U.S. patent number 3,798,006 [Application Number 05/207,793] was granted by the patent office on 1974-03-19 for catalytic converter for exhuast gases.
This patent grant is currently assigned to Tenneco, Inc.. Invention is credited to Robert N. Balluff.
United States Patent |
3,798,006 |
Balluff |
March 19, 1974 |
CATALYTIC CONVERTER FOR EXHUAST GASES
Abstract
A catalytic converter adapted for use in the exhuast systems of
internal combustion engines comprises a housing including as a part
thereof a tubular shell having a differentially hardened fibrous
lining to resiliently support, insulate, and secure a monolithic
type catalyst element. The ends of the tubular shell and the
fibrous lining are angularly deformed inwardly to protect the
corners of the catalyst, to minimize gas impingement on the fibrous
material, and to mechanically retain the catalyst in position.
Inventors: |
Balluff; Robert N. (Rives
Junction, MI) |
Assignee: |
Tenneco, Inc. (Racine,
WI)
|
Family
ID: |
22772022 |
Appl.
No.: |
05/207,793 |
Filed: |
December 14, 1971 |
Current U.S.
Class: |
422/179;
422/180 |
Current CPC
Class: |
F01N
3/2867 (20130101); F01N 3/2853 (20130101) |
Current International
Class: |
F01N
3/28 (20060101); F01n 003/14 (); B01j 009/04 () |
Field of
Search: |
;23/288F ;60/299
;423/213,214 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Richman; Barry S.
Attorney, Agent or Firm: Harness, Dickey & Pierce
Claims
I claim:
1. A catalytic converter for purifying the exhaust gas of an
internal combustion engine comprising a tubular metal shell, a gas
pervious refractory catalyst element inside said shell and arranged
so that flow through the element is substantially axial with
respect to the axis of the shell, means resiliently mounting said
element inside said shell so that the outer surface of the element
is spaced from the inner surface of the shell, an inlet conduit
having a flange fitting around the outside of and welded to one end
of the shell, an outlet conduit having a flange fitting around the
outside of and welded to the other end of the shell, said element
having inlet and outlet end faces, said resilient mounting means
comprising a nonmetallic resilient fibrous insulating layer in the
space between said surfaces and having an end portion axially
overlapping one end face of the element and bent over the adjacent
end corner of the element.
2. A converter as set forth in claim 1 wherein said layer end
portion overlaps the outlet end face of the element and extends
inwardly at an angle over the outlet end corner of the element and
the outlet end of the shell has a flange extending inwardly over
said end portion of the fibrous layer to hold said layer in place
over said outlet end corner.
3. A converter as set forth in claim 1 wherein the adjacent end of
the shell has a shoulder adjacent the bent end portion of the
fibrous layer to hold said bent layer portion in place over said
corner.
4. A converter as set forth in claim 3 wherein said fibrous layer
contains a differentially dispersed solid material deposited on the
fibers in heavy concentrations adjacent the exposed surfaces of the
layer and adjacent the outer layer surfaces in juxtaposition to
said element and shell surfaces and in materially less
concentration in the center portion of the layer whereby said
center portion is resilient, said deposited material serving to
harden and seal said exposed and outer layer surfaces and to bond
the outer layer surfaces to said element and shell.
5. A converter as set forth in claim 4 wherein said fibrous layer
is in contact with and bonded to said shell surface and said
element surface and in compression between them and serves to seal
the outside of the element.
6. A subassembly for use in a catalytic converter for purifying the
exhaust gases of an internal combustion engine comprising a tubular
metal shell having a longitudinal axis and opposite longitudinal
end portions, a cylindrical fluid pervious frangible catalyst
element having a longitudinal axis and longitudinally separated
inlet and outlet end faces each with an outer circumferential
corner, said element having an outer surface and said shell having
an inner surface larger in cross section than said element outer
surface, said element being positioned inside of said shell so that
said axes are substantially coaxial and to provide a substantially
uniform width annular space between said surfaces forming a
substantially annular chamber with an axis substantially coaxial
with said axes, an annular resilient nonmetallic fibrous insulating
member in said annular chamber and serving to resiliently mount
said element in said shell, fluid flow through said shell being
substantially parallel to said axes, said shell end portions
extending longitudinally beyond said inlet and outlet end faces of
said element to protect said corners during handling of the
subassembly, and flange means mechanically holding the shell,
element, and member in substantially permanent longitudinal
positions with respect to each other including radially extending
portions of said fibrous member extending across and engaging said
circumferential corners.
7. A combination as set forth in claim 6 wherein said flange means
includes radially extending portions of said shell engaging and
holding said fibrous member portions against said circumferential
corners.
