U.S. patent number 3,791,864 [Application Number 05/196,171] was granted by the patent office on 1974-02-12 for method of ornamenting articles by means of magnetically oriented particles.
This patent grant is currently assigned to Magnetfabrik Bonn G.m.b.H., Weilburger Lackfabrik J. Grebe. Invention is credited to Erich Steingroever.
United States Patent |
3,791,864 |
Steingroever |
February 12, 1974 |
METHOD OF ORNAMENTING ARTICLES BY MEANS OF MAGNETICALLY ORIENTED
PARTICLES
Abstract
A patterned effect can be produced in coatings applied to any
surface by employing a preliminary coating which includes a liquid
vehicle in which permanent magnet particles are suspended; the
coating being applied and then hardened, after which the particles
are magnetized under the influence of magnetic lines of force
arranged in a predetermined pattern, and another coating containing
magnetically orientable particles is applied, which particles
become oriented by the magnetic field product by the particles
first applied.
Inventors: |
Steingroever; Erich (Bonn,
DT) |
Assignee: |
Magnetfabrik Bonn G.m.b.H.
(Bonn/Bad Goldesberg, DT)
Weilburger Lackfabrik J. Grebe (Weilburg/Lahn,
DT)
|
Family
ID: |
5787506 |
Appl.
No.: |
05/196,171 |
Filed: |
November 5, 1971 |
Foreign Application Priority Data
Current U.S.
Class: |
427/550 |
Current CPC
Class: |
B44C
1/00 (20130101); B05D 3/20 (20130101); H01F
41/16 (20130101); H01F 7/0247 (20130101); H01F
13/003 (20130101); B05D 5/061 (20130101); B05D
7/54 (20130101) |
Current International
Class: |
B44C
1/00 (20060101); H01F 13/00 (20060101); H01F
7/02 (20060101); H01F 41/14 (20060101); B05D
3/14 (20060101); B05D 5/06 (20060101); H01F
41/16 (20060101); H01f 010/00 () |
Field of
Search: |
;117/234-240
;252/62.54 |
References Cited
[Referenced By]
U.S. Patent Documents
Primary Examiner: Martin; William D.
Assistant Examiner: Pianalto; Bernard D.
Attorney, Agent or Firm: Christen; Arnold B.
Claims
I claim:
1. Method of producing a pattern in a coating applied to the
surface of an object, comprising the steps of combining permanent
magnetic ferrite particles having a coercivity H.sub.c greater than
2,000 oersted in a fluid binder, applying said mixture of fluid
binder and particles to the surface of an object, hardening said
mixture to secure said magnetic particles to said object,
magnetizing said magnetic particles to define a predetermined
pattern, applying a fluid coating which includes magnetically
orientable particles, and hardening the second coating so that the
magnetically orientable particles adopt the pattern defined by the
previously applied magnetic particles.
2. Method of claim 1, wherein said magnetically orientable
particles comprise lamellar iron.
3. Method of claim 1, wherein said binder is combined with
magnetizable permanent magnetic particles having high coercivity
and consisting of a ferrite of the type MO.sup.. 6Fe.sub.2 O.sub.3,
wherein M is at least one of the elements Ba, Sr, Ca and Pb.
4. Method of claim 1, wherein said magnetically orientable
particles comprise rod-shaped iron.
5. Method of claim 1, wherein said binder comprises a primer.
6. Method of claim 1, wherein said second coating produces a
lustrous finish.
7. Method of claim 1, which includes the step of applying at least
one intermediate coating after said binder and prior to the
application of the coating including magnetically orientable
particles.
8. Method of claim 1, wherein said magnetically orientable
particles comprise powdered iron.
9. Method of claim 7, wherein said intermediate coating produces a
lustrous finish.
10. Method of claim 7, wherein said intermediate coating comprises
a synthetic plastic.
11. Method of claim 1, wherein said object comprises a steel
plate.
12. Method of claim 1, which includes the step of subjecting said
magnetic particles to the influence of magnetic lines of force to
define said pattern.
13. Method of claim 12, which includes the step of utilizing a
permanent magnet to supply said magnetic lines of force.
14. Method of claim 12, which includes the step of utilizing an
electromagnet to supply said magnetic lines of force.
Description
The present invention relates to a method for producing a pattern
on surfaces by applying a coating thereto, which contains
magnetically orientable particles, and creating a pattern in this
coating by means of magnetic fields.
It is already known to create nacre-like effects in plastic
materials by admixing thereto lamellate or rod-shaped crystals with
a high index of refraction. A known method of positioning the
crystals in a desired way within the plastic material, for instance
parallel to the surface of the object, consists in orienting the
crystals by means of an electric or magnetic field. The basic idea
of this method is derived from the fact that these crystals
naturally possess a dipole moment of force, or else that such a
moment of force can be induced in them under the effect of a
magnetic field. Under the effect of such a field the crystals
orient themselves parallel to the lines of flux. For example, a
known process for manufacturing an abrasive utilizes this
method.
