U.S. patent number 3,794,034 [Application Number 05/336,270] was granted by the patent office on 1974-02-26 for odor reductant body waste pad.
Invention is credited to John Leslie Jones, Sr..
United States Patent |
3,794,034 |
Jones, Sr. |
February 26, 1974 |
ODOR REDUCTANT BODY WASTE PAD
Abstract
A substantial proportion or all of the total thickness of an
unused single use, disposable body waste fluid absorbent pad, such
as a sanitary napkin and a baby diaper, combines a water soluble,
weakly acidic buffered solid composition having a pH range of 3.5
to 6.0, with a waste fluid absorbent pad. The absorbent pad of wood
pulp is impregnated with a dry buffered non-hygroscopic, non-toxic,
solid, acid composition having an aqueous pH range of 3.5 to 6.0.
The wood pulp pad structure density can range from the macerated
loose random fiber of typical density 1.5-2.5 lbs/cu. ft. of the
commonly sold commercial fluffed wood pulp absorbent pad sanitary
menstrual napkins, to that of a 9-10 pound weight absorbent tissue
paper sheet typically embodied in the menstrual napkin of the U.S.
Pat. No. 3,532,097, issued Oct. 6, 1970. The controlled acid pH of
the buffered absorbent pad, when the pad is wet with body waste
fluids, e.g., menstrual fluids or urine of infants, inhibits the
rapid formation of free ammonia gas and volatile amine compounds
from urea, uric acid, amino acids and peptones by bacterial and
enzyme action, and forms nonvolatile salts of the basic compounds.
The buffered pH range is not irritating to the user's skin.
Inventors: |
Jones, Sr.; John Leslie
(Pasadena, CA) |
Family
ID: |
23315333 |
Appl.
No.: |
05/336,270 |
Filed: |
February 27, 1973 |
Related U.S. Patent Documents
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Application
Number |
Filing Date |
Patent Number |
Issue Date |
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131884 |
Apr 7, 1971 |
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Current U.S.
Class: |
604/360;
604/375 |
Current CPC
Class: |
A61F
13/15211 (20130101); A61L 15/46 (20130101); A61F
13/539 (20130101); A61F 2013/5694 (20130101); A61F
13/534 (20130101); A61F 13/537 (20130101); A61L
2300/404 (20130101); A61F 2013/53782 (20130101); A61F
2013/53908 (20130101); A61F 2013/8411 (20130101); A61F
2013/530131 (20130101); A61L 2300/21 (20130101); A61F
2013/53445 (20130101); A61F 13/511 (20130101); A61F
13/64 (20130101) |
Current International
Class: |
A61F
13/15 (20060101); A61L 15/16 (20060101); A61L
15/46 (20060101); A61F 13/56 (20060101); A61f
013/16 () |
Field of
Search: |
;128/284,287,290,296,270,285 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Rosenbaum; Charles F.
Attorney, Agent or Firm: Jones, Sr.; J. L.
Parent Case Text
This application is a continuation of Ser. No. 131,884 filed Apr.
7, 1971 and now abandoned.
Claims
I claim:
1. A single use, disposable, human body waste fluid absorbent pad
combination comprising:
a waste fluid absorbent pad having cellulose fibers disposed
therein, and adapted in size and shape to being externally worn on
the human body and to receiving excreted human body waste fluid;
and,
a nontoxic, nonvolatile, water soluble, weakly acidic, dry solid
buffer composition selected from the solid acids and lithium,
sodium, potassium salts of citric, tartaric, gluconic, glutaric,
levulinic, glycolic, succinic, malic, fumaric, and phosphoric
acids, said buffer composition having an aqueous pH range of 3.5 to
6.0, said buffer composition impregnantly disposed in said
cellulose fibers disposed in said absorbent pad in a buffer
composition concentration adapted to form salts of all the volatile
chemically basic waste fluid excreta products absorbently disposed
in said cellulose fibers during use.