8. A catalytic converter for purifying the exhaust gases of
internal combustion engines comprising a housing including a
tubular shell, a frangible gas pervious refractory catalyst element
inside said shell having inlet and outlet end faces with outer
circumferential end corners and arranged so that flow through the
element and faces is substantially axial with respect to the axis
of the shell, means resiliently mounting said element inside said
shell so that the outer surface of the element is spaced from the
inner surface of the shell, an inlet means at one end of the shell,
an outlet means at the other end of the shell, said resilient
mounting means comprising a nonmetallic resilient fibrous
insulating layer in the space between said surfaces having an
axially and circumferentially extending portion axially overlapping
an end face of the element and radially extending over the adjacent
circumferential end corner of the element, said housing including
means holding said layer portion over said corner.
9. A converter as set forth in claim 8 wherein said axially and
circumferentially extending portion overlaps the inlet end face of
the element and extends over the inlet end corner.
10. A converter as set forth in claim 8 wherein said axially and
circumferentially extending portion overlaps the outlet end face of
the element and extends over the outlet end corner.
11. A converter as set forth in claim 10 including a second axially
and circumferentially extending portion axially overlapping the
inlet end face of the element and radially extending over the inlet
end corner, said housing including second means holding said second
layer portion over said inlet corner.
12. A catalytic converter for purifying the exhaust gases of an
internal combustion engine comprising a tubular metal shell having
an outer cylindrical surface of substantially round uniform
diameter cross section along most of the length of the shell, a gas
pervious refractory catalyst element inside said shell and arranged
so that flow through the element is substantially axial with
respect to the axis of the shell, means resiliently mounting said
element inside said shell so that the outer surface of the element
is spaced from the inner surface of the shell, an inlet conduit
having a flange fitting around the outside of and welded to said
round outer cylindrical surface at one end of the shell, an outlet
conduit having a flange fitting around the outside of and welded to
said round outer cylindrical surface at the other end of the
shell.
13. A converter as set forth in claim 12 including flange means
engaging the outer circumferential corner at the outlet end of the
element and providing a mechanical holding means against
substantial axial displacement of the element in a downstream
direction, said flange means comprising a fibrous layer in contact
with said corner and a radial flange on the shell in contact with
the fibrous layer.
14. A converter as set forth in claim 12 wherein said resilient
mounting means includes a fibrous sleeve in the space between the
element and shell, and flange means engaging the outer portion of
the outlet end of the element and providing a mechanical holding
means against substantial axial displacement of the element in a
downstream direction, said flange means comprising a radially
inwardly extending flange formed on the end of the shell, said
flange means further comprising a radially inwardly extending
flange formed on the fibrous sleeve and sandwiched between the
shell flange and the element.
15. A converter as set forth in claim 12 including retainer means
supported by said shell engaging the outer circumferential corner
of the element at the outlet end thereof to resist substantial
downstream displacement of the element.
16. A catalytic converter for purifying the exhaust gases of an
internal combustion engine comprising a tubular metal shell, a gas
pervious refractory catalyst element inside said shell and arranged
so that flow through the element is substantially axial with
respect to the axis of the shell, said element having a downstream
end, means resiliently mounting said element inside said shell so
that the outer surface of the element is spaced from the inner
surface of the shell, an inlet conduit at one end of the shell, an
outlet conduit at the other end of the shell, and flange means
reacting against the downstream end of the element and providing a
mechanical holding force against downstream axial displacement of
the element in one direction and comprising a fibrous layer
extending radially inwardly from the outer surface of the element
and in contact with the downstream end of the element and a radial
flange formed integrally on the shell in contact with the fibrous
layer.
17. A subassembly for use in a catalytic converter for purifying
the exhaust gases of an internal combustion engine comprising a
tubular metal shell having a longitudinal axis and opposite
longitudinal end portions, a cylindrical fluid pervious frangible
catalyst element having a longitudinal axis and longitudinally
separated inlet and outlet end faces each with an outer
circumferential corner, said element having an outer surface and
said shell having an inner surface larger in cross section than
said element outer surface, said element being positioned inside of
said shell so that said axes are substantially coaxial and to
provide a substantially uniform width annular space between said
surfaces forming a substantially annular chamber with an axis
substantially coaxial with said axes, a fibrous member in said
annular chamber and serving to resiliently mount said element in
said shell, fluid flow through said shell being substantially
parallel to said axes, said shell end portions extending
longitudinally beyond said inlet and outlet end faces of said
element to protect said corners during handling of the subassembly,
and flange means mechanically holding the element against movement
in a downstream direction in the shell including a radially
extending portion of said fibrous member extending across and
engaging said outlet circumferential corner and a radially
extending portion of said shell engaging said radially extending
fibrous member portion.
