U.S. patent number 3,795,033 [Application Number 05/223,104] was granted by the patent office on 1974-03-05 for fixing process.
This patent grant is currently assigned to Minnesota Mining and Manufacturing Company. Invention is credited to Charles A. Donnelly, James F. Sanders.
United States Patent |
3,795,033 |
Donnelly , et al. |
March 5, 1974 |
FIXING PROCESS
Abstract
Particulate thermoplastic toner is fixed on a receptor surface
by directly contacting the toner with a silicone elastomer surface
while the toner is in a fused state responsive to the adhesive
nature of the silicone elastomer and to the adhesive nature of the
receptor to provide for the substantially complete retention of the
toner on the receptor surface in a fixed condition. Preferably, the
silicone elastomer is free of high surface energy fillers and, most
preferably, is both free of high surface energy fillers and
contains low surface energy fillers blended therein.
Inventors: |
Donnelly; Charles A. (South St.
Paul, MN), Sanders; James F. (Hudson, WI) |
Assignee: |
Minnesota Mining and Manufacturing
Company (St. Paul, MN)
|
Family
ID: |
26917449 |
Appl.
No.: |
05/223,104 |
Filed: |
February 3, 1972 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
|
|
867176 |
Oct 17, 1969 |
3669707 |
Jun 13, 1972 |
|
|
Current U.S.
Class: |
492/56 |
Current CPC
Class: |
G03G
15/2057 (20130101); G03G 11/00 (20130101) |
Current International
Class: |
G03G
11/00 (20060101); G03G 15/20 (20060101); B21b
031/08 () |
Field of
Search: |
;29/132,129.5 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Guest; Alfred R.
Attorney, Agent or Firm: Alexander, Sell, Steldt &
DeLaHunt
Parent Case Text
This is a divisional application of Ser. No. 867,176, filed Oct.
17, 1969, which was issued as Pat. No. 3,669,707 on June 13, 1972.
Claims
What is claimed is:
1. A roll useful as a direct contact fuser for fixing powdered
thermoplastic toner images to a sheet upon which said images have
been deposited, comprising a cylindrical form and a silicone
elastomer offset preventing covering contiguously disposed upon the
peripheral surface of said cylindrical form, said silicone
elastomer having a release value less than 30 dynes/cm and being
substantially free of high surface energy fillers having surface
energies above about 50 dynes/cm and containing heat resistant
fluorinated resin reinforcing filler having a surface energy less
than about 50 dynes/cm in an amount sufficient to reinforce said
silicone elastomer for use as a direct contact fuser blanket.
2. The roll as recited in claim 1 wherein said silicone elastomer
contains 0.1 to 20 weight percent of said fluorinated resin.
3. The roll as recited in claim 1 wherein said fluorinated resin is
polytetrafluoroethylene.
Description
This invention relates to the field of duplication; more
particularly, it relates to the fixing of particulate thermoplastic
toner by direct contact with a silicone elastomer surface while the
toner is in a particular non-solid or fused state.
The process of this invention is particularly useful in fixing of
resinous powder images produced by electrophotography onto receptor
sheets such as sheets of paper. This powder image can be created
through a variety of commercially known methods and in creation is
not a concern of this invention. In general, the powders or toners
for which this invention is directed are heat softenable, such as
is provided by toners which contain thermoplastic resins.
Previous fixing techniques for heat-softenable toner powders
include heating by radiant means such as by coiled wires and heat
lamps, exemplary procedures being described in U.S. Pat. No.
