U.S. patent number 3,811,934 [Application Number 05/176,116] was granted by the patent office on 1974-05-21 for heating member.
This patent grant is currently assigned to Flachglas Aktiengesellschaft Delog-Detag. Invention is credited to Hans-Joachim Glaser.
United States Patent |
3,811,934 |
Glaser |
May 21, 1974 |
HEATING MEMBER
Abstract
A heating plate comprises a generally refractory substrate of,
for example, glass upon which is deposited by flame spraying, a
contact member occupying a limited portion of a surface of the
substrate for connecting the heating element in an electric
circuit. The contact member is preferably copper or a copper-based
alloy (e.g. 90 - 99 percent by weight copper, 0 - 9 percent by
weight titanium and 0 - 2 percent by weight chromium). A protective
metal (conductive) layer is provided on the contact member which is
directly formed on the substrate and a heating element is
constituted of a further conductive layer applied over the
remainder of the substrate surface and on the protective layer
covering the contact member.
Inventors: |
Glaser; Hans-Joachim
(Gelsenkirchen, DT) |
Assignee: |
Flachglas Aktiengesellschaft
Delog-Detag (Gelsenkirchen, DT)
|
Family
ID: |
5782012 |
Appl.
No.: |
05/176,116 |
Filed: |
August 30, 1971 |
Foreign Application Priority Data
Current U.S.
Class: |
428/626; 205/186;
219/543; 427/455; 428/633; 428/660; 428/935; 427/124; 428/630;
428/648; 428/926 |
Current CPC
Class: |
H05B
3/06 (20130101); H05B 3/265 (20130101); Y10T
428/12722 (20150115); Y10S 428/935 (20130101); Y10T
428/12806 (20150115); Y10S 428/926 (20130101); Y10T
428/12569 (20150115); Y10T 428/12618 (20150115); Y10T
428/12597 (20150115) |
Current International
Class: |
H05B
3/06 (20060101); H05B 3/22 (20060101); H05B
3/26 (20060101); B44d 001/18 () |
Field of
Search: |
;117/212,217,107,105.2
;219/543 ;338/308,309 ;29/611 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Weiffenbach; Cameron K.
Attorney, Agent or Firm: Ross; Karl F. Dubno; Herbert
Claims
1. A heating plate comprising: an insulating substrate; at least
one metallic electrical contact member of a copper alloy containing
at least 1 percent by weight titanium, chromium or a combination
thereof extending over only a portion of the surface of said
substrate and bonded directly thereto; a metallic protective layer
overlying said member; and an electrically conductive layer
overlying said surface and said protective layer while being in
electrically conductive relationship with said contact member
through said protective layer, said conductive layer forming a
heating element and being directly bonded to said surface over
2. The heating plate defined in claim 1 wherein said copper alloy
consists of 90 to 99 percent by weight copper, 0 to 9 percent by
weight titanium
3. The heating plate defined in claim 2 wherein said copper alloy
consists
4. The heating plate defined in claim 3 wherein said protective
layer has a
5. The heating plate defined in claim 4 wherein said protective
layer is a material selected from the group consisting of gold, a
gold alloy, tin and
6. The heating plate defined in claim 5, further comprising a
diffusion-barrier layer of nickel between said contact member and
said protective layer, said barrier layer having a thickness of 3
to 5 microns.
7. A method of making a heating plate, comprising the steps of:
Flame-spraying an electrical contact member comprising a copper
alloy containing at least 1 percent by weight of titanium, chromium
or a combination thereof onto a portion of the surface of an
insulating substrate;
coating said contact member with a protective layer of a material
selected from the group consisting of gold, a gold alloy, tin and a
tin alloy; and thereafter applying to said surface and said
protective layer an
8. The method defined in claim 7, further comprising the step of
electroplating a nickel layer upon said contact member prior to
the
9. The method defined in claim 7 wherein said protective layer
is
10. The method defined in claim 7 wherein said conductive layer
is
11. The method defined in claim 7 wherein said conductive layer is
deposited by wet-chemical process upon said surface and said
protective layer.
Description
FIELD OF THE INVENTION
The present invention relates to heating elements and, more
particularly, to a method of making a heating element and to an
improved heating element made by this method.
BACKGROUND OF THE INVENTION
Heating elements, disks, plates and the like have been provided
heretofore for many purposes, e.g., for furances, ovens and kilns,
for domestic and industrial heating tasks and as a substitute for
heating coils in appliances of varying sorts. For example, a
heating element of the plate-like type may be used for the baking
or reflowing of paints when mounted in a suitable array adjacent
the transport path of mass-produced articles such as automobiles.
