U.S. patent number 3,795,961 [Application Number 05/286,399] was granted by the patent office on 1974-03-12 for thermal and abrasion resistant sintered alloy.
This patent grant is currently assigned to Nippon Piston Ring Co., Ltd.. Invention is credited to Minoru Hasegawa, Kaoru Nara, Kentaro Takahashi.
United States Patent |
3,795,961 |
Takahashi , et al. |
March 12, 1974 |
THERMAL AND ABRASION RESISTANT SINTERED ALLOY
Abstract
An alloy prepared by molding a powdery composition comprising
0.6 to 2% of carbon, 0.5 to 4% of nickel, 0.5 to 5% of molybdenum
and 6 to 11% of cobalt, by weight, and the balance being iron, and
then sintering the molded composition, has large thermal resistance
and abrasion resistance.
Inventors: |
Takahashi; Kentaro (Ohmiya,
JA), Hasegawa; Minoru (Saitama, JA), Nara;
Kaoru (Kawaguchi, JA) |
Assignee: |
Nippon Piston Ring Co., Ltd.
(Tokyo, JA)
|
Family
ID: |
13331606 |
Appl.
No.: |
05/286,399 |
Filed: |
September 5, 1972 |
Foreign Application Priority Data
|
|
|
|
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Sep 2, 1971 [JA] |
|
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46-66978 |
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Current U.S.
Class: |
75/243;
75/246 |
Current CPC
Class: |
C22C
33/0285 (20130101); C22C 33/0242 (20130101) |
Current International
Class: |
C22C
33/02 (20060101); B22f 001/00 () |
Field of
Search: |
;75/125,123J,123K,200
;29/182.1,182 ;191/59.1 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Quarforth; Carl D.
Assistant Examiner: Hunt; B.
Attorney, Agent or Firm: Sughrue, Rothwell, Mion, Zinn &
Macpeak
Claims
What is claimed is:
1. A thermal and abrasion resistant sintered alloy consisting
essentially of a molded and sintered composition comprising from
0.6 to 2% of carbon, from 0.5 to 4% of nickel, from 0.5 to 5% of
molybdenum and from 6 to 11% of cobalt, by weight, the balance
being iron.
2. The sintered alloy of claim 1 consisting of the recited
components.
3. The sintered alloy of claim 1 exhibiting a hardness (HV) on the
order of 500 over the temperature range of from normal temperature
to about 500.degree. C.
Description
BACKGROUND OF THE INVENTION
A publicly known metal such as chromium, cobalt, tungsten, etc. has
not only a large abrasion resistance but also is prominent in its
characteristics at elevated temperatures and is applied in various
fields. However, such a metal has many problems to be solved when
it is used as sintered parts for a machine. That is, such a metal
has a high melting point so that the sintering temperature is, of
necessity, required to be elevated, and the sintering time has to
be extended, and, therefore, it is naturally disadvantageous in
cost.
SUMMARY OF THE INVENTION
The present invention provides a sintered alloy having large
thermal resistance and abrasion resistance suitable for use as a
sliding element such as, for example, a valve sheet in which high
thermal resistance and high abrasion resistance are required. That
is, the present invention comprises a sintered thermal and abrasion
resistant alloy comprising a molded and sintered powdery
composition consisting of by weight 0.6 to 2% of carbon, 0.4 to 4%
of nickel, 0.5 to 5% of molybdenum, 6 to 11% of cobalt and the
balance iron.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a graph showing the abrasion resistance of sintered
alloys of the Examples and of a conventional cast iron and a
sintered iron alloy when evaluated in a valve sheet abrasion test
machine; and
FIG. 2 is a graph showing the hardness at elevated temperatures of
sintered alloys of the Examples and of a conventional cast iron and
a sintered iron alloy.
DETAILED DESCRIPTION OF THE INVENTION
In the sintered alloy of the present invention, when the carbon
content is less than 0.6%, by weight, the alloy becomes a
ferrite-excessive structure so that a high hardness cannot be
expected while, when the carbon content is more than 2%, the alloy
changes to a cementite-excessive structure which is high in
britteleness.