3,432,639; 3,448,970; 3,449,546 and 3,452,181. These methods have
proven inefficient because of the necessity of heating the sheet,
usually paper, to a temperature near charring for prolonged periods
which in some cases causes the paper to burn. This has led to the
development of a fixing technique utilizing a heated surface which
directly contacts the heat softenable resinous toner. Generally
this is accomplished by means of a pair of nip rolls, one a fuser
roll having a peripheral surface which has a low affinity for
melted or softened toner, referred to in the art as abhesive
properties, and a pressure or backup roll usually having a
resilient cover. The fuser roll and/or the pressure roll may be
heated internally to provide heat to soften the thermoplastic
toner. A sheet, usually paper, bearing a thermoplastic powder image
is passed through the nip or contact area of the two
above-mentioned rolls to fix the powder image. Problems are
encountered with the surface materials employed, the foremost being
that as the toner is softened to become sufficiently sticky to
adhere to the sheet some of the particles may stick to the surface
of the fuser roll. This causes a splitting of the image and results
in a partial or ghost image on the next sheet, producing what is
commonly referred to in the duplicating art as an offset image.
The offset image problem has restricted the composition of the
toner contacting surface to certain materials having very high
surface release or abhesive characteristics. This had led to
complex fixing systems such as those using nip rolls which may be
coated with a tetrafluoroethylene resin such as Teflon and a system
for dispensing a silicone oil onto the heated roll. In this
cumbersome arrangement, disclosed in U.S. Pat. No. 3,291,466;
3,331,592; 3,449,548; and 3,452,181, problems are encountered in
the liquid dispensing system when the liquid supply is exhausted or
is dispensed unevenly over the surface of the heated roll,
necessitating machine down time to fill the dispenser or to replace
the applicator before efficient operation can again be realized.
Since the toner contacting surface of this invention operates
without the need for such liquids, the attending problems are
eliminated.
It is therefore an object of this invention to provide a process
and article for rapidly fixing toner images without causing image
splitting or offset images.
This and other objects of the invention are attained in one
embodiment by means of a process for fixing thermoplastic toner
comprising contacting a receptor surface bearing thermoplastic
toner with a silicone elastomer surface for a time and at a
temperature sufficient to permit said contacted toner to exist in a
state wherein the cohesive integrity exceeds the force of adhesion
exerted thereon by said silicone elastomer, and wherein the force
of adhesion between said thermoplastic toner and said receptor
surface exceeds the force of adhesion between said thermoplastic
toner and said silicone elastomer, and separating said receptor
surface and said silicone elastomer surface while said
thermoplastic toner is in said state whereby said thermoplastic
toner is substantially completely retained in fixed position upon
said receptor surface.
FIG. 1 illustrates one embodiment of a silicone elastomer surface
attached to a roll.
FIG. 2 is a sectional diagrammatic illustration of nip rolls
suitable in the practice of this invention.
With reference to FIG. 1, roll 10 is shown with journals 11 for
mounting and a silicone elastomer blanket 13 disposed upon the
cylindrical enlargement 12 which may contain means for providing
heat up to 400.degree. F. to the blanket 13.
FIG. 2 shows a pair of nip rolls 20 and 30 in pressing relationship
creating a nip 31 through which is passing a powdered image bearing
sheet 27. To prevent toner offset onto roll 20 its peripheral
surface is provided with a blanket 23 of silicone elastomer.
Rolls 20 and 30 are conventionally cooperatively rotated to draw
the sheet 27 therebetween. When this combination is used as a toner
fixing or fusing device, either roll 20, roll 30, or both are
heated or heat may be provided by an external device prior to the
arrival of the sheet 27 into the nip 31. As the sheet 27, bearing a
powdered image 28 is drawn into the heated nip 31, the powdered
image 28 is fixed to provide a permanent image 29. Roll 20
conventionally is called a fuser roll in a fixing device wherein
the roll must make direct contact with the toner image, and,
therefore, must be capable of fixing the toner without retaining
fused toner which could cause an offset image on the following
sheet.
Roll 30, the backup or pressure roll, may have a silicone blanket
26 disposed upon the core 25 in certain situations; however, in
operational situations where this roll does not contact the toner
it is not required.
