U.S. patent number 3,800,550 [Application Number 05/315,216] was granted by the patent office on 1974-04-02 for system for reliquefying boil-off vapor from liquefied gas.
This patent grant is currently assigned to Chicago Bridge & Iron Company. Invention is credited to Terry Wayne Delahunty.
United States Patent |
3,800,550 |
Delahunty |
April 2, 1974 |
**Please see images for:
( Certificate of Correction ) ** |
SYSTEM FOR RELIQUEFYING BOIL-OFF VAPOR FROM LIQUEFIED GAS
Abstract
Apparatus and processes for recondensing boil-off vapor from an
insulated storage tank containing a liquefied gas, such as
liquefied natural gas, so that it continues to comprise a part of
the stored liquefied gas. Boil-off vapor is recondensed by
refrigeration obtained from expansion of a liquefied gas stream
withdrawn from the storage tank. The expanded stream, as a vapor,
can be pressurized by feeding it to the suction side of an ejector
to which a high pressure gas is fed to supply the motive force.
Alternatively, a vapor stream derived from the stored liquefied gas
can be fed to a venturi ejector as the motive force to pressurize
boil-off vapor fed from the storage tank to the suction side of the
ejector. The combined stream from the ejector, after being
refrigerated by the withdrawn liquefied gas stream, is expanded to
the tank vapor space to cool the tank contents. Under either
system, liquefied gas stored at about atmospheric pressure can be
vaporized and distributed at a pressure greater than atmospheric
pressure.
Inventors: |
Delahunty; Terry Wayne
(Plainfield, IL) |
Assignee: |
Chicago Bridge & Iron
Company (Oak Brook, IL)
|
Family
ID: |
22755088 |
Appl.
No.: |
05/315,216 |
Filed: |
December 14, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
203726 |
Dec 1, 1971 |
3740118 |
|
|
|
Current U.S.
Class: |
62/47.1; 62/116;
62/48.2; 62/500 |
Current CPC
Class: |
F25J
1/0221 (20130101); F25J 1/0025 (20130101); F25J
1/0045 (20130101); F25J 1/0201 (20130101); F17C
2265/033 (20130101); F17C 2227/0358 (20130101); F25J
2235/60 (20130101); F25J 2290/34 (20130101); F25J
2210/62 (20130101); F25J 2240/60 (20130101); F25J
2290/62 (20130101) |
Current International
Class: |
F25J
1/00 (20060101); F25J 1/02 (20060101); F17c
013/02 () |
Field of
Search: |
;62/53,54,55 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Perlin; Meyer
Assistant Examiner: Capossela; Ronald C.
Attorney, Agent or Firm: Merriam, Marshall, Shapiro &
Klose
Parent Case Text
This is a division of application Ser. No. 203,729, filed Dec. 1,
1971, now U.S. Pat. No. 3,740,118.
Claims
What is claimed is:
1. A process which comprises:
removing a first stream of liquefied gas from an insulated storage
tank and expanding it to a low pressure cold vapor stream;
removing a second stream of liquefied gas from the storage tank and
passing it in heat exchange relationship with the cold first stream
to cool said second liquefied gas stream;
returning the cooled second liquefied gas stream to the vapor space
of the storage tank to cool the tank contents;
feeding the now warmed low pressure first stream into inspiration
communication wth a venturi ejector; and
feeding a high pressure third stream of gas through a venturi
ejector to inspirate and pressurize the low pressure vapor from the
first stream and admix therewith to form an exit stream.
2. A process according to claim 1 in which the composition of all
the streams is natural gas.
3. A process which comprises:
removing a first stream of liquefied gas from an insulated storage
tank and expanding it to a low pressure cold stream;
removing a second stream of liquefied gas from the storage tank and
passing it in heat exchange relationship with the cold first stream
to cool said second liquefied gas stream;
returning the cooled second liquefied gas stream to the vapor space
of the storage tank to cool the tank contents; and
compressing and further heating the low pressure first stream and
feeding it to a distribution line.
4. A process according to claim 3 in which the composition of all
the streams is natural gas.
5. In combination:
an enclosed insulated storage tank for a liquefied gas;
a first conduit communicating with the tank interior and a heat
exchanger outside thereof for removing liquefied gas from the tank
and sending it to the heat exchanger to be cooled;
a second conduit from the heat exchanger to the vapor space of the
tank for supplying cooled liquefied gas thereto to condense
boil-off vapor;
a third conduit communicating with the tank interior and an
expansion valve for removing liquefied gas from the tank and
expanding it through the valve;
a fourth conduit communicating with the expansion valve and the
heat exchanger for supplying the expanded gas stream as a
refrigeration source to the heat exchanger;
a fifth conduit communicating with the heat exchanger and the
suction side of a venturi ejector for supplying the expanded gas
stream at low pressure to the ejector;
a sixth conduit communicating with the ejector for supplying a high
pressure gas stream thereto; and
a seventh conduit in communication with the exit side of the
ejector to receive the combined gas stream therefrom.
