U.S. patent number 3,807,181 [Application Number 05/256,666] was granted by the patent office on 1974-04-30 for underground storage of gas.
This patent grant is currently assigned to Edeleanu Gesellschaft mbH. Invention is credited to Gerhard Kuhne.
United States Patent |
3,807,181 |
Kuhne |
April 30, 1974 |
UNDERGROUND STORAGE OF GAS
Abstract
A method is disclosed for storage of a gas which is soluble in a
liquid hydrocarbon in an underground storage cavity wherein the
cavity is continuously filled with liquid even when recovering the
gas.
Inventors: |
Kuhne; Gerhard (Pinneberg,
DT) |
Assignee: |
Edeleanu Gesellschaft mbH
(Frankfurt, DT)
|
Family
ID: |
5809317 |
Appl.
No.: |
05/256,666 |
Filed: |
May 25, 1972 |
Foreign Application Priority Data
|
|
|
|
|
May 29, 1971 [DT] |
|
|
2126823 |
|
Current U.S.
Class: |
405/59 |
Current CPC
Class: |
B65G
5/00 (20130101); F17C 11/007 (20130101) |
Current International
Class: |
F17C
11/00 (20060101); B65G 5/00 (20060101); B65g
005/00 () |
Field of
Search: |
;61/.5 ;48/190 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Stein; Mervin
Assistant Examiner: Grosz; Alexander
Attorney, Agent or Firm: Whaley; Thomas H.
Claims
I claim:
1. In a method for the storage of a gas which is soluble in a
liquid hydrocarbon the improvement which comprises first
introducing the gas into an underground cavern which contains a
storage liquid comprising a hydrocarbon in which the gas is soluble
in order to at least partially solubilize said gas for storage and,
when at least a portion of said gas is to be removed,
removing storage liquid containing said portion of said dissolved
gas substantially and,
replacing said storage liquid with a pressure equalizing amount of
a replacement liquid of higher specific gravity and immiscible with
the storage liquid.
2. A method according to claim 1 in which the replacement liquid is
water.
3. A method according to claim 1 in which the replacement liquid is
brine.
4. In a method for the storage and recovery from an underground
cavern in a salt deposit of a gas comprising hydrogen or a normally
gaseous hydrocarbon the improvement which comprises
introducing said gas to be stored into a cavern containing a lean
liquid comprising a normally liquid hydrocarbon in which the gas is
soluble in an amount sufficient to at least partially solubilize
the gas and provide a rich storage liquid,
recovering the dissolved gas by withdrawing rich storage liquid
from the cavern by volumetrically displacing the rich storage
liquid with water in an amount sufficient to substantially maintain
constant pressure conditions and
reducing the pressure thereon to liberate the dissolved gas.
5. A method according to claim 4 in which the water is brine.
6. A method according to claim 4 in which the storage liquid is a
petroleum fraction.
7. A method according to claim 4 in which the petroleum fraction is
a hydrocarbon petroleum gas oil fraction.
Description
BACKGROUND OF THE INVENTION
The invention relates to a method and to apparatus for the storage
recovery of gases soluble in liquid hydrocarbons in and from
underground cavities, caverns or voids.
It is known to use underground caverns for storing gases and
liquids for the purpose of covering peak requirements and for
storing hydrocarbons, particularly crude oils, middle distillates
and lighter hydrocarbons, for the building up of stocks. Gases,
particularly natural gas, are stored in and extracted or withdrawn
from the stores by compression and expansion of the contents of the
"dry" caverns. For this purpose, the pressures must not be below a
determined minimum pressure for the sake of the required stability,
and must not exceed a determined maximum pressure by reason of the
limited resistance of the rock to fracture, both being dependent
upon the existing depth.