Smaller heating elements of the same general type may be used for
the infrared heating and thawing of foods in toasters, broilers,
roasters and the like. Between these two extremes, there is a
variety of applications for these heating elements which depend
upon the generally planar configuration thereof.
Prior-art heating elements have been provided heretofore for these
purposes in a variety of configurations. For example, a refractory
plate (of circular or rectangular outline) has been formed with a
coil of heating wire (e.g., nichrome) so that the wire lies
substantially in the plane of the surface. Other plate-like
substrates have been formed with recesses or channels receiving
strips or coils of heating wire. Still another construction known
to the art provides a refractory plate upon which a heating element
is deposited or to which a heating element is bonded by an adhesive
or the like so that, upon firing, a ceramic-metal bond is formed.
The heating element in this case may be a metallic conductor or a
semiconductor and the passage of an electric current through the
heating element, having spaced-apart contact members which are
applied to the material forming the heating element, results in
resistive generation of heat. Heating bodies of the latter type
have proved to be especially desirable because the danger of damage
to a heating coil can be excluded and the assembly made more
compact than arrangements using wires, coils and the like. However,
heating bodies (in which the heating element is deposited upon a
refractory substrate and contact members are applied to the heating
element to afford facilities for electrical connection of the
device in a circuit) are characterized by a high production cost,
poor solderability of the contact members to other elements of the
circuit, and poor mechanical properties of the contact members.
Thus the contact members may be dislodged from the heating elements
to which they are bonded and cannot be soldered readily into a
circuit.
OBJECTS OF THE INVENTION
It is, therefore, the principal object of the present invention to
provide an improved heating body whereby the aforementioned
disadvantages are obviated.
It is another object of the invention to provide an improved method
of making a heating vody of the character described.
Still another object of the invention is to provide a heating
device in which the contact members have excellent solderability
and are bonded to the structures with such adhesion that damage to
the connection is substantially completely excluded.
SUMMARY OF THE INVENTION
These objects and others which will become apparent hereinafter are
attained, in accordance with the present invention, in a heating
plate (of disk or circular configuration or of rectangular or any
other desirable outline) which comprises a refractory substrate
(e.g., of glass or a ceramic consisting of alumina, magnesia,
silica, titania, zirconia and mixtures and combinations thereof or
of other minerals containing same) at least one but preferably two
or more metallic electrical-contact members extending over only a
limited portion of the substrate and bonded thereto directly by
flame-spraying a metal protective layer overlying this contact
member or each of the contact members and, in turn, an electrically
conductive layer overlies the protective layer in the region of the
contact member and directly is formed upon the remainder of the
substrate surface. The electrically conductive layer is thus in
electrically conducting relationship with the contact member
(through the protective layer) and forms the heating element.
In other words, the invention comprises a generally flat support
upon which is deposited a heating element of electrically
conductive material in the form of a layer and conductive members
electrically connected to the heating element. The electrically
conductive layer forming the heating element can be composed of
transparent or nontransparent metals or semiconductors in the form
of a thin film or layer, especially of gold, platinum, silver,
copper or aluminum. Suitable semiconductor heating-element layers
are composed, for example, of zinc oxide, doped with antimony. This
example merely represents one of a wide variety of semiconductive
heating elements which may be used, these substances being
generally described as metal oxide doped with a substance from
Group III or V of the Periodic Table. The electrically conductive
layer forming the heating element may be deposited in vacuo upon
the substrate (i.e., vapor-deposited) or can be formed on the
substrate by wet-chemical process. The term "wet-chemical process"
is used herein to describe electroplating or electrodeposition and
so-called chemical plating or electroless plating or
deposition.
The invention resides in applying the contact members directly to
the support by flame-spraying from a copper alloy and thereafter
coating the copper-alloy contact member with a metallic protective
layer, and only thereafter applying the electrically conductive
layer forming the heating element.
A heating plate of this type is of course of much simpler
manufacture than earlier heating elements because complications
which have faced prior-art systems in applying the contact members
to the heating element are eliminated. The contact members are
mechanically locked in the structure and are both solderable and
free from adhesion loss. In effect, therefore, the contact members
are imbedded in a body forming the heating element, thereby
ensuring excellent electrical connection between the heating
element and the contact member.