2. A single use, disposable, human body waste fluid absorbent pad
combination comprising:
a waste fluid absorbent pad having cellulose fibers disposed
therein, and adapted in size and shape to being externally worn on
the human body and to receiving excreted human body waste fluid;
and,
a nontoxic, nonvolatile, water soluble, weakly acidic, dry solid
buffer composition selected from the solid acids and solid lithium,
sodium and potassium salts of citric, tartaric glycolic, succinic,
fumaric, malic acids, and phosphoric acids, said buffer composition
having an aqueous pH range of 3.5 to 6.0, said buffer composition
impregnantly disposed in said cellulose fibers disposed in said
absorbent pad in a buffer composition concentration adapted to form
salts of all the volatile chemically basic waste fluid excreta
products absorbently disposed in said cellulose fibers during
use.
3. A single use, disposable human body waste fluid absorbent pad
combination comprising:
a waste fluid absorbent pad having cellulose fibers disposed
therein, and adapted in size and shape to external wear on the
human body and to receiving excreted human body waste fluid;
and,
a nontoxic, nonvolatile, water soluble, weakly acidic, dry solid
buffer composition selected from the dry, solid compositions of the
acids and lithium, sodium and potassium salts of citric, tartaric,
gluconic, glutaric, levulinic, glycolic, succinic, malic, fumaric
and phosphoric acids, said buffer composition having an aqueous pH
range of 3.5 to 6.0, said buffer composition uniformly impregnantly
disposed in said cellulose fibers disposed in said pad and adapted
to receive said waste fluid, the concentration of said buffer
composition adapted to form non-volatile salts of all the volatile
chemically basic waste fluid excreta products disposed on said pad
fibers.
4. A single use, disposable human body waste fluid absorbent pad
comprising:
a waste fluid absorbent pad having cellulose fibers disposed
therein, and adapted in size and shape to external wear on the
human body and to receive human body waste fluid excreted on one
face of the fiber pad; and,
a nontoxic, nonvolatile, water soluble, weakly acidic, dry, solid
buffer composition selected from the solid acids and lithium,
sodium and potassium salts of citric, tartaric, glycolic, succinic,
fumaric, malic acids, and phosphoric acids, said buffer composition
having an aqueous pH range of 3.5 to 6.0, said buffer composition
uniformly inpregnantly disposed in said cellulose fibers disposed
in said pad and adapted to receive said waste fluid, the
concentration of said buffer composition adapted to form
nonvolatile salts of all the volatile chemically basic waste fluid
excreta products disposed on said pad fibers.
5. A single use, disposable, human body waste fluid absorbent pad
comprising:
a waste fluid absorbent pad having cellulose fibers disposed
therein and adapted in size and shape to being externally worn on
the human body and to receiving excreted human body waste fluid;
and
a nontoxic, nonvolatile, water soluble, weakly acidic, dry solid
buffer composition, having an aqueous pH range of 3.5 to 6.0,
uniformly impregnantly disposed in said cellulose fibers disposed
in said absorbent pad in a composite buffer concentration adapted
to form salts of all the volatile chemically basic waste fluid
excreta products absorbently disposed in said cellulose fibers
during use.
6. In the product of claim 5, the modification wherein said waste
fluid absorbent pad having cellulose fibers disposed therein is a
menstrual waste fluid sanitary napkin pad adapted to external body
wear.
7. In the product of claim 5, the modification wherein said waste
fluid absorbent pad having cellulose fibers disposed therein is a
baby diaper waste fluid absorbent pad adapted to external body
wear.
8. In the product of claim 5, the modification wherein said
buffered, dry solid composition is uniformly concentrated in said
cellulose fibers disposed in the structure of said waste fluid
absorbent pad.
9. A single use, disposable human body waste fluid absorbent pad
comprising:
a waste fluid absorbent pad having cellulose fibers disposed
therein, and adapted in size and shape to external wear on the
human body and to receive excreted human body waste fluid on one
face of the fiber pad; and
a nontoxic, nonvolatile, water soluble, weakly acidic, dry, solid
buffer composition, having an aqueous pH range of 3.5 to 6.0,
impregnantly disposed in said cellulose fibers disposed in the pad
face to be worn adjacent to said human body, the concentration of
said buffer composition adapted to form nonvolatile salts of all
the volatile chemically basic waste fluid excreta products disposed
on said pad fibers.