6. The combination of claim 5 in which:
an eighth conduit communicates with the sixth conduit and with a
second venturi ejector;
the seventh conduit communicates with the suction side of the
second venturi ejector; and
a ninth conduit communicates with the exit side of the second
venturi ejector.
7. The combination of claim 5 in which the sixth conduit has valve
means for blocking and regulating flow of the high pressure gas
stream therethrough.
8. The combination of claim 5 including a pump in the first
conduit.
9. In combination:
an enclosed insulated storage tank for a liquefied gas;
means for removing liquefied gas from the storage tank, feeding it
through a heat exchanger to be cooled and delivering the cooled
liquefied gas to the vapor space of the tank in order to reduce the
vapor pressure therein; and
means for removing liquefied gas from the storage tank, expanding
it and passing it as a refrigeration stream through the heat
exchanger to provide refrigeration thereto.
10. The combination of claim 9 having means for feeding the
refrigeration stream from the heat exchanger to the suction side of
a venturi ejector, and means for supplying a high pressure gas to
the ejector.
11. A process which comprises:
removing a first stream of liquefied gas from an insulated storage
tank and expanding it to a low pressure cold stream;
removing a second stream of liquefied gas from the storage tank and
passing it in heat exchange relationship with the cold first stream
to cool said second liquefied gas stream;
returning the cooled second liquefied gas stream to the vapor space
of the storage tank to cool the tank contents;
feeding the now warmed low pressure first stream into inspiration
communication with a venturi ejector;
feeding a high pressure third stream of gas through a ventrui
ejector to inspirate and pressurize the low pressure vapor from the
first stream and admix therewith to form an exit stream; and
passing the exit stream to, and inspirating it through, a second
venturi ejector by passage of part of the third stream of gas
therethrough.
12. A process according to claim 11 in which the composition of all
streams is natural gas.
Description
This invention relates to apparatus and processes for storing
liquefied gases and the subsequent vaporization thereof.
A considerable number of normally gaseous materials are converted
to their liquid state for storage and shipping because the liquid
form occupies much less space than the vapor. Some of the gases
which are liquefied for this reason are natural gas, ethane,
propane, butane, oxygen, nitrogen and hydrogen.
While high boiling liquefied gases can be stored practically in
noninsulated tanks or containers it is not practical to store large
volumes of the low boiling or cryogenic liquids in such tanks. Heat
leak into the tank would be fast and would raise the temperature of
the liquid to ambient temperature. To maintain the product liquid
at ambient temperature would require very high pressures and tank
walls sufficiently thick to withstand the necessary pressures.
Large storage tanks with thick walls would be very expensive and
difficult to construct. It is more feasible to store the liquefied
gas at a temperature which has a vapor pressure at or about
atmospheric pressure because the tank then need only be able to
withstand the hydrostatic liquid load plus a small internal vapor
pressure. However, to maintain the liquid at such low temperatures
the tank must be suitably insulated to keep heat leak under
control. Heat leak nevertheless takes place and boil-off vapor
forms in the vapor space of the tank. Boil-off vapor refers to the
vapor resulting from the addition of heat to an equilibrium mixture
of liquid and vapor. Since the storage vessel is at constant
pressure and volume, and since the volume occupied by the vaporized
portion of the liquid is considerably greater than the volume
occupied by the liquid portion prior to its vaporization, the
majority of the vaporized liquid must either be removed from the
tank or be condensed to liquid.
While boil-off vapor can be conducted to a distribution line for
use, this is often undesirable because it can have a composition
different than that of the stored liquefied gas. This is
particularly so in the case of multicomponent stored product such
as liquefied natural gas which can contain, besides methane,
appreciable quantities of liquefied ethane, propane, butane and
other liquids higher boiling than methane. The boil-off vapor in
such instances will not be exactly like that of vapor formed by
vaporizing an aliquot of the liquefied gas. The effect of heat leak
into a liquefied multicomponent product preferentially vaporizes
those components having the lower boiling points. If the boil-off
vapors are removed from the storage vessel, the composition of the
stored liquid and vapor necessarily must change, going from a
mixture rich in low boiling components to a mixture rich in high
boiling components. Accordingly, to supply a standard composition
to a distribution line it is advisable to remove liquefied gas from
the tank, vaporize the liquefied gas and feed the vapor so formed
to the distribution line rather than boil-off vapor because this
minimizes, even though it may not necessarily completely eliminate,
composition change. This requires, however, that the inevitable
boil-off vapor be disposed of or processed in a way which is
compatible with such a system. It also requires that a withdrawn
liquefied gas stored at atmospheric pressure be vaporized and
brought to a pressure greater than atmospheric pressure to be
transported in a distribution line.
