U.S. patent number 3,804,059 [Application Number 05/219,072] was granted by the patent office on 1974-04-16 for device for the application of a metal coating on the internal cylindrical surface of a hollow body.
This patent grant is currently assigned to Cockerill-Ougree-Providence et Espirance-Longdoz. Invention is credited to Dominique Thomas Francois Leon Streel.
United States Patent |
3,804,059 |
Streel |
April 16, 1974 |
DEVICE FOR THE APPLICATION OF A METAL COATING ON THE INTERNAL
CYLINDRICAL SURFACE OF A HOLLOW BODY
Abstract
In a device for the application of a metal coating on the
internal surface of a hollow metal element in the form of a
cylinder of revolution there is provided a sealed enclosure adapted
to be placed on to said hollow element, a pumping set for
generating a high vacuum in said enclosure which is provided with a
hole cooperating with an orifice in said hollow element,
electrically conductive elements passing through said hole of said
enclosure from which they are insulated, a source of current
connected to said conductive elements and a vapour emitter
connected to said conductive elements and adapted to be introduced
into said hollow metal element.
Inventors: |
Streel; Dominique Thomas Francois
Leon (Cointe-Schlessin, BE) |
Assignee: |
Cockerill-Ougree-Providence et
Espirance-Longdoz (Seraing-Les-Liege, BE)
|
Family
ID: |
3874351 |
Appl.
No.: |
05/219,072 |
Filed: |
January 19, 1972 |
Foreign Application Priority Data
Current U.S.
Class: |
118/726 |
Current CPC
Class: |
F17C
1/10 (20130101); C23C 14/046 (20130101); F17C
2203/0607 (20130101); F17C 2203/0639 (20130101); F17C
2223/0153 (20130101); F17C 2221/012 (20130101); F17C
2223/0123 (20130101); F17C 2203/0648 (20130101); F17C
2201/0109 (20130101); F17C 2209/232 (20130101); F17C
2203/0636 (20130101); F17C 2203/0646 (20130101); F17C
2260/053 (20130101); F17C 2201/0119 (20130101); Y02E
60/321 (20130101); F17C 2201/032 (20130101); Y02E
60/32 (20130101) |
Current International
Class: |
C23C
14/04 (20060101); F17C 1/10 (20060101); F17C
1/00 (20060101); C23c 013/12 () |
Field of
Search: |
;118/48-49.5 |
References Cited
[Referenced By]
U.S. Patent Documents
Foreign Patent Documents
Primary Examiner: Kaplan; Morris
Attorney, Agent or Firm: Young and Thompson
Claims
What I claim is:
1. Apparatus for the application of a metal coating to the internal
cylindrical surface of a steel bottle for compressed or liquefied
gases, said bottle being of the type having a reduced neck that
opens along the axis of said cylindrical surface, said apparatus
comprising a removable sealed enclosure adapted to be placed on
said neck, said enclosure being cylindrical and having a
cylindrical side wall and opposite end walls, means carried by one
of said end walls for registry with a said neck of a said bottle
and defining an opening through said one end wall, pumping means
connected to an opening into said sealed enclosure through said
cylindrical side wall for generating a high vacuum of approximately
10.sup..sup.-4 torr in said enclosure and in said steel bottle,
electrically conductive elements passing through and insulated from
a wall of said enclosure, a source of current connected to the
external ends of said conductive elements, a vapor emitter
comprising a refractory steel wire coated with a layer of
vaporizable metal to be deposited as the coating and wound in coil
form and connected at one end to an end of an electrically
conductive bar, said wire and bar lying generally along the axis of
said bottle and connected at their opposite ends to the internal
ends of said conductive elements, said wire and bar being adapted
to pass through said hole and said neck for introduction into said
steel bottle, means mounting said bar and refractory steel wire for
sliding movement between a position in which said wire is entirely
disposed within said enclosure and a position in which said wire
extends through said opening and neck into said bottle, and means
responsive to contact between said bar and the inside of the base
of said bottle to cause an electric current to flow from said
source of current through said wire to heat said wire to emit said
vapor.
Description
The present invention relates to devices for the application of a
metal coating on the internal surface, having the form of a
circular cylinder, of a hollow unit.
Steel vessels, and bottles or cylinders in particular, are used at
the present time for conveying and containing various compressed or
liquefied gases.