The fixing roll 20 is operated at a surface speed of from 2 to 30
inches per second and at a temperature sufficient to cause the
toner to exist in a fused, non-transfer state. Generally, the
temperature ranges between 220.degree. F. and 400.degree. F.
depending upon surface speed and physical characteristics of the
toner. The time-temperature relationship of the toner in the heated
nip 31 is controlling in bringing the toner to the desired state as
hereinafter explained and thereafter fixing it upon the receptor 27
with no retention upon the silicone elastomer surface 23. Toner
residence time in the heated nip can be controlled in a variety of
ways, e.g., by adjusting roll spaced or nip width, the latter by
varying the nip pressure or deformability of nip materials. These
factors as well as the temperature are varied to provide the proper
time-temperature relationship to achieve the desired state of the
fused toner for non-transfer of the toner, in whole or in part,
during the fixing step.
The fusion of the thermoplastic toner is accomplished according to
this invention by utilization of forces and properties inherent in
the material involved in the process, i.e., silicone elastomer,
thermoplastic toner, and various receptor surfaces upon which the
toner is fixed. When the thermoplastic toner is contacted with the
heated silicone surface certain conditions must prevail to achieve
the desired results of fixing the toner to the receptor surface.
The thermoplastic toner must achieve a gross physical state
(commonly referred to as a rubbery or compliant state) wherein the
toner has a cohesive integrity greater than the force of adhesion
exerted on it by the silicone elastomer surface and the force of
adhesion between the silicone elastomer surface and the toner must
be less than the force of adhesion between the receptor and the
fused toner. The term "gross" as used herein refers to the entire
mass of thermoplastic toner, as opposed to individual particles,
for example.
The silicone elastomers required in the practice of this invention
are formed from the cure or further polymerization of silicone
gums. Silicone elastomers have an abhesive quality which can be
quantitatively described in terms of release value. Release values
are determined on an "Instron," Model TM operating at a crosshead
speed of 12 inches per minute and chart speed of 2 inches per
minute. One-inch Johnson and Johnson "Red Cross" brand waterproof
adhesive tape is used, selecting only a roll having a retention
force of about 450 grams (425-475) as measured at 80.degree. F. on
a 24 gauge, No. 4 finish stainless steel test panel. In determining
either the retention force of the tape to be used or the release
value of a sample, a 10 inch strip of tape is applied to a 6-inch
by 11/2 inch panel by passing a 41/2 pound rubber-faced tape roller
twice over the tape, using only the weight of the roller. The
sample is immediately placed in the Instron and the force in grams
necessary to strip the tape at an angle of 180.degree. is
determined. The amount of force required to strip the tape is
referred to as the "release value," and the larger the release
value, the more adhesion there has been between the adhesive tape
and the surface.
A small release value indicates an effective release coating and a
large release value indicates an ineffective release coating.
Standard tests for release value are described in TAPPI (Technical
Association for the Pulp and Paper Industry), Vol. 43, No. 8, pp.
164A (August, 1960) and TAPPI Routine Control Method "RC-283
Quality of Release Coatings," issued 1960. Many silicone elastomer
surfaces have been found to have a release value of only 1 gm./in.,
and none greater than 30 gm./in. Such materials have been found
satisfactory in the process of this invention. Materials which have
a release value greater than 100 gm./in. will not provide an
adequate toner contacting surface because when contacted and fused,
part of the toner will transfer from the receptor sheet and thus
split the image being fixed. The next sheet to be fused would be
exposed to that toner retainer retained on the elastomer surface
and an offset image would result.
Depending on the curing mechanism to be used, specific silicone
gums are prepared, all having the central, repeating linear unit
##SPC1##
when n may be as small as 2 or as large as 20,000 or more, and
where all R's in the chain may be the same, but need not be, each
individual R being monovalent alkyl or aryl group, halogenated
alkyl or aryl group or cyano alkyl group, with not more than a few
percent of total R being vinyl, phenyl or halogenated vinyl or
phenyl, the major portion of R usually being methyl groups. Where
milling is employed to incorporate the low surface energy filler
into the silicone elastomer, n is a number such that the gum is of
a millable molecular weight. Dimethyl polysiloxanes containing 1 to
4 mol percent of vinyl substituents on the main chain are
preferred. Due to compatibility with Teflon, another preferred gum
is one having methyl and perfluoroalkyl R group.