According to a more specific feature of the invention, the contact
member is composed of an alloy containing copper and at least 1
percent by weight of alloying metals selected from the group which
consists of titanium, chromium or combinations thereof. Best
results have been found with 90 to 99 percent by weight copper, 0 -
9 percent by weight titanium and 0 - 2 percent by weight chromium.
For reasons it has been unable to fully ascertain, this alloy bonds
directly to glass or ceramic substrates significantly better than
other alloys and is particularly suitable for flame-spraying
without causing difficulties during the process. In addition, it
has high solderability.
According to another feature of this invention, the protective
layer is applied in a thickness ranging between molecular thickness
and 1 micron, i.e., in a thickness up to 1 micron, and consists of
gold or a gold alloy, or tin or a tin alloy. The protective layer
should be resistant to oxidation and should be solderable or
capable of forming electrical connections of low contact
resistance. Gold, tin and their alloys fulfill these requirements.
The protective layer may be applied by chemical plating, galvanic
(electroplating) flame-spraying or vapor deposition, the latter
being preferred.
Advantageously, the diffusion barrier layer of nickel, to a
thickness of 3 to 5 microns, is applied between the copper-alloy
contact member and the protective layer, e.g., by galvanic methods.
This barrier prevents diffusion of the contact material into the
protective layer and also prevents diffusion of material from the
protective layer into the contact member. The electrically
conductive layer which preferably covers the remainder of the
surface of the substrate, is applied by vapor deposition.
The system described above has some significant advantages over the
prior art, aside from the not unimportant advantage of
substantially reduced cost. The bond between the contact member and
the substrate, especially when the latter is composed of glass, is
specially strong and ablation of the contact member need not be
feared. The contact member can be soldered with ease to other
circuit elements without the danger of dislodging because
mechanical and thermal conditions during the soldering operation.
While it is preferred to use a glass or ceramic support as
described above, it has been found that even synthetic resin (e.g.,
phenolic supports) may be used.
DESCRIPTION OF THE DRAWING
The above and other objects, features and advantages of the present
invention will become more readily apparent from the following
description, reference being made to the accompanying drawing in
which:
FIG. 1 is a plan view of a portion of a heating plate according to
the present invention;
FIG. 2 is a section taken along the line II -- II of FIG. 1;
FIG. 3 is a view similar to FIG. 2 but illustrating another
embodiment of the invention; and
FIG. 4 is a flow diagram illustrating the method of the
invention.
SPECIFIC DESCRIPTION
In FIGS. 1 and 2, it can be seen that the heating plate according
to the present invention comprises a glass substrate 1, which can
be of rectangular or any other configuration, e.g., circular, that
may be desired. An electrically conductive layer 2, (e.g. of the
order of thickness of 1 to 50 microns) is applied to this substrate
over substantially its entire surface and directly adheres thereto.
The strip-like contact member 3, to which other circuit elements
are connected by soldering, is applied adjacent an edge of the
heating plate and represents a plurality (at least 2) contact
members. The contact members 3 are applied directly to the glass
plate 1 by flame-spraying and consist of a copper-alloy body 4
which is coated with a layer 5 of gold, tin, or an alloy thereof.
In the region of the contact members, the layer 2 overlies the
protective layer 5.
FIG. 3 shows a modification wherein the substrate 1 carries
directly the flame-sprayed strip 4 of copper alloy but is coated,
in turn, with 3 to 5 microns of a nickel layer 10. The gold or tin
protective layer 5 is thereupon applied to the nickel layer and the
heating element layer 2 formed thereover.
SPECIFIC EXAMPLE
As diagrammed in FIG. 4, the substrate, e.g., glass, is degreased
and, if desirable, roughened by abrasion, in the region of the
contact strip or slightly edged over its entire surface with
hydrofluoric acid. The glass plate had a thickness of 10 mm and was
composed of quartz glass. At the first stage (I) of the process, a
copper alloy consisting of 97.3 percent by weight copper, 2.3
percent by weight titanium and 0.4 percent by weight chromium, was
deposited on the glass in the form of a strip 4 at a temperature
slightly above the melting point of the alloy. In the second stage
(II), a 4-micron layer of nickel was electro-plated at a
temperature of about 40.degree.C with a cathode-density of 25
amp,./square foot and an anode current density of 8 amp./square
foot from a nickel sulfamate plating bath. After the layer was
thoroughly dried, 0.9 microns of gold was vapor-deposited followed
by the heating element layer 2 to a thickness of 25 microns. The
heating element layer was composed of copper. The contact member
was found to be firmly adherent to the glass substrate and even
during soldering was not released therefrom.
* * * * *