U.S. patent number 3,802,078 [Application Number 05/150,462] was granted by the patent office on 1974-04-09 for cutting device and method for making same.
Invention is credited to Peter A. Denes.
United States Patent |
3,802,078 |
Denes |
April 9, 1974 |
CUTTING DEVICE AND METHOD FOR MAKING SAME
Abstract
A cutting device which may have a fine cutting edge including a
metal or alloy blade of the desired sharpened form on which is
deposited a hard cutting later of thickness less than one micron,
the cutting layer being of hard particles having a Vickers
microhardness greater than 1000 kg/mm.sup.2 embedded in a
codeposited metal or alloy matrix. Methods for producing such
cutting devices are also disclosed.
Inventors: |
Denes; Peter A. (Albuquerque,
NM) |
Family
ID: |
22534640 |
Appl.
No.: |
05/150,462 |
Filed: |
June 7, 1971 |
Current U.S.
Class: |
30/350;
204/192.16; 30/346.53 |
Current CPC
Class: |
B26B
21/60 (20130101) |
Current International
Class: |
B26B
21/60 (20060101); B26B 21/00 (20060101); B26b
009/00 (); B26b 021/54 (); C23c 015/00 () |
Field of
Search: |
;30/346.53,346.54,350
;148/6.3 ;51/26R ;204/192 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Mack; John H.
Assistant Examiner: Valentine; D. R.
Attorney, Agent or Firm: Lund; Van Metre
Claims
What is claimed is:
1. A cutting device comprising:
a. a preshaped and sharpened base composed of metal and having an
acute angle cutting edge; and
b. a composite coating formed on the cutting edge of said base and
having a thickness of less than one micron;
c. said composite coating comprising hard particles of a size less
than 500 Angstrom and having a Vickers micro-hardness greater than
1000 kg/mm.sup.2 ;
d. said composite coating further comprising a metal matrix having
said hard particles embedded and substantially uniformly
distributed therein and being effective to form a finely interwoven
structure in which said hard particles are bound together and to
said base;
e. said metal matrix being of a corrosion resistant metal;
f. said hard particles having a volume percentage between 20 and 80
percent of said composite coating.
2. A cutting device as defined in claim 1 wherein said hard
particles are selected from a group of materials consisting of
metal oxides, carbides, borides, nitrides and silicides.
3. A cutting device as defined in claim 2, said base being of
stainless steel.
4. A cutting device as defined in claim 3, said metal matrix being
of a metal alloy.
5. A cutting device as defined in claim 4, said metal matrix having
a diffusion alloy bond to said base.
Description
BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to improvements in cutting devices and more
particularly to improved cutting devices which have acute angle
cutting edges coated with an extremely hard adherent layer.
2. Description of the Prior Art
Razor blades made of a thin alloy base, such as stainless steel,
for example, provided with a thin coating which is harder than the
base, are known in the prior art. Such thin hard coatings of the
known razor or industrial blades are, however, generally of a metal
or alloy, such as, for example, chromium or the like.
Also, it has been proposed to produce razor blades and other
devices requiring fine cutting edges by mixing binder particles,
such as metals or ceramic oxides, with a metal carbide. Such
blades, however, have never been successfully manufactured because
the metal carbides, like many binders, are of ceramic nature, and a
very thin cutting edge of these materials is not self-supporting,
even with an unacceptably large percentage of binder.
Others have recommended coating flat cutting edges, such as dry
shaver heads, with a thin layer of titanium carbide or titanium
boride. Such coatings, also being of ceramic nature, do not adhere
well to the base, and, being very brittle, crumble easily.
In the past, metal hard particulate material composites have been
used successfully only in grinding tools or devices which have an
adequate supporting thickness. For example, in grinding wheels
having a coating thickness of 10 mm or more, and even in very small
grinding wheels of such thickness of 2 mm or more (these dimensions
are about 100,000 greater than the desirable coating thickness of a
razor blade), the ceramic-like materials of interest herein are
useable since they are self-supporting in such large
thicknesses.