According to the present invention, there are provided apparatus
and processes for recondensing boil-off vapor from an insulated
storage tank containing a liquefied gas so that it continues to
comprise a part of the stored liquefied gas. The boil-off vapor is
recondensed by utilization of refrigeration obtained from expansion
of a liquefied gas stream withdrawn from the storage tank
containing the same. The resulting expanded stream, as vapor, can
be pressurized by feeding it to the suction side of an ejector to
which a high pressure gas is fed to supply the motive force.
Alternatively, a vapor stream derived from the stored liquefied gas
can be fed to a venturi ejector as the motive force to pressurize
boil-off vapor fed from the storage tank to the suction side of the
ejector. The combined stream from the ejector after being
refrigerated by the withdrawn liquefied gas stream, can be expanded
to the tank vapor space to cool the tank contents. Under either
system, liquefied gas stored at about atmospheric pressure can be
vaporized and distributed at a pressure greater than atmospheric
pressure. This thus makes the systems especially useful in respect
to liquefied natural gas and other liquefied gases stored at about
atmospheric pressure.
In one embodiment of the invention, there is provided apparatus
comprising an enclosed insulated storage tank for a liquefied gas,
means for removing liquefied gas from the storage tank, feeding it
through a heat exchanger to be cooled and delivering the cooled
liquefied gas to the vapor space of the tank, and means for
removing liquefied gas from the storage tank, expanding it and
passing it as a refrigeration stream through the heat exchanger to
provide refrigeration thereto. There can also be included means for
feeding the refrigeration stream from the heat exchanger to the
suction side of a venturi ejector, and means for supplying a high
pressure gas to the ejector.
According to the same embodiment of the invention, there is
provided a process which comprises removing a first stream of
liquefied gas from a storage tank and expanding it to a low
pressure cold stream, removing a second stream of liquefied gas
from the storage tank and passing it in heat exchange relationship
with the cold first stream to cool said second liquefied gas
stream, returning the cooled second liquefied gas stream to the
vapor space of the storage tank to cool the tanks contents
including effecting at least partial condensation of boil-off
vapor, and feeding the now warmed low pressure first stream to a
distribution line, or advisably feeding it into inspiration or
suction communication with a venturi ejector while feeding a high
pressure third stream of gas through a venturi ejector to inspirate
and pressurize the low pressure vapor from the first stream and
admix therewith to form an exit stream. The exit stream, if
desired, can be passed to, and inspirated through, a second venturi
ejector by passage of part of the third stream of gas
therethrough.
According to a second embodiment of the invention, there is
provided apparatus comprising an enclosed insulated storage tank
for a liquefied gas, means for removing liquefied gas from the
storage tank, feeding it through a heat exchanger as a source of
refrigeration, and delivering it as a high pressure vapor to the
motive power inlet side of a venturi ejector, means for removing
boil-off vapor from the storage tank and delivering it to the
suction side of the ejector, means for receiving the pressurized
vapor from the ejector, passing it through the heat exchanger to
cool it and condense it to a liquid and means for receiving the
condensed liquid from the heat exchanger, expanding it and
delivering the stream to the vapor space of the tank to cool the
tank contents.
The same second embodiment of the invention provides a proces which
comprises removing a boil-off stream of vapor from a storage tank
and feeding it into suction or inspiration communication with a
venturi ejector, removing a stream of liquefied gas from the
storage tank and passing it through a heat exchanger to provide
refrigeration therein, feeding at least part of the stream from the
heat exchanger in the form of a high pressure vapor through the
venturi ejector as the motive force to pressurize the inspirated
boil-off vapor and form a combined warm vapor stream thereof,
feeding the combined warm vapor stream through the heat exchanger
to condense said stream to a cold liquid stream, and expanding the
cold liquid stream and feeding it to the vapor space of the tank to
absorb heat from the tank contents. That part of the refrigeration
stream from the heat exchanger that is not fed to the venturi
ejector can be fed as a vapor to a distribution line.
Under both of the described embodiments, complete recondensation of
boil-off vapor requires that the total heat absorbed by the liquid
spray counteract or equal the heat leak into the storage
vessel.