Silicone elastomers, formed by further polymerizing the gums just
referred to, can be characterized generally as the very sparsely
cross-linked (cured) dimethyl polysiloxane of high molecular
weight, e.g., 100,000 - 1,000,000 average molecular weight. The
sparsity of cross-linking is indicated by R/Si ratios very close to
2, generally above 1.95, or even above 1.99, and generally below
2.1 or even below 2.01, there usually being 200-500 dimethyl units
between cross-link sites. In contrast, the much more densely
cross-linked silicone resins which are considered commercially
useful fall in the range of R/Si ratios of 1.2 - 1.5.
Exemplary millable silicone gums useful in the practice of this
invention are dimethyl polysiloxane sold under the tradename
Silastic 400, polymerized vinyl dimethyl polysiloxane, sold under
the tradename Silastic 430, polymerized vinyl and phenol
polysiloxane, sold under the tradename Silastic 440, polymerized
trifluoropropyl and vinyl dimethyl polysiloxane, sold under the
tradename Silastic LS 420 and the like. The preferred gum is
polymerized vinyl dimethyl polysiloxane sold under the tradename
Silastic 430, but others are equally useful.
Other silicone elastomers can be used in the practice of this
invention. Exemplary of these are moisture curing silicone gums
such as the acetoxy terminated silicone gums and room temperature
vulcanizable silicones such as those cured using catalysts
including dibutyl tin dilaurate, tin octoate and lead octoate.
The type of fillers which may be compounded with the silicone
elastomers is a significant consideration in the present invention.
Fuser copy life or the number of copies fixed before failure of the
fuser blanket is a controlling factor in the choice of a material
or a fuser blanket. Fusers which are capable of fixing many
thousands of copies are desired in the field of duplication. Fusers
which fix over one hundred thousand copies are preferred.
Conventional compositions of silicone elastomers formulated with
high surface energy fillers such as silica, titanium oxide, and
iron oxide have a very short copy life. For example, in a silicone
elastomer fuser blanket having 20 weight percent silica (a high
surface energy filler) only 1,000 copies are fixed before
objectionable offset occurs and the blanket becomes useless.
Silicone elastomers having substantially no reinforcing fillers (at
least less than 1 percent by weight of the silicone elastomer) used
under the same conditions will fix as many as 35,000 copies before
failure occurs from mechanical breakdown of the elastomer. It has
been discovered that the addition of low surface energy reinforcing
fillers which resist thermal degradation at the fixing temperatures
(e.g., 220.degree.- 400.degree. F.) drastically improve the copy
life of silicone elastomer fusing blankets. Silicone elastomer
fusing blankets having low surface energy fillers blended therein,
such as Teflon, under similar operating conditions have been used
to fix in excess of 100,000 copies with no offset or mechanical
breakdown. A surprisingly long copy life is thereby obtained
through the addition of low surface energy fillers.
In general, low surface energy materials are the organic polymers,
which have surface energies of about 50 dynes/cm. or less. The
preferred organic polymers are the fluorinated resins having
surface energies below 30 dynes/cm. Polytetrafluoroethylene,
available under the tradename Teflon, is considered to have a
surface energy of about 18-20 dynes/cm. The conventional fillers
are inorganic materials such as silica iron oxide, titanium
dioxide, etc., which have surface energies above 50 dynes/cm., and
generally above 70 dynes/cm. Surface energies of various materials
are reported by F. M. Fowkes, "Surfaces and Interfaces I - Chemical
and Physical Characteristics," p. 197-223 (1967). In addition to
surface energy requirements, the filler must be able to withstand
the fixing temperatures for prolonged periods, generally
220.degree. F. to 400.degree. F. for at least 50 hours and,
preferably 100 hours or more. Fluorinated resins, particularly
polytetrafluoroethylene, uniquely meet these requirements due to
their release abilities, temperature resistance, and reinforcing
properties when milled into silicone elastomers.