Thus, for example, in German Auslegeschrift No. 1,246,641 there is
described a method for the subterranean storage of liquids in a
cavern in a salt deposit. In this method, the pressure of a
compressed medium is used for withdrawing the liquid through a
rising tube. The method is characterized in that for the storage
only part of the cavern is filled with the liquid to be stored,
there being introduced over the liquid, and preferably up to the
roof of the cavern, cushion of liquefied gas in equilibrium with
the overlying vapor phase, the depth of the cavern, the level of
the liquid stored in the cavern and the height of the cushion of
liquefied gas being so selected that upon withdrawal substantially
all of the liquid is removed or extracted from the cavern when all
of the liquefied gas has evaporated.
This method has the disadvantage that the salt cavern is not always
completely filled with the stored liquid. Moreover, this method is
used exclusively for the storage of liquids, the dissolved gas
serving solely as the drive medium for the extraction or withdrawal
of the liquid.
It is also known that gases which are soluble in hydrocarbons may
be dissolved in liquid hydrocarbons stored underground.
In contrast to the former method, the latter method involves
exclusively the storage of gaseous hydrocarbons.
The invention disclosed in U.S. Pat. No. 2,930,197 relates to a
method and to apparatus for the storage of gaseous petroleum
components or derivatives under high pressure in caverns, and
particularly to the storage of such components as ethylene. The gas
is stored by introducing it into the cavern through a pipe line
which terminates below the surface of a quantity of oil pumped into
the cavern. As the gas rises through the oil, a portion of the
rising gaseous petroleum constituents dissolves in the oil. The
undissolved gas is returned to the first pipe line through a second
pipe line provided in the above-ground portion of the borehole
tubing and is then pumped back into the body or pool of oil in the
cavern. This process is repeated until the oil is saturated with
the gas. The internal pressure in the cavern may amount to about 32
to 70 atmospheres according to the amount of ethylene dissolved in
the oil, for example n-heptane. The gas is recovered by opening a
valve in the above-ground portion of the borehole tubing. The
dissolved gas is liberated by the absorption oil as a result of the
increased temperature internally of the cavern when the pressure in
the cavern falls upon opening of the valve. This method has the
disadvantage that, according to the U.S. Pat. No. 2,930,197, only
part of the cavern is filled with the absorbing liquid and the
borehole is never filled therewith to a level which is
above-ground, that is, to above ground level, and is thus subject
to excess pressure increases with increasing gas filling. This
excess pressure, particularly at the generally occur depths of salt
deposits is unable to prevent the cavern from being reduced in size
and even being completely closed by the flowing together of rock
salt already plasticized by the rock pressure.
Owing to the plastic properties of salt formations or deposits, the
greater the tendency of the voids or cavities, particularly salt
caverns, to shrink the lower the counter-pressure exerted by their
contents (i.e., liquid and gas) upon the rock faces or walls. The
time for which caverns of this kind can be used is determined by
the ratio of the internal pressure to the rock or roof pressure.
The range of fluctuations of the rock or roof pressure has
disadvantageous consequences, since shrinkage stresses rise due to
partial relief or evacuation. This is a slow process because when
the internal pressure rises again, these impulses for movement are
not reduced immediately and decay only over an extended period of
time.
Caverns constantly filled with a liquid are much less susceptible
to these convergence-accelerating tendencies. The shrinkage may
even be virtually completely suppressed if the pressure of the
liquid completely filling the cavern is increased to the order of
magnitude of the rock or roof pressure. This occurs automatically
where the discharge of liquid from a cavern with liquid is stopped
by means of a shut-off device or valve provided at the top of the
borehole. The internal pressure produced in the cavern by residual
shrinkage approaches asymptotically the rock or roof pressure with
simultaneous utilization of the compressibility of the fluid.
It has also been proposed to store natural gas or methane in
chilled liquid propane. In order to attain practical significance,
this method involves a high capital expenditure for the necessary
heat insulation and considerable operating costs for maintaining a
constant low temperature in the storage tank or container. This
method seeks to convert the natural gas and propane and/or butane,
if necessary with an admixture of air into a mixture having
appropriate combustion qualities and to offer such mixture to the
consumer.