BRIEF DESCRIPTION OF THE INVENTION
In light of the above, it is a general object of the invention to
provide a cutting device which has a very hard, acute angle cutting
edge.
It is another object of the invention to provide a hard,
long-lasting cutting edge including hard cutting particles which
resist crumbling.
A further object of the invention is to provide a coating of hard
particles and binding metal or alloy to produce a cutting edge
having a fine texture for very smooth cutting.
Still another object is to provide methods by which thin and very
hard cutting coatings can be deposited upon a base of the desired
shape, like razor or industrial blades, microtome blades, or other
such blades having such fine cutting edges.
These and other objects, features, and advantages, will become
apparent to those skilled in the art from the following
description, read in conjunction with the accompanying drawings and
appended claims.
It has been found that the foregoing objects may be attained by
introducing onto a metal base or substrate a codeposition of a thin
metal or alloy layer and hard particulate material embedded
therein. The base or substrate may be shaped to define an acute
angle cutting edge of the desired ultimate shape or
configuration.
The thickness of the hard coating, determined by elasticity and
strength requirements of the fine cutting edge desired, may be less
than 1 micron thick and in many cases may be even less than 0.1
micron.
Such cutting edges are generally not re-grindable, due to the very
thin coating which in many cases will be removed by grinding.
Therefore, they may be particularly advantageously employed as
disposable cutting devices such as razor blades, industrial blades,
microtome knives and other devices with insertable blades, although
thicker bladed or larger knives such as kitchen knives and the like
may also be supplied with such cutting coatings, which,
nonetheless, may withstand quite a few sharpenings when needed,
since such cutting devices may not require resharpening for many
years of usage. Such hard coating displaying cutting surfaces may
also be employed in other acute angle cutting devices, such as
scissors, electric carving knives, or the like.
Thus, in accordance with the invention, a new cutting device is
disclosed which is formed of a shaped and sharpened metal or alloy
base on which a fine texture of particles selected from the group
consisting of metal oxides, carbides, borides, nitrides, and
silicides, having a Vickers microhardness greater than 1000
kg/mm.sup.2 and a binding metal or alloy matrix are
codeposited.
BRIEF DESCRIPTION OF THE DRAWING
The invention is shown in the accompanying drawing, wherein:
FIG. 1 illustrates a cross-section of a razor blade having a hard
cutting coating in accordance with a preferred embodiment of the
invention;
FIG. 2 shows a low pressure evaporating-gas plating apparatus in
accordance with the invention for forming the razor blade of FIG.
1;
FIG. 3 shows a cathode sputtering-gas plating apparatus in
accordance with another preferred embodiment in practicing the
method of the invention in forming the razor blade of FIG. 1;
and
FIG. 4 shows a plasma gun for still another preferred method for
forming the razor blade of FIG. 1.
In the drawing, various sizes and shapes of the parts have been
exaggerated or distorted, or omitted entirely, for clarity of
illustration and ease of description as will become apparent
below.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
A preferred embodiment of the invention is illustrated in FIG. 1 in
cross-section, showing therein a razor blade 10 having a base 11
provided with a cutting coating 12. The base 11 of the razor blade
10 may be made of a reasonably hard metal or alloy, such as
stainless steel, or the like, and is coated with the cutting layer
12 containing the very fine hard particles in a metal or alloy
matrix. The ultimate desired shape of the cutting edge is formed on
the base 11 before the deposition of the very thin coating,
although in some cases, it may be refined by grinding after the
deposition and by possible diffusion alloying.
The binding metal or alloy in layer 12 serves primarily to fortify
the cutting edge and its adherence to the base 11, the cutting role
being practically negligible. Its adherence may be additionally
increased in many cases by a diffusion alloying. Practically any
metal or alloy may be used for the binding material; however,
metals or alloys of greater hardness and stronger resistance to
atmospheric influences such as chromium, nickel, cobalt, noble
metals, alloys like stainless steel, and so forth, are
preferred.
