U.S. patent number 3,800,427 [Application Number 05/324,740] was granted by the patent office on 1974-04-02 for method for drying coal.
This patent grant is currently assigned to American Waagner-Biro Company, Inc.. Invention is credited to Roland Kemmetmueller.
United States Patent |
3,800,427 |
Kemmetmueller |
April 2, 1974 |
METHOD FOR DRYING COAL
Abstract
A method for drying coal. The coal, in the form of coal
particles, is fed into a drying chamber where the coal is suspended
in a fluidized bed while being dried in an atmosphere of steam
which is at a temperature too low to release oxygen but high enough
to extract sulphur from the coal particles. The temperature of the
atmosphere in the fluidized bed where the drying of the coal takes
place is regulated with heating coils which directly contact the
coal particles while the latter are suspended in the fluidized bed,
so that further drying is achieved by direct contact between the
coal particles and the heating coils. The coal with its reduced
sulphur and moisture content is taken in a preheated condition from
the dryer and delivered to a coke oven to reduce the extent to
which coal must be heated therein. Gas extracted from the dryer is
treated to have water condensed therefrom and to extract sulphur
therefrom. In addition, pellets of calcium oxide and/or magnesium
oxide are delivered to the fluidized bed together with the coal
particles for further extracting sulphur from the atmosphere in the
fluidized bed, these pellets also being subsequently treated, as by
roasting, to extract sulphur therefrom.
Inventors: |
Kemmetmueller; Roland
(Pittsburgh, PA) |
Assignee: |
American Waagner-Biro Company,
Inc. (Pittsburgh, PA)
|
Family
ID: |
23264893 |
Appl.
No.: |
05/324,740 |
Filed: |
January 18, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
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283155 |
Aug 23, 1972 |
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Current U.S.
Class: |
34/363; 202/227;
432/15 |
Current CPC
Class: |
C10B
57/08 (20130101); C10L 9/02 (20130101); F26B
3/084 (20130101); C10B 39/02 (20130101); Y02E
50/10 (20130101); Y02E 50/15 (20130101) |
Current International
Class: |
C10L
9/00 (20060101); C10B 57/00 (20060101); C10B
39/00 (20060101); C10B 57/08 (20060101); C10B
39/02 (20060101); F26B 3/02 (20060101); F26B
3/084 (20060101); C10L 9/02 (20060101); F26b
003/08 () |
Field of
Search: |
;34/10,26,31,32,37,40,72,57A,219 ;202/150,228,227 ;432/15,58 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: O'Dea; William F.
Assistant Examiner: Anderson; William C.
Attorney, Agent or Firm: Steinberg & Blake
Parent Case Text
CROSS REFERENCE TO RELATED APPLICATION
This application is a division of application Ser. No. 283,155,
filed Aug. 23, 1972 and entitled "Method and Apparatus for Drying
Coal."
Claims
What is claimed is:
1. In a coal-drying method method, feeding coal particles which are
to be dried to a drying chamber, drying the coal in said chamber
with heating coils supplied with steam, heating the latter steam in
the heating coils with a heat exchange while deriving heat for the
heat exchanger from coke-cooling gas used during dry-quenching of
coke from a coke oven, extracting hydrogen sulfide from the drying
chamber and reacting the hydrogen sulfide with ammonia for
extracting sulphur from the hydrogen sulfide.
2. In a coal-drying method, feeding coal particles which are to be
dried to a drying chamber, drying the coal in said chamber with
heating coils supplied with steam, heating the latter steam in the
heating coils with a heat exchanger while deriving heat for the
heat exchanger from coke-cooling gas used during dry-quenching of
coke from a coke oven, feeding to the drying chamber simultaneously
with the coal particles pellets which have a composition which will
extract sulphur from the atmosphere in the drying chamber, the
pellets being selected from the group consisting of calcium oxide
and magnesium oxide.