Description
RELATED APPLICATION
U.S. application Ser. No. 207,794, entitled "Catalytic Reactor with
Monolithic Element," filed of even date herewith of Hubert H. Nowak
and assigned to the assignee hereof concerns features relating to
the fibrous mounting layer and impregnation thereof.
BRIEF SUMMARY OF THE INVENTION
It is the basic purpose of this invention to provide an improved
type mounting for a monolithic type or honeycomb catalyst element
which is suitable for mass manufacture and for use in exhaust
systems of automotive internal combustion engines.
The invention accomplishes this purpose by use of an impregnated
fibrous sleeve to mount the monolithic catalyst element on a tube
or ring which forms a part of the converter housing. Preferably,
prior to assembly of the housing, at least the downstream end of
the sleeve and preferably the ring are angularly deformed inwardly
to provide a combination seal, retainer, and protector for the
catalyst element.
DESCRIPTION OF THE DRAWINGS
FIG. 1 is a longitudinal cross section through a catalytic
converter embodying the invention;
FIG. 2 is a cross section along the line 2--2 of FIG. 1, and;
FIG. 3 is an enlarged partial subassembly view (prior to crimping)
of the catalyst element, the fibrous sleeve, and the housing
ring.
DESCRIPTION OF THE INVENTION
The catalytic converter 1 has a three piece housing comprising an
inlet header cone 3, an outlet header cone 5, and an intermediate
round tubular ring 7 which fits inside of and is welded to annular
end sections 9 on the cones as seen at 11. The inlet and outlet
cones have suitable collars 13 at their outer ends whereby they may
be secured to conduits in the exhaust system of an internal
combustion engine. The converter 1 contains a monolithic type
honeycomb catalyst element 15 which has a large number of cellular
passages 17 through which gas can flow from the inlet chamber 19 in
cone 3 to the outlet chamber 21 in cone 5. The element 15 is
constructed of a suitable refractory or ceramic material and
appropriate catalytic material is deposited on the walls of the
passages 17 whereby the refractory material serves as a support for
the catalytic material, a more extensive description of one form of
element 15 being found in U.S. Pat. No. 3,441,381. Catalytic
elements of this type are very fragile and in the course of
manufacture, particularly on a large scale, it is very easy for
them to become damaged, particularly at the corners. They are also
subject to wearing, abrasion, chipping, and fracture in use due to
shock loads, differential expansion rates as compared with the
metal of the container, and relative abrasive movement between it
and the harder metal part.
In accordance with this invention, there is a resilient wall or
interface 23 between the element 15 and the metal ring 7. The wall
is preferably formed of ceramic fiber material such as blown
alumina silica felted fibers sold under the tradenames "Fiberfrax,"
"Cera Fiber," or "Kaowool." Other high temperature resistant
fibers, such as (but not limited to) asbestos, may also be used to
form the layer 23 in certain applications. In a typical assembly
where the element is 4 - 5 inches in diameter a felted layer or
sleeve of ceramic fibers about one-fourth inch thick is wrapped
around the element 15. This combination of fiber 23 and element 15
is then inserted into ring or shell 7, the diameter of which is
such that the wall 23 is radially compressed to a nominal
three-sixteenths inch thickness. In the presently preferred
arrangement, the fiber wrap 23 extends longitudinally beyond the
ends of the element 15, as seen at 25 and 27 for, preferably, about
one-eighth inch; and the metal shell 7 extends beyond the ends of
element 15 for, preferably, about one-fourth inch as seen at 29 and
31. The ends 29 and 31 of the ring 7 are curled or deformed
inwardly on angles of preferably about 30.degree. and this causes
the ends 25 and 27 of the fiber sleeve to curl over the corners of
the element so that they can protect them without closing off any
flow channels 17 of the element.
After assembly and end crimping of the ring 7, the element 15, and
the layer 23, a suitable rigidizer, binder, and adhesive liquid
containing a high temperature withstanding material, such as an
aqueous colloidal solution of silica containing from 15 to 40% Si
O.sub.2 by weight or other suitable organic binder is applied to
the layer 23. This solution may be applied before assembly to the
shell and/or element or may be injected by needle or other suitable
means into the layer 23. The amount of solution used is controlled
so that it is insufficient to penetrate and coat the walls of
channels 17 but large enough to provide the necessary amount of dry
silica (or binder) needed to harden the ends of the layer. After
injection the assembly 33 is put through a drying process, for
example, placed in an oven at a temperature of about 250.degree. F
or higher, so that the water or other liquid in the colloidal
solution is removed. In drying, the silica solids migrate with the
liquid vehicle to the points where vaporization occurs and are
deposited at those points to a substantially greater degree than
elsewhere. This means that the silica solids tend to concentrate at
the exposed ends 25 and 27 of the sleeve 23 and to a lesser extent
at the interfaces of the sleeve and the ring 7 and the element 15.