It is an object of this invention to provide a method for the
storage and recovery of gases, which are soluble in liquid
hydrocarbons in and from subterranean caverns in which the changing
loads or stresses applied to the caverns are avoided or
substantially reduced whereby a substantially constant storage
volume may be maintained.
SUMMARY OF THE INVENTION
A method for the storage in, and recovery from, an underground
cavern a gas solublized in a liquid hydrocarbon solvent therefrom
which comprises introducing the gas to be stored into a cavern
which is completely filled with liquid all or a part of which
comprises the solvent to form a rich solvent solution of the gas
and recovering the dissolved gas by withdrawing rich solvent from
the cavern and thereafter reducing the pressure on the rich solvent
in order to liberate the dissolved gas, while replacing the rich
solvent with a pressure-equalizing amount of a liquid comprising
lean solvent or a displacement liquid or both.
DESCRIPTION OF THE INVENTION
In the method according to the invention, the gas or gases to be
stored are introduced through a feed pipe which extends to the
lower part of a subterranean cavern which is filled completely with
liquid hydrocarbons in which the gases dissolve, the cavern being
in communication through a borehole with aboveground, the gases
being recovered by withdrawal of the liquid hydrocarbons containing
the dissolved gases by expansion.
The gas to be stored may be any normally gaseous material, for
example, hydrogen, methane, ethane, propane, ethylene and
propylene.
The method according to the invention affords the advantage that
the cavern is filled completely with a liquid medium and a
deformation or reduction in the size of the cavern is thus
substantially avoided.
A distinctive feature of the method according to the invention
comprises replacing rich solvent withdrawn from the cavern with a
volume of liquid corresponding to the volume of withdrawn liquid is
introduced to the cavern so that the liquid volume may remain equal
and the pressure ratios or conditions may be maintained
substantially constant. The liquid so introduced may comprise lean
solvent or may comprise a higher specific gravity liquid which is
preferably introduced through a further pipe which extends into the
lower part of the cavern and terminates below the orifice of the
gas feed pipe.
This development affords the advantage that the internal pressure
in the cavern remains substantially constant even upon extraction
or withdrawal of the rich solvent containing dissolved gas.
The preferred liquid of higher specific gravity is water,
particularly salt water which is introduced into the cavern.
Alternatively, the salt water in the sump or bottom of a salt
cavern may be used for equalizing the liquid volume and for
maintaining substantially constant the pressure ratios or
conditions.
The invention also comprises apparatus for carrying out the method,
the apparatus being characterized in that the borehole extending
into the underground cavity or cavern is associated with a feed
pipe one end of which extends into the lower zone or part of the
cavern whilst its other end above ground is connected by a pipe
line to a device for conveying the gaseous hydrocarbons to be
stored, the upper end of the borehole being also connected by a
further line to a separator in which the stored rich solvent may be
separated into lean solvent and a gas.
This apparatus enables the gases which are to be stored to be
introduced into the lower part of the subterranean cavern filled
with liquid which consists wholly or for the major part of one or
more liquid hydrocarbons, so that the gases as they rise are
dissolved in the liquid hydrocarbon solvent as a result of the
prevailing pressure conditions. The cavern is filled with liquid as
far as the borehole annular space disposed aboveground, to produce
the internal pressure.
The distinguishing feature of another embodiment or modification of
the invention consists in the provision of a further pipe by which
salt water, for example, in the sump of the cavern is placed in
communication with an equalizing or expansion tank disposed above
ground, the further pipe being mounted coaxially with the feed pipe
to project beyond, and preferably from, the top and bottom ends of
the pipe.
The equalization or balancing of the volume by the salt water in
the lower zone of the cavern may thus be carried out simultaneously
with the withdrawal of the dissolved gases without the stored
liquid material returning or flowing to the equalizing or expansion
tank.
It follows from the above that the application of the invention
affords particular advantages where regulatory provisions have to
be met and/or where liquid hydrocarbons have to be stored for
building up a stock. The otherwise unused capacity of a cavern is
thus additionally utilized for the storage of gases.