The resistance to atmospheric influences is also very important in
the selected hard particles, for if the thin composite layer is
attacked by materials present in the atmosphere, the occuring
chemical changes may ruin the shape and composition of the overall
cutting layer. The hard particles embedded in the binder may be
selected from the group consisting of metal oxides, carbides,
borides, nitrides, and silicides. Table I shows the Vickers
microhardness of some exemplary hard particles which may be
advantageously employed.
TABLE I ______________________________________ Material Vickers
microhardness ______________________________________ kg/mm.sup.2
Molybdenum Disilicide, MoSi.sub.2 1100 Zirconium Dioxide, ZrO.sub.2
1300 Chromium Carbide, Cr.sub.3 C.sub.2 1300 Chromium Carbide,
Cr.sub.7 C.sub.3 1500 Molybdenum Carbide, Mo.sub.2 C 1500 Zirconium
Diboride, ZrB.sub.2 1800 Tungsten Carbide, WC 2000 Titanium
Nitride, TiN 2100 Alumina, Al.sub.2 O.sub.3 2200 Chromium Trioxide,
Cr.sub.2 O.sub.3 2250 Tungsten Boride, W.sub.2 B.sub.5 2650 Silicon
Carbide, SiC 2700 Boron, B 2700 Titanium Carbide, TiC 2900 Hafnium
Carbide, HfC 2900 Hafnium Diboride, HfB.sub.2 2900 Vanadium
Carbide, VC 3000 Boron Carbide, B.sub.4 C 3000 Titanium Diboride,
TiB.sub.2 3600 ______________________________________
The method by which the composite layer of fine hard particles and
the binding metal or alloy is codeposited, is of great importance.
Such method should produce a strong and dense interwoven system of
very fine particles of the hard material and binder, with the
different materials wetting each other well to be bonded together
with great adhesion forces.
It is also important that the percentages of the constituents of
the cutting layer be within certain limits. Sufficient quantity of
binding metal or alloy should be present to secure the coherence of
the composite system to prevent the hard particles from crumbling
away. On the other hand, sufficient quantity of hard particles
should be in the composite system to obtain the desired hardness of
the cutting edge. A volume percentage between 20 and 80 per cent
fine hard particles has been found to be satisfactory in most cases
to obtain the non-crumbling edge of desired hardness.
To obtain this hard edge, deposition processes are employed in
which the deposited metals, alloys and compounds are formed on the
surface of the base from individual neutral or ionized atoms,
thereby creating a very strong adherence to the base and between
the constituents of the coating, but which, at the same time,
ensure that the interwoven texture of hard particles and binding
metal or alloy is very fine. Consequently, the individually
observable hard particles are extremely small (smaller than 500
Angstroms and, in most cases, smaller than 100 Angstroms), a
precondition in many cases for a smooth and effective cutting
surface.
In accordance with the invention, one method for obtaining a hard
cutting edge includes the combination of metal evaporation and gas
plating. As shown in FIG. 2, a low pressure evaporating-gas plating
apparatus, generally denoted by the reference numeral 2, which
includes on a base 20 a glass container 21 placed on the base 20.
The cutting device 22 is located on a heatable holder 23 within the
glass container 21 (heaters are not shown). The plating gases are
fed into the glass container 21 through a tube 24. A boat 25
suspended within the container 21 is heated above the melting point
of the bonding metal or alloy to a temperature at which, at the
particular pressure within the chamber, the constituents of the
binding alloy begin to evaporate. The base 22 for the cutting
device to be plated is placed on the holder 23 within the container
21, and the apparatus is closed and evacuated. The holder 23 and
the boat 25 are then heated to the required temperatures, and the
plating gas mixture is entered through tube 24 into the apparatus.