Further, a method for producing transparent plastic materials is
known, which can be used to manufacture objects or panels
commercially in large amounts. According to this method,
polytetrafluorethylene dispersions are used to manufacture
decorated transparent plastic materials by admixing preferably
lamellate particles with the plastic material, varying the
positions of the particles by means of a magnetic field and
subsequently drying the mixture.
Up to the present, however, there has always been the desire to
also provide opaque objects with finishes having particular
patterns, which could not be achieved with the methods hitherto
known in the coating industry. Therefore, a method has been
proposed for producing a pattern during the coating of surfaces,
according to which a finish containing magnetic components is
applied, under the effect of magnetic fields, onto the surfaces to
be coated. For this purpose, the objects are placed on devices
which product magnetic fields in accordance with the desired
patterns. The lines of magnetic flux act through the surface to be
coated and extend in arcuate paths from the north pole to the south
pole, as is well known. The surface is then covered with a coating
containing magnetic components. These magnetic particles orient
themselves in the still unhardened coating according to the lines
of magnetic flux. After hardening, the coating displays the desired
pattern which reproduces the magnetic pattern used by virtue of
differences in brightness and reflectivity.
Further, it has been proposed to create the patterns in a similar
way in panels of ceramic material, enamel, pigment solutions with
or without binders, pastes, varnishes, lacquers, and synthetic
resins, etc. either colored or uncolored. For instance, according
to this method, the powdery or pasty ceramic material is exposed to
the effect of magnetic fields, then melted, and finally
hardened.
According to the known and proposed methods the corresponding
arrangement of the magnets, in front or in back of the respective
surface to be coated or to be provided with the color patterns, has
to be maintained during the whole coating and hardening process, to
permit the lines of magnetic flux to act upon the still movable
magnetically orientable particles in the coating. Further, if the
magnets are arranged, according to both the known and proposed
processes, above the recently coated, but unhardened, layer, there
is the danger that the magnetically orientable particles will be
drawn out of the coating if the magnetic fields are too strong.
Moreover, the known methods are very time-consuming since the
hardening of the coating has to be completed while the magnetic
particles disposed therein are fixedly oriented.
The object of the present invention is therefore to provide a
method which permits the application of patterns on surface
coatings in any paint shop without requiring magnet arrangements
from the outside.
This object can be accomplished, according to the invention, by
applying a primer or other preliminary coating containing permanent
magnetic particles to the desired surface, hardening said primer
and magnetizing it according to the desired pattern, after which a
liquid coating containing magnetically orientable particles can be
applied to said primer and be hardened. The new method according to
the invention offers the advantageous possibility that the
untreated objects whose surfaces normally require a primer anyway,
can be supplied to the industry, for their subsequent treatment,
already provided with this layer of primer. Thus, only the desired
finish coating needs to be applied in the usual manner, and the
desired pattern automatically appears. The new method can further
be advantageously applied to thick objects which cannot be
magnetically influenced from the opposite side, generally the
bottom side, such as for example thick steel plates and
brickwork.
According to the invention the primer or first coating preferably
contains magnetizable permanent magnetic particles with high
coercivity and consisting of ferrite of the type MO
.times.6Fe.sub.2 O.sub.3, wherein M can be one or more of the
elements Ba, Sr, Ca or Pb. The fluid coating containing the
magnetically orientable particles can have a composition as
disclosed in the German patent application No. P 20 06 848.8. A
baking or vulcanizing or other form of hardening step can also be
used instead of the above mentioned drying step.
The originally unmagnetized permanent magnetic particles are added
to a conventional liquid vehicle, wuch as a primer and the mixture
is applied to the surface. Whilst the particles are still movable
in the primer which has not yet hardened, or even after the
particles are already fixed due to the drying of the primer, the
desired magnet arrangement, or a magnetization device having a
similar effect, is applied to the surface, either at the front or
at the back of it. The particles become magnetized and, as the
result of their high coercivity, produce a magnetic field which
corresponds to the magnet arrangement.
Generally, the primer consists of a pigmented layer in which the
permanent magnetic particles are not visible. A plate or object
which has been pre-treated in this way can thus be marketed. For
example, the manufacturer can sell this object together with
coatings containing magnetically orientable particles.