It will be noted in the first embodiment of the invention that the
ejector motive power is supplied by a stream not associated with
the stored liquid, and that in the second embodiment the ejector
motive power is from an auxiliary stream derived from the stored
liquid.
The embodiments of the invention as described are particularly
useful in conjunction with the storage of natural gas.
Ejectors being well known in the art as see Rietdejk U.S. Pat. No.
3,464,230, will not be described in detail herein.
The invention will now be described further in conjunction with the
attached drawings in which:
FIG. 1 is a schematic illustration of one embodiment of the
invention in which the liquefied gas withdrawn for refrigeration to
cool the tank contents, including boil-off vapor, is subsequently
pressurized and fed to a distribution line; and
FIG. 2 is a schematic illustration of another embodiment of the
invention for cooling the tank contents in which the liquefied gas
withdrawn for refrigeration is subsequently used, at least in part,
to pressurize withdrawn boil-off vapor.
With reference to FIG. 1, insulated storage tank 10 is of
conventional construction and comprises inner and outer metal
shells separated by insulating material. Conduit 11 communicates
with the inside of tank 10 and with pump 12 for removing liquefied
gas from the tank. Conduit 13 communicates with pump 12 and heat
exchanger 14. Liquefied gas is fed to the heat exchanger by conduit
13 where it is cooled and from which it is fed by conduit 15 to the
vapor space of tank 10. Conduit 15 communicates with spray head 16
from which the cooled liquefied gas is sprayed into the vapor space
of the tank to absorb heat which leaks into the tank.
Also as shown in FIG. 1, conduit 21 communicates with the inside of
tank 10 and with expansion valve 22 and is used to withdraw
liquefied gas from the tank. The liquefied gas is conveyed from
valve 22 by conduit 23 heat exchanger 14 to supply refrigeration
thereto. The warmed, low pressure vapor is removed from heat
exchanger 14 by conduit 24 and can be disposed of as desired. It is
advisable, however, to feed the low pressure vapor by conduit 24 to
the suction or inspiration side of venturi ejector 25 to be
pressurized.
Conduit 31, which can be a gas transmission line, conveys a high
pressure gas stream to conduit 32, through valve 33 to conduit 34
and from it to ejector 25 to provide the motive power to pressurize
the low pressure vapor supplied by conduit 24. Conduit 35 receives
the combined gas stream from ejector 25 and can distribute it to
any location desired, such as to line 50 by conduit 36 shown in
phantom. Advisably, conduit 35 communicates with the suction side
of second ejector 37. High pressure gas from conduit 31 is directed
to conduit 38, through valve 39 to conduit 40 and then to ejector
37 to provide the motive power. The combined gas stream leaves the
ejector 37 by conduit 41, at a pressure higher than in conduit 35,
is passed through valve 42 to conduit 43 and by it to distribution
line 50.
While the described ejector system is in operation, valve 44 can be
closed or throttled to regulate gas flow from conduit 31 to conduit
45 and from it to distribution line 50. Similarly, when the entire
ejector system is out of use, valves 33, 39, 42 and 46 can be
closed. Also, if only ejector 25 is in operation, valves 39 and 42
can be closed and valve 44 closed or throttled as appropriate.
Valve 44 could be left open, or partly open, to supply sufficient
gas to distribution line 50 to meet customers needs if the amount
of gas from conduits 35 and 43 is inadequate alone for this
purpose.
The system of FIG. 1 is particularly useful where liquid natural
gas liquefaction and storage facilities are both built along
pipeline sites where a natural gas stream is expanded from a high
main pressure to a customer distribution low pressure line. During
periods when the liquefaction plant is not operating, the energy of
the expansion process from the high pressure transmission gas is
available and can be economically used to operate the ejector and
overcome storage tank heat leak. Also, the expansion ratio and flow
rate from peak shaving use of the stored liquefied gas is generally
sufficient to operate the ejector.
The use of ejectors in the system is initially less costly than
conventional compressors and operating costs are lower. Ejectors
also require little servicing since they have no moving parts.
FIG. 2 illustrates another embodiment of the invention. insulated
tank 60 is of conventional type for storing a liquefied gas at
about atmospheric pressure. Conduit 61 communicates with the
interior of tank 60 and pump 62. A stream of liquefied gas is
pumped from tank 60, by means of conduit 61 and pump 62, and is
sent by conduit 63 to heat exchanger 64 to provide refrigeration.
The warmed liquefied gas leaves the heat exchanger by conduit 65
and is fed to heater 66 where it is warmed and vaporized. From
heater 66 the warmed but high pressure vapor is fed to conduit 67.
