no effect.
The pulse frequency of the output signal of the circuit 15 in FIG.
2 ensures the supply of pulses to the head to cause the coloring of
the heat-sensitive sheet even when the speed of the head in the Y
direction becomes zero. Its suitable value is 10.sup.2 to 10.sup.5
pulses per mm when the afore-mentioned pulse supply rate according
to the relative movement of the head ranges between 1 and 5 pulses
per mm. If it is outside of this range, the record density in the X
direction would be too high or too low in comparison to that in the
Y direction when the input to the recorder becomes zero even if the
pulse energy is so adjusted as to obtain a suitable record density
in the presence of the input. Although such circumstances are only
prone to fluctuations of the record density in the case of using a
single-color heat-sensitive sheet, in the case of using a
multi-color heat-sensitive sheet the color or hue of recording
would also change, so that the correspondence between input signal
and record would become indistinct.
As mentioned earlier, according to the invention clear records may
be obtained by using single-color and multi-color heat-sensitive
sheets. The selection of the record density and color of recording
can be achieved by adjusting the pulse energy supplied to the head.
To this end, a pulse energy range of 1 to 5 millijoules per pulse
is enough for any one of the afore-mentioned heads. For example,
with a silicon heads as shown in FIG. 1 and a multi-color
heat-sensitive sheet using leuco-die as shown in FIG. 12 clear
records could be obtained in green color with 1 to 2 millijoules
per pulse, in blue color with 2.5 to 3.5 millijoules per pulse and
in red color with 4 to 5 millijoules per pulse.
As mentioned earlier, the record density and color of recording are
affected by the head temperature in the initial stage of recording
before the normal recording condition sets in, and this drawback
can be overcome by having the pulse length and pulse energy
slightly increased during the initial recording stage. By this
means, it is made possible to obtain a constant record quality
without using any extra lead leading to the head and irrespective
of whether the recording is made intermittently or
continuously.
The basic arrangement according to the invention as mentioned
earlier has a further merit in that threshold values of the input
signal and time marks may be additionally recorded in a separate
color in course of the recording by positively controlling the
pulse energy.
With this function it is possible to know exact threshold values
even where the recorder is controlled from a somewhat remote place,
so that the monitoring efficiency can be improved. Also, when
applied to a time marker it is possible to record time marks
without causing any time delay of recording, so that records of
improved reliability may be obtained.
In addition to the afore-mentioned various features of the
invention, it is to be noted that it is very easy to change the
number of heads used in the recorder according to the invention.
This means that it is possible to set any given number of heads to
the recorder.
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