Silicone elastomer filled with high surface energy fillers
initially provides a good fusing blanket. However, as the elastomer
contacts the toner and the receptor sheet upon which it is borne,
abrasion occurs exposing high surface energy sites within the
blanket. Thereafter, fused toner has a tendency to adhere and
accumulate at the exposed high surface energy sites resulting in an
offset image problem. This can be temporarily remedied by cleaning
the toner accumulation from the elastomer surface but cannot be
completely eliminated. The exposure of high surface energy sites in
silicone elastomers filled with high surface energy fillers is
totally unexpected in the silicone elastomer formulation art. It
has been thought that high surface energy fillers would be
completely wet by the silicone elastomer and therefore not present
this problem.
Silicone elastomers substantially free of high surface energy
fillers provide fuser blankets without the above described offset
problem. Silicone elastomers free of fillers provide a fusing
blanket capable of use in a conventional copy machine. However,
this blanket lacks the physical strength required for prolonged
trouble free use which is a prime requisite of a fuser blanket in
copying devices. The preferred blanket is provided by blending low
surface energy fillers such as fluorocarbon resins, preferably
Teflon, into silicone elastomers which are substantially free (less
than 1 percent by weight) of high surface energy fillers. Silicone
elastomers having low surface energy fillers blended therein
provide fusing blankets capable of prolonged use without the
attendant problem of exposure of high surface sites that are seen
in silicone elastomers strengthened with high surface energy
fillers.
Silicone elastomer roll surfaces can be fabricated by a number of
techniques. The desired roll covering should be smooth and of
controlled thickness. The preferred elastomer containing low
surface energy fillers requires milling to blend the fillers
therein and therefore requires millable silicone gums. Milled
compositions are easily shaped into blankets by pressing in a
suitable die.
A suitable method for making the silicone elastomer fusing blanket
involves slowly adding a low surface energy filler to a high
viscosity silicone gum in a high shear mixing device to achieve
intimate blending of the components. The high shear mixing of the
components in the case of Telfon appears to cause the elongation of
particles of Teflon into threads or filaments thereby providing a
fiber structure within the silicone elastomer. In order to achieve
the critical reinforcing effect of the fluorocarbon resins, e.g.,
Teflon, the resins must be thoroughly intermixed such as by milling
into a millable silicone elastomer. The reinforcing properties are
not obtained, for example, by simply mixing the fluorocarbon resin
with a silicone gum without milling and then curing the
mixture.
In the preparation, conventional silicone gum curing agents are
added to the mixture after high shear mixing of the low surface
energy filler and the silicone gum. Exemplary curing agents are
benzoyl peroxide, 2,4-dichlorobenzoyl peroxide, tertiary-butyl
perbenzoate, dicumyl peroxide and other commercially recognized
silicone polymer curing agents. Curing conditions required by these
agents vary somewhat depending upon the curing agent and the
silicone gum. Generally, heat is required to cure the silicone gums
and conventionally temperatures up to 340.degree. F. are used.
Post-curing of the silicone elastomer composition may be required
if it is to be used at high temperatures. Post-curing is
accomplished by heating the elastomer in a forced air oven from 2
to 4 hours or more at temperatures up to 450.degree. F.
The low surface energy fillers preferably are fluorinated or
partially fluorinated organic resins. Exemplary of these are
polytetrafluoroethylene sold under the tradename Teflon, the
copolymer of vinylidene fluoride and hexafluoropropene sold under
the tradename Fluorel, and the terpolymer of vinylidene fluoride,
hexafluoropropene and tetrafluoroethylene, sold under the tradename
Viton B.
