U.S. patent number 3,801,317 [Application Number 05/133,789] was granted by the patent office on 1974-04-02 for electrophotographic plate.
This patent grant is currently assigned to Canon Camera Kabushiki Kaisha. Invention is credited to Takao Komiya, Hiroshi Tanaka.
United States Patent |
3,801,317 |
Tanaka , et al. |
April 2, 1974 |
**Please see images for:
( Certificate of Correction ) ** |
ELECTROPHOTOGRAPHIC PLATE
Abstract
An electrophotographic plate having high resolving power and
high sensitivity comprising a base, a composite photoconductive
layer on the base, and an insulating layer overlying the composite
photoconductive layer. The composite photoconductive layer
comprises two adjacent layers, one layer contacting the insulating
layer and comprising fine photoconductive particles and binder, and
the other contacting the base and comprising relatively coarse
photoconductive particles and binder.
Inventors: |
Tanaka; Hiroshi (Tokyo,
JA), Komiya; Takao (Tokyo, JA) |
Assignee: |
Canon Camera Kabushiki Kaisha
(Tokyo, JA)
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Family
ID: |
13296991 |
Appl.
No.: |
05/133,789 |
Filed: |
April 14, 1971 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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563899 |
Jul 8, 1966 |
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Foreign Application Priority Data
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Oct 28, 1966 [JA] |
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42-65784 |
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Current U.S.
Class: |
430/57.1; 430/67;
430/94 |
Current CPC
Class: |
G03G
5/0433 (20130101) |
Current International
Class: |
G03G
5/043 (20060101); G03g 005/08 () |
Field of
Search: |
;96/1.5,1.8 ;252/501
;117/215 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Van Horn; Charles E.
Attorney, Agent or Firm: Fitzpatrick, Cella, Harper &
Scinto
Parent Case Text
This is a division of U.S. Pat. application Ser. No. 563,899, filed
July 8, 1966.
Claims
What is claimed is:
1. An electrophotograpic plate comprising:
a. a base,
b. a composite photoconductive layer on said base, and
c. an insulating layer on said photoconductive layer;
d. said composite photoconductive layer comprising at least two
adjacent layers, one layer contacting said insulating layer and
comprising binder and fine photoconductive particles characterized
in having high resolving power, and the other layer comprising
binder and photoconductive particles characterized in having high
sensitivity, wherein the photoconductive particles of said other
layer are relatively coarse as compared to those of said one
layer.
2. An electrophotographic plate according to claim 1, wherein said
fine and coarse photoconductive particles are of different
material, and said coarse photoconductive particles have
substantially higher sensitivity than said fine photoconductive
particles.
3. An electrophotographic plate according to claim 1, wherein said
fine photoconductive particles comprise ZnO and said one layer of
same has a thickness of from 5 to 20.mu., and said coarse
photoconductive particles comprise CdS and said other layer of same
has a thickness of from 10 to 100.mu. .
Description
This invention relates to electrophotography, and more particularly
to an electrophotographic plate for use in electrophotography.
U.S. Pat. No. 3,124,456 discloses the use of a photosensitive plate
where a photoconductive layer, comprising CdS or CdSe and binder
resin, is adhered to a photoconductive base and a translucent
insulating layer is applied over the photoconductive layer.
Original image irradiation and electrostatic charging are made
simultaneously from the translucent insulating layer side to form
an electrostatic image on the insulating layer by utilizing the
difference of the charges built up in accordance with the
difference of the time constants caused by the difference of the
values of the resistances of the photoconductive layer at the
light-and-dark portions of the original image. However, to obtain
good electrostatic images with this method, the capacitance of the
translucent insulating layer must be larger than that of the
photoconductive layer, and as a practical matter, the thickness of
the translucent insulating layer is limited to the range of from 2
- 6.mu.. With such a thin insulating layer, break-down of the
surface occurs easily and long repetitive use can hardly be
expected. Furthermore, in the method described above where the
electrostatic image formed depends upon the change of the impedance
of the photoconductive layer, when the thickness of the translucent
insulating layer is increased, contrast decreases and the quality
of the image deteriorates.
U.S. Pat. No. 3,041,167 teaches the use of a photosensitive plate
in which the photoconductive layer is protected by an overcoating
layer, which is thin in comparison to the photoconductive layer.
When the electrostatic image is formed using said photosensitive
plate according to the Carlson process, it is necessary to repeat
the copying cycle, and accordingly, prior to applying the
sensitizing charge, the plate is charged to a polarity opposite to
that of the sensitizing charge; and after charging, light is
irradiated on the whole surface, and thereafter, a sensitizing
charge is made, followed by image exposure. According to this
process, the photosensitive plate is revived; however, the
obtainable electrostatic contrast is only 300 - 500 volts, which is
almost the same as that obtainable with a photosensitive plate
which has no overcoating layer. According to the process of U.S.
Pat. No. 3,041,167, after the sensitizing charge, the light image
is irradiated so that in the light exposed area, a carrier is
injected from the conductive base side to weaken the external
field, and contrast is obtained due to the difference of the
capacitances between the exposed area and the unexposed area.
According to the invention set forth in copending and commonly
assigned United States patent application Ser. No. 563,899, filed
July 8, 1966, an electrostatic image is formed on a photosensitive
plate having a conductive base, a photoconductive layer overlying
the base and exhibiting p-type or n-type semiconductivity and an
insulative layer overlying the photoconductive layer. The
photosensitive plate is characterized in having carrier charge of a
polarity corresponding to the conductivity type of the
photoconductive layer injectable from the conductive base into the
photoconductive layer and bound in the region of the interface
between the insulative and photoconductive layers. The
electrostatic image is formed on the photosensitive plate by
applying a first charge of a polarity opposite to the conductivity
type of the photoconductive layer substantially uniformly onto the
insulative layer to inject and bind carrier charge in the region of
the interface between the insulative and photoconductive layers.