3. In a coal-drying method, feeding coal particles which are to be
dried to a drying chamber, drying the coal in said chamber with
heating coils supplied with steam, heating the latter steam in the
heating coils with a heat exchanger while deriving heat for the
heat exchanger from coke-cooling gas used during dry-quenching of
coke from a coke oven, the coal particles having a size on the
order of 1/8 inch, maintaining the drying steam in the form of a
fluidized bed in a temperature range of 100.degree.-250.degree.C,
controlling the temperature in the drying chamber with heating
coils having therein steam at a temperature range of approximately
250.degree.-450.degree.C, utilizing for the coils pipes of
approximately 2 feet diameter and forming parts of partitions which
define between themselves spaces in the fluidized bed having a
width on the order of 4 inches, feeding to the fluidized bed
pellets selected from the group consisting of calcium oxide and
magnesium oxide and having a diameter on the order of 1/2 inch,
discharging the pellets and the dry coal from the drying chamber,
and then roasting the pellets.
4. In a coal-drying method, feeding coal particles which are to be
dried to a drying chamber, drying the coal in said chamber with
heating coils supplied with steam, heating the latter steam in the
heating coils with a heat exchanger while deriving heat for the
heat exchanger from coke-cooling gas used during dry-quenching of
coke from a coke oven, extracting fluid from the drying chamber,
condensing water therefrom, and utilizing said water for quenching
gas issuing from a coke oven.
Description
BACKGROUND OF THE INVENTION
The present invention relates to methods for drying coal.
The present invention relates in particular to such methods as used
in connection with coke plants where coal is converted into coke
which is then available for use in blast furnace, for example.
In conventional coke plants it is customary to deliver coal
directly from bunkers to coke ovens in which the coal is treated so
as to be converted into coke. These conventional operations are
accompanied by great disadvantages. For example, a considerable
amount of heat energy is lost with conventional coke plant
operations. In addition, these operations are accompanied by
unavoidable discharge of pollutants to the outer atmosphere,
creating problems with ecology as a result of contamination of the
atmosphere, streams of water, and terrain in the vicinity of the
coke plants. One of the more serious sources of this undesirable
contamination is the sulphur which is released from the coal during
the formation of the coke. Thus, considerable energy is required to
drive moisture from the coal and in addition sulphur is released in
an undesirable manner to the outer atmosphere with conventional
coke plant operations.
It has already been proposed to dry coal prior to delivery thereof
to the coke oven batteries, but these coal drying operations are
extremely dangerous. All known installations for drying coal suffer
to some degree from explosions which occur because of the presence
of oxygen in the coal-drying atmosphere.
SUMMARY OF THE INVENTION
It is accordingly a primary object of the present invention to
provide a method which will avoid the above problems.
In particular, it is an object of the present invention to provide
a method capable of drying coal in such a way that the risk of
explosions is eliminated.
Also it is an object of the present invention to provide a method
for drying coal in such a way that sulphur is extracted from the
coal to reduce the extent to which the sulphur pollutants are
discharged.
Furthermore, it is an object of the present invention to provide a
coal-drying method which makes use of energy available at a coke
plant and which otherwise would be wasted, so that considerable
economies will be achieved with the method and apparatus of the
invention.
Furthermore, it is an object of the invention to treat the coal
prior to delivery thereof to the coke oven battery in such a way
that the operating time required for the coke oven battery can be
considerably reduced.
Thus, it is an object of the invention to treat coal at a coke
plant in such a way that utilization is made of energy which
otherwise would be wasted, while at the same time further economies
are achieved by reducing the time required for operation of the
coke ovens to convert the coal into coke, and furthermore while
reducing the extent to which pollutants are discharged.
In accordance with the invention coal particles are delivered to
the interior of a drying chamber which is closed off from the outer
atmosphere and the coal particles are dried in the drying chamber
by utilizing for drying purposes steam which is at a temperature
high enough to extract sulphur from the coal during drying thereof
while at the same time the temperature of the steam is maintained
low enough to prevent separation of oxygen from the steam. The
drying steam is used to form a fluidized bed from the coal
particles, and in the fluidized bed there are heating coils which
control the temperature of the fluidized bed while at the same time
further drying the coal by direct contact with the coal suspended
in the fluidized bed. Hydrogen sulfide is formed in the drying
chamber as a result of extraction of sulphur from the coal, and
this hydrogen sulfide is treated in a number of ways so as to
extract the sulphur as a by-product of the method of the invention.
The coal which is discharged from the dryer in a preheated
condition free of moisture and sulphur is delivered directly to the
coke oven battery, to achieve in this way a reduction of the
operating time of a coke oven battery which is on the order of 50
percent. Water which is condensed from gas which is discharged from
the coal dryer is used to quench gas issuing from the coke oven
battery, and heat extracted from the coke during dry-quenching
thereof is used for heating in a heat exchanger steam which is used
for drying the coal, so that in this way considerable economies are
achieved.