The vessels, which consist of thick-gauge steel, are exposed to
corrosion caused by the gases or liquids they contain. As a result
of moisture present in the said gases or liquids, rust may form in
the vessels which is liable to contaminate their contents.
On the other hand, some gases, such as hydrogen in particular,
diffuse into steel to cause embrittlement of the latter, which may
give rise to serious accidents during storage in tanks or during
conveying in steel pipelines or ducts. The risk of such accidents
increases as the storage pressures in the tanks and bottles and the
pressures in the conveying pipelines are increased.
However, there is a trend towards a substantial increase in gas
pressure in the bottles and the degree of acceptable corrosion is
thus reduced considerably, so that it is necessary to incorporate
an internal protective coating.
To eliminate the shortcomings caused by corrosion and by the
decrease in the strength of the steel, it is known to protect the
internal surface of the walls of vessels, particularly bottles or
cylinders, made of steel, by covering these with a plating which
commonly consists of a thin-gauge sheet of stainless steel applied
in the course of production. In consequence of this covering, the
production cost of a vessel thus equipped, is high. This is due to
the fact that the material employed for the plating is not only
expensive but also implies high costs since considerable labour is
required to achieve the covering.
Moreover, it may occur that the coating or plating may crack or
weaken during the life of the vessel; it is then impossible to
perform any kind of restoration or repair, rendering it unusable
for its original purpose, at least.
The known methods for the application of a coating do not offer
complete satisfaction in respect of coating strength and, by their
effect on purchase price, they are likely to restrict the use of
gases in bottles.
The fundamental problem of the invention consists in producing a
device which renders it possible to apply an adherent metal coating
and which may easily undergo restoration or repair if need be, on
the internal surface, having the form of a circular cylinder, of a
hollow element, in easy, reliable and economical manner.
One solution to the problem raised by the application of a metal
coating on the cylindrical internal surface of a hollow metal
element is achieved by means of a device according to the
invention, which is characterised in that it comprises a sealed
enclosure adapted to be placed over the said hollow element, a
pumping set connected to the said sealed enclosure for the purpose
of generating a high degree of vacuum therein, a hole in the sealed
enclosure co-operating with an orifice on the axis of revolution of
the cylindrical internal surface of the said hollow element,
electrically conductive elements passing through a wall of the
enclosure from which they are insulated, a source of current
connected to the external ends of the said conductive elements, and
an emitter of metal vapours connected to the internal ends of the
said conductive elements and arranged to pass through the said hole
and the said orifice and into the hollow element.
According to one feature, the metal vapour emitter consists of a
steel wire coated with a layer made of a vapourisable metal
intended to form the said coating. This wire forming the emitter
may be positioned along the longitudinal axis of the internal
cylindrical surface of revolution which is to be coated.
The invention will be further described in connection with the
accompanying drawings which show two examples of embodiment of the
invention, solely by way of illustration.
IN THE DRAWINGS:
FIG. 1 is a diagrammatical view in section of a device according to
the invention, employed for the application of a coating on the
internal surface of a gas bottle.
FIG. 2 is a diagrammatical view, to a different scale, of another
form of sealed enclosure.
FIG. 1 shows a sealed enclosure 2 of cylindrical form equipped with
a lateral pipe 3 leading to a vacuum pump 4. This pump evacuates
the air from the enclosure 2 and generates a vacuum of
approximately 10.sup.-.sup. 4 Torr in the same. In the base of the
enclosure 2 there is an orifice 5 closed off by a hermetic
clack-valve or the like 6; around the orifice 5, on the outer
surface, there is a hermetic seat 7 against which is thrust a neck
8a of a steel bottle 8 which is to have its internal surface
provided with a protective metal coating, for example of nickel.
This bottle 8 is placed on a carrying plate 9. The clack-valve 6 is
opened by a suitable mechanism, which is not shown, which places
the inside of the bottle 8 in direct communication with the inside
of the enclosure 2; a vacuum of approximately 10.sup..sup.-4 Torr
is thus also established within the bottle 8, and the enclosure 2
is firmly thrust on to the bottle 8 in this manner.