10. In the product of claim 9, the modification wherein said waste
fluid absorbent pad having cellulose fibers disposed therein is a
menstrual sanitary napkin pad and adapted to external body
wear.
11. In the product of claim 9, the modification wherein said waste
fluid absorbent pad having cellulose fibers disposed therein is a
baby diaper absorbent pad adapted to external body wear.
Description
BACKGROUND OF THE INVENTION
It is well known that some menstruating females emit odorous
menstrual fluids. Emitted fluids can also rapidly form odorous
products on further proteolytic reaction. It is established that
some of the most perceptible odors are due to chemically basic
amine type compounds, which are volatile. The characteristic amine
type odors are embarrassing to menstruating females.
The urine impregnated diapers of infants are well known for having
and developing an ammonical odor on storage. The widespread use of
single use, disposable baby diapers is restricted by the persistent
ammonical odor of the discarded, used diapers, prior to their final
disposal outside the baby's household. In addition, the ammonical
urine products can induce a common rash on the baby's torso, due to
the alkaline pH of the urine in persistent contact with the baby's
skin.
My buffered acid pH body waste odor prevention pad can inhibit the
formation of embarrassing odors by absorbing any free ammonia and
amines present in freshly excreted body waste fluids; and also by
further inhibiting the rapid formation of ammonia and volatile
amine compounds from urea, uric acid, amino acids and the like by
bacterial and enzyme action in the waste fluids.
SUMMARY OF THE INVENTION
A substantial portion or all of the total thickness of a single
use, disposable body waste fluid absorbent pad, such as a menstrual
sanitary napkin or a baby diaper, has a water soluble, weakly
acidic, buffered solid composition having an aqueous pH range of
3.5 to 6.0 disposed in the dry reservoir absorbent pad of the
napkin and the diaper. The dry, buffered pH reservoir absorbent pad
is formed of wood pulp impregnated with a dry, buffered, non-toxic,
non-hygroscopic, solid acid composition having a typical pH range
of 3.5 to 6.0. The bleached wood pulp pad structure can range from
macerated, loose random fiber of typical density 1.5-2.5 lb/cu ft
of the commonly sold commercial fluffed wood pulp absorbent pad in
sanitary menstrual napkins, to that of a 9-10 pound weight
absorbent tissue paper sheet embodied in the menstrual mapkin of
the U.S. Pat. No. 3,532,097 issued Oct. 6, 1970, and also in the
diaper pad of U.S. Ser. No. 63,749, filed Aug. 14, 1970. The
controlled pH range of the buffered pad inhibits the rapid
formation of ammonia and volatile amines from the urea, uric acid,
amino acids and peptones in the body waste fluids, by bacterial and
enzyme action.
The acidic buffers composition also neutralizes and converts to a
relatively nonvolatile, nonodorous salt any ammonia or amine which
is initially present in the freshly excreted waste fluids or which
is formed later by bacterial or enzyme action. The buffered pH of
the pad is in the acidic range which is not irritating to the
skin.
Included in the objects of this invention are:
To provide a body waste fluid absorbent pad having a dry, solid
buffered weakly acidic chemical reservoir composition suitable for
inhibiting the formation of ammonia and volatile amine odors from
the absorbed waste fluids, and also for neutralizing any basic
compounds in the freshly excreted waste fluids.
To provide a dry, body waste fluid absorbent pad having a buffered
pH reservoir composition capable of absorbing ammonia and amines
contained in waste fluids absorbed on a pad.
To provide a dry, nontoxic, acidic pH reservoir pad, buffered to a
pH range of 3.5 to 6.0, and suitable for use in body waste fluid
absorbent pads, and which will not irritate the body skin.
To provide a dry body waste fluid absorbent pad suitable for
neutralizing and forming non-volatile salts of ammonia and amines
and other basic chemical compounds present in the body waste fluids
absorbed on the pad.