A composite layer containing the evaporated metal or alloy
incorporating the fine hard particles is then deposited on one
surface of the base 22. Dependant on the metals in the binding
alloy the constituents of the plating gas, and the temperature of
holder 23, a reaction between the metal atoms and plating gas
constituents may also take place. In most cases, the presence of
these additional compounds will not deteriorate the performance of
the cutting device. However, such additional constituents should be
limited only to acceptable ones or be completely averted by proper
selection of the reacting materials and gases and of the
temperature of the holder 23.
A second method for fabricating a fine-cutting edge by a cathode
sputtering - gas plating apparatus 3 is shown in FIG. 3. A base 30
holds a glass container 31, and the cutting device 32 is placed on
a heatable holder 33 (the heaters are not shown) within the
container 31, and the container closed and evacuated. A tube 34 is
provided into the interior chamber within the container 31, through
which the plating gases may be entered and exhausted. A boat 35 is
disposed above the holder 33 within the chamber 31. The holder 33
and the boat 35 are then heated to the required temperature, to
vaporize the metals and alloys at the particular chamber pressure,
and the plating gas mixture is entered into the apparatus through
the tube 34. The current source 36 is then connected between the
boat 35 and the holder 33 by switch 37, thus enabling the
codeposition of the sputtered metal or alloy in boat 35 and of a
hard compound deriving from the plating gases to take place on the
working piece 32. Again, additional alloys or compounds may be
deposited by reactions, between the plating gases and the
evaporated metal atoms, which, of course, may be controlled by the
proper selection of the starting materials and plating gases.
The current source 36 may be direct current if a continuous metal
or alloy -- fine particles structure is desired. On the other hand,
if it is desired to develop larger particles of the hard cutting
substance, the current source may be alternating current or pulses
in one or two directions, etc., to temporarily slow down the metal
or alloy deposition.
A third method for fine-cutting edge fabrication is by the
combination of plasma-plating of the hard particles and the binding
metal or alloy. A typical plasma-plating gun employable in the
production of the cutting coating in accordance with the invention
is shown in FIG. 4. The negative pole of the direct current source
(not shown) is connected to the cathode 41 and the positive pole
(not shown) to the anode 42, which also forms the nozzle of the
gun. (The connecting cables are not shown.) The plasma producing
area is water-cooled (not shown). The cooling water flows through
the gun by entering through hose 43a and leaving through outlet
hose 43b. A noble gas may be fed in through pipe 44 conducted to
the area where the plasma 45 is generated. The material to be
deposited, if solid, is furnished through tube 46. (If the material
to be deposited is supplied in gas form, it enters together with
the noble gas through pipe 44.)
Quite a number of atoms can be supplied to the plasma area in gas
form, such as carbon as hydrocarbons, boron as boranes, germanium,
silicon as hydrides or certain halides, tungsten as tungsten
hexafluoride, WF.sub.6, and the like.
After deposition of the composite layer, in many cases it is
desirable to fortify the bond between the base and coating. This
can be accomplished, for example, by diffusion alloying the base
with the binding metal or alloy of the coating. After the coating
has been completed, the cutting device is heated up for this
purpose in a protective atmosphere to a temperature at which the
needed diffusion can be achieved in a reasonable time.
In the following examples, the coatings and processes according to
this invention are illustrated. It is understood that the examples
are presented herein only for the better understanding of the
principles of the invention and it is not intended to limit the
scope of the invention thereto. Other examples will become apparent
to those knowledgeable in the art, based on generally discussed
details of the invention.
EXAMPLE 1
The cutting layer of a razor blade is 0.04 micron thick and its
composition is 70 percent by weight titanium diboride and 30
percent by weight rhodium. The base of the blade is a tantalum
containing stainless steel type No. 347.