Part of the high pressure vapor is fed from conduit 67 to conduit
68 and part to transmission or distribution line 71. The high
pressure gas is fed by conduit 68, through valve 69 to conduit 70
and by it to venturi ejector 72 to provide the ejector motive power
thereto. Conduit 73 communicates with the vapor space of tank 60
and the suction or inspiration side of ejector 72 to supply the low
pressure boil-off vapor thereto.
The discharge of the ejector, which contains both the compressed
boil-off vapors and the motive stream vapor, is fed to conduit 74
and by it to heat exchanger 64 where the vapor is condensed. The
condensed vapor or liquid stream is conveyed from heat exchanger 64
to conduit 75 and by it to expansion valve 76. The liquid is
expanded through valve 76 to a pressure sufficient to overcome
hydrostatic pressure and frictional resistance in conduit 77 and
spray head 78. The liquid spray from spray head 78 absorbs heat
from the vapor space and the liquefied gas stored in the tank.
The embodiment of FIG. 2 is useful where the base load plant
supplies a liquid stream according to customer demand. When the
available refrigeration from the customer demand stream is
sufficiently large to condense both the boil-off vapor and the
ejector motive stream, the application of this system is
possible.
It should be understood that the liquid fed to the vapor space of
the tanks in each embodiment of the invention need not be sprayed
therein. The cooling liquid can be dispersed in the vapor space by
other means, such as the use of splash plates, berle saddles or
other means.
The following examples are presented to illustrate but not limit,
the invention.
EXAMPLE 1
In the embodiment shown in FIG. 1, tank 10 stores liquefied natural
gas at -258.degree. F and 15.3 psia. By conduit 11, 185 gallons per
minute of liquefied natural gas are withdrawn and pumped through
heat exchanger 14. After leaving the heat exchanger, the cooled
liquefied natural gas at 25 psia and -270.degree. F is fed at 185
gallons per minute by condiit 15 to the vapor space of the
tank.
Liquefied natural gas is removed by conduit 21, expanded through
valve 22 and fed to conduit 23 at 8.5 psia and -270.degree. F at a
rate of 1.03 million standard cubic feet per day. The vapor leaves
the heat exchanger and is conveyed by conduit 24 at 8.5 psia and
-270.degree. F at a rate of 1.03 million standard cubic feet per
day to the suction side of ejector 25.
High pressure natural gas at 400 psia and 60.degree. F at a rate of
1.47 million standard cubic feet per day is fed by conduit 34 to
ejector 25. High pressure natural gas at 400 psia and 60.degree. F
is fed at a rate of 4.64 million standard cubic feet per day by
conduit 40 to ejector 37.
The combined gas streams, with valves 44 and 46 closed, fed to
conduit 43 is at 35 psia and -20.degree. F and flows at a rate of
7.14 million standard cubic feet per day.
EXAMPLE 2
The embodiment of FIG. 2 can be operated under the following
specific conditions although other conditions can obviously be
used.
Liquefied natural gas at -258.degree. F and 15.3 psia in tank 60 is
withdrawn by conduit 61 at -258.degree. F and 20 psia at a rate of
40 million standard cubic feet per day. The liquefied natural gas
leaves pump 62 and by conduit 63 is conveyed at 600 psia and
-258.degree. F at 40 million standard cubic feet per day to heat
exchanger 64. The liquid stream leaves the heat exchanger at 600
psia and -235.degree. F at a rate of 40 million standard cubic feet
per day and is conveyed by conduit 65 to heater 66 where it is
vaporized. Conduit 67 feeds the vapor at 600 psia and 60.degree. F
at a rate of 40 million standard cubic feet per day. Part of the
vapor stream from conduit 67 is directed to conduit 68 at 600 psia
and 60.degree. F at a rate of 2.1 million standard cubic feet per
day of gas, and part is directed to line 71 at 600 psia and
60.degree. F at a rate of 37.9 million standard cubic feet per
day.
Boil-off vapor is removed from the tank by conduit 73 at 15 psia
and -258.degree. F at a rate of one million standard cubic feet per
day and is fed to the suction side of ejector 72. The combined
vapor stream is fed by the ejector to conduit 74 which feeds the
vapor at 40 psia and -110.degree. F at a rate of 3.11 million
standard cubic feet per day to heat exchanger 64. After leaving the
heat exchanger the condensed stream is expanded through valve 76
and the liquid is fed at 40 psia and -258.degree. F at a rate of
3.11 million standard cubic feet per day to spray head 78 from
which it is sprayed into the vapor space of the tank to cool the
contents.
The foregoing detailed description has been given for clearness of
understanding only, and no unnecessary limitations should be
understood therefrom as modifications will be obvious to those
skilled in the art.
* * * * *