Further objects and advantages of this invention will become
apparent in the following description, to be read in conjunction
with the following drawing.
BRIEF DESCRIPTION OF THE DRAWING
FIG. 1 is a perspective partial sectional view of a menstrual
sanitary napkin containing a buffered acidic pH absorbent pad of
this invention.
FIG. 2 is a perspective partial elevational view of another
menstrual napkin modification, further illustrating the position of
a buffered acidic pH absorbent pad.
FIG. 3 is a perspective view of a disposable single use baby diaper
having a buffered acidic pH absorbent pad.
FIG. 4 is a sectional view through 4--4 of FIG. 3, further
illustrating the placement of the buffered, acidic pH absorbent
diaper pad of this invention.
DESCRIPTION OF THE PREFERRED EMBODIMENT
It is well known that menstruating females can emit odors that are
embarrassing to them. The odors can arise as the result of
proteolytic decomposition of blood and tissue waste in menstrual
fluids, which are further decomposed into products which yield
ammonia and volatile amine compounds. The odors of the ammonia and
amines are socially unpleasant. Likewise, mothers object to the
odor of ammonia in the urine impregnated, single use, disposable
infant diaper after they are removed from the infant, and before
the diapers are removed from the household.
The waste menstrual fluid and baby urine have a common problem of
odor generation. Waste fluid odor generation can be reduced and can
be inhibited by preventing bacterial and enzymatic decomposition in
the waste products. The urea, creatinine, uric acid in urine are
further converted into volatile ammonia in a wet diaper, due to
bacterial and enzymatic action. Likewise, the proteins, amino
acids, urea and nitrogen containing tissue excreta in menstrual
fluids, are converted by proteolytic and enzymatic action into
simpler molecules, including some volatile ammonia and amines. The
relatively high temperature of the sanitary napkin in use next to
the body skin further promotes the microbial incubation process,
and the rapid rate of these proteolytic and enzymatic
processes.
I have found that the biological conversion processes which lead to
the common problem of amine and ammonia formation in these body
waste fluids absorbent pads can be inhibited by controlling the pH
of the absorbent pads receiving these wastes. By controlling the pH
of the absorbent pad structure material to provide a buffered
acidic reservoir of pH range 3.5 to 6.0, the formation of
substantial amounts of free volatile ammonia and amine compounds is
prevented. The buffered pH acidic reservoir functions two-fold.
First, it inhibits bacterial growth in the proteolytic degradation
of the excretory products, since bacterial growth rate is generally
decreased in acid media. Secondly, the the ammonia and amines that
form, or which are initially excreted in the waste fluids, are
immediately neutralized by the buffer composition, forming
nonvolatile salts. The pH of the buffering composition is
controlled over a range compatible with the normal human skin.
Human urine normally ranges from pH 5.5-6.5, becoming alkaline or
near alkaline after meals. The skin of newborn babies (seven days
old) has a pH less than 5.0 (Behrendt and Green The measurement of
Anderson (Brit. J. Derm., 63, 283-96) and Martin Beare et al (Brit.
J. Derm., 70, 233-41) both show that the skin of normal children is
acidic. According to Martin Beare et al, normal children less than
three years of age have skin pH values ranging from 5.86 to 6.78.
Significantly, the higher pH value of 6.78 was in the perianal area
which can be contaminated at that age with traces of urine and
feces. The other skin areas of the body were significantly more
acidic. Anderson's pH measurements of other skin areas of young
children were significantly more acidic, ranging from pH 4.87 to
5.53. The skin of adult females was found to have an average pH of
5.50 by Draize (J. Invest. Derm., 77-85). Thus an acidic pH range
of 4.5 to 6 is typically normal for the skin of babies or
females.
This invention teaches body waste fluid pads impregnated with
nontoxic, water soluble, weakly acidic buffered, dry, solid,
acid-salt compositions having a buffered pH range of 3.5 to 6.0,
when wet with an aqueous body waste fluid. The waste fluids, urine
and menstrual fluid, impregnating the pad will be incubated at
substantially body temperature while secured on the person, or at
room temperature while awaiting final disposal in the household.