The deposition is carried out in a low pressure evaporating-gas
plating combination apparatus 2 shown in FIG. 2. The tungsten boat
25 holding rhodium metal is heated up to 3200.degree. C. The blade
22 is placed on holder 23 which is heated up to 1200.degree.C. The
following gas mixture is fed into the apparatus through tube
24:
50 cm.sup.3 /min boron trichloride, BCl.sub.3
30 cm.sup.3 /min titanium tetrachloride, TiCl.sub.4
2000 cm.sup.3 /min hydrogen, H.sub.2,
while the pump of the apparatus (not shown in the drawing) is
operated at a rate that the pressure in the chamber should be
between 20 and 35 torr. The desired layer thickness is deposited in
approximately 10 seconds. (The rhodium atoms do not react with the
titanium and boron atoms at the temperature of 1200.degree.C.)
A subsequent diffusion alloying is then carried out at
1300.degree.C. in vacuum.
EXAMPLE 2
The cutting layer of a razor blade is 0.035 micron thick and its
composition is 65 percent by weight silicon carbide and 35 percent
by weight an alloy of 30 percent by weight tungsten and 70 percent
by weight cobalt. The base of the razor is stainless steel type No.
302.
The deposition of the cutting layer is accomplished in apparatus 3
shown in FIG. 3. The hafnia boat 35 containing the tungsten-cobalt
alloy is heated up to 2400.degree.C. A razor blade 32 is placed on
holder 33 and is heated up to 1150.degree.C. Through the tube 34,
the following gas mixture is entered into the apparatus:
35 cm.sup.3 /min silicon tetrachloride, SiCl.sub.4
30 cm.sup.3 /min methane, CH.sub.4
1500 cm.sup.3 /min hydrogen, H.sub.2,
while the pump of the apparatus (not shown) is operated at a rate
to keep the pressure of the chamber between 40 and 60 torr. The
current source 36 delivers a pulse of 1000 VDC for 0.1 second
during which the holder 33 is the negative pole and 200 VDC for
0.03 second while 33 is the positive pole.
Although the cutting layer may contain a small percentage of
tungsten carbide and tungsten silicide, the cutting quality of the
blade will not be adversely influenced thereby.
EXAMPLE 3
The cutting coating of a razor blade is deposited by plasma gun 4
depicted in FIG. 4. The deposited coating consists of 40 percent
weight chromium and 60 percent by weight titanium carbide. A powder
mixture of this composition is fed into tube 46. The noble gas, for
example, argon, enters through tube 44 into the plasma plating gun.
(The deposit may contain some chromium carbide particles too which
do not appreciably decrease the cutting performance.) The particle
sizes in the interwoven texture are less than 30 Angstroms.
EXAMPLE 4
In this example, the cutting layer of the razor blade is 50 percent
by weight cobalt and 50 percent by weight boron carbide. The cobalt
particles are provided through tube 46 of the plasma plating gun 4
of FIG. 4, while a gas mixture of argon, borane and methane are fed
into the tube 44. The supplied rate of the plating gases are:
100 cm.sup.3 /min borane, B.sub.2 H.sub.6
30 cm.sup.3 /min methane, CH.sub.4.
The particle sizes of the interwoven texture are in this example
also less than 30 Angstroms. If the base of the razor blade was
correctly sharpened, the 300 Angstrom thickness of the coating
forms a radius of approximately 300 Angstroms at the coated edge of
the blade.
Although the processes above discussed have been in connection with
the manufacture of razor blades, it should be understood that the
principles of the invention are equally applicable to other acute
angle edged cutting devices. Razor ribbons can also be produced by
the disclosed methods, for instance, by depositing the hard layer
on a continuous metal alloy band from which the individual razor
ribbons are cut. Other cutting devices which have acute angle
cutting edges of special configurations can be first formed,
sharpened, then coated with the extremely hard layers according to
the invention.
Although the invention has been described and illustrated with a
certain degree of particularity, it is understood that the present
disclosure has been made only by way of example and that numerous
changes in the details of construction and the combination and
arrangement of parts may be resorted to without departing from the
spirit and scope of the invention as hereinafter claimed.
* * * * *