The time required to obtain this vacuum depends on the power of the
vacuum pump 4. As soon as the appropriate vacuum is reached within
the enclosure and the bottle, a control which is not shown causes a
metal vapour emitter 10 to slide on a guiding bar 11, so as to
enter the bottle 8 along the axis 8b of the same. This emitter
comprises a wire 10 of a diameter of approximately 1 mm consisting
of a refractory metal such as tungsten, which is wound in coil form
and sheathed with a layer of a thickness of approximately 0.1 mm
consisting of the vapourisable metal which is to form the internal
coating of the bottle. A rigid bar 12 of electrically conductive
metal is carried by arms 15 sliding on the guiding bar 11 up to the
edge of the neck; the length of the wire 10 wound in coil form and
the length of the bar 12 are a little greater than the length of
the axis 8b of the bottle. The plating metal may be nickel,
chromium, aluminium, cadmium, cobalt, zinc, or an alloy of these
metals.
When the free lower end 12a of the bar 12 comes into abutment
against the inside of the base of the bottle, this closes an
electric circuit 13 connected by the corresponding conductors 13a
to the wire 10 and to the bar 12, an electric current of
approximately 60 amps, having a voltage of approximately 24 volts,
which is supplied by a source of current 14, flows through the bar
12 and the wire 10; this latter forms an electric resistance and
undergoes heating to a high degree together with the metal
sheathing the same, which latter is rapidly brought to a
temperature exceeding its melting point; this metal is then
volatilised and deposited over the entire internal surface of the
wall of the bottle 8 in an even and homogenous layer.
The operation is completed after a period lasting from 3 to
approximately 30 seconds; if it is wished to obtain a thick coating
on the inside of the bottle, the operation may be repeated several
times if required. When the final coating has been obtained, it is
then possible to expose the bottle, with its internal coating, to a
tempering operation for the purpose of engendering a definite
degree of diffusion of the plating metal and secure a perfect
bond.
Another form of embodiment of the enclosure, which is a removable
head unit, is shown in FIG. 2. This head unit comprises a box 16
closed off by a cover 17 held in position by tightening nuts 18a
screwed to screw-threaded bolts 18 hinged on the said box; the
hermeticity of the cover is secured by means of a gasket 19. The
box has lateral pipe 16a which is connected by means of a
reinforced flexible pipe, which is not shown, to a vacuum pump
which is not shown. In the cover 17 are set, insulated by means of
plugs 17a, two electrically conductive elements 20 whereof the
external ends 20a are connected to a source of current, which is
not shown, whereas the internal ends 20b are connected to a metal
vapour emitter analogous to that illustrated in FIG. 1; the emitter
also comprises one branch consisting of a straight rigid bar 21 and
a branch formed by a steel wire 22 wound in coil form and coated
with a layer of the metal which is to be deposited. These two
branches 21 and 22 pass through a hole 23 in the bottom of the box
16. The source of current supplies a current of high intensity and
low voltage, which may amount to 62.5 amps under 24 volts, for
example.
When the head unit is placed on an axial orifice in a hollow steel
element such as a cylindrical gas bottle, and if the vacuum pump is
then placed in operation, a vacuum of approximately 10.sup..sup.-3
to 10.sup..sup.-4 Torr is then rapidly generated within the head
unit and the bottle. If the wire coil 22 is supplied with a zinc
coating of approximately 250 grs per m.sup.2 or approximately 2 grs
of zinc for the surface of the wire, and if a current of
approximately 60 amps is then allowed to flow through for
approximately 10 seconds, the zinc is vapourised almost totally as
a result of the heating of the wire 22; the vapours it produces are
condensed on the internal surface of the wall of the bottle, in
such manner that if the latter has a height of 80 cms and an
internal diameter of 20 cms, a coating of a thickness of
approximately 0.5 micron is deposited.
If it is wished to increase this thickness, it is sufficient to
repeat the operation several times, corresponding to the thickness
required; the operation is thus performed four times to obtain a
layer of 2 microns. The coating obtained is of dark grey appearance
and offers excellent protection against corrosion.
It is also possible to perform this operation whilst employing a
metal other than zinc and such as, for example, cadmium, chromium,
nickel, aluminium; moreover, after depositing the coating, it is
possible to expose it to a tempering operation intended to cause
its diffusion; it is apparent that the conditions of application
vary according to the nature of the metal to be deposited, which
are determined in each particular case; it is thus that the vacuum
within the hollow element, the intensity of the current, and the
voltage will vary according to the metal to be deposited.
* * * * *