Selective heating, instead of oven drying, can be used, if desired,
to control the areas of deposition of silica.
After complete drying, the silica serves to bond the fibers of
sleeve 23 together and to the adjacent surfaces of ring 7 and
element 15. The hardened silica provides an effective positive seal
against gas leakage from the usual broken cell walls around the
outside of the honeycomb element 15. Further, the hardened silica
rigidizes and seals the ends 25 and 27 of the fiber to form a
positive gas barrier making the sleeve gas impervious. It also
provides a positive, nonmetallic mechanical lock between the
element 15 and the metal ring 7 so that the element is well
supported but is not in contact with metal. Despite the effects
just mentioned, the bulk of the fiber wrap 23 between the hardened
surface layers has very little hardened silica, if any, and is,
after drying, practically as resilient as the original fiber layer
before hardening. Thus, the layer 23 functions as an absorbent
barrier to insulate and protect the element 15 from mechanical
shocks. It also functions as a thermal insulation barrier between
the metal shell 7 and the element 15. It is apparent that the
density and hardness of layer 23 can be controlled by control of
the nature and amount of the rigidizer and adhesive liquid.
The ring 7 and sleeve 23 serve as a carrier and protector for the
frangible element 15 and minimize the possibility of damage to the
element during assembly of the unit 33 with the headers 3 and 5. As
indicated, this assembly is completed to form converter 1 by
welding, or other suitable fastening, as shown at 11.
In use of the converter 1, exhaust gas enters the inlet header 3
and flows directly through the catalyst treated passages 17 of the
honeycomb 15 into the outlet chamber 21 and then out of the
converter. The radially extending or angular flange portions 35 and
37 at the inlet and outlet sides of the assembly 33, in addition to
the functions mentioned above, serve also to deflect gas away from
the sleeve 23 and into the element 15 to minimize impingement upon
and erosion of the sleeve.
It will be seen that the described mounting of the element 15 on
metal shell 7 has many desirable features. It enables nearly 100
percent of the volume of element 15 to be used since none of the
passages 17 are blocked off. It provides effective positive sealing
against leakage around the outside of the element, despite the
usual rough and broken outer surface of the element, and eliminates
the need for a special seal coating on the outside of the element.
It eliminates abrasion of the element by eliminating all metal
contact with the element. It provides positive mechanical locking
as well as adhesive bonding of the element to the shell 7 and
converter housing. It provides a resilient interface between the
element 15 and the shell 7 which gives a high degree of mechanical
shock resistance and which eliminates stringent dimensional
tolerances. Since the ceramic fibers are stable up to the usual
maximum catalyst operating temperatures (about 2,300.degree. F),
the converter is operative and safe at all temperatures encountered
in normal usage of the element. The simple structure of the
converter 1 enables the thickness of the layer 23 to be readily
varied in accordance with the degree of thermal and shock
insulation desired. The arrangement provides for substantially
stress-free relative movement between the element and ring 7 such
as occasioned by different rates of thermal expansion and
contraction. The thermal insulating properties of layer 23 also
minimize the temperature of the metal housing to protect the
surrounding environment, provide for faster warm-up and better heat
retention in the catalyst and minimum cross sectional thermal
gradients due to conductive heat loss into the metal shell, and
enable a better selection of metals for use in the shell because of
metal isolation from very high temperatures, for example, low
grade, low expansion ferritic stainless steel might be used.
While a presently preferred embodiment of the invention has been
illustrated and described, it will be apparent that modifications
thereof are within the spirit and scope of the invention. For
example, in some assemblies it may be desirable to provide the
flange means at one end only (preferably at the outlet end 37 to
secure mechanical holding force) and eliminate the other flange
means. Other means of holding the fiber portion 25 and/or 27 in
bent position may be used, for example, a fold or indentation in
shell 7 spaced from an end of the shell or the angle of the cone 3
or 5. Broadly, a structural assembly advantage is still achieved if
the bent corners are entirely eliminated as the sleeve 7 fits
inside of the inner ends of cones 3 and 5 and facilitates formation
of the housing. Also, the subassembly 33 may be connected to inlet
and outlet flow conduits of varying types and structures.
* * * * *