BRIEF DESCRIPTION OF DRAWINGS
The invention is illustrated by way of example in the accompanying
drawings which form part of this application and in which:
FIG. 1 is a schematic representation of a method according to the
invention;
FIG. 2 is a schematic sectional plan view taken along line 2--2 of
FIG. 1 in the direction of the arrows and illustrating the interior
of a coal dryer of the invention;
FIG. 3 is an elevation taken along line 3--3 of FIG. 2 in the
direction of the arrows and illustrating one of the partition walls
which includes heating coils as a part thereof;
FIG. 4 is a fragmentary sectional elevation taken along line 4--4
of FIG. 3 in the direction of the arrows to illustrate further
details of the structure of FIG. 3; and
FIG. 5 is a fragmentary schematic illustration of the manner in
which the coal is treated in the coal drying of the invention.
DESCRIPTION OF PREFERRED EMBODIMENTS
Referring to FIG. 1, there is illustrated therein a coal-drying
installation according to the present invention. The coal-drying
installation includes a housing means 10 which is closed off from
the outer atmosphere and which defines in its interior a drying
chamber 12, as indicated schematically in FIG. 1. A coal-feeding
means 14 is provided for feeding particles of coal into the housing
means 10 so that drying of the coal will take place in the drying
chamber 12.
As is schematically indicated in FIG. 1, the coal is initially
stored in bunkers 16. From the bunkers 16 the coal flows through
grinding units 18 so as to be reduced in this way to particles of a
predetermined size. For example the coal particles may have a size
on the order of 1/8 inch. It is to be understood that a group of
bunkers are provided for the coal, these bunkers respectively
communicating with grinders the output of which may all be combined
with a single pipe which is operatively connected with the housing
means 10, in the manner indicated for the pipe 14, so that in this
way such a feedpipe will form a coal-feeding means for feeding the
particles of coal into the drying chamber 12. The particles of coal
issue from the feeding means 14 into a central region of the
chamber 12 and are distributed throughout the entire cross section
of the chamber progressing downwardly therethrough in a manner
described in greater detail below.
As has been indicated above, it is extremely important to avoid the
presence of free oxygen within the drying chamber 12 since the
presence of oxygen will unavoidably result in dangerous explosions.
Thus, in accordance with one of the features of the present
invention the drying of the coal takes place by exposing the coal
particles in the drying chamber 12 to an atmosphere of steam which
is maintained at a temperature low enough to prevent release of
oxygen from the steam but high enough to drive sulphur out of the
particles of coal during the dying thereof. Thus moisture and
sulphur will be driven off from the particles of coal due to the
drying action which takes place in the chamber 12. Thus, the
atmosphere of steam in the chamber is maintained at a temperature
on the order of 250.degree.C, since at this temperature organically
bound H.sub.2 S will be driven off from the particles of coal. As
long as the temperature of the steam in the drying chamber 12 is
maintained at a temperature lower than 500.degree.C, there will be
no release of free oxygen from the steam, and the danger of
explosions will be avoided.
According to one of the features of the present invention the steam
used for drying purpose in the housing means 10 is derived from a
heat-exchanger means 20 shown schematically in FIG. 1 between the
housing means 10 and a bunker 22 in which coke from a coke oven is
cooled by dry-quenching. As is illustrated in FIG. 1 by the
dot-dash circuit 24, gas which is used for quenching the coke in
the bunker 22 circulates, after being heated by the coke which is
cooled in the bunker 22, through the heat exchanger means 20. Thus,
through suitable conduits and with the use of suitable fans or the
like there will be a continuous circulation of the dry-quenching
gas upwardly through the coke which is cooled in the bunker 22 and
downwardly through the heat exchanger, so that heat extracted from
the gas in the bunker 22 is given up to the fluid which is heated
in the heat exchanger means 20 during cooling of the gas before it
is returned to the bunker 22. Feedwater is fed to the heat
exchanger means 20 in any suitable way, as by a pump 24, and in
this way there will be derived from the heat exchanger means 20
steam which flows through the supply means 26. This supply means 26
takes the form of suitable steam conduits which have a control
valve 28 for controlling the flow of steam to any desired location
where use will be made thereof. However, part of the steam-supply
means includes a portion 30 of the conduit 26 which communicates
with a plenum formed at a lower interior portion of the housing
means 10, the flow of the steam into the plenum being controlled by
a valve 32. The plenum 34 is defined beneath an apertured wall 36
which is carried by and extends across the interior of the housing
means 10. This way 36 may be constructed in any known way to form a
fluidized bed of the coal particles with the steam issuing up
through the wall 36, so that in this way the coal particles are
maintained in a fluidized bed in the chamber 12 and the wall 36
together with the plenum 34 forms a fluidizing means for forming a
fluidized bed of coal particles. Thus, the wall 36 may take the
form of a wall carrying suitable nozzles, or it may take the form
of a suitably apertured plate, or it may be composed of a mesh of
rods, all of which is well known in the art.