The amount of low surface energy filler employed may vary over a
wide range, generally from about 0.1 to about 20.0 weight percent
of the total, preferably from about 0.5 to 5.0 weight percent, and
most preferably about 2.0 weight percent.
Generally, as the content of the low surface energy filler is
increased, the hardness of the composition increases. It is
desirable that there be intimate contact between the silicone
elastomer fixing surface and the substrate bearing toner powder.
Thus, fixing surfaces having a Shore A durometer hardness of less
than 80 are desirable. Hardnesses greater than 80 Shore A durometer
of the composition of a fuser-blanket generally require very high
nip pressures to get satisfactory fixing results; therefore, the
content of low surface energy filler in the preferred composition
is limited by this factor.
A fusing blanket is prepared by placing the silicone elastomer
which has the low surface energy filler and a curing agent blended
therein on a polished die which may be coated with a release
assisting substance. The die is fitted with shims to provide a
blanket of a certain thickness. The loaded die is pressed in a
platen press heated sufficiently to cause the cure of the
elastomer. The resultant sheet is adhesively or mechanically
attached to a fuser roll core to provide a completed fuser roll.
Likewise, the composition can be pressed in a similar die which has
a sheet such as a stainless steel sheet covering the bottom of the
die. The sheet preferably is coated with an adhesive. The resultant
composition bonded to the steel sheet can be mechanically or
adhesively bonded to the roll core.
To attain fixing without offsetting in whole or in part of
thermoplastic toner from the receptor surface to the silicone
elastomer requires that the cohesive integrity of the toner powder
be greater than the force of adhesion exerted thereon by the
silicone elastomer and further that the receptor have a greater
force of adhesion for the toner in the state suitable for fixing
than the silicone elastomer. Exemplary receptor surfaces are paper,
clay, ceramic, glass, plastic, and metals, e.g., aluminum or
stainless steel etc. In general, to accomplish fixing without
offsetting requires that the thermoplastic toner be in a rubbery,
compliant state which may be defined in terms of viscoelastic
properties as the state wherein the fused thermoplastic toner has a
creep modulus (defined as G.sub.(t) = 1/J.sub.(t), where J.sub.(t)
is creep compliance) in the range of between about 10.sup.8
dynes/cm..sup.2 and about 10.sup.4 dynes/cm..sup.2. Under process
operating conditions, the creep modulus of fused thermoplastic
toner is dependent on two parameters -- the temperature of the
fused thermoplastic toner and the time in which two surfaces are in
contact with each other with the fused thermoplastic toner between
the contacting surfaces.
For a given temperature, the range of contact time over which the
fused toner exhibits a modulus within the 10.sup.4 to 10.sup.8
dynes/cm..sup.2 range (generally in what is known as the rubbery
region) depends on the material and on its molecular weight. For
high molecular weight amorphous polymerers the rubbery region is
called the entanglement plateau and it may extend over several
decades of reduced time. Some semi-crystalline materials, low
molecular weight polymers, and other organic compounds may not
exhibit a plateau and thus may be in the rubbery region for a
relatively short period of reduced time. Similarly, for a given
contact time, such fused toner exhibits rubbery response
charac-teristics (generally a modulus of 10.sup.4 to 10.sup.8
dynes/cm..sup.2) over a relatively narrow temperature range.
Suitable toners for the above described process are compositions
containing thermoplastic materials such as those which at
temperatures below 80.degree. C. maintain a dry particulate state
but yet achieve a rubbery or compliant state with a creep modulus
from 10.sup.4 to 10.sup.8 dynes per cm..sup.2 when heated.
Exemplary thermoplastics useful in compounding toner powders are
epoxy resins such as that sold under the tradename Epon 1004,
polystyrene resins sold under the tradename Piccolastic D 125 and D
150. An exemplary toner powder is the following wherein all
percentages are by weight and the average particle size is 7
microns:
44% Epon 1004
52% Magnetite
4% Carbon black.