The buffered acidic pH of the waste fluid while incubating in the
impregnated pad will inhibit the bacterial and enzymatic process
leading to formation of the volatile ammonia and amine odors, since
acidic pH media generally inhibit bacterial growth processes.
Some of the nontoxic, food type, solid, weak acids useful in the
buffered pH compositions of this invention are citric, tartaric,
gluconic, glutaric, levulinic, glycolic, succinic, malic, fumaric,
and acid phosphate salts. Other similar nontoxic solid, weak acids
can be used. Preferably, the buffered acid compositions should not
be hygroscopic or deliquescent. The preferred weak acids useful in
the buffered compositions should not be the typical short chain
aliphatic acids such as acetic or butyric, due to their being
liquids, and their volatility and odor. Likewise, the long chain
fatty acids such as myristic, palmitic and stearic acids form
undesirable surfactant salts or soaps. Obviously toxic acids, such
as boric and oxalic, are undesirable.
The buffered acid compositions can typically be simply formed by
adding Na OH or Na.sub.2 CO.sub. 3 solutions to the concentration
of pure acid solutions in amounts to provide a desired buffered
acid solution in the range of pH = 4.5 to 6.0. The lower pH values
will provide a greater buffering capacity for the absorbent
pad.
The buffered acid compositions can be uniformly dispersed in the
absorbent wood pulp, either in the random macerated wet or dry wood
pulp form, or on the thin (9-10 lb) absorbent tissue as it is being
sheeted out and dried on the paper forming machine. The wood pulp
stock can be bleached white stock, for either the macerated pulp or
the tissue sheet. The buffered composition can be added to the pulp
base for the macerated pulp, as a desired aqueous concentration of
the buffered solution. The solution is sprayed on the pulp as it is
sheeted into the relatively thick, non-calendared, pulp sheet,
which is dried to a sheet stock suitable for storage, and then
disintegrated into macerated pulp for absorbent pads.
The buffered composition solution can also be sprayed on the wet
tissue stock sheet as it is made on the paper sheeting machine,
just prior to final drying of the tissue paper stock. Thus, the dry
macerated pulp composition, having a buffered, dry, solid,
non-toxic water soluble composition impregnated therein, is
suitable for use in absorbent pads for sanitary napkins and
diapers. The absorbent pad can also be a menstrual napkin comprised
of multiple ply of absorbent tissue sheet stock, as U.S. Pat. No.
3,532,097 and the pending U.S. patent application on diaper pads,
Ser. No. 63,749, filed Aug. 14, 1970. In either the macerated wood
pulp or the tissue sheet absorbent pad construction, the desired
concentration of dry, solid acidic composition can be achieved.
Dry, solid, acidic buffer compositions of sodium citrate and citric
acid have been uniformly dispersed in bleached white macerated pulp
and bleached white, absorbent tissue paper stock. Typically, 2 wt.
percent of a dry citric acid-potassium citrate buffer composition,
having an aqueous pH value of 4.0 as a 10 wt. percent solution, was
separately sprayed on macerated paper pulp and on 10 lb. weight
tissue paper, and dried. The dried buffered paper stock was formed
into diapers and napkins in accordance with the earlier reference
teachings on diaper and napkin construction.
Blind use tests of both diapers and napkins utilizing the above
modified paper stock were made. The female napkin users and the
infants' caretakers were unaware of the diaper and napkin
modification employed in the respective use tests.
Female napkin users were supplied with buffered napkin
modifications and also identical appearing napkins which were not
buffered modifications. The napkins supplied to users were numbered
in a code unknown to the users, indicating the buffered and
non-buffered modifications. The users were asked to indicate the
odorous and non-odorous napkins, immediately after the napkin's use
and also after incubating the napkin for 24 hours at room
temperature in a plastic envelope. Typically, the napkins
identified by the user after both time intervals as non-odorous, or
less odorous, was the buffered napkin, having the buffer pH
controlled composition impregnantly disposed therein.