Nickel strengthens the base structure of the alloy and improves the
thermal resistance and abrasion resistance, however, the effect is
small with a nickel content of less than 1%, while, when it becomes
more than 4%, the base structure locally changes to martensite so
that the hardness increases unnecessarily.
Molybdenum increases the tenacity of alloy as well as the impact
strength and endurance limit, and, on the other hand, improves the
heat treatment property and stabilizes the structure after
sintering, however, there is little effect with less than 0.5% of
molybdenum and even if more than 5% is present, no effect
corresponding to the increase is obtained.
Cobalt is selected for substantially improving the thermal
resistance and the abrasion resistance at elevated temperatures and
has been established to be 6 to 11% on the basis of a synergistic
effect with the other elements.
In the sintered alloy of the present invention, from a viewpoint of
providing the material with a high density and improving the
lubricating property, it is very advantageous to impregnate molten
lead into the alloy after the alloy is molded and sintered.
In this case, the amount of lead impregnated has been
experimentally confirmed to be preferably within the range of 0.05
to 5%. That is, with less than 0.05% the effect of impregnation is
not remarkable and the impregnation of more than 5% of lead
involves a problem in strength from the relation with the density
of material before impregnation.
The present invention will be further illustrated by the following
Examples by which the present invention is not intended to be
limited. All percents are by weight.
EXAMPLE 1
1.2% of graphite powder (-325 mesh), 2% of carbonyl nickel powder
(-250 mesh), 2% (as molybdenum) of ferromolyb-denum powder (-150
mesh), 10% of cobalt powder (-150 mesh) and 1.0% of zinc stearate
as a lubricant were added to reduced iron powder (-100 mesh) as
iron powder. The mixture was molded under a pressure of 4.5
ton/cm.sup.2 and sintered at 1,120.degree. to 1,170.degree. C for
30 to 60 minutes in an atmosphere of decomposed ammonium gas. The
sintered material so obtained had a density of 6.6 g/cm.sup.3 and a
Rockwell B scale hardness of 92.
The results of the abrasion test on this sintered material using a
valve sheet abrasion testing machine (rotation number 3,000 rpm,
spring pressure 35 Kg, valve velocity at the time of valve closing
0.5 m/sec., width of valve 1 mm, test repeating number 8 .times.
10.sup.5, material SUH 31B) are shown in FIG. 1, and the results of
the measurement of hardness at elevated temperatures are shown in
FIG. 2.
EXAMPLE 2
A sintered material comprising 0.68% of carbon, 0.71% of nickel,
0.66% of molybdenum, 6.92% of cobalt and the balance iron was made
under the same conditions as described in Example 1, and
impregnated with molten lead. The sintered material so obtained had
a density of 6.4 g/cm.sup.3 and a Rockwell B scale hardness of 90.
The lead content was 0.07%.
EXAMPLE 3
A sintered material comprising 1.83% of carbon, 3.88% of nickel,
4.79% of molybdenum, 10.62% of cobalt and the balance iron was made
under the same conditions as described in Example 1 and impregnated
with lead. The sintered material so obtained had a density of 6.7
g/cm.sup.3 and a hardness on the Rockwell B scale of 94. The lead
content was 4.7%.
Next, the abrasion test results using a valve sheet test machine on
Examples 1, 2 and 3 are shown in FIG. 1 and the test results of
hardness at elevated temperatures are shown in FIG. 2. For
comparison these tests were run on a conventionally known cast iron
and conventional sintered ferro alloy. In this case, the
compositions of the cast iron and ferro alloy are as follows:
Ferro alloy: Carbon 1%, chromium 3%, the balance iron.
Cast iron: Carbon 3.02%, silicon 2.01%, manganese 0.48%, chromium
0.81%, the balance iron.
* * * * *