Thus, by way of the fluidizing means 34, 36 the steam supplied by
the steam-supply means 30 will maintain the particles of coal
suspended in a fluidized bed in the drying chamber 12, The dry coal
issues from the housing means 10 through a discharge means 38 which
may take the form of a suitable discharge duct the diameter of
which is such that in combination with the rate of supply of coal
particles by the supply means 14 and the treatment of the coal in
the fluidized bed there will be an issue of dry coal at a
preselected rate from the discharge means 38.
According to a further feature of the invention, the steam in the
drying chamber 12 has its temperature regulated by way of a heating
means 40 which takes the form of coils through which steam flows,
these coils forming parts of partition walls in the manner
described in greater detail below. The steam for the heating means
40 is also derived from the supply means 26. Thus the conduit 26
has a branch 42 provided with a control valve 44 and communicating
with the heating means 40 so as to deliver to the latter the same
steam which is delivered to the plenum 34. Actually a greater
amount of steam is delivered to the heating means 40 while only a
relatively small amount of steam is delivered to the plenum 34.
However, the same single source of steam, namely the conduit 26
which derives its steam from the heat exchange means 20 is used for
supplying steam both to the heating means 40 and to the fluidizing
means 34, 36. After flowing through the heating means 40, the steam
discharges back to the inlet pipe 46 which delivers the feedwater
to the pump 24, a return flow pipe 48 being provided for this
purpose. Thus the returning fluid from the heating means 40 is
combined with the feedwater to be fed back to the heat exchanger
and reheated before being returned to the heating means 40, and the
feedwater will make up for losses such as that which occurs in
connection with the supply of steam to the plenum 34.
Referring to FIG. 2, it will be seen that the heating means 40
takes the form of a relatively large number of parallel plates 50
which are spaced from each other and mounted in any suitable way in
the interior of the housing means 10, as shown schematically in
FIG. 2. The supply pipe 42 communicates with a suitable header 52
which in turn communicates with the several plates 50 each of which
has a construction as described below and illustrated in FIGS. 3
and 4.
Thus, referring to FIG. 3, it will be seen that each plate 50 is in
the form of a wall 54 having coils 56 as a part thereof. As may be
seen from FIG. 4, each wall 54 is composed of a pair of plate
portions 54a and 54b which are fixed in any suitable way to each
other. These plate portions 54a and 54b are formed with grooves
which register with each other when the plate portions are joined
together, so that in this way each wall 54 will have as a part
thereof the coils 56 which may have a configuration as shown
schematically in FIG. 3.
The manner in which the coal particles are treated with the above
construction is shown schematically in FIG. 5. In the case where
the coal particles have a size on the order of 1/8 inch, the walls
54 may be spaced from each other by a distance D which is on the
order of 4 inches, with the coils 56 have a diameter on the order
of 2 inches. Thus, the parallel walls 54 of the heating means 40
form partitions which define between themselves upright spaces
having a width on the order of 4 inches, and it is in these
relatively narrow spaces that the coal particles are confined in
the fluidized bed above the apertured wall 36. This wall 36 is
shown in FIG. 5, schematically, as including the nozzles which
direct the steam from the plenum 34 upwardly into the drying
chamber to maintain the fluidized bed of coal.