Likewise, the infant caretakers were asked to indicate the odorous
and non-odorous diapers, also supplied as coded buffered and
non-buffered modifications. The diapers were examined for odor
immediately after use and also after incubating at room
temperature, when infant feces did not interfere with the odor
test. Typically, the caretaker correctly identified the
non-odorous, or less odorous, diapers as the buffered diaper,
having the buffer pH controlled composition impregnantly disposed
in the diapers.
Typically, the diaper's absorbent pad can be impregnated pregnated
with 1. wt percent of a buffer composition, such as NaH.sub.2
PO.sub.4 having an aqueous pH value of 4.1 to 4.5 in a 5 percent
aqueous solution. Likewise, sodium dihydrogen phosphate (NaH.sub.2
PO.sub.4) is a suitable buffer composition for for sanitary napkin
modifications of this invention.
It is desirable to optimize the concentration of dry, solid acidic
buffer composition in the absorbent pad at the lowest concentration
value consistent with minimum ammonia and amine odor concentration
during the absorbent pad use. The minimum optimal buffer
concentration is desirable to provide a low raw material cost,
adapting this invention to widespread use. In addition, the low
buffer concentration minimizes any potential skin irritation
effects. It should be noted that well known and widely used food
acids are the preferred acids of choice in the buffer compositions,
reducing the toxicity problem to nil.
Referring to FIG. 1 in detail, the menstrual napkin 1 has a
menstrual fluid absorptive section 2 and a pair of straps 3 and 4,
as disclosed in my copending patent application filed as of this
date titled INTEGRAL STRAP TISSUE NAPKIN. The multiple reservoir
apertures 5 receive menstrual fluid flow. The adhesive plug
securing means 6,6 and 7,7 bond the multiple ply tissue paper
sheets of the napkin together. The absorptive section 2 has a total
thickness 8, comprising the primary absorptive section thickness 9
and the secondary absorptive section thickness 10. All or a
fraction of the total absorptive section thickness 8 comprises
multiple ply of tissue paper sheets having the nontoxic, water
soluble, weakly acidic, buffered, dry solid composition, having an
aqueous pH of 3.5 to 6.0 impregnantly disposed therein. Preferably
the buffer impregnated tissue sheets are disposed at least adjacent
the surface of the sanitary napkin which first receives the
menstrual fluid excreta, as are required to minimize odor.
Referring to the conventional menstrual napkin 20 in FIG. 2, the
shaping cover sheet 21, of open gauze or scrim, forms the front
strap 23 and the rear strap 22. The partial sectional view
discloses the total absorptive section thickness 26 has partial
absorptive section thicknesses 24 and 25. The absorptive section
thickness 24, which is to be disposed so as to directly receive the
menstrual fluid excreta, has the buffered, dry solid composition,
whose pH range is 3.5 to 6.0, impregnantly disposed therein.
Likewise a portion of the section thickness 25, or all of 25 may
also be impregnated with the buffer composition as required to
reduce the excreta odor. The relative value of thicknesses 24 and
25 are those values which are required.
Referring to FIGS. 3 and 4 in detail, the infant diaper 30, has the
overlying plastic membrane margins 31 and 32, formed by
overwrapping and sealing the thin plastic membrane sheet 33 on to
the edge margins of absorptive pad 34. The enlarged partial
sectional view of FIG. 4 illustrates the porous cover sheet 35,
which is disposed directly adjacent the infant in diaper use. The
relative thickness values of absorptive sections 36 and 37 can be
adapted to provide maximum reduction of ammonia and amine odor, by
adjusting the thickness of buffer impregnated absorptive section 36
to the required value. Section 36 can range up to 100 percent of
the total absorptive pad thickness 38, thus decreasing section 37
to zero percent.
Other odor reductant body waste pad variations can be made without
departing from the scope of this invention. Many modifications and
variations of my improvements in an odor reductant waste pad can be
made in light of my teachings. It is therefore understood that
within the scope of the appended claims, the invention may be
practiced otherwise than as specifically described.
* * * * *