The powder is made by spray drying this formulation from a solvent
such as chloroform. Another suitable toner powder for the above
described process consists of 65 percent polystyrene and 35 percent
carbon black.
Thermoplastic toner can be prepared by several techniques; for
example, by spray drying an organic solution or emulsion of the
developer material or by an extrusion-grinding process. Particles
can be classified into the desired size range. The particle size
range of the transfer medium generally ranges from 0.5 to 50
microns, preferably between about 2 and about 15 microns for most
applications. However, specific applications may demand lower or
higher size ranges. Generally, spherical particles are preferred.
The powders preferably have a flowability angle of repose ranging
from 80 to 125.degree.. Flowability is measured by feeding a thin
stream of powder to the upper flat surface of a circular pedestal
from a vibrating funnel, thereby creating a conical deposit of
powder on the pedestal. The angle of response is defined by the
angle between the side of the cone and the pedestal at 25.degree.
C.
To better illustrate the invention, the following non-limiting
examples are provided wherein all parts and percentages are by
weight unless otherwise stated.
EXAMPLE 1
A roll was prepared by banding 980 grams of filler free silicone
gum sold under the tradename Silastic 430 on a rubber mill having a
13 inch roll. Twenty grams of powdered polytetrafluoroethylene sold
under the tradename Teflon powder grade 6 (surface energy 19-20
dynes/cm.) was slowly added to the banded silicone gum. The milling
was continued in this matter for about 15 minutes to blend the
components. Thereafter the mixture was transferred to a Banbury
high shear mixer and therein worked for 15 minutes at a temperature
of 250-290.degree. F. This mixture was then allowed to cool and
returned to the rubber mill. Fifteen grams of benzoyl peroxide in
an equal weight of silicone gum paste was blended into the mixture
on the rubber mill. After 15 minutes of blending, the mixture was
placed on a 5 mil by 10 inch by 18 inch stainless steel sheet which
had previously been primed with Dow Corning silicone rubber primer
2260 to promote adhesion of the silicone elastomer to the sheet.
The sheet was shimmed to give a final blanket thickness of 0.020
inch and pressed in a platen press at a pressure of 100 tons for 10
minutes at 260.degree. F. The blanket was then post cured for 4
hours at 400.degree. F. in a forced air oven and after cooling,
adhesively bonded to the 6 inch diameter by 12 inch long fuser roll
of an experimental copy machine. The roll had an internal heating
element which maintained the blanket surface temperature at
325.degree. F.
Powdered images were deposited on bond paper according to the
electrographic process described in French Pat. No. 1,456,993 with
a toner consisting of 60 percent magnetite and 40 percent epoxy
resin (tradename Epon 1004) which had been spheroidized with carbon
on the outside. Thereafter, each sheet was passed in turn through
the nip created by the above described fuser roll which was in
contact with a pressure roll at a nip load pressure of 25 to 50 psi
which created a nip width of one-half inch with the pressure roll.
The fuser roll was rotated counterclockwise at a surface speed of
16 inches per second and thusly was used to successfully fix in
excess of 100,000 powdered image copies.
EXAMPLES 2-4
Fusing blankets were prepared and evaluated according to the
methods described in Example 1 using silicone elastomer Silastic
430 with variations only in the content of fillers. Both high
surface energy and low surface energy filler containing
compositions were prepared and the results of their evaluation are
tabulated below with those of Example 1.
Example Weight Percent No. Filler Surface Energy Copies made Reason
for High.sup.a Low.sup.b Before failure failure 1 0 2.0 100,000 No
failure-- end test 2 0 0 35,000 Rubber failure 3 24.7 0 1,000
Objectionable offset 4 20.0 1.95 15,000 Do. .sup.a Silica .sup.b
Teflon
* * * * *