Then the photoconductive layer is exposed to a pattern of image
light while a corona discharge of a polarity opposite to that of
said first charge is applied onto the insulative layer, and
thereafter the photoconductive layer is exposed to activating light
to discharge bound carrier charge remaining in the region of the
interface and form a high contrast electrostatic image.
An object of the present invention is to provide an improved
photosensitive plate having high sensitivity and high contrast,
which is usable over a long term and which can be used with any of
the above described processes as well as with other
electrophotographic processes.
A still further object of the present invention is to provide an
inexpensive, highly sensitive photosensitive plate, which comprises
two photoconductive layers, one layer in contact with the
translucent insulating layer and composed of a mixture of fine
particles of a photoconductor and a binder, and the other layer
interposed between the base and the first photoconductive layer and
composed of large particles of a photoconductor and a binder.
The above objects and various other objects and the advantages of
the present invention will become clear from the following detailed
description, taken in conjunction with the accompanying drawings,
in which:
FIG. 1 shows a four layer photosensitive plate constructed in
accordance with the present invention, and having a base of
conductive material; and
FIG. 2 shows a four layer photosensitive plate constructed in
accordance with the present invention, and having a base of
insulative material.
The fundamental structure of an electrophotographic plate of the
present invention includes a base, a composite photoconductive
layer (described more fully hereinafter) coated or sprayed on the
base, and a layer of translucent insulating material overlying the
photoconductive layer. Depending on the electrophotographic process
used, the base may be of conductive or insulative material. The
photoconductive layer comprises two layers, one layer adjoining the
translucent insulating layer and containing fine particles of
photoconductor, and the other layer adjoining the base and
containing highly photosensitive photoconductor, for example, a
photoconductor of larger particles.
Thus, the photoconductive layer on the side where light is radiated
comprises a photoconductor of fine particles, and therefore, it is
possible to obtain an image of high resolving power. At the back of
the photoconductor of fine particles, there is the layer containing
the photoconductor of larger particles, and since the
photoconductor of larger particles is highly sensitive, the
sensitivity of photosensitive plate is high, and therefore it is
possible to obtain an electrophotographic plate of high sensitivity
and high resolving power.
In FIG. 1, 1g is a translucent insulating layer, 2g and 3g are
photoconductive layers, layer 2g comprising a photoconductor of
finer particles than those of 3g, and 4g is a conductive base.
In FIG. 2, 1h is a translucent insulating layer, 2h and 3h are
photoconductive layers, and 2h comprises finer photoconductor
particles than 3h, and 4h is an insulating base.
As to fine particle photoconductors, zinc oxide or zinc sulfide,
and cadmium oxide-selenium compounds, whose average granular
diameter is less than several .mu. can be used. Excellent results
can be expected where zinc oxide is used. Zinc oxide with granular
diameter less than 1.mu., is readily available and inexpensive, and
it is possible to increase sensitivity very simply by means of
dyes. Excellent results are obtained where particles of cadmium
sulfide, cadmium selenide activated by copper or the like are used
as high sensitivity large particle photoconductors. These compounds
are readily available, and they have the advantage of having high
photoconductivity. Similar results are obtained where the base is a
metal, and insulating layers are provided.
Especially excellent results can be obtained where cadmium sulfide
is used in layer 3, and zinc oxide is used in layer 2 in
combination with any of the above-mentioned kinds of
photoconductors, in which case the thickness of photoconductive
layer 2 containing zinc oxide is from 5 to 20.mu., and the
thickness of photoconductive layer 3 is from 10 to 100.mu..
EXAMPLE
50g of varnish (containing 20 percent of a vinyl chloride vinyl
acetate copolymerized resin), 20g of CdS, and 56g of thinner were
mixed, and the resulting mixture was coated on an aluminum plate to
a thickness of between 50 and 100.mu. when dried; and 50g of ZnO
and 50g of silicon resin varnish (containing 50 percent of resin
component), 15cc of 0.1 percent Rose Bengale ethanol solution and
100cc of thinner were mixed in a porcelain ball mill for 2 hours,
and a liquid of pink paint form was obtained; and the resulting
solution was spray coated on the above prepared CdS film so as to
have the thickness of about several .mu. when dry, and the film was
dried. Finally, 12.mu. of polyethylene terephthalate resin film
(sold by the DuPont Company under the trademark Mylar) was adhered
on ZnO layer using an adhesive.
A +6KV charge was applied to the side of the movable electrode in a
light area, and a corona discharge was made between the electrode
and the aluminum plate to charge it positively; and then in a dark
area, microfilm was enlarged about eight times by means of an
enlarger which had 150 W tungsten lamp, and the image was projected
on the photosensitive plate at an exposure of F 5.6; and while
exposure was being made through the movable electrode having the
protecting wall of the structure which allows light to pass, the
protecting wall touching the photosensitive film, a corona
discharge of 6KV was made, and the exposure and charge was made for
about 2 seconds average on the respective portions of the
photosensitive plate. After applying an overall exposure for about
2 seconds with a tungsten lamp of 100 W at the distance of 50 cm
from the plate, a toner having the negative electrostatic charge
was used, and cascade development was made by using glass balls as
carriers, and a clear positive image enlarged from the original
copy of the microfilm was obtained.
It is apparent that the present invention can be modified by the
expert in the art within the scope of the disclosure herein and the
following claims.
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