The invention is diagrammatically illustrated by way of example in
the accompanying drawing which also shows further inventive
features.
The subterranean cavity or cavern 4 contains, preferably, crude oil
which is free from gas under normal conditions, or a gas-free
fraction or refined product thereof, for example a gas oil which is
a petroleum fraction having a boiling range between kerosine and
light lubricating oils. Methane, for example, is more readily
absorbed at low temperatures than at temperatures corresponding to
the temperatures which exist in the deposits, stratum or strata in
which the cavern is disposed, but the fluids in the cavern are
subject to the high pressure applied by the weight of the salt
water column which extends to above ground level. Where a depth of
1,000 meters is involved, the pressure may for example, amount to
120 atmospheres. Solubility increases in direct proportion to the
pressure. At temperature of 35.degree.C. and a pressure of 120
atmospheres, the solubility of methane in gas oil is about 40
normal cubic meters of gas per cubic meter of gas oil. This implies
that 200,000 cubic meters of gas oil absorb 8 million normal cubic
meters of gas with only a slight increase in the total volume. Up
to 14 million normal cubic meters of gas may be stored by
increasing the pressure in the cavern, which pressure may be
increased to about 200 atmospheres where a depth of 1,000 meters is
involved.
A virtually total recovery of the gas without any residual gas
cushion in the store cavern may be obtained in optional cycles by
pressure release. For total recovery, the pressure on a volume of
the fluid mixture withdrawn from the store cavern is reduced in a
separating installation to substantially atmospheric or a still
lower pressure. The gas can be passed without further treatment by
means of a low-pressure compressor installation to a consumer
whilst the liquid product of pressure release, namely the liquid
hydrocarbon or hydrocarbons, for example the gas oil, is
simultaneously pumped back into the cavern.
The gas to be stored is passed through line 1 to a high-pressure
compressor 2 which forces the gas into an annular space 3 in a feed
pipe 5 which extends into the lower section of a subterranean
cavern 4, the annular space 3 being formed by the feed pipe 5 and
an inner coaxial pipe 6. The cavern 4 is filled mainly with oil,
only the lowermost section into which the pipe 6 extends, being
filled with salt water 7 which is immiscible with and has a higher
specific gravity than the oil.
The gas introduced under pressure is, as it rises in the oil
filling of the cavern, absorbed by the oil; this process may be
continued to saturation point.
In accordance with the changing pressure conditions prevailing in
the cavern 4 and its associated borehole 8, which pressure
conditions vary according to the depth, a gas cap develops at the
upper end 9, that is at the position of the lowest pressure. When
necessary, that is to say, when gas is to be withdrawn from the
store, the gas cap may be discharged through a separator 10. The
dry gas leaving the separator 10 is then returned by a low-pressure
compressor 11 to the gas network through the conduit 1. The oil
which separates from the gas in the separator 10 is returned by
means of a pump 12 to the annular space 3 and thus to the lower
section of the cavern.
Upon absorption of the gas, the oil in the cavern increases
slightly in volume. This increase in volume is equalized through
the pipe 6 which dips into the body of salt water 7 present in the
lowermost part of the cavern 4, a volume of salt water equal to
such increase in volume being fed from the upper end of pipe 6
through a line 13 to a salt water tank (not shown). Salt water
returns from the tank to the cavern 4 along the same path when the
volume of the oil in the cavern is reduced as a result of gas being
withdrawn from the cavern. The pressure conditions required for
storing the gas by dissolution in the oil are produced by the
weight of the salt water column in the pipe 6 which extends from
the top 14 of the borehole into the body of salt water 7 present in
the lowermost part of the cavern 4. An equalization of the volume
is not necessary when the increase in volume which would otherwise
occur can be taken up by the compressibility of the liquids in the
cavern in the form of a pressure rise without the walls of the
cavern being fractured; this is dependent upon the depth at which
the cavern is disposed, that is to say, upon the geological
conditions.
* * * * *