A number of advantages are achieved with this construction which is
shown in FIG. 5. In the first place, it has been found in practice
that by way of controls such as those derived from the valves 32
and 44 it is possible to very closely regulate the temperature of
the steam in the drying chamber. The steam within the coils 56 is
maintained at a temperature range of 250.degree.-450.degree.C,
while the coal itself is maintained at a temperature range of
100.degree.-250.degree.C, with the steam in the fluidized bed being
at a temperature on the order of 250.degree., as indicated
schematically in FIG. 5, so that in this way the organically bound
hydrogen sulfide will be driven off from the coal particles.
A further advantage achieved with the construction shown in FIG. 5
resides in the fact that the particles of coal repeatedly come
directly into contact with the walls 54 and particularly with the
heating coils 56 thereof, so that not only is the coal heated by
way of the steam in the fluidized bed, but in addition it is heated
by way of direct contact with the heating means, so that the drying
of the coal is enhanced by contact-drying of the coal as a result
of engagement of the coal particles directly with the heating means
40. Thus, an exceedingly efficient coal-drying operation free of
any possibility of explosion is achieved with the method and
apparatus of the invention. The coal which issues from the
discharge means 38 is free of ammonia, water, and sulphur, and is
in a preheated condition which is ideal for direct supply to a coke
oven.
According to a further feature of the invention, instead of
utilizing steam to form the fluidized bed, an inert gas may be
supplied to the plenum 34 by way of a conduit 58 which is capable
of being open and closed by way of a valve 60. For example,
nitrogen or cleaned stack gas may be used as the inert gas.
Irrespective of which particular inert gas is used to form the
fluidized bed, the inert gas may be preheated so that it will have
a suitable temperature. For example, the conduit 58 may communicate
with coils in the heat exchanger 20 to which the inert gas is
supplied so that the inert gas is heated by extracting heat from
the dry-quenching gas which is heated as described above when
flowing through the circuit 24.
During the operation of the drying installation through suitable
fans and conduits steam vapor and hydrogen sulfide are continuously
drawn out of the upper portion of the housing means 10 to be
delivered to a reaction unit 62. Ammonia is supplied to this unit
to react with the products flowing out of the housing means 10, and
as a result with condensation there is achieved ammonia liquor
which may be used for any desired purpose as well as
(NH.sub.4).sub.2 S which is delivered to a heating unit 64 to
retrieve from the latter ammonia as well as various
sulphur-containing products.
According to a further feature of the invention, the sulphur
content of the atmosphere in the drying chamber 12 is reduced by
operatively connecting with the housing means 10 a supply means 66
for supply to the drying chamber 12 pellets which will extract
sulphur from the atmosphere in the chamber 12. These pellets may be
calcium oxide and/or magnesium oxide pellets having a diameter on
the order of 1/2 inch in the case where the coal particles have a
diameter on the order of 1/8 inch. These pellets when progressing
through the fluidized bed to the discharge means 38 combine with
sulphur to form Ca So.sub.4 and/or Mg So.sub.4. The latter pellets
are discharged together with the coal particles onto a sizing
screen 68 by the discharge means 38. The mesh of the sizing screen
is such that the smaller coal particles fall downwardly through the
screen onto a conveyor 70 which conveys the dry preheated coal to
the coke oven. The pellets which do not fall through the screen
travel along the latter and drop onto a conveyor 72 which delivers
the pellets to roasting ovens where the pellets return to their
initial composition with extraction of sulphur dioxide
therefrom.
With an installation as described above it is possible,
particularly with the size ranges of the coal particles and heating
means to achieve and output of the order of 100 tons of dry
preheated coal per hour. This dry preheated coal is delivered
directly to a coke oven battery, and with the use of this coal in
the coke oven battery it has been found possible to reduce the
operating time of the coke oven battery by 50 percent. Because
sulphur is driven from the coal during the drying thereof the
possibility of polluting the atmosphere with products from the coke
oven batteries is greatly diminished. Moreover, the amount of water
needed to quench coke oven gas issuing from the ovens is greatly
reduced.
Thus, with the method of the invention the possibility of polluting
atmosphere, streams, and adjoining terrain is very greatly reduced.
In addition, the possibility of explosions occurring at the drying
installations is also eliminated. Furthermore, the operations are
carried out in such a way that use is made of energy which
otherwise would be wasted, so that considerable economies are
achieved. Furthermore, the coal delivered to the coke ovens is in a
condition which greatly reduces the time required for operation of
the coke ovens, as pointed out above.
* * * * *