A particular feature of the invention consists in that the finish
coating containing the magnetically orientable particles may either
be directly applied to the primer or to further intermediate layers
of varnish, plastic, resin or similar materials to said primer,
since the lines of magnetic flux will act through these layers. The
time required for the magnetization can be considerably reduced by
this new method, since the magnetization of the primer can be
carried out in its dry condition, thus only requiring a fraction of
a second. It is also possible to obtain particular patterns by
applying the magnet several times, and in different directions, to
the primer, without having to take into consideration the hardening
time, since the primer is already hard and dry. The whole working
cycle becomes more flexible, since the step of applying the primer,
of magnetizing it and of applying the coating containing the
magnetically orientable particles can be carried out completely
independent from each other. The product of the first and second
steps can be stored in large quantities, in order to be furnished
to the second or third step, respectively, according to the
demand.
According to the invention the magnetically orientable particles
preferably consist of powdery lamellate or rod-shaped iron and the
object or the surface to be treated may consist of a ferromagnetic
base, particularly a steel plate. However, the new method is
independent of the thickness of the steel plate and is also
effective on wood, plastic, ceramics and similar materials.
A particularly suitable device to carry out the method of the
invention to magnetize the permanent magnetic particles of the
primer layer comprises an electric conductor which is shaped
according to the desired magnetic field, which can be applied to
the primer and through which a high electric current is sent. This
can preferably be achieved by the use of a conventional circuit
which utilizes the discharge from a condenser. Further, apparatus
to carry out the method of the invention is characterized in that
the electric conductor is insulated and is imbedded in recesses
provided in the surface of an iron terminal.
According to a particular feature of the invention the permanent
magnetic particles are made of a material having a (B.sup..
H).sub.max value of 1-4.sup.. 10.sup.6 gauss.sup.. oersted. The
coercivity H.sub.c has preferably a value which is higher than
2,000 oersted and the retentivity B.sub.r has a value of 2,000 to
4,000 gauss.
Following is a description of a composition which is suitable for a
primer according to the invention although it is not to be
construed that other compositions are not equally suitable. The
primer is hardened by baking and the desired pattern is afterwards
applied to it by magnetization:
20 parts of ricinine alkyd
10 parts of urea or melamine resin
10 parts of titanium dioxide
10 parts of talc
15 parts of benzol hydrocarbon and
35 parts of OX 300, that is a powdery anisotropic ferrite of the
type of MO.sup.. 6Fe.sub.2 O.sub.3, wherein M can be one or more of
the elements Ba, Sr, Co or Pb.
The method according to the invention has particularly proved to be
suitable for objects made of ferromagnetic material, particularly
steel plate, and provided with a permanent magnetic primer of the
type above described.
Other advantages, features and applications of the present
invention will be apparent from the following detailed description
with relation to the accompanied drawings, in which:
FIG. 1 shows a magnetic plate which has been provided with a
striped pattern,
FIG. 2 shows a rose-like pattern provided on an iron surface,
and
FIG. 3 shows a top view of another form of magnetic pattern
plate.
To create the magnetic field a permanent magnetic plate can be used
which is provided with a pattern defined by striped areas of
alternating polarity. This pattern is produced by magnetization of
the plate according to a known procedure which is similar to the
one used in the manufacture of permanent magnets. Instead of the
permanent magnetic plate an electromagnet can also be used in which
insulated electric conductors are imbedded in parallel grooves
provided in the surface of an iron plate 1. When a strong electric
current is sent through the conductors the pattern shown in FIG. 1
appears on the object or surface 2 provided with the primer
containing the magnetic particles. The permanent magnetic particles
can also be magnetized by the lines of flux in such a way that they
invisibly carry the pattern 2 of FIG. 1 on the primed surface and
with the result that lines of flux run from the permanent magnetic
particles along lines N to the particles along the parallel lines
S. This pattern can be immediately made visible by applying the
finish coating containing particles which are sensitive to the
magnetic fields of the magnetic particles in the primer defining
said invisible pattern on plate 2.
FIG. 2 shows a six-poled, frontal magnetization effect produced by
a ring magnet made of barium ferrite. The shape and the range of
the magnetic field can be very accurately determined therein.
FIG. 3 shows a magnetic plate to produce a particular pattern
containing an arrangement of circles and rectangles. Such a pattern
can also be obtained by combining electromagnets. For example,
elongated strips 4 cut out of a flexible permanent magnet, or
electromagnets corresponding in shape thereto and other forms of
magnetic metal parts 5 can be located at various distances from
said strips 4, or correspondingly shaped electromagnets are fixedly
arranged in a mounting support 3.
The surfaces provided with such new and aesthetically arranged
patterns of magnetic particles can be applied to household objects,
to the panelling of safes and building walls generally, and can
also be used in furniture and in the glass and ceramic industry,
particularly for the manufacture of tiles.
The final coating, or coatings, of liquid material containing
magnetically orientable particles can thus be applied after the
treated surfaces, or panels, have been put in place.
* * * * *